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At least 1,711 records · Page 95

Performance Assessment of a Dual-purpose HP-TES for a Typical Year Comparing Different Climate Zones

Complete electrification of heating and cooling systems in the United States would overload the existing electrical grid. To this end, recent research efforts have focused on energy storage as one way to reduce ever-increasing peak electricity demands. One such technology is heat pump integrated thermal-energy storage (HP-TES) systems, which can enable load-shifting and reduce demand during peak hours. In this work, a Modelica model of a 4-Ton, dual-mode (heating and cooling) HP-TES system using a room-temperature phase-change material (PCM) integrated through a secondary hydronic loop was developed and simulated for a typical meteorological year in Riverside, CA (ASHRAE Climate Zone 2B), and Chicago, IL (ASHRAE Climate Zone 5A), for a DOE small office prototype building. The COP improvement and demand reduction were analyzed during the time-of-use peak hours along with the required recharge cycle energy demand. A typical summer in Riverside, CA resulted in model-predicted peak COP increases of 50 – 100% compared to the baseline heat pump, especially at higher outdoor temperatures, coupled with maximum peak energy reductions of 22%. During shoulder and winter season simulations, heating energy savings were higher as outdoor temperatures dropped below the PCM phase change temperature. For Chicago, IL, backup heating was necessary to meet the required system capacity for very cold ambient conditions, resulting in winter peak energy savings between 16 – 60% when accounting for backup heating requirements. The recharge energy was found to be mostly below the baseline HP energy during the peak. With improved component selections and controls, the recharge energy may be reduced. The outcomes from the simulations can provide first-order estimates for potential peak energy savings, challenges, and required controls in any location before conducting any field testing.

25 ENERGY STORAGE↗

Crossing The Gap Using Variational Quantum Eigensolver: A Comparative Study

Within the evolving domain of quantum computational chemistry, the Variational Quantum Eigensolver (VQE) has been developed to explore not only the ground state but also the excited states of molecules. In this study, we compare the performance of Variational Quantum Deflation (VQD) and Subspace-Search Variational Quantum Eigensolver (SSVQE) methods in determining the low-lying excited states of $LiH$. Our investigation reveals that while VQD exhibits a slight advantage in accuracy, SSVQE stands out for its efficiency, allowing the determination of all low-lying excited states through a single parameter optimization procedure. We further evaluate the effectiveness of optimizers, including Gradient Descent (GD), Quantum Natural Gradient (QNG), and Adam optimizer, in obtaining $LiH$'s first excited state, with the Adam optimizer demonstrating superior efficiency in requiring the fewest iterations. Moreover, we propose a novel approach combining Folded Spectrum VQE (FS-VQE) with either VQD or SSVQE, enabling the exploration of highly excited states. We test the new approaches for finding all three $H_4$'s excited states. Folded Spectrum SSVQE (FS-SSVQE) can find all three highly excited states near $-1.0$ Ha with only one optimizing procedure, but the procedure converges slowly. In contrast, although Folded spectrum VQD (FS-VQD) gets highly excited states with individual optimizing procedures, the optimizing procedure converges faster.

Chen, I-Chi↗

Comparative Effects of Radiation Sterilization Modality on Medical PVC Tubing

As the production volume of single-use, polymer-based medical devices increases each year, so does the need for throughput capacity to sterilize the devices. Around 80% of radiation-sterilized devices are processed using gamma-ray radiation from industrial cobalt-60 sources. Supply chain, security, and disposal concerns are prompting manufacturers and contract sterilizers to explore alternatives to irradiation using cobalt-60 gamma-rays, such as electron beam (E-beam) and X-ray radiation. Advantages of these ‘machine’ sources over radioisotope-based sources are that they do not decay, a characteristic that requires cobalt-60 to be replaced over time, they can be turned off when not in use, and they do not represent the same level of concern regarding misuse. One of the barriers to direct transition from gamma-ray sterilization to E-beam or X-ray sterilization is concern over the relatively unknown effects of sterilization dose of these alternative modalities on the performance of medical device polymers. Commercially available medical devices sterilized with gamma-ray irradiation exhibit acceptable device function, acceptable mechanical performance, and acceptable discoloration. To be viable, alternate sterilization methods must not only achieve acceptable sterilization, but the process must also result in a product with functional, mechanical, and visual effects acceptable to customers and the regulator. Flexible polyvinyl chloride (PVC) is a plastic material that is commonly found in single-use medical devices and is known for its sensitivity to radiation processing. For instance, transparent PVC is known to yellow upon irradiation. To encouraging sterilization alternatives to cobalt-60 gamma-ray, we directly compared the effects of gamma-ray, E-beam, and X-ray radiation exposure at similar sterilization-relevant doses on key properties of medical grade PVC tubing.

