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NASA NTRS1976

Laser plasmadynamic energy conversion

The generation of electrons ions by interacting an intense laser beam with cesium vapor is considered. Theoretical calculation shows that the conversion efficiency is as high as 40 percent if the entire photon energy is utilized in ionizing the cesium vapor that is generated initially by the incoming laser beam. An output voltage is expected to be generated across two electrodes, one of which is the liquid cesium, by keeping the other electrode at a different work function. Evaluation of the laser plasmadynamic (LPD) converter was performed using pulsed ruby and Nd-glass lasers. Although the results obtained to date indicate an efficiency smaller than that of theoretical predictions, an unoptimized LPD converter did demonstrate the capability of converting laser energy at large power levels. The limitations in the performance may by due to converter geometry, the types of lasers used, and other limitations inherent to the cesium plasma.

Shimada, K.↗

NASA NTRS1977

Thermal energy storage heat exchanger: Molten salt heat exchanger design for utility power plants

The use of thermal energy storage (TES) in the latent heat of molten salts as a means of conserving fossil fuels and lowering the cost of electric power was evaluated. Public utility systems provided electric power on demand. This demand is generally maximum during late weekday afternoons, with considerably lower overnight and weekend loads. Typically, the average demand is only 60% to 80% of peak load. As peak load increases, the present practice is to purchase power from other grid facilities or to bring older less efficient fossil-fuel plants on line which increase the cost of electric power. The widespread use of oil-fired boilers, gas turbine and diesel equipment to meet peaking loads depletes our oil-based energy resources. Heat exchangers utilizing molten salts can be used to level the energy consumption curve. The study begins with a demand analysis and the consideration of several existing modern fossil-fuel and nuclear power plants for use as models. Salts are evaluated for thermodynamic, economic, corrosive, and safety characteristics. Heat exchanger concepts are explored and heat exchanger designs are conceived. Finally, the economics of TES conversions in existing plants and new construction is analyzed. The study concluded that TES is feasible in electric power generation. Substantial data are presented for TES design, and reference material for further investigation of techniques is included.

Ferarra, A.↗

NASA NTRS2005

Making the Most of Waste Energy

The Thermo-Mechanical Systems Branch at NASA s Glenn Research Center is responsible for planning and conducting research efforts to advance thermal systems for space, aerospace, and non-aerospace applications. Technological areas pertain to solar and thermal energy conversion. For example, thermo-mechanical systems researchers work with gas (Stirling) and liquid/vapor (Rankine) systems that convert thermal energy to electrical power, as well as solar dynamic power systems that concentrate sunlight to electrical power. The branch s development of new solar and thermal energy technologies is propelling NASA s missions deep into unfamiliar territories of space. Solar dynamic power systems are actively improving the health of orbiting satellites, giving them longer life and a stronger radiation tolerance, thus, creating less need for on-orbit maintenance. For future missions, NASA may probe even deeper into the mysterious cosmos, with the adoption of highly efficient thermal energy converters that have the potential to serve as the source of onboard electrical power for satellites and spacecraft. Research indicates that these thermal converters can deliver up to 5 times as much power as radioisotope thermoelectric generators in use today, for the same amount of radioisotope. On Earth, energy-converting technologies associated with NASA s Thermo-Mechanical Systems Branch are being used to recover and transform low-temperature waste heat into usable electric power, with a helping hand from NASA.

Source record↗

NASA NTRS1975

Potassium topping cycles for stationary power

A design study was made of the potassium topping cycle powerplant for central station use. Initially, powerplant performance and economics were studied parametrically by using an existing steam plant as the bottom part of the cycle. Two distinct powerplants were identified which had good thermodynamic and economic performance. Conceptual designs were made of these two powerplants in the 1200 MWe size, and capital and operating costs were estimated for these powerplants. A technical evaluation of these plants was made including conservation of fuel resources, environmental impact, technology status, and degree of development risk. It is concluded that the potassium topping cycle could have a significant impact on national goals such as air and water pollution control and conservation of natural resources because of its higher energy conversion efficiency.

