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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,693 records · Page 94
All sourcesNASA NTRSDOE OSTI
DOE OSTI2013

CHARACTERIZING TWO SOLAR-TYPE KEPLER SUBGIANTS WITH ASTEROSEISMOLOGY: KIC 10920273 AND KIC 11395018

Determining fundamental properties of stars through stellar modeling has improved substantially due to recent advances in asteroseismology. Thanks to the unprecedented data quality obtained by space missions, particularly CoRoT and Kepler, invaluable information is extracted from the high-precision stellar oscillation frequencies, which provide very strong constraints on possible stellar models for a given set of classical observations. In this work, we have characterized two relatively faint stars, KIC 10920273 and KIC 11395018, using oscillation data from Kepler photometry and atmospheric constraints from ground-based spectroscopy. Both stars have very similar atmospheric properties; however, using the individual frequencies extracted from the Kepler data, we have determined quite distinct global properties, with increased precision compared to that of earlier results. We found that both stars have left the main sequence and characterized them as follows: KIC 10920273 is a one-solar-mass star (M = 1.00 {+-} 0.04 M {sub Sun }), but much older than our Sun (t = 7.12 {+-} 0.47 Gyr), while KIC 11395018 is significantly more massive than the Sun (M = 1.27 {+-} 0.04 M {sub Sun }) with an age close to that of the Sun (t = 4.57 {+-} 0.23 Gyr). We confirm that the high lithium abundance reported for these stars should not be considered to represent young ages, as we precisely determined them to be evolved subgiants. We discuss the use of surface lithium abundance, rotation, and activity relations as potential age diagnostics.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2021

Synthesis and Characterization of Magnesium Vanadates as Potential Magnesium-Ion Cathode Materials through an Ab Initio Guided Carbothermal Reduction Approach**

Many technologically relevant materials for advanced energy storage and catalysis feature reduced transition-metal (TM) oxides that are often nontrivial to prepare because of the need to control the reducing nature of the atmosphere in which they are synthesized. In this report, we show that an ab initio predictive synthesis strategy can be used to produce multi-gram-scale products of various MgV x O y -type phases (δ-MgV 2 O 5 , spinel MgV 2 O 4 , and MgVO 3 ) containing V 3+ or V 4+ relevant for Mg-ion battery cathodes. Characterization of these phases using 25 Mg solid-state NMR spectroscopy illustrates the potential of 25 Mg NMR for studying reversible magnesiation and local charge distributions. Rotor-assisted population transfer (RAPT) is used as a much-needed signal-to-noise enhancement technique. The ab initio guided synthesis method is seen as a step forward towards a predictive synthesis strategy for targeting specific complex TM oxides with variable oxidation states of technological importance.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2015

Thermal Properties Measurement Report

The Thermal Properties Measurement Report summarizes the research, development, installation, and initial use of significant experimental thermal property characterization capabilities at the INL in FY 2015. These new capabilities were used to characterize a U 3 Si 2 (candidate Accident Tolerant) fuel sample fabricated at the INL. The ability to perform measurements at various length scales is important and provides additional data that is not currently in the literature. However, the real value of the data will be in accomplishing a phenomenological understanding of the thermal conductivity in fuels and the ties to predictive modeling. Thus, the MARMOT advanced modeling and simulation capability was utilized to illustrate how the microstructural data can be modeled and compared with bulk characterization data. A scientific method was established for thermal property measurement capability on irradiated nuclear fuel samples, which will be installed in the Irradiated Material Characterization Laboratory (IMCL).

