Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Alternative Relativity”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,693 records · Page 94
All sourcesNASA NTRSDOE OSTI
DOE OSTI2014

Bioconversion of natural gas to liquid fuel: Opportunities and challenges

Natural gas is a mixture of low molecular weight hydrocarbon gases that can be generated from either fossil or anthropogenic resources. Although natural gas is used as a transportation fuel, constraints in storage, relatively low energy content (MJ/L), and delivery have limited widespread adoption. Advanced utilization of natural gas has been explored for biofuel production by microorganisms. In recent years, the aerobic bioconversion of natural gas (or primarily the methane content of natural gas) into liquid fuels (Bio-GTL) by biocatalysts (methanotrophs) has gained increasing attention as a promising alternative for drop-in biofuel production. Methanotrophic bacteria are capable of converting methane into microbial lipids, which can in turn be converted into renewable diesel via a hydrotreating process. In this paper, biodiversity, catalytic properties and key enzymes and pathways of these microbes are summarized. Bioprocess technologies are discussed based upon existing literature, including cultivation conditions, fermentation modes, bioreactor design, and lipid extraction and upgrading. This review also outlines the potential of Bio-GTL using methane as an alternative carbon source as well as the major challenges and future research needs of microbial lipid accumulation derived from methane, key performance index, and techno-economic analysis. An analysis of raw material costs suggests that methane-derived diesel fuel has the potential to be competitive with petroleum-derived diesel. (C) 2014 The Authors. Published by Elsevier Inc.

Fei, Q↗
DOE OSTI2016

Stiff and Transparent Multilayer Thin Films Prepared Through Hydrogen-Bonding Layer-by-Layer Assembly of Graphene and Polymer [Super Stiff and Highly Transparent Multilayer Thin Films Prepared through Hydrogen-Bonding Layer-by-Layer Assembly of Graphene and Polymer]

Due to their exceptional orientation of 2D nanofillers, layer–by–layer (LbL) assembled polymer/graphene oxide thin films exhibit unmatched mechanical performance relative to any conventionally produced counterparts with similar composition. Unprecedented mechanical property improvement, by replacing graphene oxide with pristine graphene, is demonstrated in this work. Polyvinylpyrrolidone–stabilized graphene platelets are alternately deposited with poly(acrylic acid) using hydrogen bonding assisted LbL assembly. Transmission electron microscopy imaging and the Halpin–Tsai model are used to demonstrate, for the first time, that intact graphene can be processed from water to generate polymer nanocomposite thin films with simultaneous parallel–alignment, high packing density, and exfoliation. A multilayer thin film with only 3.9 vol% of highly exfoliated, and structurally intact graphene, increases the elastic modulus (E) of a polymer multilayer thin film by 322% (from 1.41 to 4.81 GPa), while maintaining visible light transmittance of ≈90%. This is one of the greatest improvements in elastic modulus ever reported for a graphene–filled polymer nanocomposite with a glassy (E > 1 GPa) matrix. In conclusion, the technique described here provides a powerful new tool to improve nanocomposite properties (mechanical, gas transport, etc.) that can be universally applied to a variety of polymer matrices and 2D nanoplatelets.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Solving a system of linear equations: From centralized to distributed methods

For a wide range of control engineering applications, the problem of solving a system of linear equations is often encountered and has been well studied. Traditionally, this problem has been mainly solved in a centralized manner. However, for applications related to large-scale complex networked systems, centralized algorithms are often subjected to some practical issues due to limited computational power and communication bandwidth. As a promising and viable alternative, distributed algorithms can effectively address the issues associated with centralized algorithms by solving the problem efficiently in a multi-agent setting that accords with the distributed nature of networked systems. Distributed algorithms decompose the entire problem into many sub-problems that are solved by individual agents in a cooperative manner. In this survey paper, we provide a detailed overview of the state of the art relevant to distributed algorithms for solving a system of linear equations. We will first review basic distributed algorithms including both discrete-time and continuous-time algorithms. Then we will discuss the extended algorithms to achieve communication efficiency. Furthermore, we will also introduce distributed algorithms to obtain the minimum-norm solution for a system of linear equations with multiple solutions, as well as the least-squares solutions when there is no solution. Finally, the relationship of distributed algorithms for solving a system of linear equations to the existing distributed optimization algorithms is discussed.

