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At least 1,711 records · Page 95
All sourcesNASA NTRSDOE OSTI
NASA NTRS1974

Early chemical history of the solar system

By using equilibrium thermodynamics, the sequence of condensation of mineral phases from a cooling nebula of solar composition has been calculated. The theoretical models suggest that the chemistry and mineralogy of Ca-Al-rich inclusions in C2 and C3 chondrites were established during condensation at temperatures above 1300 K. Fractionation of such inclusions is necessary to account for the refractory element depletions of ordinary and enstatite chondrites relative to the carbonaceous chondrites. The metal-silicate fractionation in ordinary chondrites took place in the nebula at a temperature below 1000 K and at .00001 atm total pressure. The volatile element depletion of C2 and C3 chondrites relative to C1 chondrites took place during chondrule formation: the most volatile elements are depleted in ordinary chondrites because they accreted before these elements were totally condensed.

Grossman, L.↗
NASA NTRS1973

New infrared sources associated with H II regions

The H II regions studied have generally been those which contain OH or H2O maser sources and which have been shown to contain compact condensations of ionized gas which may be connected with star formation processes. A brief account of two such sources, W3 and NGC 7538, is given. On the basis of the reported observations it is concluded that in general H II condensations are infrared sources in the range from 3 to 20 microns. The condensations are hidden optically by large quantities of obscuring matter.

Wynn-Williams, C. G.↗
NASA NTRS1973

Analysis of SRM model nozzle calibration test data in support of IA12B, IA12C and IA36 space shuttle launch vehicle aerodynamics tests

Variations of nozzle performance characteristics of the model nozzles used in the Space Shuttle IA12B, IA12C, IA36 power-on launch vehicle test series are shown by comparison between experimental and analytical data. The experimental data are nozzle wall pressure distributions and schlieren photographs of the exhaust plume shapes. The exhaust plume shapes were simulated experimentally with cold flow while the analytical data were generated using a method-of-characteristics solution. Exhaust plume boundaries, boundary shockwave locations and nozzle wall pressure measurements calculated analytically agree favorably with the experimental data from the IA12C and IA36 test series. For the IA12B test series condensation was suspected in the exhaust plumes at the higher pressure ratios required to simulate the prototype plume shapes. Nozzle calibration tests for the series were conducted at pressure ratios where condensation either did not occur or if present did not produce a noticeable effect on the plume shapes. However, at the pressure ratios required in the power-on launch vehicle tests condensation probably occurs and could significantly affect the exhaust plume shapes.

Baker, L. R., Jr.↗
NASA NTRS1974

Space shuttle orbiter mechanical refrigeration system

A radiator/condenser was designed which is efficient in both condensation (refrigeration) and liquid phase (radiator) operating modes, including switchover from the refrigeration mode to the radiator mode and vice versa. A method for predicting the pressure drop of a condensing two-phase flow in zero-gravity was developed along with a method for predicting the flow regime which would prevail along the condensation path. The hybrid refrigeration system was assembled with the two radiator/condenser panels installed in a space environment simulator. The system was tested under both atmospheric and vacuum conditions. Results of the tests are presented.

Williams, J. L.↗
NASA NTRS1974

Mercury - Internal structure and thermal evolution

Mercury's thermal evolution and internal structure are modeled based on the planet's gross physical properties (which imply a high metallic iron content) and predictions for its chemistry made from the Lewis-Cameron model of condensation of the primitive solar nebula (which implies that Mercury may be composed only of those materials that condensed at temperatures near that of metallic iron condensation in the cooling nebula). Various heat sources, initial temperatures, and thermal conductivities are considered for a homogeneous model and a differentiated two-layer model. Density distributions are calculated from the mean density and estimates of the present-day temperature. The moment of inertia and the hydrostatic value of the second degree harmonic coefficient of Mercury's gravity field are found for the differentiated and undifferentiated models. These results should be useful for preliminary interpretation of the Mariner 10 measurements of Mercury's gravitational field.

Siegfried, R. W., II↗
NASA NTRS1975

Combustion problems of nitramine propellants

This study has, as its distinctive feature, a detailed examination of the condensed-phase processes in the combustion of nitramine propellants. As a consequence of a recently developed model for the combustion of ammonium perchlorate (AP)/composite propellants, it is hypothesized that the condensed-phase degradation of the nitramine oxidizer particles to a vaporizable state is the overall rate-limiting step. It is also assumed that the gas-phase details are secondary in importance and need be studied only to the extent of supplying the correct boundary conditions on the condensed-phase/vapor-phase heat transfer. Because of imprecise understanding of the gas-phase processes in the presence of combustion, several plausible models are considered for the gas phase. It is found that all of the gas-phase models considered lead to predictions sufficiently close to experimental trends to conclude that the precise details of gas-phase processes are not of critical importance in determining propellant combustion behavior.