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2026

Polymer Deconstruction and Redesign Strategies for Plastics Recycling

Advancing plastics recycling requires both the selective deconstruction of existing polymers and the design of new materials that enable efficient reuse without loss of performance. This perspective highlights an integrated approach that is rooted in polymer chemistry, catalysis, and process engineering which can enable a circular plastics economy. Here, we outline recent advances in catalytic, solvolytic, and enzymatic pathways for plastic deconstruction, and examine the molecular design principles driving next-generation recyclable-by-design and bio-based polymers. Despite these advances, major knowledge gaps remain in understanding the evolution of polymer morphology and catalyst structure during deconstruction, assessing deconstruction processes with realistic polymers, and offering redesigned polymers with competitive cost and environmental advantage over conventional plastics. United States Department of Energy (U.S. DOE) national laboratories offer unique capabilities to address these challenges through in situ and operando characterization, high-throughput experimentation, environmental studies, technoeconomic and life cycle assessment, scale-up support, and collaboration networks. Advances made in understanding plastic deconstruction mechanisms and structure-property correlations of redesigned polymers inform emerging research directions including autonomous experimentation, real-time feedback-enabled process optimization, and protein engineering for enzymatic depolymerization.

36 MATERIALS SCIENCE↗
DOE OSTI2015

Visualizing nanoscale 3D compositional fluctuation of lithium in advanced lithium-ion battery cathodes

The distribution and concentration of lithium in Li-ion battery cathodes at different stages of cycling is a pivotal factor in determining battery performance. Non-uniform distribution of the transition metal cations has been shown to affect cathode performance; however, the Li is notoriously challenging to characterize with typical high-spatial-resolution imaging techniques. Here, for the first time, laser–assisted atom probe tomography is applied to two advanced Li-ion battery oxide cathode materials—layered Li 1.2 Ni 0.2 Mn 0.6 O 2 and spinel LiNi 0.5 Mn 1.5 O 4 —to unambiguously map the three dimensional (3D) distribution of Li at sub-nanometer spatial resolution and correlate it with the distribution of the transition metal cations (M) and the oxygen. The as-fabricated layered Li 1.2 Ni 0.2 Mn 0.6 O 2 is shown to have Li-rich Li 2 MO 3 phase regions and Li-depleted Li(Ni 0.5 Mn 0.5 )O 2 regions while in the cycled layered Li 1.2 Ni 0.2 Mn 0.6 O 2 an overall loss of Li and presence of Ni rich regions, Mn rich regions and Li rich regions are shown in addition to providing the first direct evidence for Li loss on cycling of layered LNMO cathodes. The spinel LiNi 0.5 Mn 1.5 O 4 cathode is shown to have a uniform distribution of all cations. These results were additionally validated by correlating with energy dispersive spectroscopy mapping of these nanoparticles in a scanning transmission electron microscope. Thus, we have opened the door for probing the nanoscale compositional fluctuations in crucial Li-ion battery cathode materials at an unprecedented spatial resolution of sub-nanometer scale in 3D which can provide critical information for understanding capacity decay mechanisms in these advanced cathode materials.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Anisotropic Characterizations of Electrospun PAN Nanofiber Mats Using Design of Experiments

This paper deals with the dielectric and mechanical characterizations of polyacrylonitrile (PAN)-aligned electrospun nanofiber mats. A two factor three level full factorial experiment is conducted to understand the effect of various parameters on dielectric and mechanical responses. These responses are recorded against randomly oriented and aligned nanofiber mats. Improved properties of electrospun mats have applications in the field of energy storage and nanocomposite reinforcement. Dielectric and mechanical characterizations of PAN mats are vital, as the aligned electrospun mats were found to be useful in advanced energy and mechanical reinforcement applications. Therefore, it is paramount to understand the effects of system parameters to these properties. The design of experiment (DoE) includes two factors and three level full factorial experiments with concentrations of PAN solutions at 8 wt.%, 9 wt.%, and 10 wt.%, and speed of the rotating mandrel (collector) at 3 volt (V), 4 V, and 5 V inputs. The electric field intensity used in the experiment is 1 kV/cm. DoE is conducted to understand the nonlinear interactions of parameters to these responses. The dielectric and mechanical characterizations of 8 wt.%, 9 wt.%, and 10 wt.% with different speeds for the original and improved systems are discussed. It was observed that at 9 wt.% and at all mandrel speeds, the dielectric and tensile properties are optimum.