Rossbach, R. J.↗

DOE OSTI2024

Impact of Surface Enhanced Raman Spectroscopy in Catalysis

Catalysis stands as an indispensable cornerstone of modern society, underpinning the production of over 80% of manufactured goods and driving over 90% of industrial chemical processes. As the demand for more efficient and sustainable processes grows, better catalysts are needed. Understanding the working principles of catalysts is key, and over the last 50 years, surface-enhanced Raman Spectroscopy (SERS) has become essential. Discovered in 1974, SERS has evolved into a mature and powerful analytical tool, transforming the way in which we detect molecules across disciplines. In catalysis, SERS has enabled insights into dynamic surface phenomena, facilitating the monitoring of the catalyst structure, adsorbate interactions, and reaction kinetics at very high spatial and temporal resolutions. This review explores the achievements as well as the future potential of SERS in the field of catalysis and energy conversion, thereby highlighting its role in advancing these critical areas of research.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS1995

Pair cascades in extragalactic jets. 1: Gamma rays

A model of the approximately 0.1-10 GeV gamma-ray jets observed by the EGRET instrument on the Compton Gamma Ray Observatory (CGRO) is developed. It is shown that the soft X-ray background in an active galactic nuclei (AGN) contributes an opacity to pair production and that a gamma-ray photosphere or 'gamma-sphere' can be defined whose radius increases with gamma-ray energy E(sub gamma). It is proposed that the observed gamma-ray emission is due to inverse Compton scattering of the ambient soft X-rays by relativistic pairs accelerated in situ by shock fronts in a relativistic jet. For a wide range of assumed physical conditions, the emission at a given E(sub gamma) originates from near the associated gamma-spheres; emission from below the gamma-sphere initiates a cascade down to the energy where the gamma-rays can escape freely. In this model, the slope of the emergent gamma-ray spectrum is determined by the scattered, soft X-ray spectrum and the variation of the particle acceleration rate with jet radius. In general it is expected that the variation in the gamma-ray flux will be either slower or later at higher energy. It is also shown that the efficiency of conversion of energy from injected high-energy pairs to 0.1-10 GeV gamma-rays is typically high so that the models are radiatively efficient. It is argued that the observed gamma-ray jets are likely to be particle-dominated, though magnetically confined. The gamma-ray spectrum should continue down to an energy approximately 5 MeV emitted from an annihilation radius within which the pair content of the jet is limited by annihilation. This is probably the site of the beamed hard X-ray emission. It is speculated that the relativistic jets associated with radio-loud AGNs are powered electromagnetically by a spinning black hole and that they are collimated by an encircling MHD wind leaving the accretion disk at a slower speed. Powerful FR2 radio sources are formed when the hole spins rapidly and the relativistic core accelerates the MHD sheath; low-power FR1 sources ensue when the opposite occurs. Finally, it is suggested that the key factor which determines whether or not a given active nucleus can form a jet and a radio to gamma-ray nonthermal continuum is the central density of mass-losing stars which, when large, precludes the formation of a super-Alfvenic, collimating wind.

Blandford, R. D.↗

NASA NTRS2005

Feasibility Study of a Nuclear-Stirling Plant for the Jupiter Icy Moons Orbiter

NASA is undertaking the design of a new spacecraft to explore the planet Jupiter and its three moons Calisto, Ganymede and Europa. This proposed mission, known as Jupiter Icy Moons Orbiter (JIMO) would use a nuclear reactor and an associated electrical generation system (Reactor Power Plant-RPP) to provide power to the spacecraft. The JIMO spacecraft is envisioned to use this power for science and communications as well as Electric Propulsion (EP). Among other potential power-generating concepts, previous studies have considered Thermoelectric and Brayton Power conversion systems, coupled to a liquid metal reactor for the JIMO mission. This paper will explore trades in system mass and radiator area for a nuclear reactor power conversion system, however this study will focus on Stirling power conversion. The Stirling convertor modeled in this study is based upon the Component Test Power Convertor design that was designed and operated successfully under the Civil Space Technology Initiative for use with the SP-100 nuclear reactor i the 1980's and early 1990's. The study design is such that two of the four convertors would operate at any time to generate the 100 kWe while the others are held in reserve. For this study the Stirling convertors hot-side temperature is 1050 K, would operate at a temperature ratio of 2.4 for a minimum mass system and would have a system efficiency of 29%. The Stirling convertor would generate high voltage (400 volt), 100 Hz single phase AC that is supplied to the Power Management and Distribution system. The waste hear is removed from the Stirling convertors by a flowing liquid sodium-potassium eutectic and then rejected by a shared radiator. The radiator consists of two coplanar wings, which would be deployed after the reactor is in space. System trades were performed to vary cycle state point temperatures and convertor design as well as power output. Other redundancy combinations were considered to understand the affects of convertor size and number of spares to the system mass.