Kumar, R. N.↗
NASA NTRS1975

Validity of trace element cosmothermometer

A reply is made to previous criticisms of the claim that the range of accretion of ordinary chondrites can be narrowed to 500-420 K (from 560-405 K) using volatile metals as cosmothermometers. Questions concerning uncertainties in vapor pressure data, entropy of mixing, methods of analysis, uncertainties in condensation curves, metamorphic transport, alloy formation, condensation of Tl, condensation of In, and concordance with other thermometers (FeO contents of silicates) are addressed. It is concluded that the original claim is valid.

Anders, E.↗
NASA NTRS1975

Edible carbohydrates from formaldehyde in a spacecraft

The autocatalytic nature of the base catalyzed condensation of formaldehyde to formose sugars is eliminated by using as a cocatalyst, an aldose, or ketose having an alpha-hydrogen. This is more strongly complexed by base than is formaldehyde and the cocatalyst and sugar products accumulate as catalyst complexes instead of formaldehyde. Because of the presence of alpha-hydrogen atoms in cocatalysts and formose sugars, their removal by cross Cannizzaro reaction of complexed sugars does not occur, so the formose reaction behaves autocatalytically due to this accumulation. It is believed that a given catalytic formose complex is not a discrete complexed sugar, but rather, a scrambled dynamic mixture of sugars having weakened structures. The sugar complexes derive from a common salt-like formaldehyde complex, which, because of the absence of alpha-hydrogen, has a greater tendency to undergo Cannizzaro reaction, rather than formose condensation. Because of this, the Cannizzaro reaction can proceed without measurable formose condensation. The reverse is not possible.

Weiss, A. H.↗
NASA NTRS1976

Purging of multilayer insulation by gas diffusion

An experimental investigation was conducted to determine the time required to purge a multilayer insulation (MLI) panel with gaseous helium by means of gas diffusion to obtain a condensable (nitrogen) gas concentration of less than 1 percent within the panel. Two flat, rectangular MLI panel configurations, one incorporating a butt joint, were tested. The insulation panels consisted of 15 double-aluminized Mylar radiation shields separated by double silk net spacers. The test results indicated that the rate which the condensable gas concentration at the edge or at the butt joint of an MLI panel was reduced was a significant factor in the total time required to reduce the condensable gas concentration within the panel to less than 1 percent. The experimental data agreed well with analytical predictions made by using a simple, one-dimensional gas diffusion model in which the boundary conditions at the edge of the MLI panel were time dependent.

Sumner, I. E.↗
NASA NTRS1975

Chemistry of solar material

The calculated chemical compositions of the gaseous and condensed phases in the primitive solar nebula are presented for both equilibrium and disequilibrium condensation. The implications for the compositions of individual solar-system bodies will be briefly discussed. Condensation from an otherwise solar-composition gas in which carbon is more abundant than oxygen is mentioned.

Barshay, S. S.↗
NASA NTRS1976

Comments on the origin of Mercury

The ratio between the mass of condensed matter in Mercury's nebular zone and the final mass of condensed matter in the planet is calculated, and the result suggests that condensed matter equal to more than 10 times the planet's mass was lost from that zone. Five hypotheses to account for this loss are considered: (1) the temperature in Mercury's zone was appreciably higher than the suggested value of 1400 K, (2) the excess was expelled by solar mass outflow, (3) the excess was dragged down by the sun during its contraction, (4) the excess was knocked out by Jupiter-perturbed planetesimals, and (5) the excess was knocked out by earth- and Venus-perturbed planetesimals. The plausibility of each hypothesis is examined, and it is concluded that only planetesimal scattering by earth and Venus appears to be ruled out

Kaula, W. M.↗
NASA NTRS1976

Chemical fractionations in meteorites. IX - C3 chondrites

Radiochemical neutron activation is applied to the analysis of four C3V chondrites and three C3O chondrites for 17 trace elements (U, Re, Ir, Ni, Au, Sb, Ge, Ag, Rb, Cs, Bi, Tl, Br, Se, Te, In, and Cd). It is shown that both classes exhibit a typical chondritic step pattern, reflecting loss of volatiles during chondrule formation. It appears that the H2S/H2 ratio is the key variable to account for the condensation of chalcophile elements as a function of H2S. C3O's seem to have condensed in a region where enough metallic Fe was present to buffer the H2S pressure, whereas C3V's condensed in a more oxidized region where H2S was in excess. Accretion temperatures for both subclasses is determined. Sb and Au show variable depletion, presumably reflecting variable loss during chondrule formation.

Anders, E.↗
NASA NTRS1976

Chemistry of primitive solar material

The paper reviews chemical processes that occurred in the cooler outer regions of the primitive solar nebula (PSN) at the time of intimate chemical contact between the preplanetary condensate and the nebular gas. The elemental composition of the PSN is discussed, the 15 most abundant elements in it are listed, and numerical models of it are examined. Various condensation models are described and tested against observed properties of the planets, their satellites, and the asteroids. The chemistry of abundant volatile elements in the PSN is investigated along with stability limits of graphite in a solar-composition gas, regions of dominance of the most abundant carbon-containing gas species in the same gas, and implications of the moon's composition for its origin. Some theories that have been proposed as alternatives to the condensation models are noted.