Wang, Peng↗
DOE OSTI2018

Long-term simulation of space-charge effects

The long-term macroparticle tracking simulation is computationally challenging but needed in order to study space-charge effects in high intensity circular accelerators. To address the challenge, in this paper, we proposed using a fully symplectic particle-in-cell model for the long-term space-charge simulation. We analyzed the artificial numerical emittance growth in the simulation and suggested using threshold numerical filtering in frequency domain to mitigate the emittance growth in the simulation. Furthermore, we also explored alternative frozen space-charge simulations and observed qualitative agreement with the self-consistent simulations.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2021

TMTpro Complementary Ion Quantification Increases Plexing and Sensitivity for Accurate Multiplexed Proteomics at the MS2 Level

Multiplexed proteomics is a powerful tool to assay cell states in health and disease, but accurate quantification of relative protein changes is impaired by interference from co-isolated peptides. Most widely, this issue is alleviated by MS3-based quantification, reducing sensitivity and requiring specialized instrumentation. An alternative approach is quantification by complementary ions, which allows accurate and precise multiplexed quantification at the MS2 level and is compatible with the most widely distributed instruments. However, complementary ions of the popular TMT tag form inefficiently and plexing is limited to five channels. In this work, we evaluate and optimize complementary ion quantification for the recently released TMTPro tag, which increases plexing capacity to 8 channels (TMTProC). We find that the beneficial fragmentation properties increase quantification signal five-fold compared to TMT. This increased sensitivity results in ~50% more proteins quantified compared to TMTPro-MS3 and even slightly outperforms TMTPro-MS2. Furthermore, TMTProC quantification is more accurate than TMTPro-MS2 and even superior to TMTPro-MS3. To demonstrate the power of TMTProC, we analyzed a human and yeast interference sample and were able to quantify 13,290 proteins in 24 fractions. Thus, TMTProC advances multiplexed proteomics data quality and widens access to accurate multiplexed proteomics beyond laboratories with MS3-capable instrumentation.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2014

Development of a Multi-Point Quantitation Method to Simultaneously Measure Enzymatic and Structural Components of the Clostridium thermocellum Cellulosome Protein Complex

Clostridium thermocellum has emerged as a leading bioenergy-relevant microbe due to its ability to solubilize cellulose into carbohydrates, mediated by multi-component membrane-attached complexes termed cellulosomes. To probe microbial cellulose utilization rates, it is desirable to be able to measure the concentrations of saccharolytic enzymes and estimate the total amount of cellulosome present on a mass basis. Current cellulase determination methodologies involve labor-intensive purification procedures and only allow for indirect determination of abundance. We have developed a method using multiple reaction monitoring (MRM-MS) to simultaneously quantitate both enzymatic and structural components of the cellulosome protein complex in samples ranging in complexity from purified cellulosomes to whole cell lysates, as an alternative to a previously-developed enzyme-linked immunosorbent assay (ELISA) method of cellulosome quantitation. The precision of the cellulosome mass concentration in technical replicates is better than 5% relative standard deviation for all samples, indicating high precision for determination of the mass concentration of cellulosome components.

absolute quantitation↗
DOE OSTI2019

Energy of injection-induced seismicity predicted from in-situ experiments

The ability to predict the magnitude of an earthquake caused by deep fluid injections is an important factor for assessing the safety of the reservoir storage and the seismic hazard. Here, we propose a new approach to evaluate the seismic energy released during fluid injection by integrating injection parameters, induced aseismic deformation, and the distance of earthquake sources from injection. We use data from ten injection experiments performed at a decameter scale into fault zones in limestone and shale formations. We observe that the seismic energy and the hydraulic energy similarly depend on the injected fluid volume (V), as they both scale as V 3/2 . They show, however, a large discrepancy, partly related to a large aseismic deformation. Therefore, to accurately predict the released seismic energy, aseismic deformation should be considered in the budget through the residual deformation measured at the injection. Alternatively, the minimal hypocentral distance from injection points and the critical fluid pressure for fault reactivation can be used for a better prediction of the seismic moment in the total compilation of earthquakes observed during these experiments. Complementary to the prediction based only on the injected fluid volume, our approach opens the possibility of using alternative monitoring parameters to improve traffic-light protocols for induced earthquakes and the regulation of operational injection activities.