Schmitz, Paul C.↗

NASA NTRS1990

The FCRAO extragalactic CO survey: Global properties of galaxies

Since stars form in molecular clouds, a critical element in studies of galaxy evolution is knowledge of the molecular content of a large sample of galaxies. To this end, researchers undertook a survey of CO emission from galaxies using the Fire College Radio Astronomy Observatory (FCRAO) 14-m millimeter telescope at 115 GHz. The aim was to better understand the differences found among and within galaxies with regard to the efficiency of star and cloud formation. The galaxies observed as part of the FCRAO Extragalactic CO Survey were selected on the basis of their optical or infrared properties. The galaxies observed thus far are (1) brighter than B sub T (sub o)=12.5 in the blue, or (2) brighter than 20 Jy at 100 microns. From major axis CO observations at 45 seconds resolution and spacing in over 200 galaxies, researchers determined the CO radial distributions, and derived global CO fluxes (cf. Kenney and Young 1988); H2 masses were derived using the conversion factor N(H2)/I sub CO=2.8 times 10 to the 20th power cm(-2)/K km s(-1)) (Bloemen et al. 1986). Here, researchers concentrate on the global galaxy properties within the sample. Neutral hydrogen (HI) masses for the sample galaxies were taken from Huchtmeier et al. (1983), blue luminosities and morphological types were taken from RC2. IR luminosities, colors, dust temperatures and dust masses were determined from coadded Infrared Astronomy Satellite (IRAS) data (Young et al. 1989). They have chosen to first compare absolute luminosities and masses in order to determine the slope and scatter in each correlation; next they investigate luminosity independent ratios in order to intercompare large and small galaxies.

Young, J. S.↗

NASA NTRS1993

Pinatubo and pre-Pinatubo optical-depth spectra: Mauna Loa measurements, comparisons, inferred particle size distributions, radiative effects, and relationship to lidar data

The Ames airborne tracking sunphotometer was operated at the National Oceanic and Atmospheric Administration (NOAA) Mauna Loa Observatory (MLO) in 1991 and 1992 along with the NOAA Climate Monitoring and Diagnostics Laboratory (CMDL) automated tracking sunphotometer and lidar. June 1991 measurements provided calibrations, optical-depth spectra, and intercomparisons under relatively clean conditions; later measurements provided spectra and comparisons for the Pinatubo cloud plus calibration checks. June 1991 results are similar to previous MLO springtime measurements, with midvisible particle optical depth at the near-background level of 0.012 +/- 0.006 and no significant wavelength dependence in the measured range (lambda = 0.38 to 1.06 micrometers). The arrival of the Pinatubo cloud in July 1991 increased midvisible particle optical depth by more than an order of magnitude and changed the spectral shape of to an approximate power law with an exponent of about -1.4. By clearly September 1991, the spectrum was broadly peaked near 0.5 micrometers, and by July 1992, it was peaked near 0.8 micrometers. Our optical-depth spectra include corrections for diffuse light. NOAA- and Ames Research Center (ARC)-measured spectra are in good agreement. Columnar size distributions inverted from the spectra show that the initial (July 1991) post-Pinatubo cloud was relatively rich in small particles (r less than 0.25 micrometers), which were progressively depleted in the August-September 1991 and July 1992 periods. Conversely, both of the later periods had more of the optically efficient medium-sized particles (0.25 less than r less than 1 micrometers) than did the fresh July 1991 cloud. These changes are consistent with particle growth by condensation and coagulation. Photometer-inferred column backscatter values agree with those measured by the CMDL lidar on nearby nights. Combining lidar-measured backscatter profiles with photometer-derived backscatter-to-area ratios gives peak particle areas that could cause rapid heterogeneous loss of ozone, given sufficiently low particle acidity and suitable solar zenith angles (achieved at mid- to high latitudes). Top-of-troposphere radiative forcings for the September 1991 and July 1992 optical depths and size distributions over MLO are about -5 and -3 W/sq m, respectively (hence comparable in magnitude but opposite in sign to the radiative forcing caused by the increase in manmade greenhouse gases since the industrial revolution). Heating rates in the Pinatubo layer over MLO are 0.55 +/- 0.13 and 0.41 +/- 0.14 K/d for September 1991 and July 1992, respectively.