cobalt-60↗

Comparative Analysis of HEATNETS for Geothermal Network Performance: Preprint

Thermal energy networks (TENs), also known as 5th generation district energy systems, or more specifically geothermal networks when exchanging heat with geothermal boreholes, are an important technology for decarbonization. In these networks an ambient loop connects buildings and thermal sources, such as a borehole field, to exchange energy and maintain a desired loop temperature. Water-source heat pumps are used at the buildings to connect to the ambient or thermal loop to meet to the building heating and cooling loads and maintain comfort. A semi-transient, reduced-order technical model and techno-economic model, called HEATNETS, has been developed at NREL that captures the flow of energy around a TEN. In this work, a comparison of the HEATNETS technical model and a well-known coding platform used for modeling geothermal networks, TRNSYS, has been completed for a proposed geothermal network as a verification process. Hourly data provided from the TRNSYS simulation included building loads, pumping power, heat pump power, temperature entering and leaving the borehole field, and mass flow rates. The hourly borehole temperatures were used to create a linear regression model utilized in HEATNETS to estimate the borehole field heat exchange. The building loads and mass flow rates were direct inputs to HEATNETS while the pumping power, heat pump power, borehole temperatures, and coefficients of performance were all simulated and calculated by HEATNETS, allowing for direct comparison of the thermal energy transfer, rather than also comparing control systems responses. HEATNETS considers the full process from design inputs to economic outputs and can provide modeling options for high-level initial system design and operational optimization. This study shows that HEATNETS, while not intended to replace other modeling tools, can be a unique modeling tool for the performance of a full geothermal network system.

15 GEOTHERMAL ENERGY↗

Comparing CRT and Pandora Tagged Tracks in ICARUS

The ICARUS Liquid Argon Time Projection Chamber (LArTPC) is used to investigate short-baseline neutrino oscillations and the possible existence of sterile neutrinos. To aid in identifying and rejecting cosmic ray backgrounds, the system is outfitted with external Cosmic Ray Taggers (CRTs). The CRT is able to measure more tracks and at a wider range of angles, useful in further detailing future calibrations. This project compared the most probable values (MPVs) of charge deposition between CRT tagged and TPC tagged tracks. The Y-Z maps of charge scale for both datasets show a strong correlation, not just in their overall structure, but also in how they reflect known detector effects. Both reconstruction paths showed similar structures in their charge distribution, such as less effective wire section or mechanical support, confirming that CRT-tagged tracks, despite being external, respond to the same calibration landscape as Pandora tracks, validating previous Pandora reconstructions and values. Overall, the analysis supports the idea that the CRT tags are a useful addition to ICARUS calibration efforts. Their broad angular range and independence from Pandora reconstruction make them a helpful secondary tool and a potential asset in extending calibration across the detector volume.

Thayer, Abbie [Fermilab; Colorado State U.]↗

Comparing Control Performance Between Simulation and Experiment using the Microreactor Automated Control System Testbed

