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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,711 records · Page 95
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Extrapolating carbon dynamics of seasonally dry tropical forests across geographic scales and into future climates: improving simulation models with empirical observations. Final report

This research focused on seasonally dry tropical forests (SDTFs), a biome that exhibits strong variation in ecological, hydrological and physical characteristics. Climate change is expected to strongly impact the atmospheric environment of SDTFs, and long-term trends in precipitation seasonality have already been detected. The extent to which such changes in seasonal moisture availability will impact SDTF carbon dynamics is highly uncertain, and much of this uncertainty hinges on poorly-understood belowground processes. Thus, the central objectives of this research were to qualitatively and quantitatively describe how belowground processes mediate the response of SDTF carbon dynamics to environmental change. We accomplished these aims through field campaigns in four tropical countries to characterize soil biogeochemistry and plant hydraulic traits, ecosystem-scale field experiments that manipulated both nutrients and rainfall, and simulation modeling.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1993

Global climate change and terrestrial net primary production

A process-based model was used to estimate global patterns of net primary production and soil nitrogen cycling for contemporary climate conditions and current atmospheric CO2 concentration. Over half of the global annual net primary production was estimated to occur in the tropics, with most of the production attributable to tropical evergreen forest. The effects of CO2 doubling and associated climate changes were also explored. The responses in tropical and dry temperate ecosystems were dominated by CO2, but those in northern and moist temperate ecosystems reflected the effects of temperature on nitrogen availability.

Melillo, Jerry M.↗
NASA NTRS2007

Hydrogen Peroxide Concentrator

A relatively simple and economical process and apparatus for concentrating hydrogen peroxide from aqueous solution at the point of use have been invented. The heart of the apparatus is a vessel comprising an outer shell containing tubular membranes made of a polymer that is significantly more permeable by water than by hydrogen peroxide. The aqueous solution of hydrogen peroxide to be concentrated is fed through the interstitial spaces between the tubular membranes. An initially dry sweep gas is pumped through the interiors of the tubular membranes. Water diffuses through the membranes and is carried away as water vapor mixed into the sweep gas. Because of the removal of water, the hydrogen peroxide solution flowing from the vessel at the outlet end is more concentrated than that fed into the vessel at the inlet end. The sweep gas can be air, nitrogen, or any other gas that can be conveniently supplied in dry form and does not react chemically with hydrogen peroxide.

