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At least 1,693 records · Page 94

Corrosion Testing of Refractory in Contact with Molten Glasses Designed for Waste Vitrification – VSL Touchpoint Matrix Glasses (Revision 1)

It is known that the predictive life of the refractory ceramic liner of nuclear waste glass melters is conservative, as demonstrated by performance of these materials such as in the Defense Waste Processing Facility (DWPF).[1] The motivation for this task is to maximize the useful life of the melters that will be operated at the Waste Treatment and Immobilization Plant (WTP), which will in turn minimize procurement and disposal costs and melter outage times, as well as to identify maximum loadings in the waste glass of those species that corrode melter components. This task was initiated jointly with Pacific Northwest National Laboratory (PNNL) with the objective to develop a methodology and model to enable more accurate prediction of refractory service life under prototypic conditions from laboratory-scale material corrosion tests.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Cathodic Protection Modeling for Hanford Underground Double-Shell Tank Farms

Hanford stores millions of gallons of radioactive and chemically hazardous waste from the production of weapon materials in tank farms consisting of underground carbon-steel storage tanks surrounded by reinforced concrete. Six of these Hanford tank farms use double-shell storage tanks (DSTs). The DST farms were constructed from 1968 to 1986 with a planned 40–50 year design life, so some are already operating beyond their initial life expectancy. Ultrasonic testing (UT) has indicated significant thinning on the bottom of the secondary (outer) liner of these tanks, believed to arise from groundwater intrusion driving concrete side corrosion. There is no direct access to the steel/concrete interface between the tank and the concrete pad, making it difficult to apply a chemical-based mitigation strategy or to conduct repairs, but cathodic protection (CP) is a possible method to inhibit further concrete-side corrosion. Hanford already uses CP to protect below grade steel piping within the tank farms and connected to the tanks, but this system was not designed to protect the tank bottoms. CP design must account for the structures surrounding the DSTs, including the steel reinforcing bars (rebar) within the concrete pad and vault, various process lines, and the existing CP system. In this study, finite element analysis (FEA) modeling was carried out to simulate CP protection of 1) a single tank and CP anode to develop options for modeling the rebar and to compare to a simpler circuit model and 2) the entire Hanford AN tank farm as a representative example consisting of seven tanks, associated piping, and both existing and new CP anodes. Both circuit and FEA models predict that significant protective current could be delivered to the bottoms of the tanks with the addition of tank-protection anodes below the depth of the tanks. Simulations with only the existing pipe-protection anodes active confirmed that only a very small current to the tank bottoms is predicted under present conditions. Multiple simplified representations of the dome and wall rebar were tested to reduce the computational complexity of the tank-farm simulations, resulting in modeling the rebar as edge elements with a prescribed effective circumference that matches the real rebar surface area. The geometry of the rebar is also simplified into horizontal hoops around the tank walls and radial rebar over the dome with increased effective circumference to retain the target surface area. This simplification was found to greatly reduce the complexity and solution time of the models without large changes in current distributions, especially to the tank bottom. A range of values were tested for model parameters such as soil and concrete resistivities and polarization resistance to investigate their impact on the current and electric potential distributions. Depending on the parameters used, FEA simulations predict some risk of overprotection, particularly on the piping system; since overprotection can also lead to surface damage associated with hydrogen gas generation at the interface (e.g. hydrogen embrittlement or damage to coatings), this needs to be considered when refining the design of the new CP system. Comparison between the FEA models and the circuit model representation demonstrated that the circuit model could not match the predicted FEA current distribution, even when using the exact same surface areas. This discrepancy appeared to be at least partly attributable to the impact of the relative positions of the tank components and anodes to each other and to the ground surface. The FEA model accounts for the relative positions since it solves the governing equations in three dimensions, but the circuit model cannot account for the positioning. In particular, the circuit model underpredicts the current to the tank bottom and overpredicts the current to the dome compared to FEA for the baseline geometry. The FEA models omitted the electrically isolated rebar in the bottom concrete slab. However, a circuit based stray current model estimated that only 2.1% of the total current through the slab would stray into the rebar, corresponding to ~0.21 A for a target current density of 2 mA/ft2 to the tank bottom. The estimated corrosion driven by this amount of stray current is predicted to yield a lifetime of >400 years for the minimum rebar diameter, assuming an acceptable cross-section area loss of 10%.

d'Entremont, Anna [Savannah River National Laborat↗

Containment margins in FFTF for postulated failure of in-vessel post-accident heat removal

