Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Phase evolution”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,693 records · Page 94
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Magnetic ground states of honeycomb lattice Wigner crystals

Lattice Wigner crystal states stabilized by long-range Coulomb interactions have recently been realized in two-dimensional moiré materials. We employ large-scale unrestricted Hartree-Fock techniques to unveil the magnetic phase diagrams of honeycomb lattice Wigner crystals. For the three lattice filling factors with the largest charge gaps, $n=2/3,1/2,1/3$, the magnetic phase diagrams contain multiple phases, including ones with non-collinear and non-coplanar spin arrangements. We discuss magnetization evolution with external magnetic field, which has potential as an experimental signature of exotic spin states. Our theoretical results could potentially be validated in moiré materials formed from group VI transition metal dichalcogenide twisted homobilayers.

36 MATERIALS SCIENCE↗
DOE OSTI2026

Kinetic-controlled transformations of group-III arsenide nanocubes

Tracking the structural evolution of colloidal nanocrystals (NCs) facilitates the mechanistic studies of their materials chemistry. NC engineering via phase transformation reveals the chemical and physical determinants that drive lattice-scale dynamic processes such as cation exchange. Here, in this study, we employed NCs to demonstrate the cation exchange process from Cu 3 As to InAs and GaAs within nanocubes. The symmetry conversion in unit cells from cubic Cu 3 As to hexagonal InAs and GaAs can be described using a schematic cellular automaton model, which suggests a simplified cube-to-sphere transition. The strong covalent characteristics of III–V materials highlight the kinetic control that navigates the tailorable transformation through either an isotropic trajectory, leading to hollow structures, or a topotaxial trajectory, with abundant stacking faults. The reconstruction of complex covalent bonds is envisioned as the foundation for the synthesis of NCs.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2021

TOI-431/HIP 26013: a super-Earth and a sub-Neptune transiting a bright, early K dwarf, with a third RV planet

ABSTRACT We present the bright (Vmag = 9.12), multiplanet system TOI-431, characterized with photometry and radial velocities (RVs). We estimate the stellar rotation period to be 30.5 ± 0.7 d using archival photometry and RVs. Transiting Exoplanet Survey Satellite (TESS) objects of Interest (TOI)-431 b is a super-Earth with a period of 0.49 d, a radius of 1.28 ± 0.04 R⊕, a mass of 3.07 ± 0.35 M⊕, and a density of 8.0 ± 1.0 g cm−3; TOI-431 d is a sub-Neptune with a period of 12.46 d, a radius of 3.29 ± 0.09 R⊕, a mass of $9.90^{+1.53}_{-1.49}$ M⊕, and a density of 1.36 ± 0.25 g cm−3. We find a third planet, TOI-431 c, in the High Accuracy Radial velocity Planet Searcher RV data, but it is not seen to transit in the TESS light curves. It has an Msin i of $2.83^{+0.41}_{-0.34}$ M⊕, and a period of 4.85 d. TOI-431 d likely has an extended atmosphere and is one of the most well-suited TESS discoveries for atmospheric characterization, while the super-Earth TOI-431 b may be a stripped core. These planets straddle the radius gap, presenting an interesting case-study for atmospheric evolution, and TOI-431 b is a prime TESS discovery for the study of rocky planet phase curves.

Osborn, Ares↗
DOE OSTI2021

Anomalous strain-energy-driven macroscale translation of grains during nonisothermal annealing

We report a mode of grain growth, involving the macroscopic translation of grain centers during nonisothermal annealing. Through synchrotron high-energy x-ray diffraction microscopy, we find dissolution of semicoherent precipitates generates dislocations, thereby raising the stored strain energy within grains. Here, the subsequent evolution of grains shows unexpected grain translations over length scales of 10-100 mu m. Phase-field simulations reveal that such translations are not uncommon in strain-energy-driven grain growth, wherein different regions of a grain may grow and shrink simultaneously.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Ultrafast electron diffraction: Visualizing dynamic states of matter