In the advanced reactor domain, a flexible and scalable software/hardware infrastructure is crucial for integrating and validating various control technologies. This study used the Microreactor Automated Control System (MACS) hardware platform as a testbed. MACS was originally designed to mirror Idaho National Laboratory (INL)'s Microreactor Applications Research Validation and Evaluation (MARVEL), a 85-kW thermal fission microreactor. It features control drums for simulated reactivity control; lights that function as a surrogate reactor core, with the brightness being proportional to the reactor power; and light sensors that emulate neutron detectors. To transform MACS into a physical twin of MARVEL for evaluating control methods, the Control and Optimization Modular Modeling Application for Nuclear Deployment (COMMAND) software was employed. This software integrated the hardware with two models of the MARVEL core, based on Reactor Excursion and Leak Analysis Program (RELAP5-3D) and Monte Carlo N-Particle (MCNP) models. The study aimed to demonstrate the gap between control theory and actual practice—a gap that often necessitates empirical adjustments such as control gain retuning, filters, time discretization, and integrator anti-windup measures. Controllers were developed based on increasingly complex simulations without hardware, starting from the base MARVEL model and then introducing actuator saturation constraints and sensor noise. The final control strategy was then tested using MACS, and a comparative performance analysis was conducted.

46 - INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AN↗

Comparative investigation of iterative solutions of the all-frequency stable formulation and its vector-potential-only variation

An all-frequency stable formulation has been proposed and applied to solve low-frequency and multiscale electromagnetic problems to avoid the low-frequency breakdown catastrophe of the traditional vector wave equation. Based on the potential representation of the fields, this formulation involves vector and scalar potentials, as well as an auxiliary potential to enforce the gauge condition. In this paper, such a formulation is first simplified to involve vector potential only. Their iterative solutions are then sought by using an incomplete LU preconditioner and an iterative solver. The iterative performance of both formulations are investigated in a comparative study.

Mekonnen, Minyechil↗

Design of a Cryogenic Assembly for Comparing Qubit Infrared Packaging Inefficiencies

It is well known that everything emits infrared (IR) light in the form of thermal radiation. IR radiation on superconducting qubits carries enough energy to cause decoherence and so-called “quasiparticle poisoning.” Therefore, proper IR shielding is needed to keep the qubit in a high-coherence state. However, trying to extract IR-specific information from a qubit is difficult, so a microwave kinetic inductance detector (MKID) can be used instead. We show that the IR shielding inefficiencies of MKID packages can only be compared with other packaging inefficiencies. We create a cryogenic assembly CAD design, consisting of magnetic shield cans, a copper mounting plate and mounts, and an MKID enclosure, which thermalizes the assembly to dilution refrigerator temperatures. Phase 1 of this design involves using a narrowband IR laser source to test the IR shielding of packaging at the laser’s wavelength. When the best IR shielding packaging is determined, the superconducting qubit can replace the MKID, allowing the qubit to avoid decoherence due to IR radiation and boost its performance and coherence lifetime.

Mailliard, Robert J. [Fermilab] (ORCID:00090000277↗

Comparative Genomics of Nitrogen Cycling Pathways in Bacteria and Archaea

Despite the explosion of metagenomic sequencing data, using -omics data to indicate environmental biogeochemistry remains a challenge. One or a few genes (referred to as marker genes) in a metabolic pathway of interest in meta-omic data are normally used to represent the prevalence of a biogeochemical reaction. This method often fails to demonstrate a consistent relationship between gene abundance and an ecosystem process rate. One reason this may occur is if a marker gene is not a good representative of a complete pathway. Here, we map the presence of 11 nitrogen (N)-cycling pathways in over 6000 complete bacterial and archaeal genomes using the Integrated Microbial Genomes database. Incomplete N-cycling pathways occurred in 39% of surveyed archaeal and bacterial species revealing a weakness in current marker-gene analyses. Moreover, we found that most organisms have limited ability to utilize inorganic N in multiple oxidation states. This suggests that inter-organism exchange of inorganic N compounds is common, highlighting the importance of both community composition and spatial structure in determining the extent of recycling versus loss in an ecosystem.