This study was performed to complete the assessment of potential melt-through consequences for the postulated failure of post-accident heat removal following a hypothetical core disruptive accident (HCDA) in the FFTF. The SPRAY, SOFIRE, CACECO, HAA-3B, and COMRADEX codes were used to determine potential site boundary radiation doses. Parametric comparisons were made to evaluate the effects of natural hydrogen-oxygen recombination, reactor cavity liner failures and containment coolers. Containment pressure relief, vent/purge options, and the effects of exhaust filtration were also included in the study. The potential site boundary radiation exposures for all options considered were within 10 CFR 100 guideline values.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Characterization of radiative heat transfer in a spark-ignition engine through high-speed experiments and simulations

A combined experimental and Large-Eddy Simulation (LES) study of molecular radiation is presented for combustion in a homogeneous pre-mixed spark-ignition engine. Molecular radiation can account for ~10% of the engine heat loss and could have a noticeable impact on the local conditions within the combustion chamber. The Transparent Combustion Chamber (TCC) engine, a single-cylinder two-valve research engine with a transparent liner and piston for optical access, was used for this study. High-speed infrared emission spectroscopy and radiative post-processing of LES calculations have been performed to gain insight into the timescales and magnitude of radiative emissions of molecular gases during the combustion process. Both the measurements and simulations show significant Cycle-to-Cycle Variations (CCV) of radiative emission. There is agreement in the instantaneous radiative spectrum of experiment and simulation, but the crank-angle development of the radiative spectrum shows disagreement. The strengths and limitations of the optical experiments and radiative simulations are seen in the results and suggest pathways for future efforts in characterizing the influence of molecular radiation. In particular, focusing on the relative changes of the spectral features will be important as they contain information about the thermochemical properties of the gas mixture.

02 PETROLEUM↗

MUSE-INGS ON AM1354-250: COLLISIONS, SHOCKS, AND RINGS

We present Multi Unit Spectroscopic Explorer observations of AM1354-250, confirming its status as a collisional ring galaxy that has recently undergone an interaction, creating its distinctive shape. We analyze the stellar and gaseous emission throughout the galaxy finding direct evidence that the gaseous ring is expanding with a velocity of ∼70 km s{sup −1} and that star formation is occurring primarily in H ii regions associated with the ring. This star formation activity is likely triggered by this interaction. We find evidence for several excitation mechanisms in the gas, including emission consistent with shocked gas in the expanding ring and a region of LINER-like emission in the central core of the galaxy. Evidence of kinematic disturbance in both the stars and gas, possibly also triggered by the interaction, can be seen in all of the velocity maps. The ring galaxy retains a weak spiral structure, strongly suggesting the progenitor galaxy was a massive spiral prior to the collision with its companion an estimated 140 ± 12 Myr ago.

79 ASTRONOMY AND ASTROPHYSICS↗

THE NUCLEAR ACTIVITIES OF NEARBY S0 GALAXIES

We present a study of nuclear activities in nearby S0 galaxies. After cross-matching the Sloan Digital Sky Survey Data Release 7 with the Third Reference Catalog of Bright Galaxies (RC3) and visually checking the SDSS images, we derive a sample of 583 S0 galaxies with the central spectrophotometric information. In order to separate nebular emission lines from the underlying stellar contribution, we fit the stellar population model to the SDSS spectra of these S0 galaxies. According to the BPT diagram, we find that 8% of S0 galaxies show central star-forming activity, while the fractions of Seyfert, Composite, and low-ionization nuclear emission-line regions (LINERs) are 2%, 8%, and 21.4%, respectively. We also find that star-forming S0s have the lowest stellar masses, over one magnitude lower than the others, and that the active S0s are mainly located in the sparse environment, while the normal S0s are located in the dense environment, which might suggest that the environment plays an important role in quenching star formation and/or AGN activity in S0 galaxies. By performing bulge-disk decomposition of 45 star-forming S0s in g - and r -bands with the 2D fitting software Galfit, as well as exploiting the catalog of 2D photometric decompositions of Meert et al., we find that the bulges of approximately one-third of star-forming S0 galaxies (16/45) are bluer than their disks, while for other types of S0s the bulge and disk components show similar color distributions. Besides, the Sérsic index of most star-forming S0s bulges is less than two, while for normal S0s, it is between two and six.