Parrish, Clyde F.↗
NASA NTRS2016

40 Years of Processing Pieces of Space

This year marks the 40th year anniversary for the Antarctic Search for Meteorite (ANSMET) program. In 1976, the ANSMET program led the first expedition to Antarctica. The ANSMET program is a US-led field-based science project that recovers meteorite samples from Antarctica. Once a year from late November to late January, a field team consisting of 8 to 12 people, spends 6-8 weeks camping on the ice and collecting meteorites. Since 1976, more than 22,000 meteorite samples have been recovered. These meteorites come from asteroids, planets and other bodies of the solar system. Once collected, the Antarctic meteorites are shipped to NASA/Johnson Space Center (JSC) Houston, TX. in a refrigerated truck and are kept frozen to minimize oxidation until they are ready for initial processing. In Antarctica each meteorite is given a field tag which consists of numbers, once in the lab, this is replaced by an official tag, consisting of the Antarctic field location and year collected. The types and numbers of meteorites that have been classified include 849 carbonaceous chondrites, 135 enstatites, 512 achondrites, 64 stony, 115 irons, 48 others (27 R chondrites, 7 ungrouped), 6,161 H chondrites, 7,668 L chondrites, and 4,589 LL chondrites. Although 80-85 percent of the collected meteorites fall in the ordinary chondrite group, the other approximately 15 percent represent rare types of achondrites and carbonaceous chondrites. These rare meteorites include 25 lunar meteorites, 15 Martian meteorites, scores of various types of carbonaceous chondrites, and unique achondrites. The Antarctic meteorites that have been collected are processed in the Meteorite Processing Lab at JSC in Houston, TX. Initial processing of the meteorites begins with thawing/drying the meteorites in a nitrogen glove box for 24 to 48 hours. The meteorites are then photographed, measured, weighed and a description of the interior and exterior of each meteorite is written. The meteorite is broken and a representative sample, either a 1-3 gram chip or thin section is sent to the Smithsonian Institution for classification. After Antarctic meteorites have been classified and approved by the Nomenclature Committee of the Meteoritical Society, they are announced in the Antarctic Meteorite Newsletter, which is published twice per year (fall and spring) so that scientists may review which meteorites are available to study. Requests for Antarctic Meteorite samples are welcomed from research scientists, regardless of their current state of funding for meteorite studies. Since its inception over 3,300 requests have been made for pieces of these meteorites and over 400 investigators worldwide are active in the study of meteorites.. Research on these samples has been published in more than1500 peer reviewed articles; a listing of papers for any meteorite sample can be generated by accessing http://curator.jsc.nasa.gov/antmet/referencesearch.cfm. Antarctic meteorite samples requested by scientists are prepared several different ways. Most samples are prepared as chips, either using a rock splitter or using a chisel and chipping bowl. In special situations, a researcher may request a meteorite slab in which case the samples are cut using a diamond-bladed bandsaw inside of a dry nitrogen glove box. The meteorites are always cut in a 100 percent liquid-free environment. Additionally, thin/thick sections of Antarctic meteorites are also prepared at JSC. The meteorite thin section lab at JSC can prepare standard 30-micron thin sections, thick sections of variable thickness (100 to 200 microns), or demountable sections using superglue, all section are prepared without using water. Although many of the techniques used back in the '70's are still used today, advances in computers, software, databases, available tools and instrumentation have helped to streamline and shorten the duration of the classification process. In conjunction with present day missions to asteroids and other planets, meteorite studies have not only led to a better understanding of the complex histories of these bodies but have also tied certain meteorite groups to particular asteroid bodies. New meteorite discoveries by the ANSMET program provide a cost effective method for obtaining samples of previously unsampled bodies, allowing scientists to learn more about the origin, composition, and evolution of the solar system. Preservation in our cleanrooms at NASA allows material to be archived for future generations and advances in instrumentation and analysis.

Satterwhite, C. E.↗
DOE OSTI2025

Restoring Historic Forest Disturbance Frequency Would Partially Mitigate Droughts in the Central Sierra Nevada Mountains

Forest thinning and prescribed fire are expected to improve the climate resilience and water security of forests in the western U.S., but few studies have directly modeled the hydrological effects of multi-decadal landscape-scale forest disturbance. By updating a distributed process-based hydrological model (DHSVM) with vegetation maps from a distributed forest ecosystem model (LANDIS-II), we simulate the water resource impacts of forest management scenarios targeting partial or full restoration of the pre-colonial disturbance return interval in the central Sierra Nevada mountains. In a fully restored disturbance regime that includes fire, thinning, and insect mortality, reservoir inflow increases by 4%–9% total and 8%–14% in dry years. At sub-watershed scales (10–100 km2), thinning dense forests can increase streamflow by >20% in dry years. In a thinner forest, increased understory transpiration compensates for decreased overstory transpiration. Consequentially, 73% of streamflow gains are attributable to decreased overstory rain and snow interception loss. Thinner forests can increase headwater peak flows, but reservoir-scale peak flows are almost exclusively influenced by climate. Uncertainty in future precipitation causes high uncertainty in future water yield, but the additional water yield attributable to forest disturbance is about five times less sensitive to annual precipitation uncertainty. This partial decoupling of the streamflow disturbance response from annual precipitation makes disturbance especially valuable for water supply during dry years. Our study can increase confidence in the water resource benefits of restoring historic forest disturbance frequencies in the central Sierra Nevada mountains, and our modeling framework is widely applicable to other forested mountain landscapes.

