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At least 1,693 records · Page 94

Leaf chlorophyll content as a proxy for leaf photosynthetic capacity

Improving the accuracy of estimates of forest carbon exchange is a central priority for understanding ecosystem response to increased atmospheric CO 2 levels and improving carbon cycle modelling. However, the spatially continuous parameterization of photosynthetic capacity (Vcmax) at global scales and appropriate temporal intervals within terrestrial biosphere models (TBMs) remains unresolved. This research investigates the use of biochemical parameters for modelling leaf photosynthetic capacity within a deciduous forest. Particular attention is given to the impacts of seasonality on both leaf biophysical variables and physiological processes, and their interdependent relationships. Four deciduous tree species were sampled across three growing seasons (2013-2015), approximately every 10 days for leaf chlorophyll content (Chl Leaf ) and canopy structure. Leaf nitrogen (N Area ) was also measured during 2014. Leaf photosynthesis was measured during 2014-2015 using a Li-6400 gas-exchange system, with A-Ci curves to model Vcmax. Results showed that seasonality and variations between species resulted in weak relationships between Vcmax normalized to 25°C (Vcmax 25 ) and N Area ( R 2 = 0.62, P < 0.001), whereas Chl Leaf demonstrated a much stronger correlation with Vcmax 25 ( R 2 = 0.78, P < 0.001). The relationship between Chl Leaf and N Area was also weak ( R 2 = 0.47, P < 0.001), possibly due to the dynamic partitioning of nitrogen, between and within photosynthetic and nonphotosynthetic fractions. The spatial and temporal variability of Vcmax 25 was mapped using Landsat TM/ETM satellite data across the forest site, using physical models to derive Chl Leaf . TBMs largely treat photosynthetic parameters as either fixed constants or varying according to leaf nitrogen content. This research challenges assumptions that simple N Area - Vcmax 25 relationships can reliably be used to constrain photosynthetic capacity in TBMs, even within the same plant functional type. It is suggested that Chl Leaf provides a more accurate, direct proxy for Vcmax 25 and is also more easily retrievable from satellite data. These results have important implications for carbon modelling within deciduous ecosystems.

59 BASIC BIOLOGICAL SCIENCES↗

Multi-Hybrid Power Vehicles with Cost Effective and Durable Polymer Electrolyte Membrane Fuel Cell and Li-ion Battery

Anima Bose, the principal investigator of the project, originally proposed to develop composite membranes to operate PEMFCs at much higher temperatures than 80°C and to alleviate the flooding problems often encountered in Nafion menmbrane containing fuel cells. The PI has successfully created composite membranes by blending small quantities of octasilane-poss (OSP) with Nafion. The composite membranes exhibited temperature tolerance up to 110°C without scarifying cell performance as determined by polarization curves and proton conductivity measurements. These membranes also exhibited superior water management performance as evident from the lack of flooding. Furthermore, these fuel cells performed well under reduced humidities. Structural and thermal analyses revealed that these Nafion-octasilane composite membranes are homogenous at concentrations up to 3 wt% of the OSP and that the siloxane offers additional thermal stability.

25 ENERGY STORAGE↗

Fracture Network Influence on Rock Damage and Gas Transport following an Underground Explosion

Simulations of rock damage and gas transport following underground explosions that omit preexisting fracture networks in the subsurface cannot fully characterize the influence of geo-structural variability on gas transport. Previous studies do not consider the impact that fracture network structure and variability have on gas seepage. In this study, we develop a sequentially coupled, axi-symmetric model to look at the damage pattern and resulting gas breakthrough curves following an underground explosion given different fracture network realizations. We simulate 0.327 and 0.164 kT chemical explosives with burial depths of 100 m for 90 stochastically generated fracture networks. Gases quickly reach the surface in 30% of the higher yield simulations and 5% of the lower yield simulations. The fast breakthrough can be attributed to the formation of connected pathways between fractures to the surface. The formation of a connected damage pathway to the surface is not clearly correlated with the fracture intensity (P32) in our simulations. Breakthrough curves with slower transport are highly variable depending on the fracture network sample. The variability in the breakthrough behavior indicates that ignoring the influence of fracture networks on rock damage, which strongly influences the hydraulic properties following an underground explosion, will likely lead to a large underestimation of the uncertainty in the gas transport to the surface. This work highlights the need for incorporation of fracture networks into models for accurately predicting gas seepage following underground explosions.