58 GEOSCIENCES↗
DOE OSTI2014

An electrically driven terahertz metamaterial diffractive modulator with more than 20 dB of dynamic range

We design and experimentally demonstrate a switchable diffraction grating for terahertz modulation based on planar active metamaterials, where a Schottky gate structure is implemented to tune the metamaterial resonances in real-time via the application of an external voltage bias. The diffraction grating is formed by grouping the active split-ring resonators into an array of independent columns with alternate columns biased. We observe off-axis diffraction over a wide frequency band in contrast to the narrow-band resonances, which permits operation of the device as a relatively high-speed, wide-bandwidth, high-contrast modulator, with more than 20 dB of dynamic range.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2022

Study of self-interaction-errors in barrier heights using locally scaled and Perdew-Zunger self-interaction methods

We study the effect of self-interaction errors on the barrier heights of chemical reactions. For this purpose we use the well-known Perdew-Zunger [J. P. Perdew and A. Zunger, Phys. Rev. B,23, 5048 (1981)] self-interaction-correction(PZSIC), as well two variations of the recently developed, locally scaled self-interaction correction (LSIC) [Zope et al.,J. Chem. Phys.151, 214108 (2019)] to study the barrier heights of the BH76 benchmark dataset. Our results show that both PZSIC and especially the LSIC methods improve the barrier heights relative to the local density approximation(LDA). The version of LSIC that uses the iso-orbital indicator z as a scaling factor gives a more consistent improvement than an alternative version that uses an orbital-dependent factor based on the ratio of orbital densities to the total electron density. We show that LDA energies evaluated using the self-consistent and self-interaction-free PZSIC densities can be used to assess density-driven errors. Furthermore, the LDA reaction barrier errors for the BH76 set are found to contain significant density-driven errors for all types of reactions contained in the set, but the corrections due to adding SIC to the functional are much larger than those stemming from the density for the hydrogen transfer reactions and of roughy equal size for the non-hydrogen transfer reactions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Using angular two-point correlations to self-calibrate the photometric redshift distributions of DECaLS DR9

Calibrating the redshift distributions of photometric galaxy samples is essential in weak lensing studies. The self-calibration method combines angular auto- and cross-correlations between galaxies in multiple photometric redshift (photo-z) bins to reconstruct the scattering rates matrix between redshift bins. In this paper, we test a recently proposed self-calibration algorithm using the DECaLS Data Release 9 and investigate to what extent the scattering rates are determined. We first mitigate the spurious angular correlations due to imaging systematics by a machine learning based method. We then improve the algorithm for χ 2 minimization and error estimation. Finally, we solve for the scattering matrices, carry out a series of consistency tests, and find reasonable agreements: (1) finer photo-z bins return a high-resolution scattering matrix, and it is broadly consistent with the low-resolution matrix from wider bins; (2) the scattering matrix from the Northern Galactic Cap is almost identical to that from Southern Galactic Cap; (3) the scattering matrices are in reasonable agreement with those constructed from the power spectrum and the weighted spectroscopic subsample. We also evaluate the impact of cosmic magnification. Although it changes little the diagonal elements of the scattering matrix, it affects the off-diagonals significantly. The scattering matrix also shows some dependence on scale cut of input correlations, which may be related to a known numerical degeneracy between certain scattering pairs. In conclusion, this work demonstrates the feasibility of the self-calibration method in real data and provides a practical alternative to calibrate the redshift distributions of photometric samples.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2025

