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At least 1,693 records · Page 94

Theoretical determination of chemical rate constants using novel time-dependent methods

The work completed within the grant period 10/1/91 through 12/31/93 falls primarily in the area of reaction dynamics using both quantum and classical mechanical methodologies. Essentially four projects have been completed and have been or are in preparation of being published. The majority of time was spent in the determination of reaction rate coefficients in the area of hydrocarbon fuel combustion reactions which are relevant to NASA's High Speed Research Program (HSRP). These reaction coefficients are important in the design of novel jet engines with low NOx emissions, which through a series of catalytic reactions contribute to the deterioration of the earth's ozone layer. A second area of research studied concerned the control of chemical reactivity using ultrashort (femtosecond) laser pulses. Recent advances in pulsed-laser technologies have opened up a vast new field to be investigated both experimentally and theoretically. The photodissociation of molecules adsorbed on surfaces using novel time-independent quantum mechanical methods was a third project. And finally, using state-of-the-art, high level ab initio electronic structure methods in conjunction with accurate quantum dynamical methods, the rovibrational energy levels of a triatomic molecule with two nonhydrogen atoms (HCN) were calculated to unprecedented levels of agreement between theory and experiment.

Dateo, Christopher E.↗

Troilite formation kinetics and growth mechanism in the solar nebula

Troilite formation via the reaction Fe(s) + H2S(g) + H2(g) is the major mechanism for S retention in grains in the solar nebula. Thermodynamic calculations predict that troilite condenses from a solar composition gas. We present experimental results on the kinetics and growth of troilite crystals on Fe metal at temperature (450-650 C) and composition (50-1000 ppm H2S in H2) conditions similar to those in the solar nebula. The fraction of Fe reacted (based on gravimetric data) is plotted at 450, 505, 575, and 650 C. The thickness change of unreacted iron (measured by optical microscopy) is plotted at 575 and 650 C vs. time. the weight change per unit area varies as the square root of time at the lower temperatures and varies linearly with time at the highest temperature. The growth behavior along the lower isotherms is due to diffusion. This behavior suggests sulfide diffusion to the metal-sulfide interface and suggests Fe(2+) diffusion to the sulfide-gas interface. The reaction along the highest isotherm appears to be interface controlled. The formation of troilite crystals is a rapid process forming measurable layers in a few hours. The crystalgrowth is complicated. Initially there are intergrowths of troilite into the pure Fe metal. As the reaction progresses two distinct layers of troilite crystals form. One is in contact with the Fe metal and consists of small randomly oriented crystals with pore space between them. The outermost layer contains large crystals that are all oriented in the same direction. The intergrowth layer is much smaller at 650 C than at 575 C. This suggest that FeS nucleation is inhibited at the higher temperature, accounting for the initially slower reaction rate. Once nucleated, the reaction kinetics are apparently controlled by the growth of the crystals at the interface.

Lauretta, D. S.↗

Eurasian Reindeer Pastoralism in a Changing Climate: Indigenous Knowledge and NASA Remote Sensing

It is intended that Reindeer Mapper/EALAT will be able to provide reindeer herders with an efficient tool for managing the real-time movements and migrations of their herds through enabling improved efficiency in linking different members of the herder settlements or communities and providing real-time local, satellite or other data (e.g., ice melt in lakes and rivers, weather events), thus enabling real time adjustments to herd movements to avoid problems such as changing weather/climate conditions, freeze-thaw "lock-out" problems, or take advantage of availability of better pasturelands along migration routes. The system is being designed to incorporate local data to allow users to bring their own data into the system for analysis in addition to the data provided by the system itself. With the local information of the population, up to date environmental data and habitat characteristics, the system could generate maps depicting important features of interest for reindeer managers. One of the products derived from the planned Reindeer Mapper system will be a web-based graphic display that allows analysts to quickly pinpoint areas of interest such as those with large concentrations of reindeer and provide surrounding environmental information. The system could be automatically updated with near-real-time information such as hourly precipitation and snowfall rate and accumulation, daily surface and air temperatures, and vegetation cover conditions. The system could bring attention to the proximity of human and animal populations as part of the need for control response. A local GIS will bring these many layers together with several supporting models, showing only a straightforward graphic of the real-time situation in the field. Because the system proposed will be operating in the Internet environment, it should be virtually accessible from any network computers and wireless remote access from the field. The International Center for Reindeer Husbandry in Kautokeino, Norway, is providing regional and international coordination of and access to data sets and expertise, and will act as overall clearinghouse for EALAT information.