Russell, P. B.↗

NASA NTRS2016

Development of Filled-Skutterudite Based Thermopile for High Temperature Sensors for Space and Terrestrial Applications

The Thermal Energy Conversion Technologies Group at the Jet Propulsion Laboratory has been pursuing the development of thermopiles capable of higher temperature operation in support of terrestrial and space sensing applications in extreme environments. The next-generation sensor technology would rely on filled skutterudite (SKD) compounds, the same materials currently being considered for use in the enhanced Multi-Mission Radioisotope Thermoelectric Generator (eMMRTG). We report on the design, development and fabrication of SKD-based prototype thermopile devices. The beginning-of-life (BOL) experimental and predicted performance of the SKD-based prototype thermopile in terms of electrical resistance, output voltage, current, power output and efficiency in the 423 to 723 K operating temperature range is reported and discussed.

Smith, Kevin L.↗

DOE OSTI2025

EV Charging Infrastructure Energization An Overview of Approaches for Simplifying and Accelerating Timelines to Processing EV Charging Load Service Requests

The United States has seen significant growth in electric vehicle (EV) adoption, leading to increased demand for EV charging infrastructure. Over the past decade, EV charging infrastructure site developers, site hosts, and electric distribution utilities have navigated the process to integrate chargers onto the electric grid. Site developers and site hosts have raised the alarm that the integration process for high-powered EV charging projects does not meet the needs of the EV market for timeliness or cost. High-powered charging stations typically require a load service request or an agreement with the local utility to connect to the grid. The process of energizing a new high-powered charging site can be complex and time-consuming, often taking up to 2 years. This timeline is the result of current utility energization processes having been designed for construction projects that take longer to build (i.e., buildings). The specific challenges stem from various factors, including compartmentalization in application processes, the integration of EV charging process approvals with other distributed energy resources (DERs), and the need to ensure grid reliability. The energization process needs to evolve to meet the growing demand for high-powered EV charging. This white paper compiles information gathered through various conversations with key stakeholders, including utilities, utility regulators, EV charging operators, site developers, and authorities having jurisdiction (AHJ) as well as through an extensive literature review. This document identifies the challenges and provides potential solutions to streamline the process of connecting EV charging infrastructure to the power grid in the United States, serving as a starting point for future conversations around these solutions. The solutions noted in this white paper require collaborative efforts among utilities, regulators, and EV charging infrastructure developers to streamline the grid connection process for EV charging infrastructure. They are broadly organized into four areas: 1. Increase data access and transparency: Develop automated load service request tools, integrate hosting capacity and load service request analyses, incorporate EV adoption forecasts, and provide transparency on the processing queue. 2. Improve energization processes and timing: Create fast-track options based on prescreening criteria, provide flexibility or phased approvals in the load service request/interconnection process, build internal knowledge within utilities about EV charging technologies, and provide standardized workforce training. 3. Promote economic efficiency: Right size distribution components to accurately reflect the load requirements of EV charging infrastructure, make proactive investments in grid infrastructure based on EV adoption forecasts and growth projections, and consider energy equity and environmental justice factors such as equitable access to EV charging when planning infrastructure. 4. Improve grid reliability and resilience: Use load management/power control systems (PCS) at EV charging stations, adopt and implement harmonized standards for communication protocols and information models between the EV charging and grid control infrastructure, and address cybersecurity considerations by implementing robust security measures and standards for EV charging infrastructure—with particular emphasis on clarifying the security requirements for the interface to the grid. The objective of the solutions proposed in this white paper is to accelerate the timeline and decrease costs associated with connecting EV charging infrastructure to the grid. Electric utilities, utility regulators, EV charging infrastructure developers, and site hosts will first need to understand which solutions are available in their service territory, and if warranted, which combination of solutions would support their specific needs. Through the successful implementations of solutions at scale detailed here, industry will demonstrate a new and innovative ecosystem where timely deployment and energization of EV charging infrastructure with greater grid resiliency and reliability is a reality.