42 ENGINEERING↗
DOE OSTI2016

Seismic Fracture Characterization Methodologies for Enhanced Geothermal Systems

Executive Summary The overall objective of this work was the development of surface and borehole seismic methodologies using both compressional and shear waves for characterizing faults and fractures in Enhanced Geothermal Systems. We used both surface seismic and vertical seismic profile (VSP) methods. We adapted these methods to the unique conditions encountered in Enhanced Geothermal Systems (EGS) creation. These conditions include geological environments with volcanic cover, highly altered rocks, severe structure, extreme near surface velocity contrasts and lack of distinct velocity contrasts at depth. One of the objectives was the development of methods for identifying more appropriate seismic acquisition parameters for overcoming problems associated with these geological factors. Because temperatures up to 300º C are often encountered in these systems, another objective was the testing of VSP borehole tools capable of operating at depths in excess of 1,000 m and at temperatures in excess of 200º C. A final objective was the development of new processing and interpretation techniques based on scattering and time-frequency analysis, as well as the application of modern seismic migration imaging algorithms to seismic data acquired over geothermal areas. The use of surface seismic reflection data at Brady's Hot Springs was found useful in building a geological model, but only when combined with other extensive geological and geophysical data. The use of fine source and geophone spacing was critical in producing useful images. The surface seismic reflection data gave no information about the internal structure (extent, thickness and filling) of faults and fractures, and modeling suggests that they are unlikely to do so. Time-frequency analysis was applied to these data, but was not found to be significantly useful in their interpretation. Modeling does indicate that VSP and other seismic methods with sensors located at depth in wells will be the most effective seismic tools for getting information on the internal structure of faults and fractures in support of fluid flow pathway management and EGS treatment. Scattered events similar to those expected from faults and fractures are seen in the VSP reported here. Unfortunately, the source offset and well depth coverage do not allow for detailed analysis of these events. This limited coverage also precluded the use of advanced migration and imaging algorithms. More extensive acquisition is needed to support fault and fracture characterization in the geothermal reservoir at Brady's Hot Springs. The VSP was effective in generating interval velocity estimates over the depths covered by the array. Upgoing reflection events are also visible in the VSP results at locations corresponding to reflection events in the surface seismic. Overall, the high temperature rated fiber optic sensors used in the VSP produced useful results. Modeling has been found useful in the interpretation of both surface reflection seismic and VSP data. It has helped identify possible near surface scattering in the surface seismic data. It has highlighted potential scattering events from deeper faults in the VSP data. Inclusion of more detailed fault and fracture specific stiffness parameters are needed to fully interpret fault and fracture scattered events for flow properties (Pyrak-Nolte and Morris, 2000, Zhu and Snieder, 2002). Shear wave methods were applied in both the surface seismic reflection and VSP work. They were not found to be effective in the Brady's Hot Springs area. This was due to the extreme attenuation of shear waves in the near surface at Brady's. This does not imply that they will be ineffective in general. In geothermal areas where good shear waves can be recorded, modeling suggests they should be very useful for characterizing faults and fractures.

15 GEOTHERMAL ENERGY↗
DOE OSTI2012

Advanced Nuclear Fuel Cycle Effects on the Treatment of Uncertainty in the Long-Term Assessment of Geologic Disposal Systems - EBS Input

