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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,693 records · Page 94
All sourcesNASA NTRSDOE OSTI
DOE OSTI2018

Water Remediation: PVA-Based Magnetic Gels as Efficient Devices to Heavy Metal Removal

Scientific and technological researches are devoted to obtain materials capable of retaining different kinds of pollutants, contributing to contamination solutions. In this context, hydrogels have emerged as great candidates because of their excellent absorption properties as well as good mechanical, thermal and chemical properties. More specifically, ferrogels (magnetic gels) present the extra advantage of being easily manipulated by a permanent magnet. Here, we present the results derived from the application of ferrogels as efficient tools to extract heavy metal pollutants from wastewater samples. The gels were prepared following the method of freezing and thawing of a polyvinyl alcohol aqueous solution with magnetic nanoparticles coated with polyacrylic acid. Ferrogels were fully characterized and their ability to retain Cu{sup 2+} and Cd{sup 2+}, as model heavy metals, was studied. Thus kinetics and mechanisms of adsorption were evaluated and modeled. The concentration of MNPs on the PVA matrix was key to improve the adsorption capability (approximately the double of retention is improved by the MNPs addition). The adsorption kinetics was determined as pseudo-second order model, whereas the Langmuir model was the most appropriate to explain the behavior of the gels. Finally reuse ability was evaluated to determine the real potential of these materials, the ferrogels demonstrated high efficiency up to about five cycles, retaining about 80–90% of their initial adsorption capability. All the results indicated that the materials are promising candidates able to compete with the commercial technology regarding to water remediation.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Particle Size-Dependent Zero-Field Exchange Bias in LaFeO {sub 3} Nanoparticles

The present communication deals with particle size-dependent zero-field cooled exchange effect in LaFeO{sub 3} (LFO). LFO nanoparticles were prepared by PVA-based sol-gel method. The sample was calcined at different temperatures (700, 750, and 800 {sup ∘}C) to tune the average particle size. The detailed crystal structural and their geometrical parameters were examined by means of Rietveld refinement using x-ray diffraction data. The different techniques such as Scherrer’s method, Williamson Hall method, FESEM, and TEM were applied to accurately determine the average particle size. Zero-field cooled exchange bias and weak ferromagnetism in antiferromagnetic nanoparticles was observed for all samples using hysteresis loop measurement. The training effect was studied to confirm that the loop shift originates due to exchange bias. Exchange bias as well as coercivity are strongly related to the particle size at low and room temperature. The results clearly demonstrate that the process of calcination tailor the overall properties of material which makes it a promising candidate for device applications.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2018

Nucleation and growth of tungsten nanotendrils grown under divertor-like conditions

Tungsten is the primary candidate for plasma-facing materials in the critical regions of a magnetic fusion energy (MFE) device, such as a tokamak. However, tungsten (and many other metals) grow copious nanotendril "fuzz" when exposed to fusion-relevant He-bearing plasmas, and the impact of this fuzz on reactor operation is still unknown. Further, the mechanism of fuzz growth is also poorly understood at present. In order to experimentally probe the growth mechanisms, we developed a new sample preparation technique to examine the interface of individual nanotendril roots with the substrate (substrate/tendril interface) using electron microscopy and measured the grain boundary character distributions (GBCDs) of substrate/tendril interfaces, the GBs within individual tendrils (tendril/tendril interfaces), and GBs within the substrate (substrate/substrate interfaces). We find the substrate/tendril and tendril/tendril GBCDs are essentially indistinguishable, but very different from the substrate/substrate GBCDs, which implies that tendril growth periodically forms new GBs at the substrate/tendril interface, and these GBs are pushed upward to become tendril/tendril interfaces within the fuzz mat. These results will help guide future computational modelling studies to elucidate the details of the growth mechanisms.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2018

Development of coring procedures applied to Si, CdTe, and CIGS solar panels

Most of the research on the performance and degradation of photovoltaic modules is based on macroscale measurements of device parameters such as efficiency, fill factor, open-circuit voltage, and short-circuit current. Our goal is to develop the capabilities to allow us to study the degradation of these parameters in the micro- and nanometer scale and to relate our results to performance parameters. To achieve this objective, the first step is to be able to access small samples from specific areas of the solar panels without changing the properties of the material. In this paper, we describe two coring procedures that we developed and applied to Si, CIGS, and CdTe solar panels. In the first procedure, we cored full samples, whereas in the second we performed a partial coring that keeps the tempered glass intact. The cored samples were analyzed by different analytical techniques before and after coring, at the same locations, and no damage during the coring procedure was observed.