Boardman, Eli N. [University of Nevada, Reno, NV (↗
DOE OSTI2024

Photoinitiated thermoset polymerization through controlled release of metathesis catalysts encapsulated in poly(phthalaldehyde)

Photoinitiated polymerization enables spatiotemporal control of reaction conditions and can thereby generate materials with high complexity while consuming minimal energy. Where ring opening metathesis polymerization (ROMP) is concerned, photo-activated processes are typically enabled by chemical inhibition of ruthenium carbenes via the careful design of complexed ligands such that photoactivation can proceed through an isomerization or ligand dissociation event. In this contribution, we have explored a new approach to photoinitiation of ROMP based on physical inhibition through microencapsulation and controlled release of metathesis catalysts. Micron-sized particles of poly(phthalaldehyde) (PPA), catalyst, and photoacid generator were fabricated by spray drying. The particles were dispersed in dicyclopentadiene monomer, after which polymerization was initiated through temperature or UV exposure, both inducing depolymerization of the PPA particles and in situ catalyst release. The monomer/particle dispersions were found to be stable and reproducibly polymerizable with 3 weeks of storage at room temperature. Furthermore, the dispersions can be used for both photo- and thermal-initiated frontal ROMP, yielding a polymerized thermoset of equivalent properties to conventional bulk- and frontally-polymerized analogues. In conclusion, this work will ultimately enable new manufacturing techniques for ROMP-based materials, due to the modular, easily tunable nature of the underlying initiating system and its unparalleled stability.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Evaluation of Expansion in ETF Grout Compositional Variants

In summary, the Base Case grout, Mix K, prepared according to the protocol provided (short stirring time after struvite precipitation of about 30 minutes) expanded when cured in a dry and damp sealed bag. Two variants, Mix M, 100 % slag in the dry mix, did not expand when prepared and cured under the same dry and damp conditions. Mix L, precipitated struvite removed, showed very slight expansion after curing 289 days for both dry and damp curing which was expressed as slight bulging at the bottom of the container. Mix N, 100 % dilution of the simulant, did not expand when cured under dry conditions or in a sealed container in damp conditions. However, a cylinder of Mix N cured in a container that was slit and taped back together did expand in damp conditions. This condition enabled the grout to be exposed to more moisture that the grout sample cured in the capped container and stored in the same zip top bag with the damp towel. This information is provided to support processing and containerization of the ETF ammonia grout.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
NASA NTRS1979

Basaltic volcanism - The importance of planet size

The volumetrically abundant basalts on the earth, its moon, and the eucrite parent planet all have chemical compositions that are controlled to a large extent by dry, low-pressure, crystal-liquid equilibria. Since this generalization is valid for these three planetary bodies, we infer that it may also apply to the other unsampled terrestrial planets. Other characteristics of basaltic volcanism show variations which appear to be related to planet size: the eruption temperatures, degrees of fractionation, and chemical variety of basalts and the endurance of basaltic volcanism all increase with planet size. Although the processes responsible for chemical differences between basalt suites are known, no simple systematization of the chemical differences between basalts from planet to planet has emerged.

Walker, D.↗
NASA NTRS1988

Effect of wet tropospheric path delays on estimation of geodetic baselines in the Gulf of California using the Global Positioning System

Surface Meteorological (SM) and Water Vapor Radiometer (WVR) measurements are used to provide an independent means of calibrating the GPS signal for the wet tropospheric path delay in a study of geodetic baseline measurements in the Gulf of California using GPS in which high tropospheric water vapor content yielded wet path delays in excess of 20 cm at zenith. Residual wet delays at zenith are estimated as constants and as first-order exponentially correlated stochastic processes. Calibration with WVR data is found to yield the best repeatabilities, with improved results possible if combined carrier phase and pseudorange data are used. Although SM measurements can introduce significant errors in baseline solutions if used with a simple atmospheric model and estimation of residual zenith delays as constants, SM calibration and stochastic estimation for residual zenith wet delays may be adequate for precise estimation of GPS baselines. For dry locations, WVRs may not be required to accurately model tropospheric effects on GPS baselines.

Tralli, David M.↗
NASA NTRS1996

Where on Mars Should We Search for Life?

