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At least 1,693 records · Page 94

Significance of large-scale circulation in magnetic storm characteristics with application to AE-C neutral composition data

Theoretical analysis of a magnetic storm in February 1974 leads to the following conclusions: (1) Wind-induced diffusion leads to depletion of O and He and enhancements of Ar at high latitudes. (2) The same process increases O and He and decreases Ar at low latitudes. (3) There is substantial agreement between theory and neutral composition data from the AE-C closed source neutral mass spectrometer; the low-latitude enhancements of O and He, in magnitude comparable to or even larger than those of N2 and Ar, are observed, which is characteristic for the circulation mechanism. (4) To achieve agreement with the composition measurements, a heat input rate of 1.7 ergs/sq cm s is required above 120 km. (5) Changes in the neutral composition associated with the annual variations have significant effects on the magnetic storm dynamics.

Mayr, H. G.↗

Intercomparison of neutral composition measurements from the satellite Esro 4, Aeros A, Aeros B, and Atmosphere Explorer C

Number-density data obtained at orbital 'crossover' points with the neutral-gas mass spectrometers aboard the Esro 4, Aeros A, AE-C, and Aeros B satellites are intercompared. All the mass spectrometers were designed to measure the ambient number densities of atomic oxygen, molecular nitrogen, helium, and argon. It is found that the agreement for N2 and O is satisfactory within the experimental errors and that the He measurements exhibit unexpectedly large discrepancies far outside the error range. Calibration and instrument sources of error are considered.

Trinks, H.↗

Distribution functions for energetic oxygen atoms in the earth's lower atmosphere

Direct photolysis of O3 and quenching of O(1D) by N2 provide abundant sources of fast oxygen atoms for earth's lower atmosphere. The concentration of atoms with energy above 0.7 eV may exceed the concentration of O(1D) for all altitudes below 18 km, and these atoms may play an important role in lower-atmospheric chemistry. Distribution functions for O(3P) are given for the energy interval 0.1-1.3 eV and a range of altitudes from 0 to 62 km.

Logan, J. A.↗

On the sources of ultraviolet absorption in spectra of Titan and the outer planets

In response to observations of the ultraviolet deficiencies shown by all of the outer planets and Titan, models have been proposed to explain the low albedos in terms of absorption by particles in the upper atmospheres of these objects. These particles are generally believed to be photochemically formed from gases in the upper atmospheres, primarily methane and hydrogen. Such processes may also be operative on Titan. Results of some laboratory experiments on proton irradiation of mixtures of gases including CH4, H2, and NH3 have shown that liquid and solid materials are produced that are strong ultraviolet absorbers. However, the material produced from the CH4 + H2 mixture was colorless, indicating that species containing elements other than carbon and hydrogen are necessary for the production of color. Two such elements are nitrogen (as NH3 or N2) and sulfur (as H2S); colored materials have been produced from such mixtures. None of these materials has spectral properties identical to those shown by the planets. Therefore it is necessary that mixtures (and/or cloud layers) of the photochemical materials be present.

Scattergood, T.↗

Angular distribution of photoelectrons at 584 A using polarized radiation

Photoelectron angular distributions for Ar, Xe, N2, O2, CO, CO2, and NH3 have been obtained at 584 A by observing the photoelectrons at a fixed angle and simply rotating the plane of polarization of a highly polarized photon source. The radiation from a helium dc glow discharge source was polarized (84%) using a reflection type polarizer

Hancock, W. H.↗

Extension of pulmonary O2 tolerance in man at 2 ATA by intermittent O2 exposure

To study extension of O2 tolerance by interruption of hyperoxic exposure, five healthy volunteers were exposed to oxygen at 2 ATA on an intermittent schedule of 20 min breathing O2, alternating with 5 min on a normoxic N2-O2 mixture. The cycle was repeated until symptoms or signs of O2 toxicity caused cessation of the experiment. Tracheal irritation and burning on inspiration occurred after 6-9 'oxygen hours' of exposure and progressed to severe tracheobronchial burning sensation, chest pain, and dyspnea after 11-15 h of O2. With intermittent O2 administration, nearly a doubling of the average duration of actual oxygen breathing was required to induce marked vital capacity change (more than 10%) as compared to the previous studies of continuous O2 exposure.

Hendricks, P. L.↗

Ion cyclotron resonance studies of some reactions of N/+/ ions

Product distributions and rate constants for the reactions of ground-state N(+) ions with CO, NO, CO2, and CH4 were measured. Rate constants were obtained using ion-cyclotron-resonance trapped-ion methods, and product distributions were obtained using a tandem (Dempster-ICR) mass spectrometer. Rapid nitrogen isotope exchange was also observed in N(+)-N2 collisions.

Anicich, V. G.↗

A dynamical model of upper-atmospheric helium

This numerical study of the global distribution of helium in the terrestrial thermosphere is based on the extension of a three-dimensional single-fluid numerical model of the thermosphere previously developed by the authors to treat the dynamics of a minor gas imbedded in a background gas made up of N2, O2, and O. The Cira (1972) model of the upper atmosphere, based on satellite drag data, is used to specify the background gas density and temperature as functions of altitude, latitude, and local time for a given day of the year. Specific emphasis is placed on a study of the helium distribution at solstice, i.e., the 'winter helium bulge'. Effects of solar activity, eddy diffusion, and exospheric transport on the global distribution of helium are investigated. The model reproduces the general features of the winter helium bulge, including the variation of its amplitude with solar activity, as determined by comparison of data from several recent satellite-borne mass spectrometers.