14 SOLAR ENERGY↗
DOE OSTI2016

Ultralow-frequency Raman system down to 10 cm{sup −1} with longpass edge filters and its application to the interface coupling in t(2+2)LGs

Ultralow-frequency (ULF) Raman spectroscopy becomes increasingly important in the area of two-dimensional (2D) layered materials; however, such measurement usually requires expensive and nonstandard equipment. Here, the measurement of ULF Raman signal down to 10 cm{sup −1} has been realized with high throughput by combining a kind of longpass edge filters with a single monochromator, which are verified by the Raman spectrum of L-cystine using three laser excitations. Fine adjustment of the angle of incident laser beam from normal of the longpass edge filters and selection of polarization geometry are demonstrated how to probe ULF Raman signal with high signal-to-noise. Davydov splitting of the shear mode in twisted (2+2) layer graphenes (t(2+2)LG) has been observed by such system in both exfoliated and transferred samples. We provide a direct evidence of twist-angle dependent softening of the shear coupling in t(2+2)LG, while the layer-breathing coupling at twisted interfaces is found to be almost identical to that in bulk graphite. This suggests that the exfoliation and transferring techniques are enough good to make a good 2D heterostructures to demonstrate potential device application. This Raman system will be potentially applied to the research field of ULF Raman spectroscopy.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2019

Quasi-2D superconductivity in FeTe 0.55 Se 0.45 ultrathin film [Quasi Two-Dimensional Superconductivity in FeTe 0.55 Se 0.45 ultrathin film]

Iron-chalcogenide FeTe 0.55 Se 0.45 was found to be a promising topological superconducting candidate recently, which may host Majorana bound state in the vortex core and thus attracts intensive research interests in this material. In this report, mechanically exfoliated FeTe 0.55 Se 0.45 superconducting thin films close to the two-dimensional (2D) limit, i.e. sample thickness is on the order of coherence length, were studied systematically by means of electrical transport and point-contact Andreev-reflection spectroscopy (PCARS) measurements. The quasi-2D nature of FeTe 0.55 Se 0.45 thin films is evidenced by the observation of Berezinskii–Kosterlitz–Thouless (BKT) transition and anisotropic upper critical fields in the vicinity of superconducting transition. Compared to bulk samples, we found that the superconducting transition temperature is only slightly suppressed even for films down to 5 nm. The superconducting gap symmetry remains unchanged and the gap size is weakly affected by tailoring thickness. Furthermore, our findings suggest that the superconductivity of FeTe 0.55 Se 0.45 thin films is rather robust against reduced dimensions. It provides a novel platform for device applications for quantum computations in combination with possible realization of Majorana modes in this material.

2D superconductivity↗
DOE OSTI2021

Cryogenic single-port calibration for superconducting microwave resonator measurements

Superconducting circuit testing and materials loss characterization requires robust and reliable methods for the extraction of internal and coupling quality factors of microwave resonators. Additionally, a common method, imposed by limitations on the device design or experimental configuration, is the single-port reflection geometry, i.e. reflection-mode. However, impedance mismatches in cryogenic systems must be accounted for through calibration of the measurement chain while it is at low temperatures. In this paper, we demonstrate a data-based, single-port calibration using commercial microwave standards and a vector network analyzer with samples at millikelvin temperature in a dilution refrigerator, making this method useful for measurements of quantum phenomena. Finally, we cross reference our data-based, single-port calibration and reflection measurement with over-coupled 2D- and 3D-resonators against well established two-port techniques corroborating the validity of our method.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2016

SU-F-J-07: Evaluating the Adequacy of Biopsy Specimens for Genetic Signature Assessment by Measuring the Metabolic Activity in Specimens Obtained Under 18F-FDG PET/CT Guidance