There is persuasive evidence that liquid water has been a significant geological processes on Mars. In particular, evidence suggests that one of the major epochs of liquid water on Mars was during and after the late heavy bombardment. During this time life originated on Earth and may have originated on Mars as well. Liquid water per se, independent of models for the temperature or atmospheric pressure, motivate the question of life. Promising sites for searching for evidence of life on Mars include dry lake beds, the ancient cratered terrain, and the South Polar permafrost. Life on Earth in environments that are analogous to those that might have provided the final refuge for life on Mars provide clues to where and how to search for evidence of past life.

McKay, Christopher P.↗
NASA NTRS2003

Software Computes Tape-Casting Parameters

Tcast2 is a FORTRAN computer program that accelerates the setup of a process in which a slurry containing metal particles and a polymeric binder is cast, to a thickness regulated by a doctor blade, onto fibers wound on a rotating drum to make a green precursor of a metal-matrix/fiber composite tape. Before Tcast2, setup parameters were determined by trial and error in time-consuming multiple iterations of the process. In Tcast2, the fiber architecture in the final composite is expressed in terms of the lateral distance between fibers and the thickness-wise distance between fibers in adjacent plies. The lateral distance is controlled via the manner of winding. The interply spacing is controlled via the characteristics of the slurry and the doctor-blade height. When a new combination of fibers and slurry is first cast and dried to a green tape, the shrinkage from the wet to the green condition and a few other key parameters of the green tape are measured. These parameters are provided as input to Tcast2, which uses them to compute the doctor-blade height and fiber spacings needed to obtain the desired fiber architecture and fiber volume fraction in the final composite.

deGroh, Henry C., III↗
NASA NTRS2018

Process for Preparing Aerogels from Polyamides

Polyamide aerogels and methods of making the same are discussed. One example method can include the act of creating a mixture of at least one diamine with at least one diacid chloride in a first solvent. The mixture can comprise a plurality of amine capped polyamide oligomers. Such a method can also include the acts of adding a cross-linking agent to the mixture to create a gel and performing one or more solvent exchanges to remove the first solvent. Additionally, such a method can include the act of subjecting the gel to supercritical drying to polyamide aerogel.

Meador, Mary Ann B.↗
DOE OSTI2021

Assessing the Relative Climate Impact of Carbon Utilization for Concrete, Chemical, and Mineral Production

Estimates show that 6.2 gigatons of carbon dioxide (CO2) can be captured and utilized across three pathways, concrete, chemical, and minerals, by 2050. However, it is difficult to compare the climate benefit across these three carbon capture and utilization (CCU) pathways to determine the most effective use of captured CO2. The life cycle assessment methods to evaluate the climate benefit of CCU chemicals should additionally account for the change in material properties of concrete due to CO2 utilization. Furthermore, with most CO2 utilization technologies being in the early stages of research and development, the uncertainty and variability in process and inventory data present a significant challenge in evaluating the climate benefit. We present a stochastically determined climate return on investment (ROI) metric to rank and prioritize CO2 utilization across 20 concrete, chemical and mineral pathways based on the realized climate benefit. We show that two concrete pathways, which use CO2 during concrete mixing, and two chemical pathways, which produce formic acid through hydrogenation of CO2 and carbon monoxide through dry reforming of methane, generate the greatest climate ROI and are the only CCU pathways with a higher likelihood of generating a climate benefit than a climate burden.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2021

A Parameterization of Turbulent Dissipation and Pressure Damping Time Scales in Stably Stratified Inversions, and its Effects on Low Clouds in Global Simulations