Dust stars in the minimal exponential measure model

Here, we report the existence of horizonless compact object solutions supported by dust in the minimal exponential measure (MEMe) model, a theory which modifies the couplings between gravity and matter without introducing dynamical degrees of freedom. For a perfect fluid source, the field equations for the MEMe model can be rewritten as the Einstein field equations sourced by a perfect fluid with a transformed equation of state, which can endow a sufficiently dense cloud of dust with an effective pressure. The resulting dust-supported horizonless compact objects can have masses below ∼10 −11 ⁢𝑀 ⊙ , making them suitable as massive compact halo objects comprising a significant mass fraction for dark matter. A necessary condition for the existence of these compact object solutions is that the single free parameter in the MEMe model is positive valued. Additionally, we find that this positive sign for the parameter can provide a mechanism for suppressing the formation of (primordial) black holes from the gravitational collapse of matter below a certain mass scale.

alternative gravity theories↗
DOE OSTI2020

Anaerobic guilds responsible for mercury methylation in boreal wetlands of varied trophic status serving as either a methylmercury source or sink

Wetlands are common sites of active Hg methylation by anaerobic microbes; however, the amount of methylmercury produced varies greatly, as Hg methylation is dependent upon both the availability of Hg and the composition and activity of the microbial community involved. In this study, we identified the major microbial guilds responsible for Hg methylation along a trophic gradient composed of two sites and three different types of wetlands: a bog–fen peatland gradient and a black alder swamp, serving as net sources and a sink for methylmercury respectively. Iron-reducing bacteria in the Geobacteraceae were important Hg methylators across all wetlands and seasons examined, as evidenced by abundant 16S rRNA and hgcA transcripts clustering with this family. Molybdate inhibited Hg methylation more efficiently in the peatlands than in the swamp, suggesting an increasing role of sulfate-reducing bacteria and/or related syntrophs in the methylation of Hg with decreasing trophic status. Further, sulfate addition failed to increase Hg methylation rates in the peatlands, suggesting that SRBs/syntrophs were instead likely metabolizing alternative substrates such as syntrophic fermentation of organic compounds with methanogens. These results highlight the interconnectivity of anaerobic metabolism and importance of community dynamics on the methylation of Hg in wetlands with different trophic status.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2019

Physical Operating Principles of Palladium–Barium Cathodes of Microwave Devices

High-resolution X-ray diffraction method (XRD) is used to determine sizes and crystallographic orientation of the nanocrystallites of the Pd and Pd{sub 5}Ba phases in palladium–barium cathode. Electron spectroscopy for chemical analysis (ESCA) is used to study Ba and Pd chemical states in cathode material and determine the phase composition including dissolved microimpurities in the phases. The comparison of the XRD and ESCA data makes it possible to reveal effects related to the formation of the BaO crystallites in the cathode material, which are responsible for the emission properties. Electron-energy loss spectroscopy is used to determine the concentration of oxygen vacancies in the BaO crystallites that are formed in the cathode material due to activation. An original crystallite model of the working palladium–barium cathodes that is based on the results of this work may serve as an alternative to the known film model and makes it possible to optimize technology of cathode fabrication and activation.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2021

Molecular phylogenetic analysis of the Paguristes tortugae Schmitt, 1933 complex and selected other Paguroidea (Crustacea: Decapoda: Anomura)

Morphological characters, as presently applied to describe members of the Paguristes tortugae Schmitt, 1933 species complex, appear to be of limited value in inferring phylogenetic relationships within the genus, and may have similarly misinformed understanding of relationships between members of this complex and those presently assigned to the related genera Areopaguristes Rahayu & McLaughlin, 2010 and Pseudopaguristes McLaughlin, 2002. Previously undocumented observations of similarities and differences in color patterns among populations additionally suggest genetic divergences within some species, or alternatively seem to support phylogenetic groupings of some species. In the present study, a Maximum Likelihood (ML) phylogenetic analysis was undertaken based on the H3, 12S mtDNA, and 16S mtDNA sequences of 148 individuals, primarily representatives of paguroid species from the western Atlantic. This molecular analysis supported a polyphyletic Diogenidae Ortmann, 1892, although incomplete taxonomic sampling among the genera of Diogenidae limits the utility of this finding for resolving family level relationships. Several hypotheses regarding the evolutionary relationships among hermit crab genera were refuted by the Kishino-Hasegawa (KH). ShimodairaHasegawa (SH) and Approximately Unbiased (AU) tree topology tests, among them the hypothesis that Areopaguristes is monophyletic. A lack of support for the monophyly of Areopaguristes calls into question the phylogenetic validity of gill number for the differentiation of Paguristes, Areopaguristes, and Pseudopaguristes. The study was inconclusive with regard to the relationships among these three genera, but previously unknown diversity within both Paguristes and Areopaguristes was demonstrated. Existence of an undescribed species confounded under the name Paguristes tortugae Schmitt, 1933 was supported by genetics, morphology, and coloration. A second undescribed species with remarkable similarity to Areopaguristes hummi Wass, 1955 was discovered based on genetics and coloration.