Since the discovery of electron-wave duality, electron scattering instrumentation has developed into a powerful array of techniques for revealing the atomic structure of matter. Beyond detecting local lattice variations in equilibrium structures with the highest possible spatial resolution, recent research efforts have been directed toward the long-sought-after dream of visualizing the dynamic evolution of matter in real time. The atomic behavior at ultrafast timescales carries critical information on phase transition and chemical reaction dynamics, the coupling of electronic and nuclear degrees of freedom in materials and molecules, and the correlation among structure, function, and previously hidden metastable or nonequilibrium states of matter. Ultrafast electron pulses play an essential role in this scientific endeavor, and their generation has been facilitated by rapid technical advances in both ultrafast laser and particle accelerator technologies. Here this review presents a summary of the noteworthy developments in this field in the last few decades. The physics and technology of ultrafast electron beams is presented with an emphasis on the figures of merit most relevant for ultrafast electron diffraction experiments. Recent developments in the generation, manipulation, and characterization of ultrashort electron beams aimed at improving the combined spatiotemporal resolution of these measurements are discussed. The fundamentals of electron scattering from atomic matter and the theoretical frameworks for retrieving dynamic structural information from solid-state and gas-phase samples is described. Essential experimental techniques and several landmark works that have applied these approaches are also highlighted to demonstrate the widening applicability of these methods. Ultrafast electron probes with ever-improving capabilities, combined with other complementary photon-based or spectroscopic approaches, hold tremendous potential for revolutionizing our ability to observe and understand energy and matter at atomic scales.

43 PARTICLE ACCELERATORS↗
DOE OSTI2021

Advanced Detection of Wellbore Failure for Safe and Secure Utilization of Subsurface Infrastructure

The main goal of this project was to create a state-of-the-art predictive capability that screens and identifies wellbores that are at the highest risk of catastrophic failure. This capability is critical to a host of subsurface applications, including gas storage, hydrocarbon extraction and storage, geothermal energy development, and waste disposal, which depend on seal integrity to meet U.S. energy demands in a safe and secure manner. In addition to the screening tool, this project also developed several other supporting capabilities to help understand fundamental processes involved in wellbore failure. This included novel experimental methods to characterize permeability and porosity evolution during compressive failure of cement, as well as methods and capabilities for understanding two-phase flow in damaged wellbore systems, and novel fracture-resistant cements made from recycled fibers.

36 MATERIALS SCIENCE↗
DOE OSTI2023

ACE: Proton beam upgrade plan at Fermilab

aFor Snowmass and P5, Fermilab recently proposed a new upgrade plan known as Accelerator Complex Evolution (ACE) to occur after PIP-II upgrade in tandem with DUNE/LBNF operation. The first phase of ACE, ACE-MIRT, is the ACE Main Injector Ramp and Targetry upgrade, which would raise the LBNF beam power from 1.2 MW to 2 MW by shortening the Main Injector cycle time to around 0.65s. The second phase of ACE, AC-BR, is the ACE Booster Replacement, which would replace the Booster with a new machine and achieve 2.4 MW for DUNE/LBNF. The implications for the Fermilab neutrino program and future experiments hosted at Fermilab will be discussed.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2024

Accelerator challenges in the Fermilab Neutrino Program

In Fermilab's 2022-2023 proton complex run, Fermilab recovered from an unexpected failure in the neutrino focusing horn to achieve a record beam power of 960 kW. For Snowmass and P5, Fermilab recently proposed a new upgrade plan known as Accelerator Complex Evolution (ACE) to occur after PIP-II upgrade in tandem with DUNE/LBNF operation. The first phase of ACE, is the ACE Main Injector Ramp and Targetry upgrade, would raise the LBNF beam power from 1.2 MW to 2 MW by shortening the Main Injector cycle time to around 0.65s. The second phase of ACE, the ACE Booster Replacement, would replace the Booster with a new machine and achieve 2.4 MW for DUNE/LBNF. The core accelerator challenges, present and future, for operating intense neutrino beams at Fermilab will be highlighted.