59 BASIC BIOLOGICAL SCIENCES↗

Comparative Characterization of Magnetic Properties of Textured Ni–5 at.%W Alloy Substrates

The hysteresis loss of Ni–5 at.%W (Ni5W) substrate contributes considerably to the alternating current (AC) loss of coated conductors (CCs) working at low transporting current or low-frequency field. In the present work, the evolution of texture and magnetic properties in Ni5W substrates is analyzed and also the relationship between magnetic properties and the extrinsic characteristics (evolved due to the processing techniques) is determined. By making the comparison, we discovered the magnetic domain structures of Ni5W substrates for the first time, achieving a strip/branched domain structures in the recrystallized substrates. The hysteresis loss has been decreased dramatically for the recrystallized substrates. Interestingly, we also observed that this loss is also related to the annealing temperature in the fully recrystallized substrates. The reduced loss can be mainly attributed toward the decrease of grain boundary, which proves the contribution of grain size toward the reduction of hysteresis loss. This result provides a new insight to tailor the hysteresis loss of Ni5W substrates used for coated conductors.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Non-stationary Geostatistical Modeling: A Case Study Comparing LVA Estimation Frameworks

Incorporating locally varying anisotropy (LVA) in geostatistical modeling improves estimates for structurally complex domains where a single set of anisotropic parameters modeled globally do not account for all geological features. In this work, the properties of two LVA-geostatistical modeling frameworks are explored through application to a complexly folded gold deposit in Ghana. The inference of necessary parameters is a significant requirement of geostatistical modeling with LVA; this work focuses on the case where LVA orientations, derived from expert geological interpretation, are used to improve the grade estimates. The different methodologies for inferring the required parameters in this context are explored. The results of considering different estimation frameworks and alternate methods of parameterization are evaluated with a cross-validation study, as well as visual inspection of grade continuity along select cross sections. Results show that stationary methodologies are outperformed by all LVA techniques, even when the LVA framework has minimal guidance on parameterization. Findings also show that additional improvements are gained by considering parameter inference where the LVA orientations and point data are used to infer the local range of anisotropy. Considering LVA for geostatistical modeling of the deposit considered in this work results in better reproduction of curvilinear geological features.

58 GEOSCIENCES↗

Experimental Investigations to Enhance the Tribological Performance of Engine Oil by Using Nano-Boric Acid and Functionalized Multiwalled Carbon Nanotubes: A Comparative Study to Assess Wear in Bronze Alloy

In various mechanical systems, lubricants are generally used to reduce friction and wear; thus, the total energy loss in the mechanical systems can be minimized by the proper enhancement of lubrication properties. In general, friction modifiers and antiwear additives are used to improve the tribological properties of the lubricant. However, the use of these additives has to be phased out due to their fast chemical degradation in their applications and other environmental issues. In recent years, the use of nanoparticles as a potential lubricant additive has received considerable attention because of its excellent mechanical and tribological characteristics. The present work describes the tribological behavior of nano-boric acid, multiwalled carbon nanotubes (MWCNTs), and functionalized multiwalled carbon nanotubes (FMWCNTs) modified with carboxylic acid. These nanoparticles were used to enhance the tribological properties of engine oil (SAE20W40) used to lubricate bronze alloy samples. The performance of these nano-coolants was assessed on a linear reciprocating ball-on-flat tribometer. Results highlight the friction and wear behavior of the nano-boric acid, MWCNTs, and FMWCNTs under three varying parameters such as the effect of nanoparticles concentration, load-carrying capacity, and sliding speed. The addition of nano-boric acid, MWCNTs, and FMWCNTs has significantly improved the tribological properties of the base lubricant. The addition of 0.5 wt.% of nano-boric acid, MWCNTs, and FMWCNTs to the base lubricant has decreased the coefficient of friction by 19.76, 30.55, and 35.65%, respectively, and a significant reduction in wear volume by 55.17, 71.42, and 88.97% was obtained in comparison with base lubricant.