12S↗
DOE OSTI2014

Energy Efficiency Adult Tracking Report - Final

Postwave tracking study for the Energy Efficiency Adult Campaign This study serves as measure of key metrics among the campaign’s target audience, homeowners age 25+. Key measures include: Awareness of messages relating to the broad issue; Recognition of the PSAs; Relevant attitudes, including interest, ease of taking energy efficient steps, and likelihood to act; Relevant knowledge, including knowledge of light bulb alternatives and energy efficient options; and Relevant behaviors, including specific energy-saving behaviors mentioned within the PSAs. Wave 1: May 27 – June 7, 2011 Wave 2: May 29 – June 8, 2012 Wave 3: May 29 – June 19, 2014 General market sample of adults 25+ who own their homes W1 sample: n = 704; W2: n=701; W3: n=806 Online Survey Panel Methodology Study was fielded by Lightspeed Research among their survey panel. Sample is US Census representative of US homeowners by race/ethnicity, income, age, region, and family status. At least 30% of respondents were required to have not updated major appliances in their home in the past 5 years (dishwasher, stove, refrigerator, washer, or dryer).

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2015

Determination of Adsorption Capacity and Kinetics of Amidoxime-Based Uranium Adsorbent Braided Material in Unfiltered Seawater Using a Flume Exposure System

PNNL has developed a recirculating flume system for exposing braided adsorbent material to natural seawater under realistic temperature and flow-rate exposure conditions. The flumes are constructed of transparent acrylic material; they allow external light to pass into the flumes and permit photosynthetic growth of naturally present marine organisms (biofouling). Because the system consists of two flumes, replicate experiments can be conducted in which one of the flumes can be manipulated relative to the other. For example, one flume can be darkened to eliminate light exposure by placing a black tarp over the flume such that dark/light experiments can be conducted. Alternatively, two different braided adsorbents can be exposed simultaneously with no potential cross contamination issues. This report describes the first use of the PNNL flume system to study the impact of biofouling on adsorbent capacity. Experiments were conducted with the ORNL AI8 braided adsorbent material in light-exposed and darkened flumes for a 42-day exposure experiment. The major objective of this effort is to develop a system for the exposure of braided adsorbent material to unfiltered seawater, and to demonstrate the system by evaluating the performance of adsorption material when it is exposed to natural marine biofouling as it would be when the technology is used in the marine environment. Exposures of amidoxime-based polymeric braid adsorbents prepared by Oak Ridge Natural Laboratory (ORNL) were exposed to ambient seawater at 20°C in a flume system. Adsorption kinetics and adsorption capacity were assessed using time series determinations of uranium adsorption and one-site ligand saturation modeling. Biofouling in sunlight surface seawater has the potential to significantly add substantial biogenic mass to adsorption material when it is exposed for periods greater than 21 days. The observed biomass increase in the light flume was approximately 80% of the adsorbent mass after 42 days. The amount of biomass increase retained by the adsorbent in the dark flume was only a quarter of that observed in the light-exposed flume. Biofouling in sunlit surface seawater has the potential to reduce uranium adsorption capacity by ~30% after 42 days of exposure. Minimal or no adsorption loss due to biofouling occurred in the dark flume exposure. Attempts to assess time series measurements of uranium adsorption capacity using “snips” off a master braid are fraught with problems due to the inability to easily determine the mass of the adsorbent material when the biofouling is present. The ability to determine the adsorption of biogenically important trace elements (e.g. Fe, Mn, Zn, Cu, and Sr) on biofouled adsorbents is also problematic.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