43 PARTICLE ACCELERATORS↗
DOE OSTI2022

The Open Cluster Chemical Abundances and Mapping Survey. VII. APOGEE DR17 [C/N]–Age Calibration

Large-scale surveys open the possibility to investigate Galactic evolution both chemically and kinematically; however, reliable stellar ages remain a major challenge. Detailed chemical information provided by high-resolution spectroscopic surveys of the stars in clusters can be used as a means to calibrate recently developed chemical tools for age-dating field stars. Using data from the Open Cluster Abundances and Mapping survey, based on the Sloan Digital Sky Survey/Apache Point Observatory Galactic Evolution Experiment 2 survey, we derive a new empirical relationship between open cluster stellar ages and the carbon-to-nitrogen ([C/N]) abundance ratios for evolved stars, primarily those on the red giant branch. With this calibration, [C/N] can be used as a chemical clock for evolved field stars to investigate the formation and evolution of different parts of our Galaxy. We explore how mixing effects at different stellar evolutionary phases, like the red clump, affect the derived calibration. We have established the [C/N]–age calibration for APOGEE Data Release 17 (DR17) giant star abundances to be $\mathrm{log}{[\mathrm{Age}(\mathrm{yr})]}_{\mathrm{DR}17}=10.14\,(\pm 0.08)+2.23(\pm 0.19)\,[{\rm{C}}/{\rm{N}}]$, usable for $8.62\leqslant \mathrm{log}(\mathrm{Age}[\mathrm{yr}])\leqslant 9.82$, derived from a uniform sample of 49 clusters observed as part of APOGEE DR17 applicable primarily to metal-rich, thin- and thick-disk giant stars. This measured [C/N]–age APOGEE DR17 calibration is also shown to be consistent with asteroseismic ages derived from Kepler photometry.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2021

Distant Relatives: The Chemical Homogeneity of Comoving Pairs Identified in Gaia

Comoving pairs, even at the separations of $\mathcal{O}$(10 6 ) are a predicted reservoir of conatal stars. Here we present detailed chemical abundances of 62 stars in 31 comoving pairs with separations of 10 2 –10 7 au and 3D velocity differences <2 km s -1 . This sample includes both bound comoving pairs/wide binaries and unbound comoving pairs. Observations were taken using the Magellan Inamori Kyocera Echelle (MIKE) spectrograph on board the Magellan/Clay Telescope at high resolution (R~ 45,000) with a typical signal-to-noise ratio of 150 pixel -1 . With these spectra, we measure surface abundances for 24 elements, including Li, C, Na, Mg, Al, Si, Ca, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Sr, Y, Zr, Ba, La, Nd, and Eu. Taking iron as the representative element, our sample of wide binaries is chemically homogeneous at the level of 0.05 dex, which agrees with prior studies on wide binaries. Importantly, even systems at separations 2 × 10 5 –10 7 au are homogeneous to 0.09 dex, as opposed to the random pairs, which have a dispersion of 0.23 dex. Assuming a mixture model of the wide binaries and random pairs, we find that 73 ± 22% of the comoving pairs at separations 2 × 10 5 –10 7 au are conatal. Our results imply that a much larger parameter space of phase space may be used to find conatal stars, to study M-dwarfs, star cluster evolution, exoplanets, chemical tagging, and beyond.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1973

A pilot level decision analysis of thermionic reactor development strategy for nuclear electric propulsion

The development policy for thermionic reactors to provide electric propulsion and power for space exploration was analyzed to develop a logical procedure for selecting development alternatives that reflect the technical feasibility, JPL/NASA project objectives, and the economic environment of the project. The partial evolution of a decision model from the underlying philosophy of decision analysis to a deterministic pilot phase is presented, and the general manner in which this decision model can be employed to examine propulsion development alternatives is illustrated.

Menke, M. M.↗
NASA NTRS1978

Thermal control of low-pressure fractionation processes

Thermal models detailing the solidification paths for shallow basaltic magma chambers (both open and closed systems) were calculated using finite-difference techniques. The total solidification time for closed chambers are comparable to previously published calculations; however, the temperature-time paths are not. These paths are dependent on the phase relations and the crystallinity of the system, because both affect the manner in which the latent heat of crystallization is distributed. In open systems, where a chamber would be periodically replenished with additional parental liquid, calculations indicate that the possibility is strong that a steady-state temperature interval is achieved near a major phase boundary. In these cases it is straightforward to analyze fractionation models of the basaltic liquid evolution and their corresponding cumulate sequences. This steady thermal fractionating state can be invoked to explain large amounts of erupted basalts of similar composition over long time periods from the same volcanic center and some rhythmically layered basic cumulate sequences.

Usselman, T. M.↗
NASA NTRS1979

Solitary waves in stratified shear flows

An analysis is described of long, finite-amplitude internal waves in a stratified shear flow. Both regular and singular modes are considered with a nonlinear critical layer employed in the latter case. A three-layer model is used to develop the theory and closed-form expressions are obtained relating the phase speed to the Richardson number, the latter quantity being taken as O(1). The amplitude evolution equation is found to be either the Korteweg-de Vries equation or the Benjamin-Davis-Ono equation depending upon the distance of the more remote boundary from the edge of the shear layer.