Maynard, N. G.↗

Providing Internet Access to High-Resolution Lunar Images

The OnMoon server is a computer program that provides Internet access to high-resolution Lunar images, maps, and elevation data, all suitable for use in geographical information system (GIS) software for generating images, maps, and computational models of the Moon. The OnMoon server implements the Open Geospatial Consortium (OGC) Web Map Service (WMS) server protocol and supports Moon-specific extensions. Unlike other Internet map servers that provide Lunar data using an Earth coordinate system, the OnMoon server supports encoding of data in Moon-specific coordinate systems. The OnMoon server offers access to most of the available high-resolution Lunar image and elevation data. This server can generate image and map files in the tagged image file format (TIFF) or the Joint Photographic Experts Group (JPEG), 8- or 16-bit Portable Network Graphics (PNG), or Keyhole Markup Language (KML) format. Image control is provided by use of the OGC Style Layer Descriptor (SLD) protocol. Full-precision spectral arithmetic processing is also available, by use of a custom SLD extension. This server can dynamically add shaded relief based on the Lunar elevation to any image layer. This server also implements tiled WMS protocol and super-overlay KML for high-performance client application programs.

Plesea, Lucian↗

Providing Internet Access to High-Resolution Mars Images

The OnMars server is a computer program that provides Internet access to high-resolution Mars images, maps, and elevation data, all suitable for use in geographical information system (GIS) software for generating images, maps, and computational models of Mars. The OnMars server is an implementation of the Open Geospatial Consortium (OGC) Web Map Service (WMS) server. Unlike other Mars Internet map servers that provide Martian data using an Earth coordinate system, the OnMars WMS server supports encoding of data in Mars-specific coordinate systems. The OnMars server offers access to most of the available high-resolution Martian image and elevation data, including an 8-meter-per-pixel uncontrolled mosaic of most of the Mars Global Surveyor (MGS) Mars Observer Camera Narrow Angle (MOCNA) image collection, which is not available elsewhere. This server can generate image and map files in the tagged image file format (TIFF), Joint Photographic Experts Group (JPEG), 8- or 16-bit Portable Network Graphics (PNG), or Keyhole Markup Language (KML) format. Image control is provided by use of the OGC Style Layer Descriptor (SLD) protocol. The OnMars server also implements tiled WMS protocol and super-overlay KML for high-performance client application programs.

Plesea, Lucian↗

Adopting Industry Standards for Control Systems Within Advanced Life Support

This paper gives a description of OPC (Object Linking and Embedding for Process Control) standards for process control and outlines the experiences at JSC with using these standards to interface with I/O hardware from three independent vendors. The I/O hardware was integrated with a commercially available SCADA/HMI software package to make up the control and monitoring system for the Environmental Systems Test Stand (ESTS). OPC standards were utilized for communicating with I/O hardware and the software was used for implementing monitoring, PC-based distributed control, and redundant data storage over an Ethernet physical layer using an embedded din-rail mounted PC.

Young, James Scott↗

Thermal Structure of Titan's Troposphere and Middle Atmosphere

The thermal structure of Titan's atmosphere is reviewed, with particular emphasis on recent Cassini-Huygens results. Titan's has a similar troposphere-stratosphere-mesosphere pattern like Earth, but with a much more extended atmosphere, because of the weaker gravity, and also much lower temperatures, because of its greater distance from the sun. Titan's atmosphere exhibits an unusually large range in radiative relaxation times. In the troposphere, these are long compared to seasonal time scales, but in the stratosphere they are much shorter than a season. An exception is near the winter pole, where the stratospheric relaxation times at 100-170 km become comparable to the seasonal time scale; at the warm stratopause, they are comparable to a Titan day. Hence, seasonal behavior in the troposphere should be muted, but significant in the stratosphere. This is reflected in the small meridional contrast observed in temperatures in the troposphere and the large stratospheric contrasts noted above. A surprising feature of the vertical profiles of temperature is the abrupt transition between these regimes in at high northern latitudes in winter, where the temperatures in the lower stratosphere exhibit a sudden drop with increasing altitude. This could be a radiative effect, not associated with spatial variations in gaseous opacity, but rather from an optically thick condensate at thermal-infrared wavelengths. A curious aspect of Titan's middle atmosphere is that the axis of symmetry of the temperature field is tilted by several degrees relative to the rotational axis of the moon itself. Whether this is driven by solar heating or gravitational perturbations is not known. Titan's surface exhibits weak contrasts in temperature, approximately 3 K in the winter hemisphere. At low latitudes, there is evidence of a weak nocturnal boundary layer on the morning terminator, which is not radiatively controlled, but can be explained in terms of vertical mixing with a small eddy viscosity.

