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NASA NTRS1992

Environmental projects. Volume 14: Removal of contaminated soil and debris

Numerous diverse activities at the Goldstone Deep Space Communications Complex (GDSCC) are carried out in support of six parabolic dish antennas. Some of these activities can result in possible spills or leakages of hazardous materials and wastes stored both above ground in steel drums and below ground in underground storage tanks (UST's). These possible leaks or spills, along with the past practice of burial of solid debris and waste in trenches and pits, could cause local subsurface contamination of the soil. In 1987, the Jet Propulsion Laboratory (JPL), retained Engineering-Science, Inc. (E-S), Pasadena, California, to identify the specific local areas within the GDSCC with subsurface soil contamination. The E-S study determined that some of the soils at the Apollo Site and the Mars Site were contaminated with hydrocarbons, while soil at a nonhazardous waste dumpsite at the Mojave Base site was contaminated with copper. This volume is a JPL-expanded version of the PE209 E-S report, and it also reports that all subsurface contaminated soils at the GDSCC were excavated, removed, and disposed of in an environmentally acceptable way, and the excavations were backfilled and covered in accordance with accepted Federal, State, and local environmental rules and regulations.

Kushner, Len↗

NASA NTRS1993

Development of a Cone Penetrometer for Measuring Spectral Characteristics of Soils in Situ

A patent was recently granted to the U.S. Army for an adaptation of a soil cone penetrometer that can be used to measure the spectral characteristics (fluorescence or reflectance) of soils adjacent to the penetrometer rod. The system can use a variety of light sources and spectral analytical equipment. A laser induced fluorescence measuring system has proven to be of immediate use in mapping the distribution of oil contaminated soil at waste disposal and oil storage areas. The fiber optic adaptation coupled with a cone penetrometer permits optical characteristics of the in-situ soil to be measured rapidly, safely, and inexpensively. The fiber optic cone penetrometer can be used to gather spectral data to a depth of approximately 25 to 30 m even in dense sands or stiff clays and can investigate 300 m of soil per day. Typical detection limits for oil contamination in sand is on the order of several hundred parts per million.

Lee, Landris T., Jr.↗

NASA NTRS1992

Effect of DCB extraction on Mossbauer and spectral data for a Hawaiian palagonitic soil (PN-9): Iden tification of pigmentary phases

The study of palagonitic soils is an active area of research in martian geoscience because the spectral and magnetic properties of a subset are spectral and/or magnetic analogues of martian bright regions. An understanding of the composition, distribution, and mineralogy of ferric-bearing phases for palagonitic soils forms, through spectral and magnetic data, a basis for inferring the nature of ferric-bearing phases on Mars. Progress has been made in this area, but the data set is incomplete, especially with respect to the nature of pigmenting phases. The purpose of this study is to identify the nature of the pigment for Hawaiian palagonitic soil PN-9 by using extraction procedures to selectively remove iron oxide phases. This soil was collected at the same locale as samples Hawaii 34 and VOL02. All three soils are good spectral analogues for martian bright regions.

Morris, Richard V.↗

NASA NTRS1992

Infrared (8-14 microns) remote sensing of soil particle size

Particle size of soils plays a significant role in erosion potential and other mechanical properties. Most soils are dominated by the residual mineral quartz, which displays prominent reststrahlen bands in the 8-14 microns atmospheric window. The Earth Observing System will likely provide world-wide multispectral imagery in the 8-14 microns region via the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) instrument. The ratio of ASTER bands 10/14 can be used to estimate particle size in soils, if other ASTER bands are used to minimize the confusion factors provided by soil moisture, vegetation cover, soil organic content, and the presence of abundant minerals other than quartz. Use of band ratios minimizes the effects of poor surface temperature estimates, but maximizes the need for high signal-to-noise data.

Salisbury, John W.↗

NASA NTRS1992

Soil moisture variability within remote sensing pixels

The effects of topography and the level of soil moisture on the variability of soil moisture within remote sensing pixels were assessed during the First ISLSCP Field Experiment (FIFE) during 1987 and 1989. Soil moisture data from flat, sloped, and valley-shaped pixels were obtained over a wide range of moisture conditions. Relative elevation data were obtained for each study area to create digital elevation models with which to quantify topographic variability. Within-pixel soil moisture variability was shown to increase with increased topographic heterogeneity. The flat pixel had significantly lower standard deviations and fewer outlier points than the slope and valley pixels. Most pixel means had a positive skewness, indicating that most pixels will have areas of markedly higher than average soil moisture.