58 GEOSCIENCES↗

Coordination chemistry in fused-salt solutions

Spectrophotometric work on structural determinations with fused-salt solutions is reviewed. Constraints placed on the method, as well as interpretation of the spectra, are discussed with parallels drawn to aqueous spectrophotometric curves of the same materials.

Gruen, D. M.↗

Tensile and flexural strength of non-graphitic superhybrid composites: Predictions and comparisons

Equations are presented and described which can be used to predict bounds on the tensile and flexural strengths of nongraphitic superhybrid (NGSH) composites. These equations are derived by taking into account the measured stress-strain behavior, the lamination residual stresses and the sequence of events leading to fracture. The required input for using these equations includes constituents, properties (elastic and strength), NGSH elastic properties, cure temperature, and ply stress influence coefficients. Results predicted by these equations are in reasonably good agreement with measured data for strength and for the apparent knees in the nonlinear stress-strain curve. The lower bound values are conservative compared to measured data. These equations are relatively simple and are suitable for use in the preliminary design and initial sizing of structural components made from NGSH composites.

Chamis, C. C.↗

Effect of temperature on composite sandwich structures subjected to low velocity impact

The effect of low velocity projectile impact on sandwich-type structural components was investigated. The materials used in the fabrication of the impact surface were graphite-, Kevlar-, and boron-fibers with appropriate epoxy matrices. The testing of the specimens was performed at moderately low- and high-temperatures as well as at room temperature to assess the impact-initiated strength degradation of the laminates. Eleven laminates with different stacking sequences, orientations, and thicknesses were tested. The low energy projectile impact is considered to simulate the damage caused by runway debris, the dropping of the hand tools during servicing, etc., on the secondary aircraft structures fabricated with the composite materials. The results show the preload and the impact energy combinations necessary to cause catastrophic failure in the laminates tested. A set of faired curves indicating the failure thresholds is shown separately for the tension-and compression-loaded laminates. The specific-strengths and -modulii for the various laminates tested are also given.

Sharma, A. V.↗

Impact-initiated damage thresholds in composites

An experimental investigation was conducted to study the effect of low velocity projectile impact on the sandwich-type structural components. The materials used in the fabrication of the impact surface were graphite-, Kevlar-, and boron-fibers with appropriate epoxy matrices. The testing of the specimens was performed at moderately low- and high-temperatures as well as at room temperature to assess the impact-initiated strength degradation of the laminates. Eleven laminates with different stacking sequences, orientations, and thicknesses were tested. The low energy projectile impact is considered to simulate the damage caused by runway debris, dropping of the hand tools during servicing, etc., on the secondary aircraft structures fabricated with the composite materials. The results show the preload and the impact energy combinations necessary to cause catastrophic failures in the laminates tested. A set of faired curves indicating the failure thresholds is shown separately for the tension- and compression-loaded laminates. The specific-strengths and -moduli for the various laminates tested are also given.

Sharma, A. V.↗

VLBI maps of 3C 273 and 3C 345 at 2.3 GHz

Maps of the quasars 3C 273 and 3C 345 made at 2.3 GHz with an eight station VLBI array are presented. Five compact components spanning 45 milli-arcsec are seen in 3C 273, and four are seen in 3C 345. Comparisons with maps at higher and lower frequencies show that in both sources the core, which dominates the high-frequency 'core-jet' structure, is strongly self-absorbed at 2.3 GHz and below. The jet components have flat spectra, peaking between 2 and 5 GHz. In both sources the VLBI jet curves toward the direction of the arcsecond-scale outer jet.

Cohen, M. H.↗

Improved performance design of gallium arsenide solar cells for space

An improved design, shallow junction heteroface, n-p, gallium arsenide solar cell for space applications is reported, with a predicted AM0 efficiency in the 21.9 to 23.0 percent range. The optimized n-p structure, while slightly more efficient, has the added advantage of being less susceptible to radiation-induced degradation by virtue of this thin top junction layer. Detailed spectral response curves and an analysis of the loss mechanisms are reported. The details of the design are readily measurable. The optimized designs were reached by quantifying the dominant loss mechanisms and then minimizing them by using computer simulations.

Parekh, R. H.↗

Constructing R-Curves From Residual-Strength Data

Old data exploited in new concept. Method devised for estimating crack-extension resistance curve (R-curve) from residual-strength data on precracked fracture specimens. Enables inference of additional information from simple test results, and information used to estimate failure loads of more complicated structures of same material and thickness.