Flasar, F. M.↗

IADC Vulnerability Report, IT32-21

Numerous mission support hardware systems and their spares are maintained outside of the habitable volume of the International Space Station (ISS), and are arranged covered by a multi-layer insulation (MLI) thermal blanket which provides both thermal control and a measure of protection from micrometeoroids and orbital debris (MMOD). The NASA Hypervelocity Impact Technology (HVIT) group at the Johnson Space Center in Houston Texas has assessed the protection provided by MLI in a series of hypervelocity impact tests using a 1 mm thick aluminum 6061-T6 rear wall to simulate the actual hardware behind the MLI. HVIT has also evaluated methods to enhance the protection provided by MLI thermal blankets. The impact study used both aluminum and steel spherical projectiles accelerated to speeds of 7 km/s using a 4.3 mm, two-stage, light-gas gun at the NASA White Sands Test Facility (WSTF).

Christiansen, E. L.↗

A Compact Dual-Band Bowtie Antenna for RF and ISM bands Operation

Traditionally, bowtie antennas have been known to exhibit wide impedance characteristics, omnidirectional radiation patterns, and linear polarization. There is a broad range of applications from medical imaging, archaeological survey, and Ground Penetrating Radar (GPR) to trackers and sensor networks where wideband bowtie antenna designs are required for their operations. Broadening the bandwidth of bowtie antenna requires widening the flare angle of the bowtie arms, which consequently results in a large surface area that may not be suitable for space-constrained applications. Moreover, drawback attributes of the wideband bowtie designs feature inconsistent radiation pattern across the bandwidth and low signal-to-noise (SNR) ratios. As it is known, the SNR would be improved in dual- or multi-band antennas due to their reduced bandwidth. To this end, dual-band/multi-band antennas are preferred over wideband antennas in applications where more than a single frequency of interest is present. Previously, a two-port double-dipole elements was reported, whose arms were orthogonally interleaved to facilitate operation in both the standard WLAN frequency bands (J. M. Steyn and et. al, Progress in Electromagnetic Research, Vol. – 10 pp. 151-161). Even though the antenna is not very compact it does exhibit good cross-polarization, moderate gain in both frequency bands. Another dual-band bowtie antenna which excites two bands using a single transmission line was reported (Wen Chao Zheng and et. al, IEEE Trans. Antennas propag., 2014). The design was compact and did not need multi-port feeding network. In this paper, a dual-band compact bowtie antenna operating at 900 MHz (RF band) and 2.45 GHz (ISM band) using a single excitation port is introduced. It is printed on a 1.54mm thick dielectric substrate (εr = 3.38). The antenna consists of two sets of bowtie arms, a microstrip transmission line to feed the bowtie arms, and a ground plane acting as a reflector to partially reduce the back radiation. One of the bowtie arms of each frequency is printed on the top layer and the other arm, which is mirror imaged, is printed on the bottom layer of the substrate. The length of the bowtie controls the resonance frequency of the antenna and the flare angle controls the bandwidth of the antenna. The microstrip transmission line, connected to a 50 Ω SMA probe, feeds the bowtie antenna. The compact antenna can be used for both RF and ISM band applications. The bowtie arms at the lower frequency band are miniaturized by elongating their electrical lengths. The influence of miniaturizing the bowtie arms and the supporting partial ground plane is observed in the reduced peak gain and degraded front-to-back ratio. These are partly neutralized using four quarter-wave choke-slots in the ground plane with two on each side of the feeding transmission line. The proposed antenna is numerically investigated and finalized by the finite-element based full-wave EM solver, ANSYS HFSS. The miniaturization has reduced the ground plane size by ~45% and the arms size by ~41%. In addition to the size reduction benefits, the antenna shows reasonable peak gain and front-to-back ratio in both the bands. The corresponding results will be presented and discussed at the conference.

Saininad Naik↗

The James Webb Space Telescope Mission: Optical Telescope Element Design, Development, and Performance

The James Webb Space Telescope (JWST) is a large, infrared space telescope that has recently started its science program which will enable breakthroughs in astrophysics and planetary science. Notably, JWST will provide the very first observations of the earliest luminous objects in the universe and start a new era of exoplanet atmospheric characterization. This transformative science is enabled by a 6.6 m telescope that is passively cooled with a 5 layer sunshield. The primary mirror is comprised of 18 controllable, low areal density hexagonal segments, that were aligned and phased relative to each other in orbit using innovative image-based wave front sensing and control algorithms. This revolutionary telescope took more than two decades to develop with a widely distributed team across engineering disciplines. We present an overview of the telescope requirements, architecture, development, superb on-orbit performance, and lessons learned. JWST successfully demonstrates a segmented aperture space telescope and establishes a path to building even larger space telescopes.