Purpose: Genetic profiling of biopsied tissue is the basis for personalized cancer therapy. However biopsied materials may not contain sufficient amounts of DNA needed for analysis. We propose a method to determine the adequacy of specimens for performing genetic profiling by quantifying metabolic activity. Methods: We measured the response of two radiation detectors to the activity contained in the minimum amount of tumor cells needed for genetic profiling in biopsy specimens obtained under 2-deoxy-2-({sup 18}F)fluoro-D-glucose ({sup 18}F-FDG) PET/CT guidance. The expected tumor cell concentration in biopsy specimens was evaluated from the amount of DNA needed (∼100 µg) and the number of pathology sections typically used for the analysis. The average {sup 18}F-FDG uptake per cell was measured by incubating KPC-4662 pancreatic tumor cells and HT-29 colorectal adenocarcinoma tumor cells in {sup 18}F-FDG containing solution (activity concentrations between 0.0122 and 1.51 MBq/mL and glucose concentrations of 3.1 and 1 g/L) for 1 to 1.75 hours and then measuring the activity of a known number of cells. Measurements of surrogate specimens obtained using 18G needle biopsies of gels containing these cells in expected concentrations (∼10{sup 4} µL{sup −1}) were performed using an autoradiography CCD based device (up to 20 min exposure) and a scintillation well counter (∼1 min measurements) about 3 and 5 hours after the end of incubation respectively. Results: At start of autoradiography there were between 0.16 and 1.5 {sup 18}F-FDG molecules/cell and between 1.14 and 5.43×10{sup 7} {sup 18}F-FDG molecules/mL. For the scintillation well counter, sample to minimum-detectable-count rate ratios were greater than 7 and the counting error was less than 25% for ≤80 s measurement times. Images of the samples were identifiable on the autoradiograph for ∼10 min and longer exposure times. Conclusion: Scintillation well counter measurements and CCD based autoradiography have adequate sensitivity to detect the tumor burden needed for genetic profiling in 18G core needle biopsies. Supported in part through the NIH/NCI Cancer Center Support Grant P30 CA008748 and by a sponsored research agreement with Biospace Lab S.A.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2013

Method of detecting system function by measuring frequency response

Methods of rapidly measuring an impedance spectrum of an energy storage device in-situ over a limited number of logarithmically distributed frequencies are described. An energy storage device is excited with a known input signal, and a response is measured to ascertain the impedance spectrum. An excitation signal is a limited time duration sum-of-sines consisting of a select number of frequencies. In one embodiment, magnitude and phase of each frequency of interest within the sum-of-sines is identified when the selected frequencies and sample rate are logarithmic integer steps greater than two. This technique requires a measurement with a duration of one period of the lowest frequency. In another embodiment, where selected frequencies are distributed in octave steps, the impedance spectrum can be determined using a captured time record that is reduced to a half-period of the lowest frequency.

25 ENERGY STORAGE↗
DOE OSTI2022

Electrical Analysis of Pulsed Laser Annealed Poly-Si:Ga/SiOx Passivating Contacts

High-efficiency single crystalline silicon (c-Si) solar cells require precise control of dopant diffusion profiles and highly active doping concentrations through thermal annealing. Conventional furnace annealing has been successfully employed for dopant diffusion in aluminum back-surface field (Al-BSF), passivated emitter and rear contact (PERC), and Topcon cells. However, furnace annealing limits some next-generation polycrystalline silicon (poly-Si) on SiOx passivating contacts. This limitation largely affects p-type passivating contacts by not being able to: 1) control the dopant diffusion accurately to prevent B segregation at the SiOx and c-Si interface; and 2) provide highly activated doping concentrations for low contact resistivity. In this contribution, we use a nanosecond excimer laser to examine the passivation quality and electrical performance of both B- and Ga-doped poly-Si/SiOx passivating contacts. The core of this method is to take advantage of the nonequilibrium nature of the anneal through rapid melting and recrystallizing the poly-Si in a short timescale and to achieve doping concentrations above the solid solubility limit. Simulations were performed on polished surfaces to visualize the doping diffusion profiles under different laser conditions, and secondary ion mass spectrometry (SIMS) was used to verify the experimental diffusion profiles post pulsed laser melting (PLM). The results show the dopant diffusion profiles can be tuned precisely through PLM. The electrical analysis using VdP-Hall measurements reveals that the active doping concentration reached 10^21 cm-3 for B and ~2×10^21 cm-3 for Ga in poly-Si, far exceeding their solid solubility limit in Si, with a nearly 100% dopant activation achieved for B, and 20% for Ga. This highly activated dopant profile results in a low contact resistivity of <15 mO·cm^2 for B-doped contacts and <40 mO·cm^2 for Ga-doped contacts. We demonstrate that the passivation quality of the laser annealed contacts shows a linear dependency with the laser energy density and the number of pulses. PLM was also performed on random pyramid textured samples, and we found that preferential melting exists for the tips of pyramids, which can be pursued further for selective pinhole opening. Additionally, we perform thermal stability tests of these hyperdoped passivating contacts and show that under certain laser conditions, the B-doped samples exhibit good thermal stability with near full activation for temperatures up to 800°C. Lastly, we transfer this technique to a larger area by overlapping laser spots and show uniform passivation quality and electrical performance. We are currently implementing this PLM annealed p-type passivating contacts into double-side back-junction poly-Si/SiOx passivating contact devices. Our results show that PLM can not only enable the next generation of high-efficiency c-Si photovoltaics technology but can also benefit the c-Si integrated circuit industry through hyperdoping other semiconductors with atoms that may otherwise have a low solubility.