24 POWER TRANSMISSION AND DISTRIBUTION↗

DOE OSTI2026

FY25 Electric Grid Security Annual Report

Sandia’s Electric Grid Security program advances a national vision of energy dominance and accessibility, while applying our national security -emphasis on ensuring of a secure, resilient, and affordable electric system for all users. Our achievements reflect a strategic approach combining technology development; modeling, simulation, and data analytics; and partnered demonstrations and outreach to further the adoption of advanced grid and storage technologies. Our FY25 efforts leverage the strengths of our partnerships—spanning Sandia’s core science and technology competencies as well as external technology leaders—to develop the solutions today which enable the grid of tomorrow. Key accomplishments in this report that support our strategy span our technical program areas and include: • New open-source analytical tools for systems -level planning and optimization, including significant advances to the QuESt analytical environment; • Further advancement of artificial intelligence and machine learning to enhanced grid operations and planning as we rise to the challenge of new large loads; • Development of solid-state power conversion technologies and a new medium-voltage research lab; • New technologies to assess wildfire vulnerabilities and mitigate potential impacts; • Advanced applications of new cybersecurity technologies with industry partners; • Contributions to understanding the impacts of electromagnetic pulses and geomagnetic disturbances on grid components; and • Digital twin development for hybrid microgrids with multiple generators, storage, and loads. This report indicates key areas of research and engagement and summarizes the impact of Sandia’s contributions through notable accomplishments, journal publications, patents, and technical conferences and presentations. It is provided with the hope that readers discover ways we can further team to create our modern grid and apply the outcomes of our efforts. The bulk of work described herein is funded by several offices within the U.S. Department of Energy (USDOE), including the Office of Electricity (OE); Cybersecurity, Energy Security, and Emergency Response (CESER); former offices such as the Office of Energy Efficiency and Renewable Energy (EERE), the Grid Deployment Office (GDO), the Office of Clean Energy Demonstrations (OCED), and other key programs at USDOE. As we continue to state in these annual reports, the contributors to our successes are too numerous to name here, though our team wishes to express our deep gratitude to the numerous program and project sponsors at the US Department of Energy, who often function equally as technical collaborators; our many partners in industry, academia, utilities, and other national labs; and fellow researchers and business partners at Sandia whose leadership and creativity have enabled the accomplishments described herein.

24 POWER TRANSMISSION AND DISTRIBUTION↗

DOE OSTI2021

Fermi-type particle acceleration from magnetic reconnection at the termination shock of a relativistic striped wind

An oblique-rotating pulsar generates a relativistic striped wind in a pulsar wind nebula (PWN). The termination shock of the PWN compresses the Poynting-flux-dominated flow and drives magnetic reconnection. By carrying out particle-in-cell simulations of the termination shock of the PWN, we study the shock structure as well as the energy conversion processes and particle acceleration mechanisms. With the recent advances in the numerical methods, we extend the simulations to the ultrarelativistic regime with a bulk Lorentz factor of up to γ 0 = 10 6 . Magnetic reconnection at the termination shock is highly efficient at converting magnetic energy to particle kinetic energy and accelerating particles to high energies. Similar to earlier studies, we find that the resulting energy spectra crucially depend on λ/d e (λ is the wavelength of the striped wind and de is the relativistic plasma skin depth). When λ/d e is large (λ ≳ 40d e ), the downstream particle spectra form a power-law distribution in the magnetically dominated relativistic wind regime. By analyzing particle trajectories and statistical quantities relevant to particle energization, we find that Fermi-type mechanism dominates the particle acceleration and power-law formation. We find that the results for particle acceleration are scalable as γ 0 and σ 0 increase to large values. The maximum energy for electrons and positrons can reach hundreds of TeV if the wind has a bulk Lorentz factor of γ0 ≈ 106 and a magnetization parameter of σ 0 = 10, which can explain the recent observations of high-energy gamma rays from PWNe

79 ASTRONOMY AND ASTROPHYSICS↗

NASA NTRS1976

System studies of coal fired-closed cycle MHD for central station power plants

This paper presents a discussion of the closed cycle MHD results obtained in a recent study of various advanced energy conversion (ECAS) power systems. The study was part of the first phase of this ECAS study. Since this was the first opportunity to evaluate the coal fired closed cycle MHD system, a number of iterations were required to partially optimize the system. The present paper deals with the latter part of the study in which the direct coal fired, MHD topping-steam bottoming cycle was established as the current choice for central station power generation. The emphasis of the paper is on the background assumptions and the conclusions that can be drawn from the closed cycle MHD analysis. The author concludes that closed cycle MHD has efficiencies comparable to that of open cycle MHD and that both systems are considerably more efficient than the other system studies in Phase 1 of the GE ECAS. Its cost will possibly be slightly higher than that of the open cycle MHD system. Also, with reasonable fuel escalation assumptions, both systems can produce lower cost electricity than conventional steam power plants. Suggestions for further work in closed cycle MHD components and systems is made.