The Used Fuel Disposition (UFD) Campaign within the Department of Energy's Office of Nuclear Energy (DOE-NE) Fuel Cycle Technology (FCT) program has been tasked with investigating the disposal of the nation's spent nuclear fuel (SNF) and high-level nuclear waste (HLW) for a range of potential waste forms and geologic environments. The planning, construction, and operation of a nuclear disposal facility is a long-term process that involves engineered barriers that are tailored to both the geologic environment and the waste forms being emplaced. The UFD Campaign is considering a range of fuel cycles that in turn produce a range of waste forms. The UFD Campaign is also considering a range of geologic media. These ranges could be thought of as adding uncertainty to what the disposal facility design will ultimately be; however, it may be preferable to thinking about the ranges as adding flexibility to design of a disposal facility. For example, as the overall DOE-NE program and industrial actions result in the fuel cycles that will produce waste to be disposed, and the characteristics of those wastes become clear, the disposal program retains flexibility in both the choice of geologic environment and the specific repository design. Of course, other factors also play a major role, including local and State-level acceptance of the specific site that provides the geologic environment. In contrast, the Yucca Mountain Project (YMP) repository license application (LA) is based on waste forms from an open fuel cycle (PWR and BWR assemblies from an open fuel cycle). These waste forms were about 90% of the total waste, and they were the determining waste form in developing the engineered barrier system (EBS) design for the Yucca Mountain Repository design. About 10% of the repository capacity was reserved for waste from a full recycle fuel cycle in which some actinides were extracted for weapons use, and the remaining fission products and some minor actinides were encapsulated in borosilicate glass. Because the heat load of the glass was much less than the PWR and BWR assemblies, the glass waste form was able to be co-disposed with the open cycle waste, by interspersing glass waste packages among the spent fuel assembly waste packages. In addition, the Yucca Mountain repository was designed to include some research reactor spent fuel and naval reactor spent fuel, within the envelope that was set using the commercial reactor assemblies as the design basis waste form. This milestone report supports Sandia National Laboratory milestone M2FT-12SN0814052, and is intended to be a chapter in that milestone report. The independent technical review of this LLNL milestone was performed at LLNL and is documented in the electronic Information Management (IM) system at LLNL. The objective of this work is to investigate what aspects of quantifying, characterizing, and representing the uncertainty associated with the engineered barrier are affected by implementing different advanced nuclear fuel cycles (e.g., partitioning and transmutation scenarios) together with corresponding designs and thermal constraints.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2018

Preliminary Characterization and Mechanical Performance of Additively Manufactured HT9

Laser-blown powder deposition of HT9 was performed to evaluate the feasibility of using advanced manufacturing to fabricate creep strength enhanced ferritic steels. The as-printed materials were tensile tested at room temperature, 330°C, and 550°C to provide a baseline value for the strength levels. The as-fabricated strengths are then compared with wrought materials in the published literature. The strength parameters for the as-fabricated HT9 was found to be significantly higher than that of wrought HT9 without sacrifice in ductility. Two different heat treatment cycles, deemed ACO3 and FCRD, involving two different austentizing temperatures (1065°C and 1040°C) and tempering temperatures (750°C and 760°C) were then evaluated. The heat-treated samples were also tensile tested and were found to show strength and ductility parameters which closely mimicked that of the wrought HT9 literature data. Detailed multi-scale characterization was performed at various length scales. The as-fabricated structure showed a refined martensitic structure with a significant fraction of δ-ferrite present. Closer examination using TEM showed a refined distribution of carbides (predominantly M 23 C 6 and MX or M2X), which would have precipitated during the deposition process. Upon heat treatment, it was seen that the precipitates were more homogenous and refined in the case of the specimens heat treated according to the ACO 3 cycle although there was no significant difference in the strength or the hardness results. However, the specimens heat-treated per the FCRD cycle showed significantly smaller prior austenite grains (measure and give quantitative numbers), which could result in better Charpy toughness. However, the toughness was not evaluated and will be performed in the future. In addition, possible thermos-mechanical treatments (TMT) to refine the grain structure and improve the toughness without compromising the ductility will also be evaluated in the future.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Sphingolipidomics analysis of large clinical cohorts. Part 2: Potential impact and applications