Charpentier, Michael A.↗

NASA NTRS1993

Intercomparisons between passive and active microwave remote sensing, and hydrological modeling for soil moisture

Soil moisture estimations from a distributed hydrological model and two microwave sensors were compared with ground measurements collected during the MAC-HYDRO'90 experiment. The comparison was done with the purpose of evaluating the performance of the hydrological model and examining the limitations of remote sensing techniques used in soil moisture estimation. An image integration technique was used to integrate and analyze rainfall, soil properties, land cover, topography, and remote sensing imagery. Results indicate that the hydrological model and microwave sensors successfully picked up temporal variations of soil moisture and that the spatial soil moisture pattern may be remotely sensed with reasonable accuracy using existing algorithms.

Wood, E. F.↗

NASA NTRS1992

Soil nitrogen cycling and nitrous oxide flux in a Rocky Mountain Douglas-fir forest - Effects of fertilization, irrigation and carbon addition

Nitrous oxide fluxes and soil nitrogen transformations were measured in experimentally-treated high elevation Douglas-fir forests in northwestern New Mexico. On an annual basis, forests that were fertilized with 200 kg N/ha emitted an average of 0.66 kg/ha of N2O-N, with highest fluxes occurring in July and August when soils were both warm and wet. Control, irrigated, and woodchip treated plots were not different from each other, and annual average fluxes ranged from 0.03 to 0.23 kg/ha. Fertilized soil mineralized 277 kg/ha per year in contrast to 18 kg/ha per year in control plots. Relative recovery of (N-15)H4-N applied to soil in laboratory incubations was principally in the form of NO3-N in the fertilized soils, while recovery was mostly in microbial biomass-N in the other treatments. Fertilization apparently added nitrogen that exceeded the heterotrophic microbial demand, resulting in higher rates of nitrate production and higher nitrous oxide fluxes. Global inputs of nitrogen into forests are not currently contributing significantly to the increasing concentrations of nitrous oxide in the atmosphere.

Matson, Pamela A.↗

NASA NTRS1992

Soil moisture verification study of the ESTAR microwave radiometer - Walnut Gulch, AZ 1991

The application of an electronically steered thinned array L-band radiometer (ESTAR) for soil moisture mapping is investigated over the arid rangeland Walnut Gulch Watershed. Antecedent rainfall and evaporation for the flights are very different and result in a wide range of soil moisture conditions. The high spatial variability of rainfall events within this region results in moisture conditions with dramatic spatial patterns. Sensor performance is verified using two approaches. Microwave data are used in conjunction with a microwave emission model to predict soil moisture. These predictions are compared to ground observations of soil moisture. A second verification is possible using an extensive data set. Both tests showed that the ESTAR is capable of providing soil moisture with the same level of accuracy as existing systems.

Jackson, T. J.↗

NASA NTRS1992

Development of soil moisture retrieval algorithm for L-band SAR measurements

A study of algorithm development and testing for soil moisture retrieval for bare fields using L-band synthetic aperture radar (SAR) imagery is reported. First-order surface scattering models predict that the copolarization ratio is sensitive to soil moisture but not to surface roughness. All possible ratios of the co-polarization signals and their linear combinations are evaluated. The best sensitivity to soil moisture is achieved from measurements as predicted by the first-order surface scattering model. The effects of system noise and volume scattering of soil are evaluated. To minimize the effect of the volume scattering, an algorithm which includes both the surface and volume scattering has been developed and tested using Jet Propulsion Laboratory Airborne SAR (JPL AIRSAR) data. The results show that the estimation of soil moisture can be improved after removing the system noise and including the volume scattering effect at large incidence angles.

Shi, Jiancheng↗

NASA NTRS1992

Estimation of bare soil evaporation using multifrequency airborne SAR

It is shown that for homogeneous areas soil moisture can be derived from synthetic aperture radar (SAR) measurements, so that the use of microwave remote sensing can given realistic estimates of energy fluxes if coupled to a simple two-layer model repesenting the soil. The model simulates volumetric water content (Wg) using classical meterological data, provided that some of the soil thermal and hydraulic properties are known. Only four parameters are necessary: mean water content, thermal conductivity and diffusitivity, and soil resistance to evaporation. They may be derived if a minimal number of measured values of Wg and surface layer temperature (Tg) are available together with independent measurements of energy flux to compare with the estimated values. The estimated evaporation is shown to be realistic and in good agreement with drying stage theory in which the transfer of water in the soil is in vapor form.