79 ASTRONOMY AND ASTROPHYSICS↗

Physical Properties of the Star-forming Regions in the Interacting Galaxies NGC 3395/NGC 3396

We report long-slit spectroscopy of the early major merger galaxies NGC 3395/NGC 3396. The spectra are consistent with those for star-forming galaxies, but there is some indication of LINER-like active galactic nucleus activity in the center of NGC 3396. The total star formation rate in the regions observed is 2.83 M {sub ⊙} yr{sup −1}, consistent with estimates for the entire galaxies. The highest abundances are in the centers of the galaxies, with the abundances decreasing with distance. There is a correlation between high abundance and high ionization parameter, both of which can be attributed to the presence of massive stars. Modeling with SB 99 indicates the star-forming regions are younger than 10 Myr. There are 1000–2000 WNL stars in the system, along with several thousand O stars, consistent with the ages of the star-forming regions. The highest electron densities are found in young regions with high star formation rates. The electron temperatures are higher than results for non-interacting galaxies, which is probably due to shock waves produced by the galaxy–galaxy interaction, the outflow of gas from massive stars, and/or collisions between gas clouds in the galaxies. There is star formation in the bridge of material between the galaxies. These regions are among the youngest in the system and have low abundances, suggesting the gas was pulled from the outer parts of the galaxies. X-ray point sources, probably high-mass X-ray binaries, are associated with several star-forming regions.

79 ASTRONOMY AND ASTROPHYSICS↗

Emission Line Properties of Seyfert Galaxies in the 12 μm Sample

We present optical and ultraviolet spectroscopic measurements of the emission lines of 81 Seyfert 1 and 104 Seyfert 2 galaxies that comprise nearly all of the IRAS 12 μm AGN sample. We have analyzed the emission-line luminosity functions, reddening, and other diagnostics. For example, the narrow-line regions (NLR) of Seyfert 1 and 2 galaxies do not significantly differ from each other in most of these diagnostics. Combining the Hα/Hβ ratio with a new reddening indicator—the [S ii]6720/[O ii]3727 ratio—we find the average E(B–V) is 0.49 ± 0.35 for type 1 and 0.52 ± 0.26 for type 2 Seyferts. The NLR of Sy 1s has an ionization level insignificantly higher than that of Sy 2s. For the broad-line region (BLR), we find that the C iv equivalent width correlates more strongly with [O iii]/Hβ than with UV luminosity. Our bright sample of local active galaxies includes 22 Seyfert nuclei with extremely weak broad wings in Hα, known as Seyfert 1.9s and 1.8s, depending on whether or not broad Hβ wings are detected. Aside from these weak broad lines, our low-luminosity Seyferts are more similar to the Sy 2s than to Sy 1s. In a BPT diagram, we find that Sy 1.8s and 1.9s overlap the region occupied by Sy 2s. We compare our results on optical emission lines with those obtained by previous investigators, using AGN subsamples from the Sloan Digital Sky Survey. The luminosity functions of forbidden emission lines [O ii]λ3727 Å, [O iii]λ5007 Å, and [S ii]λ6720 Å in Sy 1s and Sy 2s are indistinguishable. They all show strong downward curvature. Unlike the LFs of Seyfert galaxies measured by the Sloan Digital Sky Survey, ours are nearly flat at low luminosities. The larger number of faint Sloan “AGN” is attributable to their inclusion of weakly emitting LINERs and H ii+AGN “composite” nuclei, which do not meet our spectral classification criteria for Seyferts. In an Appendix, we have investigated which emission line luminosities can provide the most reliable measures of the total non-stellar luminosity, estimated from our extensive multi-wavelength database. The hard X-ray or near-ultraviolet continuum luminosity can be crudely predicted from either the [O iii]λ5007 Å luminosity or the combinations of [O iii]+Hβ or [N ii]+Hα lines, with a scatter of ±4 times for Sy 1s and ±10 times for Sy 2s. Although these uncertainties are large, the latter two hybrid (NLR+BLR) indicators have the advantage of predicting the same HX luminosity independent of Seyfert type.

79 ASTRONOMY AND ASTROPHYSICS↗

Transient Radio Emission from Low-redshift Galaxies at z < 0.3 Revealed by the VLASS and FIRST Surveys