Highlights: • Sphingolipids have diverse biological roles in essentially every eukaryotic cell. • An understanding of these roles is improving due to advances in mass spectrometry. • Resulting sphingolipidomic profiles are becoming increasingly detailed. • This improves our understanding of disease and identifies potential biomarkers. • This review discusses biomedical applications of sphingolipidomics. It has been known for decades that the regulation of sphingolipids (SLs) is essential for the proper function of many cellular processes. However, a complete understanding of these processes has been complicated by the structural diversity of these lipids. A well-characterized metabolic pathway is responsible for homeostatic maintenance of hundreds of distinct SL species. This pathway is perturbed in a number of pathological processes, resulting in derangement of the “sphingolipidome.” Recently, advances in mass spectrometry (MS) techniques have made it possible to characterize the sphingolipidome in large-scale clinical studies, allowing for the identification of specific SL molecules that mediate pathological processes and/or may serve as biomarkers. This manuscript provides an overview of the functions of SLs, and reviews previous studies that have used MS techniques to identify changes to the sphingolipidome in non-metabolic diseases.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2017

Advanced Tele-operation and Shared Autonomy for Nuclearized Robotic Systems - 17333

Remotely-initiated operations have existed for more than 50 years in the nuclear weapons complex, as the environments are far too extreme for humans. We introduce the scope of the nuclear waste cleanup effort and describe some existing applications of robotics technology at specific sites. We offer summaries of both the technology that is currently used, as well as a discussion of the types of problems that the technology is applied to. We contrast this with the current state of practice in other areas where robots are deployed in the real world, such as with military infantry units. We then go on to summarize and discuss the current state of the art in advanced tele-operation research and in shared autonomy, where humans collaborate with closed-loop automation to complete tasks. Our discussion focuses on areas with particular relevance to nuclear waste management, such as remote inspection and manipulation. Armed with this background, we then identify specific technology gaps that must be closed in order to successfully bring advanced tele-operation and shared autonomy technologies to bear on problems in nuclear waste management, such as (1) environmental remediation; (2) sampling, characterization, and disposition of tanks with hazardous and highly radioactive waste and (3) decontamination and decommissioning of facilities with gloveboxes and hot cells. We propose a roadmap for how to transition the current state of the art approaches in advanced robotics and shared autonomy to practice in the nuclear industry and how to close the technology gaps previously identified. This roadmap covers not only the technical advances that need to be made, but also considers the social and societal aspects. Drawing parallels with the adoption of similar technologies in the military and other areas, we offer concrete suggestions for how to deploy these new technologies effectively into the nuclear industry from a human-centered perspective. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2011

Biorefinery and Hydrogen Fuel Cell Research (Final Technical Report)

In this project we focused on several aspects of technology development that advances the formation of an integrated biorefinery. These focus areas include: [1] establishment of pyrolysis processing systems and characterization of the product oils for fuel applications, including engine testing of a preferred product and its pro forma economic analysis; [2] extraction of sugars through a novel hotwater extaction process, and the development of levoglucosan (a pyrolysis BioOil intermediate); [3] identification and testing of the use of biochar, the coproduct from pyrolysis, for soil applications; [4] developments in methods of atomic layer epitaxy (for efficient development of coatings as in fuel cells); [5] advancement in fermentation of lignocellulosics, [6] development of algal biomass as a potential substrate for the biorefinery, and [7] development of catalysts from coproducts. These advancements are intended to provide a diverse set of product choices within the biorefinery, thus improving the cost effectiveness of the system. Technical effectiveness was demonstrated in the pyrolysis biooil based diesel fuel supplement, sugar extraction from lignocelluose, use of biochar, production of algal biomass in wastewaters, and the development of catalysts. Economic feasibility of algal biomass production systems seems attractive, relative to the other options. However, further optimization in all paths, and testing/demonstration at larger scales are required to fully understand the economic viabilities. The various coproducts provide a clear picture that multiple streams of value can be generated within an integrated biorefinery, and these include fuels and products.