Orange, Thomas W.↗

On the Gortler vortex instability mechanism at hypersonic speeds

The linear instability of the hypersonic boundary layer on a curved wall is considered. As a starting point the viscosity of the fluid is taken to be a linear function of temperature and real-gas effects are ignored. It is shown that the flow is susceptible to Gortler vortices and that they are trapped in the logarithmically thin adjustment layer in which the temperature of the basic flow changes rapidly to its free stream value. The vortices decay exponentially in both directions away from this layer and are most unstable when their wavelength is comparable with the depth of the adjustment layer. The non-uniqueness of the neutral stability curve associated with incompressible Gortler vortices is shown to disappear at high Mach numbers if the appropriate fast streamwise dependence of the instability is built into the disturbance flow structure. It is shown that in the hypersonic limit wall-cooling has a negligible effect on the stability of a fluid with a given value of the Chapman constant.

Hall, Philip↗

On the Goertler vortex instability mechanism at hypersonic speeds

The linear instability of the hypersonic boundary layer on a curved wall is considered. As a starting point, the viscosity of the fluid is taken to be a linear function of temperature and real-gas effects are ignored. It is shown that the flow is susceptible to Goertler vortices and that they are trapped in the logarithmically thin adjustment layer in which the temperature of the basic flow changes rapidly to its free stream value. The vortices decay exponentially in both directions away from this layer and are most unstable when their wavelength is comparable with the depth of the adjustment layer. The nonuniqueness of the neutral stability curve associated with incompressible Goertler vortices is shown to disappear at high Mach numbers if the appropriate 'fast' streamwise dependence of the instability is built into the disturbance flow structure. It is shown that in the hypersonic limit, wall-cooling affects the leading-order term in the expansion of the Goertler number which is independent of the wavenumber, and which is due to the curvature of the basic state but it has a negligible effect on the other terms which are dependent on the wavenumber.

Hall, Philip↗

Gravitational microlensing - The effect of a single lens and the impact of sparse sampling

Topics in gravitational microlensing are examined. One issue is that even in cases in which the surface mass density is quite low, microlensing events cannot be considered as caused by individual stars. Whenever a high-magnification event occurs, the quasar has crossed a caustic. These caustics, however, are complex structures even for low surface-mass densities. This is illustrated by removing a single low-mass star from an ensemble of microlenses. The magnification patterns and light curves are compared with and without this star. The differences are striking and much more complex than expected. The effect of sparse sampling on the perception of microlensed light curves is examined, and attention is given to the influence of poor time coverage on simulated light curves. A regular monitoring program for microlensing candidates (especially 2237 + 0305) with a dedicated telescope is needed to make observations in different wavebands each night.

Wambsganss, Joachim↗

Testing and analysis of flat and curved panels with multiple cracks

An experimental and analytical investigation of multiple cracking in various types of test specimens is described in this paper. The testing phase is comprised of a flat unstiffened panel series and curved stiffened and unstiffened panel series. The test specimens contained various configurations for initial damage. Static loading was applied to these specimens until ultimate failure, while loads and crack propagation were recorded. This data provides the basis for developing and validating methodologies for predicting linkup of multiple cracks, progression to failure, and overall residual strength. The results from twelve flat coupon and ten full scale curved panel tests are presented. In addition, an engineering analysis procedure was developed to predict multiple crack linkup. Reasonable agreement was found between predictions and actual test results for linkup and residual strength for both flat and curved panels. The results indicate that an engineering analysis approach has the potential to quantitatively assess the effect of multiple cracks in the arrest capability of an aircraft fuselage structure.

Broek, David↗

Scanning Laser Infrared Molecular Spectrometer (SLIMS)

This prototype innovation is a novel design that achieves very long, effective laser path lengths that are able to yield ppb (parts per billion) and sub-ppb measurements of trace gases. SLIMS can also accommodate multiple laser channels covering a wide range of wavelengths, resulting in detection of more chemicals of interest. The mechanical design of the mirror cell allows for the large effective path length within a small footprint. The same design provides a robust structure that lends itself to being immune to some of the alignment challenges that similar cells face. By taking a hollow cylinder and by cutting an elliptically or spherically curved surface into its inner wall, the basic geometry of a reflecting ring is created. If the curved, inner surface is diamond-turned and highly polished, a surface that is very highly reflective can be formed. The surface finish can be further improved by adding a thin chrome or gold film over the surface. This creates a high-quality, curved, mirrored surface. A laser beam, which can be injected from a small bore hole in the wall of the cylinder, will be able to make many low-loss bounces around the ring, creating a large optical path length. The reflecting ring operates on the same principle as the Herriott cell. The difference exists in the mirror that doesn't have to be optically aligned, and which has a relatively large, internal surface area that lends itself to either open air or evacuated spectroscopic measurements. This solid, spherical ring mirror removes the possibility of mirror misalignment caused by thermal expansion or vibrations, because there is only a single, solid reflecting surface. Benefits of the reflecting ring come into play when size constraints reduce the size of the system, especially for space missions in which mass is at a premium.