We present the discovery of a sample of 18 low-redshift (z < 0.3) galaxies with transient nuclear radio emission. These galaxies are not detected or are weakly detected in the Faint Images of the Radio Sky at Twenty cm survey, performed from 1993–2009, but have brightened significantly in radio flux (by a factor of ≳5) in the epoch I (2017–2019) observations of the Very Large Array Sky Survey (VLASS). All 18 galaxies have been detected in VLASS epoch II observations, from 2020–2021, from which the radio flux has been found to evolve slowly (with variability amplitudes of ≳40%) over a period of about 3 yr. 15 galaxies have been observed in the Rapid ASKAP Continuum Survey, and a flat or inverted spectral slope between 888 MHz and 3 GHz is found. Based on the Sloan Digital Sky Survey spectra taken before the radio brightening, 14 of the 18 galaxies can be classified as LINERs or normal galaxies with weak or no nuclear activity. Most galaxies are red and massive, with more than half having central black hole masses above 10 8 M ⊙ . We find that only one galaxy in our sample displays an optical flare lasting for at least two months, with a long decay in the infrared light curve that can be explained as the dust-heated echo emission of a central optical flare, such as a stellar tidal disruption event. We discuss several possibilities for the transient radio emission and conclude that it is likely associated with a newborn radio jet triggered by short sporadic fueling of a supermassive black hole. Such a scenario can be tested with further multifrequency radio observations of these sources, via measuring their radio flux variability and spectral evolution.

79 ASTRONOMY AND ASTROPHYSICS↗

The Intrinsic Sizes of Odd Radio Circles

Abstract A new class of sources, the so-called odd radio circles (ORCs), have been discovered by recent sensitive, large-area radio continuum surveys. The distances of these sources have so far relied on photometric redshifts of optical galaxies found at the centers of or near ORCs. Here we present Gemini rest-frame optical spectroscopy of six galaxies at the centers of, or potentially associated with, the first five ORC discoveries. We supplement this with Legacy Survey imaging and Prospector fits to theirgriz+W1/W2 photometry. Of the three ORCs with central galaxies, all lie at distances (z= 0.27–0.55) that confirm the large intrinsic diameters of the radio circles (300–500 kpc). The central galaxies are massive (M * ∼ 10 11 M ☉ ), red, unobscured ellipticals with old (≳1 Gyr) stellar populations. They have LINER spectral types that are shock-powered or active galactic nucleus (AGN)-powered. All three host low-luminosity, radio-quiet AGN. The similarity of their central galaxies is consistent with a common origin, perhaps as a blast wave from an ancient starburst. The other two ORCs are adjacent and have no prominent central galaxies. However, thez= 0.25 disk galaxy that lies between them hosts a Type 2, moderate-luminosity AGN. They may instead be the lobes of a radio jet from this AGN.

Astronomy & Astrophysics↗

( NuSTAR NuSTAR) resolves the first dual AGN above 10 keV in SWIFT J2028.5+2543

We have discovered heavy obscuration in the dual active galactic nucleus (AGN) in the Swift/Burst Alert Telescope (BAT) source SWIFT J2028.5+2543 using Nuclear Spectroscopic Telescope Array (NuSTAR). While an early XMM-Newton study suggested the emission was mainly from NGC 6921, the superior spatial resolution of NuSTAR above 10 keV resolves the Swift/BAT emission into two sources associated with the nearby galaxies MCG +04-48-002 and NGC 6921 (z = 0.014) with a projected separation of 25.3 kpc (91″). NuSTAR's sensitivity above 10 keV finds both are heavily obscured to Compton-thick levels (N {sub H} ≈ (1–2) × 10{sup 24} cm{sup −2}) and contribute equally to the BAT detection (L{sub 10−50 keV}{sup int} ≈ 6 × 10{sup 42} erg s{sup −1}). The observed luminosity of both sources is severely diminished in the 2–10 keV band (L{sub 2−10 keV}{sup obs}<0.1×L{sub 2−10 keV}{sup int}), illustrating the importance of >10 keV surveys like those with NuSTAR and Swift/BAT. Compared to archival X-ray data, MCG +04-48-002 shows significant variability (>3) between observations. Despite being bright X-ray AGNs, they are difficult to detect using optical emission-line diagnostics because MCG +04-48-002 is identified as a starburst/composite because of the high rates of star formation from a luminous infrared galaxy while NGC 6921 is only classified as a LINER using line detection limits. SWIFT J2028.5+2543 is the first dual AGN resolved above 10 keV and is the second most heavily obscured dual AGN discovered to date in the X-rays other than NGC 6240.