Barshay, S. S.↗
NASA NTRS1977

A unified acquisition system for acoustic data

A multichannel, acoustic AM carrier system was developed for a wide variety of applications, particularly for aircraft noise and sonic boom measurements. Each data acquisition channel consists of a condenser microphone, an acoustic signal converter, and a Zero Drive amplifier, along with peripheral supporting equipment. A control network insures continuous optimal tuning of the converter and permits remote calibration of the condenser microphone. With a 12.70-mm (1/2-in.) condenser microphone, the converter/Zero Drive amplifier combination has a frequency response from 0 Hz to 20 kHz (-3 db), a dynamic range exceeding 70 db, and a minimum noise floor of 50 db ref. 20 micro Pa) in the band 22.4 Hz to 22.4 kHz. The system requires no external impedance matching networks and is insensitive to cable length, at least up to 900 m (3,000 ft). System gain varies only + or - 1 db over the temperature range 4 to 54 C (40 to 130 F). Adapters are available to accommodate 23.77-mm (1-in.) and 6.35-mm (1/4-in.) microphones and to provide 30-db attenuation. A field test to obtain the acoustical time history of a helicopter flyover proved successful.

Zuckerwar, A. J.↗
NASA NTRS1976

The parameters of a VCM test for the selection of space materials

Materials for space applications must have low outgassing rates at normal operating temperatures and the outgassing products should include a minimum of condensables at the temperatures of nearby surfaces. A screening method, developed years ago, consists of holding a material sample at 398 K (125 C) for 24 hours and measuring its percentage total mass loss (TML) and the percentage volatile condensable mass (VCM) accreted on a 298 K (25 C) collector. In general, the material is acceptable if the TML is less than 1 percent and the VCM is less than 0.1 percent. This paper presents an analysis of the test and its results. It shows that the results of TML and VCM can be used to provide data on outgassing rates and to derive an 'equivalent activation energy' for the material. The energy variables are needed for the calculation of pressure in compartments, the molecular contamination of critical surfaces, and other problems in molecular flow and surface physics. The analysis points out the criticality of the test and its limits with regards to the detection of condensables from certain materials.

Scialdone, J. J.↗
NASA NTRS1977

Microphysical processes affecting stratospheric aerosol particles

Physical processes which affect stratospheric aerosol particles include nucleation, condensation, evaporation, coagulation and sedimentation. Quantitative studies of these mechanisms to determine if they can account for some of the observed properties of the aerosol are carried out. It is shown that the altitude range in which nucleation of sulfuric acid-water solution droplets can take place corresponds to that region of the stratosphere where the aerosol is generally found. Since heterogeneous nucleation is the dominant nucleation mechanism, the stratospheric solution droplets are mainly formed on particles which have been mixed up from the troposphere or injected into the stratosphere by volcanoes or meteorites. Particle growth by heteromolecular condensation can account for the observed increase in mixing ratio of large particles in the stratosphere. Coagulation is important in reducing the number of particles smaller than 0.05 micron radius. Growth by condensation, applied to the mixed nature of the particles, shows that available information is consistent with ammonium sulfate being formed by liquid phase chemical reactions in the aerosol particles. The upper altitude limit of the aerosol layer is probably due to the evaporation of sulfuric acid aerosol particles, while the lower limit is due to mixing across the tropopause.

Hamill, P.↗
NASA NTRS1978

Evaluation of a large capacity heat pump concept for active cooling of hypersonic aircraft structure

Results of engineering analyses assessing the conceptual feasibility of a large capacity heat pump for enhancing active cooling of hypersonic aircraft structure are presented. A unique heat pump arrangement which permits cooling the structure of a Mach 6 transport to aluminum temperatures without the aid of thermal shielding is described. The selected concept is compatible with the use of conventional refrigerants, with Freon R-11 selected as the preferred refrigerant. Condenser temperatures were limited to levels compatible with the use of conventional refrigerants by incorporating a unique multipass condenser design, which extracts mechanical energy from the hydrogen fuel, prior to each subsequent pass through the condenser. Results show that it is technically feasible to use a large capacity heat pump in lieu of external shielding. Additional analyses are required to optimally apply this concept.

Pagel, L. L.↗
NASA NTRS1977

Trace elements in the Allende meteorite. III - Coarse-grained inclusions revisited

Radiochemical neutron activation analytic determinations of several elements in coarse-grained inclusions of the Allende meteorite are reported. The condensation and fractionation behavior of these and other elements are described. Evidence was found for a post-accretion thermal event which redistributed some trace elements. The solar system ratio of Zr/Hf is computed on the basis of the minimum variation in the inclusion, and the percentage of high-temperature condensates in the earth and moon are calculated on the basis of the mean U content of the inclusions. The mean value of the enrichment factors of 21 refractory elements relative to C1 chondrites is provided, and the elements that did or did not condense in a solid solution of melilite are listed.

Grossman, L.↗