Infrared observatories↗

How to Build a Connected Community: Policies to Promote Grid-interactive Efficient Buildings and Demand Flexibility

Efficient, connected, grid-interactive, smart, and flexible buildings are key to decarbonizing the U.S. energy economy, optimizing energy use, reducing electric consumers’ bills, integrating variable renewable energy resources, and improving the reliability and performance of the nation’s electricity grids. Such grid-interactive efficient buildings have high levels of energy efficiency layered with other distributed energy resources (DERs) and intelligent controls to provide demand flexibility. Policy support is unfolding at the federal, state, and local levels to transform homes and workplaces into state-of-the-art energy-efficient buildings and community-level grid services. This paper starts by describing the potential benefits. Next, it highlights existing policies — with a focus on state-level actions — that support grid-interactive efficient building deployment and demand flexibility. Finally, it identifies current trends and gaps, policies and programs that promote grid-interactive efficient buildings, and aggregations of grid-interactive efficient buildings referred to as Virtual Power Plants.

Schwartz, Lisa C↗

Berry curvature memory through electrically driven stacking transitions

In two-dimensional layered quantum materials, the interlayer stacking order determines both crystalline symmetry and quantum electronic properties such as Berry curvature, topology and electron correlation. Electrical stimuli can strongly influence quasi-particle interactions and the free energy landscape, thus making it possible to access hidden stacking orders with novel quantum properties and enabling dynamic engineering of these attributes. In this paper, we demonstrate electrically driven stacking transitions and a new type of nonvolatile memory based on Berry curvature in few-layer WTe 2 . The interplay of out-of-plane electric fields and electrostatic doping controls in-plane interlayer sliding and creates multiple polar and centrosymmetric stacking orders. In-situ nonlinear Hall transport reveals such stacking rearrangements result in a layer-parity-selective Berry curvature memory in momentum space, where the sign reversal of the Berry curvature only occurs in odd layer crystals. Our findings open an avenue towards exploring coupling between topology, electron correlations, and ferroelectricity in hidden stacking orders and demonstrate a new low energy cost, electrically-controlled topological memory in the atomically thin limit.

36 MATERIALS SCIENCE↗

Crossflow instability control on a swept-wing: Preliminary studies

The pressure distribution on a swept wing causes the streamlines at the edge of the boundary layer to be curved. This pressure gradient normal to the external streamline creates a velocity component normal to the external streamline within the boundary layer which is referred to as the crossflow velocity. Because the crossflow velocity profile perpendicular to the wing surface has an inflection point, the profile is unstable. The stationary instability mode takes the form of crossflow vortices. Under these conditions, the boundary layer on the wing is extremely unstable and transition to turbulent flow takes place much closer to the leading edge of the wing than it would on an unswept wing. Higher skin friction drag is associated with turbulent flow, and so better aircraft performance could be obtained if the crossflow could be eliminated One method of controlling crossflow that is being investigated is boundary-layer suction. An extensive airfoil suction experiment in the 8 feet Transonic Pressure Tunnel (TPT) at NASA Langley Research Center will begin late in 1994. Because of the size, complexity, and expense associated with this test, a number of 'risk-reduction' tests are currently being conducted. The 20 x 28 in. Shear Flow Control Tunnel at NASA Langley is being used for some of these tests. Prior to the summer of 1994, a flat plate with a swept leading edge was installed in the 20 x 28 in. tunnel, with a displacement body mounted on the tunnel ceiling that created a pressure distribution on the plate similar to the pressure distribution on a swept wing. The flow over the plate was investigated during the summer of 1994 using a laser Doppler velocimeter (LDV) system. The LDV measurements indicated the possible presence of multiple disturbance modes, a rarely-seen phenomena since, in most tests, one disturbance mode dominates. The possible existence of multiple disturbance modes in the flat plate boundary layer, however, means that the flow in the 20 x 28 in. tunnel is of interest itself, and will be investigated more thoroughly in the future. With a view to these investigations, the boundary layer traverse mechanism in the 20 x 28 in. tunnel was modified to improve its performance, and strain gauges were mounted on the traverse in order to monitor its deflection during a test. Other preliminary work conducted in the 20 x 28 in. tunnel included the use of an infrared camera system. Previous work with this system showed that transition indeed could be detected, but the signal produced by the crossflow vortices was too weak to be detected. It was hoped that spraying the flat plate with naphthalene would augment the heat transfer associated with the crossflow vortices so that they would show up in a IR image; however, experiments showed that this would not work. Another set of tests was conducted in the 20 x 28 in. tunnel to determine the tripping requirements for a set of airfoil-shaped struts that will be used in the 8 feet TPT experiment. Since the Reynolds number associated with these struts is small, a laminar boundary layer would separate early, causing large fluctuations in the flow field. A turbulent boundary layer would remain attached further back, but tripping from laminar to turbulent flow at low Reynolds number is very difficult. However, trip strip configurations were found that should effectively trip the boundary layer at the required conditions. Currently underway is an investigation of the data acquisition requirements for the 8 feet TPT experiment, with the purpose of the finding the minimum amount of data needed to characterize sufficiently the swept-wing boundary layer. This study is being conducted using a numerically generated data set.