Zauderer, B.↗

NASA NTRS1993

Power Conditioning System Modelling for Nuclear Electric Propulsion

NASA LeRC is currently developing a Fortran based model of a complete nuclear electric propulsion (NEP) vehicle that would be used for piloted and cargo missions to the Moon or Mars. The proposed vehicle design will use either a Brayton or K-Rankine power conversion cycle to drive a turbine coupled with a rotary alternator. Two thruster types are also being studied, ion and magnetoplasmadynamic (MPD). In support of this NEP model, Rocketdyne developed a power management and distribution (PMAD) subroutine that provides parametric outputs for selected alternator operating voltages and frequencies, thruster types, system power levels, and electronics coldplate temperatures. The end-to-end PMAD model described is based on the direct use of the alternator voltage and frequency for transmitting power to either ion or MPD thrusters. This low frequency transmission approach was compared with dc and high frequency ac designs, and determined to have the lowest mass, highest efficiency, highest reliability and lowest development costs. While its power quality is not as good as that provided by a high frequency system, it was considered adequate for both ion and MPD engine applications. The low frequency architecture will be used as the reference in future NEP PMAD studies.

Metcalf, Kenneth J.↗

NASA NTRS1994

Review of solar cell temperature coefficients for space

Energy conversion efficiency is an important parameter for solar cells, and well reported in the literature. However, solar cells heat up in sunlight, and the efficiency decreases. The temperature coefficient of the conversion efficiency is thus also extremely important, especially in mission modeling, but is much less well reported. It is of value to have a table which compiles into a single document values of temperature coefficients reported in the literature. In addition to modeling performance of solar cells in Earth orbit, where operating temperatures may range from about 20 C to as high as 85 C, it is of interest to model solar cells for several other recently proposed missions. These include use for the surface of Mars, for solar electric propulsion missions that may range from Venus to the Asteroid belt, and for laser-photovoltaic power that may involve laser intensities equivalent several suns. For all of these applications, variations in operating temperature away from the nominal test conditions result in significant changes in operating performance. In general the efficiency change with temperature is non-linear, however, in the range from negative 100 C through room temperature to a few hundred degrees C, efficiency is usually quite well modeled as a linear function of temperature (except for a few unusual cell types, such as amorphous silicon, and for extremely low bandgap cells, such as InGaAs).

Landis, Geoffrey A.↗

DOE OSTI2024

A Reactor Scale-Up Methodology from Lab-Scale to Pilot-Scale Operations: Numerical Modeling of THFA Dehydration to DHP in Packed-Bed Reactors

This manuscript discusses developing a model-based scale-up methodology for a successful technology transfer of gas-phase catalytic reactors from a lab-scale to a pilot-scale operation. The manuscript demonstrates the methodology for gas-phase dehydration of tetrahydrofurfuryl alcohol (THFA) to dihydropyran (DHP) process over commercial Al 2 O 3 catalysts. A two-dimensional reactor model was developed using COMSOL Multiphysics 6.1 software. The model solves heat and mass transport equations in bed-scale and particle scales simultaneously. This powerful feature enables accurate prediction of the heat and mass transfer limitations in pilot-scale reactors, if any exists. Further, the model uses isothermal lab-scale experimental data to derive and validate the reaction chemistry, flow fields and boundary conditions. The model was then scaled-up to project conversion, selectivity, yield and formation rate of DHP in a pilot-scale reactor. The results highlight the complex nature of chemistry, heat, and mass transfer effects in lab-scale and pilot-scale reactors. The model results inform the possible operational limitations of the pilot-scale reactor and design strategies to improve process efficiency. Although the scale-up approach is explained through the THFA dehydration process, the methodology is applicable to any catalytic packed-bed reactor models for a successful process scale-up.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2021

Charge-spin interconversion in epitaxial Pt probed by spin-orbit torques in a magnetic insulator

We measure spin-orbit torques (SOTs) in a model system of all-epitaxial ferrite/Pt bilayers to gain insights into charge-spin interconversion in Pt. With negligible electronic conduction in the insulating ferrite, the crystalline Pt film acts as the sole source of charge-to-spin conversion. A small fieldlike SOT independent of Pt thickness suggests a weak Rashba-Edelstein effect at the ferrite/Pt interface. By contrast, we observe a sizable dampinglike SOT that depends on the Pt thickness, from which we deduce the dominance of an extrinsic spin-Hall effect (skew scattering) and Dyakonov-Perel spin relaxation in the crystalline Pt film. Furthermore, our results point to a large internal spin-Hall ratio of ≈ 0.8 in epitaxial Pt. Furthermore, our experimental work takes an essential step towards understanding the mechanisms of charge-spin interconversion and SOTs in Pt-based heterostructures, which are crucial for power-efficient spintronic devices.

36 MATERIALS SCIENCE↗