Scott, David C.↗

Systems and methods for periodic nodal surface based reactors, distributors, contactors and heat exchangers

The present disclosure relates to a transport mechanism apparatus for transporting at least one of a gas or a fluid. The transport mechanism may have an inlet, an outlet and an engineered cellular structure forming a periodic nodal surface, which may include a triply periodic minimal surface (TPMS) structure. The structure is formed in a layer-by-layer three dimensional (3D) printing operation to include cells propagating in three dimensions, where the cells include non-intersecting, continuously curving wall portions having openings, and where the opening in the cells form a plurality of flow paths throughout the transport mechanism from the inlet to the outlet, and where portions of the cells form the inlet and the outlet.

Iyer, Jaisree Kannan↗

Type Ia supernovae from merging white dwarfs. II. Post-merger detonations

Merging carbon-oxygen (CO) white dwarfs are a promising progenitor system for Type Ia supernovae (SNe Ia), but the underlying physics and timing of the detonation are still debated. If an explosion occurs after the secondary star is fully disrupted, the exploding primary will expand into a dense CO medium that may still have a disk-like structure. This interaction will decelerate and distort the ejecta. Here we carry out multidimensional simulations of 'tamped' SN Ia models, using both particle and grid-based codes to study the merger and explosion dynamics and a radiative transfer code to calculate synthetic spectra and light curves. We find that post-merger explosions exhibit an hourglass-shaped asymmetry, leading to strong variations in the light curves with viewing angle. The two most important factors affecting the outcome are the scale height of the disk, which depends sensitively on the binary mass ratio, and the total {sup 56}Ni yield, which is governed by the central density of the remnant core. The synthetic broadband light curves rise and decline very slowly, and the spectra generally look peculiar, with weak features from intermediate mass elements but relatively strong carbon absorption. We also consider the effects of the viscous evolution of the remnant and show that a longer time delay between merger and explosion probably leads to larger {sup 56}Ni yields and more symmetrical remnants. We discuss the relevance of this class of aspherical 'tamped' SN Ia for explaining the class of 'super-Chandrasekhar' SN Ia.

79 ASTRONOMY AND ASTROPHYSICS↗

Aeroelastic Modeling of Offshore Turbines and Support Structures in Hurricane-Prone Regions (Poster)

US offshore wind turbines (OWTs) will likely have to contend with hurricanes and the associated loading conditions. Current industry standards do not account for these design load cases (DLCs), thus a new approach is required to guarantee that the OWTs achieve an appropriate level of reliability. In this study, a sequentially coupled aero-hydro-servo-elastic modeling technique was used to address two design approaches: 1.) The ABS (American Bureau of Shipping) approach; and 2.) The Hazard Curve or API (American Petroleum Institute) approach. The former employs IEC partial load factors (PSFs) and 100-yr return-period (RP) metocean events. The latter allows setting PSFs and RP to a prescribed level of system reliability. The 500-yr RP robustness check (appearing in [2] and [3] upcoming editions) is a good indicator of the target reliability for L2 structures. CAE tools such as NREL's FAST and Bentley's' SACS (offshore analysis and design software) can be efficiently coupled to simulate system loads under hurricane DLCs. For this task, we augmented the latest FAST version (v. 8) to include tower aerodynamic drag that cannot be ignored in hurricane DLCs. In this project, a 6 MW turbine was simulated on a typical 4-legged jacket for a mid-Atlantic site. FAST-calculated tower base loads were fed to SACS at the interface level (transition piece); SACS added hydrodynamic and wind loads on the exposed substructure, and calculated mudline overturning moments, and member and joint utilization. Results show that CAE tools can be effectively used to compare design approaches for the design of OWTs in hurricane regions and to achieve a well-balanced design, where reliability levels and costs are optimized.

17 WIND ENERGY↗