Bridges, David H.↗

Characterizing Land-Atmosphere Interactions During the Afternoon-to-Evening Transition Using ARM SGP Observations

The land-atmosphere (LA) system consists of the soil, vegetation, and lowest layer of the atmosphere. The energy and water transport processes in this system contribute to the structure and the daily cycle of the atmospheric boundary layer (ABL), which is the layer between the land surface and the free troposphere that controls the exchange of momentum, energy, and water. The state of the ABL is the result of complex two-way interactions between local processes such as surface fluxes and entrainment at the ABL top as well as large-scale and mesoscale processes such as advection and subsidence.

54 ENVIRONMENTAL SCIENCES↗

Impact of Aquarius and SMAP Satellite Sea Surface Salinity Observations on Coupled El Niño/Southern Oscillation Forecasts

This study demonstrates the positive impact of including gridded Aquarius and SMAP sea surface salinity (SSS) into initialization of coupled forecasts for the tropical Indo-Pacific. An experiment that assimilates conventional ocean observations serves as the control. In a separate experiment, Aquarius and SMAP satellite SSS are additionally assimilated into the control initialization. Analysis of the initialization differences with the control indicates that SSS assimilation causes a freshening and shallowing of the mixed layer depth (MLD) near the equator and enhanced Kelvin wave amplitude. For each month from September 2011 to September 2018, 12 month coupled ENSO forecasts are initialized from both the control and satellite SSS assimilation experiments. The experiment assimilating Aquarius and SMAP SSS significantly outperforms the control relative to observed NINO3.4 sea surface temperature anomalies. This work highlights the importance of inclusion of satellite SSS for improving the initialization ENSO coupled forecasts.

Hackert, Eric C.↗

Amplified crossflow disturbances in the laminar boundary layer on swept wings with suction

Solution charts of the Orr-Sommerfeld equation for stationary crossflow disturbances are presented for 10 typical velocity profiles on a swept laminar flow control wing. The critical crossflow Reynolds number is shown to be a function of a boundary layer shape factor. Amplification rates for crossflow disturbances are shown to be proportional to the maximum crossflow velocity. A computer stability program called MARIA, employing the amplification rate data for the 10 crossflow velocity profiles, is constructed. This code is shown to adequately approximate more involved computer stability codes using less than two percent as much computer time while retaining the essential physical disturbance growth model.

Dagenhart, J. R.↗

3D Printed Carbon Aerogels for Polymer-Electrolyte Fuel Cells

Carbon aerogels (CA) are known for ultra-low density, very high surface area, fine porous structure, and excellent electrical conductivity. Recent advances in high resolution 3D printing at LLNL enable the manufacturing of complex structured CA electrodes which have been demonstrated in electrolysis, flow battery, and supercapacitor applications. Polymer-electrolyte fuel cells (PEFC) may be an excellent candidate for these materials/methods as designers seek to optimize membrane-electrode assemblies to achieve higher efficiencies. A major challenge to PEFC design is two-phase flow due to water production which causes pore flooding and leads to cell instability and degradation. To mitigate these effects, groups have investigated the creation of liquid specific pathways in the porous layers to alleviate liquid buildup and enhance gas diffusion. While some progress has been made, traditionally manufactured GDLs, which consist of randomly distributed carbon fibers, are limiting. 3D printed CAs are a promising solution as complex macroporous electrode structures can be manufactured out of micro and nano porous filaments with a high level of control. Additionally, the process may allow for the consolidation of multiple layers (MPL, GDL, & flow channels) into a single printed architecture. In this work various CA lattice structures were printed using a direct ink write (DIW) method and liquid breakthrough pressures were measured to demonstrate the ability to tune the water pathways to achieve specific pressure thresholds. Furthermore, a discussion of the prospects for printed CA electrodes in PEFC will focus on material properties, synthesis techniques, and current challenges.

36 MATERIALS SCIENCE↗