doping diffusion profile↗
DOE OSTI2013

The Role of Gamma-ray Imaging in Performing Radiological Characterisation at the Magnox Storage Ponds at the Bradwell Decommissioning Site - 13628

A gamma-ray imaging device has been used to perform radiological characterisation work at the spent fuel ponds complex at the site of the Bradwell Magnox Power Station, which is currently undergoing accelerated decommissioning. The objective of using a gamma-ray imaging system was to independently verify previous radiological survey work and to evaluate the adequacy of the random distribution of the destructive core sampling which had been performed. In performing this work the gamma-ray imager clearly identified the exact locations of the sources of radiation that gave rise to the elevated gamma dose rates measured by conventional health physics surveys of the area. In addition, the gamma-ray imager was able to characterise each hotspot as being either dominated by Cs-137 or by Co-60. The gamma imaging survey was undertaken with a RadScan gamma imaging system deployed on the walkways which run along the lengths of the ponds; this enabled the whole imaging survey to be performed with minimal dose uptake, demonstrating the ALARP principle within decommissioning. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2023

Alkali element (Li, Na, K, and Rb) doping of Cu 2 BaGe 1– x Sn x Se 4 films

Cu 2 BaGe 1–x Sn x Se 4 (CBGTSe) represents an exemplary system within the I 2 –II–IV–X 4 (I = Ag, Cu; II = Sr, Ba; IV = Ge, Sn; X = S, Se) family, which has been introduced to target suppressing the formation of anti-site defects and associated defect clusters within the analogous kesterite Cu 2 ZnSn(S,Se) 4 . Previous studies on CBGTSe films showed relatively low hole carrier densities (<10 13 cm –3 ), which may limit their corresponding application as active layers within photovoltaic, thermoelectric, and optoelectronic devices. In the current study, we explore the incorporation of alkali elements (Li, Na, K, and Rb) into CBGTSe films as prospective dopants to address the low hole carrier density and to allow for property tunability. First, incorporation of Na-, K-, and Rb-dopants noticeably increases the average grain sizes for CBGTSe films, while the Li-dopant has relatively limited impact. In addition, the alkali-dopants lead to a 1 to 3 orders of magnitude increase in hole carrier density (up to 10 15 cm –3 is achieved using K doping, corresponding to the alkali element yielding the highest doping efficiency). Here, the alkali-doped films show slightly lower minority carrier lifetimes and carrier mobility values than the non-doped samples, and these values are found to follow an approximate universal dependence with carrier density (also considering data derived from other previously explored vacuum-deposited I 2 –II–IV–X 4 chalcogenide films). As alkali-doping can significantly increase carrier densities, alkali elements can be considered useful p-type dopants for CBGTSe, as well as prospectively for other analogous I 2 –II–IV–X 4 systems.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Distinct Composition‐Dependent Topological Hall Effect in Mn 2‐x Zn x Sb

Abstract Spintronics, an evolving interdisciplinary field at the intersection of magnetism and electronics, explores innovative applications of electron charge and spin properties for advanced electronic devices. The topological Hall effect (THE), a key component in spintronics, has gained significance due to emerging theories surrounding noncoplanar chiral spin textures. This study focuses on Mn 2‐x Zn x Sb, a material crystalizing in centrosymmetric space group with rich magnetic phases tunable by Zn contents. Through comprehensive magnetic and transport characterizations, we found that the high‐Zn ( x > 0.6) samples display THE which is enhanced with decreasing temperature, while THE in the low‐Zn ( x < 0.6) samples show an opposite trend. The coexistence of those distinct temperature dependencies for THE suggests very different magnetic interactions/structures for different compositions and underscores the strong coupling between magnetism and transport in Mn 2‐x Zn x Sb. The findings contribute to understanding topological magnetism in centrosymmetric tetragonal lattices, establishing Mn 2‐x Zn x Sb as a unique platform for exploring tunable transport effects and opening avenues for further exploration in the realm of spintronics.