09 BIOMASS FUELS↗
DOE OSTI2014

Recent advances in long-pulse high-confinement plasma operations in Experimental Advanced Superconducting Tokamak

A long-pulse high confinement plasma regime known as H-mode is achieved in the Experimental Advanced Superconducting Tokamak (EAST) with a record duration over 30 s, sustained by Lower Hybrid wave Current Drive (LHCD) with advanced lithium wall conditioning and divertor pumping. This long-pulse H-mode plasma regime is characterized by the co-existence of a small Magneto-Hydrodynamic (MHD) instability, i.e., Edge Localized Modes (ELMs) and a continuous quasi-coherent MHD mode at the edge. We find that LHCD provides an intrinsic boundary control for ELMs, leading to a dramatic reduction in the transient power load on the vessel wall, compared to the standard Type I ELMs. LHCD also induces edge plasma ergodization, broadening heat deposition footprints, and the heat transport caused by ergodization can be actively controlled by regulating edge plasma conditions, thus providing a new means for stationary heat flux control. In addition, advanced tokamak scenarios have been newly developed for high-performance long-pulse plasma operations in the next EAST experimental campaign.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2015

Groundwater flow characterization in a fractured bedrock aquifer using active DTS tests in sealed boreholes

In recent years, wireline temperature profiling methods have evolved to offer new insight into fractured rock hydrogeology. Important advances in wireline temperature logging in boreholes make use of active line source heating alone and then in combination with temporary borehole sealing with flexible impervious fabric liners to eliminate the effects of borehole cross-connection and recreate natural flow conditions. Here, a characterization technique was developed based on combining fiber optic distributed temperature sensing (DTS) with active heating within boreholes sealed with flexible borehole liners. DTS systems provide a temperature profiling method that offers significantly enhanced temporal resolution when compared with conventional wireline trolling-based techniques that obtain a temperature–depth profile every few hours. The ability to rapidly and continuously collect temperature profiles can better our understanding of transient processes, allowing for improved identification of hydraulically active fractures and determination of relative rates of groundwater flow. Here, the advantage of a sealed borehole environment for DTS-based investigations is demonstrated through a comparison of DTS data from open and lined conditions for the same borehole. Evidence for many depth-discrete active groundwater flow features under natural gradient conditions using active DTS heat pulse testing is presented along with high resolution geologic and geophysical logging and hydraulic datasets. Implications for field implementation are discussed.

15 GEOTHERMAL ENERGY↗
DOE OSTI2019

The ARM Radar Network: At the Leading-edge of Cloud and Precipitation Observations

The ARM observatories include radars that span a range of frequencies and capabilities to characterize the three-dimensional structure and properties of atmospheric hydrometeors. Improving our ability to predict future weather and climate conditions is strongly linked to achieving significant advancements in our understanding of cloud and precipitation processes. Observations are critical to making these advancements because they both improve our understanding of these processes and provide constraints on numerical models. Historically, instruments for observing cloud properties have limited cloud-aerosol investigations to a small subset of cloud-process interactions. To address these challenges, the last decade has seen the U.S. DOE ARM facility significantly upgrade and expand its surveillance radar capabilities towards providing holistic and multi-scale observations of clouds and precipitation. These upgrades include radars that operate at four frequency bands covering a wide range of scattering regimes, improving upon the information contained in earlier ARM observations. The traditional ARM emphasis on the vertical column is maintained, providing more comprehensive, calibrated, and multiparametric measurements of clouds and precipitation. Furthermore, the ARM radar network now features multiple scanning dual-polarization Doppler radars to exploit polarimetric and multi-Doppler capabilities that provide a wealth of information on storm microphysics and dynamics under a wide range of conditions. While the diversity in wavelengths and detection capabilities are unprecedented, there is still considerable work ahead before the full potential of these radar advancements is realized. This includes synergy with other observations, improved forward and inverse modeling methods, and well-designed data-model integration methods. The overarching goal is to offer a comprehensive characterization of a complete volume of the cloudy atmosphere and to act as a natural laboratory for the study of cloud processes.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2017