Straus, J. M.↗

Satellite measurements of ionic concentrations applied to low altitude incoherent scatter interpretations

The determination of ion and electron temperatures and electron density from incoherent scatter radar data has in the past involved assumptions concerning the ionospheric composition below 250 km. Using a very large data base of measurements of O(+), O2(+), NO(+), and N2(+) made by the Atmosphere Explorer C satellite, a model has been developed of the ionic concentration between 130 and 300 km as a function of solar zenith angle. As the effect of the new model is to increase the radar determinations of the temperature, this may explain previous discrepancies between Langmuir probe and incoherent scatter temperatures, where the comparisons have been made at these low altitudes

Torr, M. R.↗

Further developments in oxidation of methane traces with radiofrequency discharge

The radiofrequency discharge, previously shown to oxidize trace levels of methane in oxygen, was studied with contaminated air at 50, 600, and 760 torr. As with oxygen, the concentration of methane traces could be reduced by several orders of magnitude, and no organic reaction products were detected in the effluent; however, substantial concentrations of NOx (0.1-6%) were formed during treatment. The concentration of NOx was decreased by using a large diameter electrode. There is evidence that the process will oxidize N2 and NO as well as organic impurities in oxygen or oxygen/inert gas atmospheres.

Flamm, D. L.↗

Global exospheric temperatures from ESRO 4 scale height measurements

The scale height temperatures considered are based on molecular nitrogen measurements by the gas analyzer aboard the ESRO 4 in the altitude range from 280 to 310 km during the interval from December 1972 to April 1974, a period of low solar activity. At the altitude of measurement during the considered period, the scale height temperature is essentially the exospheric temperature. The mean scale height temperature derived from 1833 independent N2 scale heights is 708 K. It is concluded that the ESRO 4 data provides evidence of mean global temperatures of less than 800 K.

Keating, G. M.↗

Double-discharge stabilization of supersonic CO laser mixtures

Experiments have been conducted to study the applicability of a CW double-discharge stabilization scheme under conditions appropriate for high-energy lasers in supersonic flows. Steady arc-free volume discharges have been produced in a Mach 3 supersonic-flow test cavity using an auxiliary discharge to stabilize the main discharge at low-current densities in N2 and He/CO mixtures. A significant result is the lack of observed plasma E/N changes in response to auxiliary-discharge current changes. Also, where glow discharges were obtained, the energy loading achieved was less than the threshold required for laser operation.

Srinivasan, G.↗

Small-signal gain diagnostic measurements in a flowing CO2 pin discharge laser

Small-signal gain diagnostic measurements were conducted on closed loop, high power, carbon dioxide laser to assess the coupling between gas flow velocity and resonator saturation. Parameters investigated included optical cavity and discharge power. Results of gain measurements within and downstream of the excitation volume are presented for a laser gas composition He:N2:CO2 of 10:7:1 at 90 torr. The gain at constant discharge power was observed to be dependent upon discharge power level and time. An important result of this study is that the effects of gain swept downstream of the discharge region must be considered in the resonator design if efficient extraction of stored optical energy is desired.

Blech, R. A.↗

Electrolytic pretreatment of urine

Electrolysis has been under evaluation for several years as a process to pretreat urine for ultimate recovery of potable water in manned spacecraft applications. The conclusions that were drawn from this investigation are the following: (1) A platinum alloy containing 10 percent rhodium has been shown to be an effective, corrosion-resistant anode material for the electrolytic pretreatment of urine. Black platinum has been found to be suitable as a cathode material. (2) The mechanism of the reactions occurring during the electrolysis of urine is two-stage: (a) a total Kjeldahl nitrogen and total organic carbon (TOC) removal in the first stage is the result of electrochemical oxidation of urea to CO2, H2O, and ammonia followed by chloride interaction to produce N2 from ammonia, (b) after the urea has been essentially removed and the chloride ions have no more ammonia to interact with, the chloride ions start to oxidize to higher valence states, thus producing perchlorates. (3) Formation of perchlorates can be suppressed by high/low current operation, elevated temperature, and pH adjustment. (4) UV-radiation showed promise in assisting electrolytic TOC removal in beaker tests, but was not substantiated in limited single cell testing. This may have been due to non-optimum configurations of the single cell test rig and the light source.

Source record↗

Distribution of E/N and N sub e in a cross-flow electric discharge laser

The spatial distribution of the ratio of electric field to neutral gas density on a flowing gas, multiple pin-to-plane discharge was measured in a high-power, closed loop laser. The laser was operated at a pressure of 140 torr (1:7:20, CO2, N2, He) with typically a 100 meter/second velocity in the 5 x 8 x 135 centimeter discharge volume. E/N ratios ranged from 2.7 x 10 to the minus 16th power to 1.4 x 10 to the minus 16th power volts/cu cm along the discharge while the electron density ranged from 2.8 x 10 to the 10th power to 1.2 x 10 to the 10th power cm/3.

Dunning, J. W., Jr.↗

Apollo 14 coarse fines (4-10 mm) sample location and classification

The 4 to 10 mm sieve fraction from the soil samples collected during the Apollo 14 Mission was identified and described. Examination and description of the fines were carried out in nitrogen-filled, stainless steel cabinets during a general examination of the Apollo 14 sample collection. Each particle was held between forceps, dusted in a jet of N2, and placed on a teflon-covered stage. They were examined with a binocular microscope, separated by lithology, and the lithologic types described. Weights of individual particles in the fraction ranged from about 0.10 to 0.50 gm, large enough in size for studies of age, chemistry, and petrology to be accomplished.

Kramer, F. E.↗