79 ASTRONOMY AND ASTROPHYSICS↗

Engine Operating Conditions, Fuel Property Effects, and Associated Fuel–Wall Interaction Dependencies of Stochastic Preignition

This work for the Coordinating Research Council (CRC) explores dependencies on the opportunity for fuel to impinge on internal engine surfaces (i.e., fuel–wall impingement) as a function of fuel properties and engine operating conditions and correlates these data with measurements of stochastic preignition (SPI) propensity. SPI rates are directly coupled with laser–induced florescence measurements of dye-doped fuel dilution measurements of the engine lubricant, which provides a surrogate for fuel–wall impingement. Literature suggests that SPI may have several dependencies, one being fuel–wall impingement. However, it remains unknown if fuel-wall impingement is a fundamental predictor and source of SPI or is simply a causational factor of SPI. In this study, these relationships on SPI and fuel-wall impingement are explored using 4 fuels at 8 operating conditions per fuel, for 32 total test points. The fuels were directly injected at two different injection timings: an earlier injection timing that initially targets the piston crown and a later injection timing that targets the cylinder liner. At each injection timing, the engine was operated at both 90°C and 70°C coolant and lubricant temperatures, and 185 and 200 kPa absolute intake manifold pressure. This work serves as an exploratory effort to down select conditions and provide initial fuel properties of interest for a secondary study to explore fuel property specific effects on fuel-wall interaction and SPI propensity. Significant findings from this initial operating condition and fuel property exploratory work are: 1. reduced engine operating coolant and lubricant temperatures, along with 2. retarded injection timings were required to increase SPI propensity. Moreover, at these conditions some fuel specific effects were also observed; specifically, increased ethanol content increased measured dye–wall (i.e., fuel–wall) interaction. However, despite increased dye–wall interaction, the increased volatility of the ethanol containing fuels also reduced the estimated fuel retention in the top-ring zone and associated measured SPI propensity. Thus, the findings of this unique approach to explore relationships between fuel-wall impingement and SPI highlight that SPI propensity is more directly proportional to retained fuel, and not simply fuel–wall impingement. Furthermore, fuel retention was found to be directly influenced by complex fuel property and engine operating condition relationships. Either retarded injection timings and/or increased fuel volatility increased fuel wall-impingement, while less volatile fuels and/or reduced coolant temperatures increased fuel retention. Therefore, for a given operating condition, the data highlights that greater volatile fuels exhibit increased fuel wall impingement without increased fuel retention or SPI propensity, while less volatile fuels could exhibit reduced fuel-wall impingement but increased fuel retention and SPI propensity rates.

33 ADVANCED PROPULSION SYSTEMS↗

Cyclic Thermal and Structural Testing of a Hot Particle Storage Bin

Thermal energy storage is a key element in concentrating solar energy systems. In 2017 a Roadmap toward a third-generation system that could meet the SunSHOT goals of 0.06 $/kWe recommended increasing temperatures to > 700° C for heat transfer media to in-crease thermal efficiencies and lower levelized costs of heat. In 2021, the U.S. Department of Energy selected the particle pathway, G3P3, to build a 1 MWt prototype solar tower with 6 MWh thermal energy storage at the NSTTF in Albuquerque, NM. Of the primary components, the falling particle receiver, and particle-to-sCO2 heat exchanger have been demonstrated at the 250 kWt capacity. The storage component is now being demonstrated as part of the G3P3-USA and G3P3-KSA pilot plants. Storage bin liner materials have been demonstrated by KSU in 2016 and 2019. A flowing particle storage container was demonstrated in 2020 by KSU. The testing presented in this work will be the first to test the particle to wall interactions with mono-lithic refractory insulation, and to validate a transient thermal transport model with the unique kinetics of bulk solids in funnel-flow where cooler particles near the walls flow inward toward a hot central flow channel. This work will also de-risk and characterize the specific design of the G3P3-USA storage bin.

Sment, Jeremy↗

Development of high pressure gas systems

This paper presents a report on the latest advances and technology in the design, construction, testing, and operation of high pressure gas bimetallic pipe systems and high pressure gas tube fittings facilitating greater alinement and manufacturing tolerances, and the supercleaning of high pressure gas systems under field conditions. The following specific topics are discussed: - Analysis of noncorrosive steels versus bimetallic, high strength steels - Analysis of various protective finishes versus bimetallic piping - Testing of high pressure systems - Pipe liner adhesion properties under varying operating conditions - Modified flared tube fittings taking into account pressure ranges, materials, costs involved in manufacture, various methods employed to permit sealing of the fitting while meeting cleanliness requirements - Cleaning requirements appertaining to high pressure gas systems and a discussion of investigations on the effects of velocity and temperature as related to various cleaning chemicals. The presentation concludes with a discussion on the possible applications of materials and methods in commercial industry.

Fitting↗

Simple test for physical stability of cryogenic tank insulation

Qualitative test determines the ability of insulation liners used on liquid hydrogen tanks to withstand stresses produced by the thermal shocks imparted to the insulation during tank filling and drainage. Test specimens are bonded to metal plates with a low thermal expansion coefficient and are immersed in liquid hydrogen.

Rossello, D.↗