Abstract It is difficult for coarse‐resolution global models of the atmosphere to accurately simulate the observed distribution of low clouds. In particular, it is difficult for moist turbulence closure models to simulate sufficiently bright near‐coastal stratocumulus (Sc) without simulating overly bright marine shallow cumuli (Cu). To parameterize bright Sc, a turbulence parameterization must damp the turbulent fluxes of heat and moisture above cloud top in order to prevent excessive entrainment of dry air into cloud top. To parameterize dim shallow Cu, the subgrid variances of temperature and moisture must remain large, in order to permit partial cloudiness. However, damping the fluxes but not the variances just above cloud top is difficult if a parameterization uses a single “master” time scale to damp both. In nature, the above‐cloud fluxes are damped by pressure fluctuations, whereas scalar variances are damped by a different process, namely, turbulent dissipation. In a stably stratified inversion above cloud, pressure damping is large but turbulent dissipation is small. To avoid this problem, a multitime scale parameterization for damping has been developed. The damping parameterization has been implemented in a global model and evaluated. The parameterization is capable of dimming shallow Cu while producing adequately bright Sc.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

ORNL FACE Final Harvest, 2009, with data on leaf characteristics and tree mass

During the final year of the Oak Ridge National Laboratory (ORNL) free-air CO2 enrichment (FACE) experiment, 16 trees were felled and processed during July 2009. The trees had been grown for 12 years in ambient or elevated CO2. Two data sets are reported. Leaf characteristics (leaf mass per unit area, leaf thickness, average leaf size, carbon and nitrogen concentrations) are reported for each 1-meter section of the tree crowns in data set "Canopy_subsamples.csv". The measurements were made on approximately 20 subsamples collected from each 1-meter section of the canopy. Wood dry mass, total tree height, basal area, total leaf mass and leaf area are reported in "Tree_harvest.csv", based on field measurements of fresh mass and dry mass to fresh mass ratio of subsamples. The ORNL FACE experiment, including photos of the harvesting activity, is described at: https://richnorby.org/home/face-home/.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

Model data for a watershed-scale study in the Portage River Basin (OH) examining the effects of subsurface drainage on the hydrologic response of an agricultural watershed.

This study builds on Rathore et al. (2024, WRR) and investigates the role of artificial tile-drainage on various aspects of watershed hydrological response, with a particular focus on peakflow. The model-data for the original modeling-focused paper (Rathore et al., 2024, WRR) is archived at Rathore et al. (2024, ESS-DIVE). Hence, this model-data archive provides scripts that are specific to this study that includes model updates, processing and analysis scripts. For details and models files of original model, readers are referred to Rathore et al. (2024, ESS-DIVE). The key difference between the model configuration in this study and Rathore et al. (2024, WRR) is that the tile drains are applied to the entire domain, to study the impact of tile-drains on different aspects of hydrological response. Additional scenario considering intensified precipitation after a dry period was also simulated. The Watershed Workflow package is implemented in Python3. The Jupyter notebooks can be executed through multiple open-source tools, for example, Anaconda Jupyter Lab, VS Studio Code, etc. Other data files include CSV and HDF5 files, which can be read through Python scripts.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

PINCH POINT ANALYSIS OF GAS COOLERS IN TRANSCRITICAL R1336mzz(Z) HIGH-TEMPERATURE HEAT PUMPS

The majority of high-temperature heat pumps (HTHPs) operate subcritical vapor compression cycles, where the maximum sink temperature is limited by the critical temperature of refrigerants. In HTHPs with a sink temperature of ≥ 150°C, transcritical cycles overcome this limitation by rejecting heat in the supercritical regions of refrigerant. Supercritical refrigerants in gas coolers have a large temperature glide and substantial nonlinear variation in specific heat capacity vs. temperature. Closely matching the refrigerant glide temperature and the heat sink temperature profile greatly impacts the heat transfer characteristic of gas coolers and the overall performance of HTHPs. This study conducts a pinch point analysis for the gas cooling process of supercritical R1336mzz(Z) in HTHPs. A finite volume element model of a supercritical R1336mzz(Z) counterflow gas cooler is built and solved. This study evaluates the influences of operating conditions, including inlet and outlet of coolants, refrigerant evaporation temperature and superheat degree, pinch temperature difference, and heat rejection pressure, on the performance of HTHPs. The optimal discharge pressures in gas coolers are proposed for industrial spray dryers in providing drying air at 170°C−210°C. The results of the present study help design gas coolers in transcritical R1336mzz(Z) HTHPs.

Wang, Pengtao↗