Nabi, Md Rafique Un↗
DOE OSTI2013

Solvothermal synthesis of CeF{sub 3}: Er{sup 3+}, Yb{sup 3+} nanoplates with visible upconversion luminescence by 980 nm excitation

Graphical abstract: The visible upconversion emission including blue emission (487 nm), green emissions (523 nm, 546 nm) and red emission (654 nm) of Er{sup 3+}, Yb{sup 3+} in CeF{sub 3} nanoplates was observed under 980 nm excitation. The emission intensity increases remarkably with the increase of Er{sup 3+} content from x = 0.001 to 0.02 and then decreases obviously with the increase of Er{sup 3+} content ranging from x = 0.02 to 0.25. Highlights: ► CeF{sub 3}: Er{sup 3+}, Yb{sup 3+} nanoplates have been successfully synthesized by a solvothermal method with further calcinations. ► The visible upconversion emission of Er{sup 3+}, Yb{sup 3+} in CeF{sub 3} nanoplates was observed and never been reported before. ► The upconversion mechanisms of CeF{sub 3}: Er{sup 3+}, Yb{sup 3+} nanoplates have been investigated. -- Abstract: CeF{sub 3}: Er{sup 3+}, Yb{sup 3+} nanoplates have been successfully synthesized by a solvothermal method with further calcinations. The crystalline phase, size and optical properties were characterized using powder X-ray diffraction (XRD), field emission-scanning electron microscopy (FE-SEM), X-ray photoelectron spectroscopy (XPS), energy dispersive spectroscopy (EDS) and upconversion luminescence (UCL). All the as-prepared samples showed blue emission (487 nm), green emissions (523 nm, 546 nm) and red emission (654 nm) under 980 nm excitation. The main mechanism of upconversion is attributed to the energy transfer (ET) among Yb{sup 3+} and Er{sup 3+} ions in excited states. The results illustrate the large potential of this new class of material for photonic applications involving optoelectronics devices.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

A 0.2–2 GHz Time-Interleaved Multistage Switched-Capacitor Delay Element Achieving 2.55–448.6 ns Programmable Delay Range and 330 ns/mm 2 Area Efficiency

Simulation of radar returns, full-duplex systems, and signal repeaters require hundreds of ns of programmable broadband radio frequency (RF) delay in the signal path to simulate large distances in the case of radar returns, for signal cancellation in full-duplex, and for isolation from reflections in signal repeaters. However, programmable broadband RF delay has been limited to ones of ns due to challenges in miniaturization with low loss and low power consumption. In this work, we present a 0.2–2 GHz digitally programmable RF delay element based on a time-interleaved multistage switched-capacitor (TIMS-SC) approach. The proposed approach enables hundreds of ns of broadband RF delay by employing sample time expansion in multiple stages of switched-capacitor storage elements. Further, the delay element was implemented in a 45 nm SOI CMOS process and achieves a 2.55–448.6 ns programmable delay range with < 0.12% delay variation across 1.8 GHz of bandwidth at maximum delay, 2.42 ns programmable delay steps, and 330 ns/mm 2 area efficiency. Through the proposed approach, the device shows minimal delay change across a -40 °C to 85 °C temperature range and < 0.25 dB gain variation across delay settings. The device achieves 26 dB gain, 7.4 dB noise figure, and consumes 74 mW from a 1 V supply with an active area of 1.36 mm 2 .

42 ENGINEERING↗
DOE OSTI2014

Parylene C Aging Studies

Parylene C is used in a device because of its conformable deposition and other advantages. Techniques to study Parylene C aging were developed, and "lessons learned" that could be utilized for future studies are the result of this initial study. Differential Scanning Calorimetry yielded temperature ranges for Parylene C aging as well as post-deposition treatment. Post-deposition techniques are suggested to improve Parylene C performance. Sample preparation was critical to aging regimen. Short-term (%7E40 days) aging experiments with free standing and ceramic-supported Parylene C films highlighted "lessons learned" which stressed further investigations in order to refine sample preparation (film thickness, single sided uniform coating, machine versus laser cutting, annealing time, temperature) and testing issues ("necking") for robust accelerated aging of Parylene C.

Achyuthan, Komandoor↗
DOE OSTI2018

FY2018 Report on Fission Chamber Development at LANL

This report provides a description of a subset of FY18 activities conducted by Los Alamos National Laboratory (LANL) as part of the Nuclear Physics: Cumulative Fission Product Yields (Fission R-values) task of the NA-22 sponsored F2016 Venture Project. Specifically, this report describes the design, fabrication and testing of the Mark II fission chamber that was fielded as part of fission R-value measurements on the Flattop critical assembly located at the National Criticality Experiments Research Center (NCERC). Historically, fission product R-value measurements were performed by chemical separation and beta counting of samples from carefully controlled fission chamber experiments. These measurements form the basis for reporting data used in debris diagnostics and subsequent modeling. It was also the means to extract absolute cumulative fission product yields (yield per fission or $Y_i/f$ for the $i_{th}$ fission product) that are included in the international nuclear data libraries, and ultimately used in diagnostic evaluations and device modeling. The challenge for this effort was to design a functional fission chamber given the harsh neutron and gamma fields and severe space limitations of the Flattop critical assembly.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