36 MATERIALS SCIENCE↗

Comparative In Vitro Evaluation Between Zirconia and Veneer Ceramic Materials Using Different Techniques

Zirconia surface treatment using different techniques could be employed to overcome the delamination issue reported between veneering ceramic materials and the corresponding zirconia core. The study subjected yttria partially stabilized zirconia core material to grinding and sandblasting as a first surface treatment. An airbrush gun spraying technique was used to coat a uniform thin layer of veneering ceramic (IPS e.max Ceram and Noritake Cerabien ZR) on the core materials followed by performing laser scanning as a second surface treatment. The specimens were investigated for surface topography, interface analysis, elemental compositions, phase transformation, and fracture mode patterns using profilometer, SEM, EDS, XRD, and stereomicroscope. The impact of laser scanning on the shear bond strength before and after storage of specimens in artificial saliva was also studied. Transformable tetragonal phase to monoclinic was predominant in sandblasted specimens followed by laser scanning with observation of micro-cracks at interface. The grinding followed by laser scanning yielded satisfactory outcomes in terms of the presence of coating property. The phase transformation was not detected through the latter technique. The technique greatly enhanced the roughness property and bond strength values which might be considered as a reliable application to improve the longevity of fixed dental crowns in load bearing areas.

36 MATERIALS SCIENCE↗

Comparing Empty and Filled Fullerene Cages with High-Resolution Trapped Ion Mobility Spectrometry

We have used trapped ion mobility spectrometry (TIMS) to obtain highly accurate experimental collision cross sections (CCS) for the fullerene C{sub 80}{sup −} and the endohedral metallofullerenes La{sub 2}@C{sub 80}{sup −}, Sc{sub 3}N@C{sub 80}{sup −}, and Er{sub 3}N@C{sub 80}{sup −} in molecular nitrogen. The CCS values of the endohedral fullerenes are 0.2% larger than that of the empty cage. Using a combination of density functional theory and trajectory calculations, we were able to reproduce these experimental findings theoretically. Two effects are discussed that contribute to the CCS differences: (i) a small increase in fullerene cage size upon endohedral doping and (ii) charge transfer from the encapsulated moieties to the cage thus increasing the attractive charge-induced dipole interaction between the (endohedral) fullerene ion and the nitrogen bath gas molecules. .

77 NANOSCIENCE AND NANOTECHNOLOGY↗

A comparative analysis on how different governance contexts may influence Strategic Environmental Assessment

Highlights: • Cultural and institutional values impact how SEA is interpreted and carried out. • Governance contexts influence how SEA systems operate. • SEA systems are facing constraints of a more normative and cognitive nature. • SEA capacity is ‘context-influenced’ and dependent of SEA institutionalisation. - Abstract: This paper explores the relationship between governance contexts and the development and outcomes of Strategic Environmental Assessment (SEA). The main objective of this paper is to understand if, and how, the governance context may influence the system and institutionalisation of SEA, and the capacity of SEA to reach its objectives. The research methodology is based on the comparison of six country-cases that have an established SEA system, including three European countries, two Asian countries and one in Latin American, with distinct national culture and political-administrative setting. Results show that cultural and institutional values impact how SEA is interpreted and carried out, and that SEA systems are facing constraints of a more normative and cognitive nature. Connecting governance contexts and patterns in the SEA systems confirm that SEA is not ‘context free’, but instead ‘context-influenced’, while its capacity is dependent on its level of adaptation to the governance environment.

54 ENVIRONMENTAL SCIENCES↗

Comparative Analysis of Natural Gas Cogeneration Incentives on Electricity Production in Latin America

An analysis to assess the influence of country-dependent variables and incentives on the feasibility of natural gas cogeneration projects in Latin America is presented in this work. The analysis is performed using a hypothetical industrial plant, where the cogeneration solution consists in the recovery of waste heat from the power generation for steam production. The feasibility is evaluated by calculating the Return of Investment (ROI) and the Internal Rate of Return (IRR) of the project. Eight Latin American countries are studied considering their specific natural gas markets, regulation, and macroeconomic variables. Two scenarios, electricity production for self-consumption and electricity production with power surplus sale, are independently analyzed considering the effects of available incentives. In the countries where the project is feasible, the application of incentives leads to a significant reduction in the ROI and, consequently, to an increment in the IRR. The effect of the interest rate and environmental impact were also analyzed. In general terms, along the region, the regulation for cogeneration is incipient while incentives are very standard and similar respect to lowering of import, Value-Added Tax (VAT), and income taxes, which seems to be designed purely to promote capital investment. Following the results from this study, it is of paramount importance to create new policy instruments in the future to advance the regulatory framework for cogeneration in Latin America.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