Soares, Joao V.↗

NASA NTRS1992

The mass balance of soil evolution on late Quaternary marine terraces, northern California

Mass-balance interpretation of a soil chronosequence provides a means of quantifying elemental addition, removal, and transformation that occur in soils from a flight of marine terraces in northern California. Six soil profiles that range in age from several to 240,000 yr are developed in unconsolidated, sandy-marine, and eolian parent material deposited on bedrock marine platforms. Soil evolution is dominated by (1) open-system depletion of Si, Ca, Mg, K, and Na; (2) open-system enrichment of P in surface soil horizons; (3) relative immobility of Fe and Al; and (4) transformation of Fe, Si, and Al in the parent material to secondary clay minerals and sesquioxides. Net mass losses of bases and Si are generally uniform with depth and substantial, in some cases approaching 100 percent; however, the rate of loss of each element differs markedly, causing the ranking of each by relative abundance to shift with time. Loss of Si from the sand fraction by dissolution and particle-size diminution, from about 100 percent to less than 35 percent over 240 ky, mirrors a similar gain in the silt and clay size fractions. The Fe originally present in the sand fraction decreases from greater than 80 percent to less than 10 percent, whereas the amount of Fe present in the clay and crystalline oxyhydroxide fractions increases to 25 percent and 70 percent, respectively.

Merritts, Dorothy J.↗

NASA NTRS1992

A toy model for estimating N2O emissions from natural soils

A model of N2O emissions from natural soils, whose ultimate objective is to evaluate what contribution natural ecosystems make to the global N2O budget and how the contribution would change with global change, is presented. Topics covered include carbon and nitrogen available in the soil, delivery of nitrifiable N, soil water and oxygen status, soil water budget model, effects of drainage, nitrification and denitrification potentials, soil fertility, N2O production, and a model evaluation. A major implication of the toy model is that the tropics account for more than 80 percent of global emission.

Fung, Inez↗

NASA NTRS1994

Petrographic characterization of lunar soils: Application of x ray digital-imaging to quantitative and automated analysis

The rocks and soils of the moon will be the raw materials for various engineering needs at a lunar base, such as sources of hydrogen, oxygen, metals, etc. The material of choice for most of the bulk needs is the regolith and its less than 1 cm fraction, the soil. For specific mineral resources it may be necessary to concentrate minerals from either rocks or soils. Therefore, quantitative characterizations of these rocks and soils are necessary in order to better define their mineral resource potential. However, using standard point-counting microscopic procedures, it is difficult to quantitatively determine mineral abundances and virtually impossible to obtain data on mineral distributions within grains. As a start to fulfilling these needs, Taylor et al. and Chambers et al. have developed a procedure for characterization of crushed lunar rocks using x ray digital imaging. The development of a similar digital imaging procedure for lunar soils as obtained from a spectrometer is described.

Higgins, Stefan J.↗

NASA NTRS1994

Measurement of the fluorescence of crop residues: A tool for controlling soil erosion

Management of crop residues, the portion of a crop left in the field after harvest, is an important conservation practice for minimizing soil erosion and for improving water quality. Quantification of crop residue cover is required to evaluate the effectiveness of conservation tillage practices. Methods are needed to quantify residue cover that are rapid, accurate, and objective. The fluorescence of crop residue was found to be a broadband phenomenon with emission maxima at 420 to 495 nm for excitations of 350 to 420 nm. Soils had low intensity broadband emissions over the 400 to 690 nm region for excitations of 300 to 600 nm. The range of relative fluorescence intensities for the crop residues was much greater than the fluorescence observed of the soils. As the crop residues decompose their blue fluorescence values approach the fluorescence of the soil. Fluorescence techniques are concluded to be less ambiguous and better suited for discriminating crop residues and soils than reflectance methods. If properly implemented, fluorescence techniques can be used to quantify, not only crop residue cover, but also photosynthetic efficiency in the field.

Daughtry, C. S. T.↗

NASA NTRS1994

Aspects of spatial and temporal aggregation in estimating regional carbon dioxide fluxes from temperate forest soils

We examine the influence of aggregation errors on developing estimates of regional soil-CO2 flux from temperate forests. We find daily soil-CO2 fluxes to be more sensitive to changes in soil temperatures (Q(sub 10) = 3.08) than air temperatures (Q(sub 10) = 1.99). The direct use of mean monthly air temperatures with a daily flux model underestimates regional fluxes by approximately 4%. Temporal aggregation error varies with spatial resolution. Overall, our calibrated modeling approach reduces spatial aggregation error by 9.3% and temporal aggregation error by 15.5%. After minimizing spatial and temporal aggregation errors, mature temperate forest soils are estimated to contribute 12.9 Pg C/yr to the atmosphere as carbon dioxide. Georeferenced model estimates agree well with annual soil-CO2 fluxes measured during chamber studies in mature temperate forest stands around the globe.