Status and Update of the RaDIATE Collaboration R&D Program

The Radiation Damage In Accelerator Target Environments (RaDIATE) collaboration was founded in 2012 and currently consists of over 50 participants and 11 institutions globally. Due to the increasing power of future proton accelerator sources in target facilities, there is a critical need to further understand the physical and thermo-mechanical radiation response of target facility materials. Thus, the primary objective of the RaDIATE collaboration is to draw on existing expertise in the nuclear materials and accelerator targets fields to generate new and useful materials data for application within the accelerator and fission/fusion communities. Current research activities of the collaboration include post irradiation examination (PIE) of decommissioned components from existing beamlines such as the NuMI beryllium beam window and graphite NT-02 target material. PIE of these components includes advanced microstructural analyses (SEM/TEM, EBSD, EDS) and micro-mechanics technique such as nano-indentation, to help characterize any microstructural radiation damage incurred during operation. New irradiation campaigns of various candidate materials at both low and high energy beam facilities are also being pursued. Beryllium helium implantation studies at the University of Surrey as well as high energy proton irradiation of various materials at Brookhaven National Laboratory’s BLIP facility have been initiated. The program also extends to beam-induced thermal shock experiments using high intensity beam pulses at CERN’s HiRadMat facility, followed by advanced PIE activities to evaluate thermal shock resistance of the materials. Preliminary results from ongoing research activities, as well as the future plans of the RaDIATE collaboration R&D program will be discussed.

43 PARTICLE ACCELERATORS↗
DOE OSTI2018

Characterization Report on Fuels for NEAMS Model Validation

ABSTRACT U3Si2 has become a material of interest for its potential as an accident tolerant fuel used in commercial light water reactors. In order to better understand the nature of the 5f-electrons and mechanisms that govern electrical and heat transport in U3Si2, and to accurately model this compound at all relevant temperatures we have performed detailed studies of this material by means of the heat capacity, electrical resistivity, Seebeck and Hall effects, and thermal conductivity. Polycrystalline samples of U3Si2 were prepared by arc-melting stoichiometric amounts of elemental U and Si. All the results obtained, especially small magneto-resistivity, large low-temperature heat capacity, and characteristic dependence of the Seebeck coefficient, point to delocalized nature of 5f-electrons in U3Si2. The thermal conductivity is ~8.5 W/m-K at room temperature and we show that the lattice part of the total thermal conductivity is small, with electrons dominating heat transport above 300 K. This knowledge of the details of the heat transport in U3Si2 will be useful for researchers working on modeling and simulations of this new advanced fuel.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2021

Development of platforms for functional characterization and production of phenazines using a multi-chassis approach via CRAGE

Phenazines (Phzs), a family of chemicals with a phenazine backbone, are secondary metabolites with diverse properties such as antibacterial, anti-fungal, or anticancer activity. The core derivatives of phenazine, phenazine-1-carboxylic acid (PCA) and phenazine-1,6-dicarboxylic acid (PDC), are themselves precursors for various other derivatives. Recent advances in genome mining tools have enabled researchers to identify many biosynthetic gene clusters (BGCs) that might produce novel Phzs. Here, to characterize the function of these BGCs efficiently, we performed modular construct assembly and subsequent multi-chassis heterologous expression using chassis-independent recombinase-assisted genome engineering (CRAGE). CRAGE allowed rapid integration of a PCA BGC into 23 diverse γ-proteobacteria species and allowed us to identify top PCA producers. We then used the top five chassis hosts to express four partially refactored PDC BGCs. A few of these platforms produced high levels of PDC. Specifically, Xenorhabdus doucetiae and Pseudomonas simiae produced PDC at a titer of 293 mg/L and 373 mg/L, respectively, in minimal media. These titers are significantly higher than those previously reported. Furthermore, selectivity toward PDC production over PCA production was improved by up to 9-fold. The results show that these strains are promising chassis for production of PCA, PDC, and their derivatives, as well as for function characterization of Phz BGCs identified via bioinformatics mining.

54 ENVIRONMENTAL SCIENCES↗