Maslowe, S. A.↗
NASA NTRS1986

The effect of beam-driven return current instability on solar hard X-ray bursts

The problem of electrostatic wave generation by a return current driven by a small area electron beam during solar hard X-ray bursts is discussed. The marginal stability method is used to solve numerically the electron and ion heating equations for a prescribed beam current evolution. When ion-acoustic waves are considered, the method appears satisfactory and, following an initial phase of Coulomb resistivity in which T sub e/T sub i rise, predicts a rapid heating of substantial plasma volumes by anomalous ohmic dissipation. This hot plasma emits so much thermal bremsstrahlung that, contrary to previous expectations, the unstable beam-plasma system actually emits more hard X-rays than does the beam in the purely collisional thick target regime relevant to larger injection areas. Inclusion of ion-cyclotron waves results in ion-acoustic wave onset at lower T sub e/T sub i and a marginal stability treatment yields unphysical results.

Cromwell, D.↗
NASA NTRS1987

Analytical electron microscopy of fine-grained phases in primitive interplanetary dust particles and carbonaceous chondrites

In order to describe the total mineralogical diversity within primitive extraterrestrial materials, individual interplanetary dust particles (IDPs) collected from the stratosphere as part of the JSC Cosmic Dust Curatorial Program were analyzed using a variety of AEM techniques. Identification of over 250 individual grains within one chondritic porous (CP) IDP shows that most phases could be formed by low temperature processes and that heating of the IDP during atmospheric entry is minimal and less than 600 C. In a review of the mineralogy of IDPs, it was suggested that the occurrence of other silicates such as enstatite whiskers is consistent with the formation in an early turbulent period of the solar nebula. Experimental confirmation of fundamental chemical and physical processes in a stellar environment, such as vapor phase condensation, nucleation, and growth by annealing, is an important aspect of astrophysical models for the evolution of the Solar System. A detailed comparison of chondritic IDP and carbonaceous chondrite mineralogies shows significant differences between the types of silicate minerals as well as the predominant oxides.

Mackinnon, Ian D. R.↗
NASA NTRS1987

The effects of stimulated star formation on the evolution of the galaxy. III - The chemical evolution of nonlinear systems

The evolution of models for star formation in galaxies with disk and halo components is discussed. Two phases for the halo (gas and stars) and three for the disk (including clouds) are used in these calculations. The star-formation history is followed using nonlinear phase-coupling models which completely determine the populations of the phases as a function of time. It is shown that for a wide range of parameters, including the effects of both spontaneous and stimulated star formation and mass exchange between the spatial components of the system, the observed chemical history of the galaxy can easily be obtained. The most sensitive parameter in the detailed metallicity and star-formation history for the system is the rate of return of gas to the diffuse phase upon stellar death.

Shore, Steven N.↗
NASA NTRS1988

Mg II line profiles of the Mira S Carinae

High-dispersion IUE observations obtained to investigate the evolution of the shock structure of the Mira S Carinae (S Car) produced, despite very limited phase coverage, a set of five spectra of the Mg II h and k lines. There is significant emission from both the h and k lines at velocities of -150 km/sec relative to the stellar photosphere. The h-to-k ratio of the Mg II doublet remains below the theoretically predicated values of 2:1 to 1:1, and shows a smooth dependence on the optical phase. Archival studies of other Miras (e.g., R Car) indicate that S Car is not unique in possessing unusual and highly variable Mg II h and k line profiles.

Brugel, Edward W.↗
NASA NTRS1989

Multiple coherent mode interaction in a developing round jet

The integral energy method has been used in order to study the nonlinear interactions of the large-scale coherent structure in a spatially developing round jet. The streamwise development of a jet is obtained in terms of the mean flow shear layer momentum thickness, the wave mode kinetic energy and the wave mode phase angle. It is shown that the nonlinear interaction between wave modes is dependent on the wave mode phase angles. The initial wave mode phase angles as well as the initial energy densities play a significant role in the streamwise evolution of the large-scale coherent wave modes and the mean flow.

Lee, S. S.↗