Kicklighter, David W.↗

NASA NTRS1993

The effect of SST and soil moisture anomalies on GLA model simulations of the 1988 U.S. summer drought

A series of simulations of the late spring and early summer of 1988 were conducted in order to study the relative importance of different boundary forcings to the Goddard Laboratory for Atmospheres (GLA) model's simulation of the heat wave and drought over the Great Plains of the United States during this time period. Separate 60-day simulations were generated from 10, 20, and 30 May 1988 with a variety of boundary condition datasets. For the control experiment, climatological boundary conditions were used. This was followed by experiments in which either the observed 1988 sea surface temperatures (SST) or derived 1988 soil moisture values, or both, were used in place of the climatological fields. Additional experiments were conducted in which only tropical or midlatitude SST anomalies were used. The impact of the different boundary forcings was evaluated relative to the control simulations of the precipitation and surface air temperature over the Great Plains. It was found that the tropical SST anomalies had a significant effect in reducing precipitation in this area, while the midlatitude anomalies did not. Due to the prescribed climatological soil moistures for the SST experiments, a significant increase in surface temperature did not occur in these simulations. In contrast, the simulations with the anomalous 1988 soil moistures produced both a larger reduction of precipitation and a significant increase in surface temperature over the Great Plains. The simulations with both anomalous SST and soil moisture showed only a slight augmentation of the heat wave and drought relative to the experiments with anomalous soil moisture alone.

Atlas, R.↗

NASA NTRS1993

Remote sensing studies of immature soils on the Moon (Reiner-gamma formation)

On the base of laboratory results and telescopic data it is shown that the spectropolarization ratio P(sub max(sup B))/P(sub max(sup R)) for blue and red spectral regions is a remote sensing parameter of lunar soil maturity. It correlates with value of maturity index derived from morphological or ferromagnetic methods of exposure age determination. This parameter is equal to 0.315 for Reiner-gamma formation. So Reiner-gamma area is covered by immature soil. An extensive spectral mapping of the Reiner-gamma formation with high spatial resolution (0.2 km/pixel) was produced. This result was obtained at the 2-meter aperture telescope of Pic-du-Midi (France). The data sets consist in repeated runs comprising 10 selected narrow-band images (from 0.4 to 1.05 micron). The analysis of these data suggests that such a type of immature material includes not more than 28% of agglutinattes. We find the model grain size of fine fraction to be 40 micrometers grain size, of more immature soil 400-500 micrometers, and of the formation soil 120-150 micrometers. The exposure age of the Reiner-gamma immature soil is equal about 10 x 10(exp 6) years.

Shevchenko, V. V.↗

NASA NTRS1997

The Aggregate Description of Semi-Arid Vegetation with Precipitation-Generated Soil Moisture Heterogeneity

Meteorological measurements in the Walnut Gulch catchment in Arizona were used to synthesize a distributed, hourly-average time series of data across a 26.9 by 12.5 km area with a grid resolution of 480 m for a continuous 18-month period which included two seasons of monsoonal rainfall. Coupled surface-atmosphere model runs established the acceptability (for modelling purposes) of assuming uniformity in all meteorological variables other than rainfall. Rainfall was interpolated onto the grid from an array of 82 recording rain gauges. These meteorological data were used as forcing variables for an equivalent array of stand-alone Biosphere-Atmosphere Transfer Scheme (BATS) models to describe the evolution of soil moisture and surface energy fluxes in response to the prevalent, heterogeneous pattern of convective precipitation. The calculated area-average behaviour was compared with that given by a single aggregate BATS simulation forced with area-average meteorological data. Heterogeneous rainfall gives rise to significant but partly compensating differences in the transpiration and the intercepted rainfall components of total evaporation during rain storms. However, the calculated area-average surface energy fluxes given by the two simulations in rain-free conditions with strong heterogeneity in soil moisture were always close to identical, a result which is independent of whether default or site-specific vegetation and soil parameters were used. Because the spatial variability in soil moisture throughout the catchment has the same order of magnitude as the amount of rain failing in a typical convective storm (commonly 10% of the vegetation's root zone saturation) in a semi-arid environment, non-linearitv in the relationship between transpiration and the soil moisture available to the vegetation has limited influence on area-average surface fluxes.

White, Cary B.↗