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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,675 records · Page 93

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DOE OSTI2022

Ultrafast perturbation of magnetic domains by optical pumping in a ferromagnetic multilayer

Ultrafast optical pumping of spatially nonuniform magnetic textures is known to induce far-from-equilibrium spin transport effects. Here, we use ultrafast x-ray diffraction with unprecedented dynamic range to study the laser-induced dynamics of labyrinth domain networks in ferromagnetic CoFe/Ni multilayers. We detected azimuthally isotropic, odd order, magnetic diffraction rings up to fifth order. The amplitudes of all three diffraction rings quench to different degrees within 1.6 ps. In addition, all three of the detected diffraction rings both broaden by 15% and radially contract by 6% during the quench process. We are able to rigorously quantify a 31% ultrafast broadening of the domain walls via Fourier analysis of the order-dependent quenching of the three detected diffraction rings. Here, the broadening of the diffraction rings is interpreted as a reduction in the domain coherence length, but the shift in the ring radius, while unambiguous in its occurrence, remains unexplained. In particular, we demonstrate that a radial shift explained by domain-wall broadening can be ruled out. With the unprecedented dynamic range of our data, our results provide convincing evidence that labyrinth domain structures are spatially perturbed at ultrafast speeds under far-from-equilibrium conditions, albeit the mechanism inducing the perturbations remains yet to be clarified.

36 MATERIALS SCIENCE↗

DOE OSTI2021

Cytochrome P450–catalyzed biosynthesis of furanoditerpenoids in the bioenergy crop switchgrass ( Panicum virgatum L.)

Specialized diterpenoid metabolites are important mediators of plant-environment interactions in monocot crops. To understand metabolite functions in plant environmental adaptation that ultimately can enable crop improvement strategies, a deeper knowledge of the underlying species-specific biosynthetic pathways is required. Furthermore, we report the genomics-enabled discovery of five cytochrome P450 monooxygenases (CYP71Z25-CYP71Z29) that form previously unknown furanoditerpenoids in the monocot bioenergy crop Panicum virgatum (switchgrass). Combinatorial pathway reconstruction showed that CYP71Z25-CYP71Z29 catalyze furan ring addition directly to primary diterpene alcohol intermediates derived from distinct class II diterpene synthase products. Transcriptional co-expression patterns and the presence of select diterpenoids in switchgrass roots support the occurrence of P450-derived furanoditerpenoids in planta. Integrating molecular dynamics, structural analysis and targeted mutagenesis identified active site determinants that contribute to the distinct catalytic specificities underlying the broad substrate promiscuity of CYP71Z25-CYP71Z29 for native and non-native diterpenoids.

59 BASIC BIOLOGICAL SCIENCES↗

DOE OSTI2021

Gas Phase Synthesis of Benzene via the Propargyl Radical Self-Reaction

Polycyclic Aromatic Hydrocarbons (PAHs) have been invoked in fundamental molecular mass growth processes in our galaxy. We provide compelling evidence of the formation of the very first ringed aromatic and building block of PAHs - benzene - via the self-recombination of two resonantly stabilized propargyl (C 3 H 3 ) radicals in dilute environments using isomer selective synchrotron-based mass spectrometry coupled to theoretical calculations. Along with benzene, three other structural isomers (1,5-hexadiyne, fulvene, 2-ethynyl-1,3-butadiene) and o-benzyne are detected and their branching ratios quantified experimentally and verified with the aid of computational fluid dynamics and kinetic simulations. Furthermore, these results uncover molecular growth pathways not only in interstellar, circumstellar, and solar systems environments, but also in combustion systems gaining us a better understanding of the hydrocarbon chemistry of our universe.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS1972

Mascons - Progress toward a unique solution for mass distribution.

Through a series of analyses with high-altitude Lunar Orbiter and low-altitude Apollo 15 Doppler gravity data, it is shown that the Serenity mascon is a thin body whose horizontal dimensions are well determined and show a strong correlation with circular wrinkle ridge structure. Analysis to date has not uniquely determined the depth of the anomalous mass. However, geological evidence strongly suggests that the mass excess is near the surface, because (1) the surface solution has a geometry highly suggestive of the partial filling of a ringed circular basin, and (2) the boundaries of the anomalous mass separate regions of shallow and deep mare flooding.

Phillips, R. J.↗

NASA NTRS1974

Design and fabrication of a boron reinforced intertank skirt

Analytical and experimental studies were performed to evaluate the structural efficiency of a boron reinforced shell, where the medium of reinforcement consists of hollow aluminum extrusions infiltrated with boron epoxy. Studies were completed for the design of a one-half scale minimum weight shell using boron reinforced stringers and boron reinforced rings. Parametric and iterative studies were completed for the design of minimum weight stringers, rings, shells without rings and shells with rings. Computer studies were completed for the final evaluation of a minimum weight shell using highly buckled minimum gage skin. The detail design is described of a practical minimum weight test shell which demonstrates a weight savings of 30% as compared to an all aluminum longitudinal stiffened shell. Sub-element tests were conducted on representative segments of the compression surface at maximum stress and also on segments of the load transfer joint. A 10 foot long, 77 inch diameter shell was fabricated from the design and delivered for further testing.

Henshaw, J.↗

NASA NTRS1983

Two-dimensional photometry of planetary nebulae

In connection with the study of planetary nebulae, problems still exist in understanding such basic properties as three-dimensional structure, optical opacity to the central star's ionizing flux, and electron temperature and electron density variations within the nebular gas. To study these properties, two-dimensional images taken in many spectral lines are required. However, such a study presents a formidable problem in data analysis. In the present investigation, an attempt has been made to overcome the difficulties by using an imaging system which encodes the data digitally. Calibrated intensity maps could be constructed to test models of ionization structure and to produce two-dimensional maps of electron temperature and density. Both the results of a uniform-shell test and the nature of the solutions for the volume emissivity were found to support a nebular model in which the bright ring is part of a closed shell of variable density that resembles the torus proposed by Minkowski and Osterbrock (1960).

Kupferman, P. N.↗

NASA NTRS1984

Transition and mixing in impulsively started jets and vortex rings

A new method is used to analyze transition in impulsively started jets and vortex rings. The method uses similarity variables to reduce the equations for unsteady particle paths to a quasi-autonomous system with the Reynolds number as a parameter. The flow pattern is represented in terms of the phase portrait of this system and the structure of the flow is defined by its critical points. Flow transition is examined in terms of bifurcations in the topology of the phase portrait which occur as the Reynolds number is increased. There is no assumption that the flow is parallel or that it is subjected to small disturbances. The method of analysis, through straightforward, is new and lies outside the usual small disturbance theory used to determine the stability of various profile shapes.

Cantwell, B. J.↗

NASA NTRS1988

High-temperature combustor liner tests in structural component response test facility

Jet engine combustor liners were tested in the structural component response facility at NASA Lewis. In this facility combustor liners were thermally cycled to simulate a flight envelope of takeoff, cruise, and return to idle. Temperatures were measured with both thermocouples and an infrared thermal imaging system. A conventional stacked-ring louvered combustor liner developed a crack at 1603 cycles. This test was discontinued after 1728 cycles because of distortion of the liner. A segmented or float wall combustor liner tested at the same heat flux showed no significant change after 1600 cycles. Changes are being made in the facility to allow higher temperatures.

Moorhead, Paul E.↗

NASA NTRS1987

Structural analysis of a bolted joint concept for the Space Shuttle's solid rocket motor casing

The Space Shuttle Challenger accident is thought to have been caused by the failure of one of the tang-clevis joints which join together the casing segments of the Solid Rocket Motors (SRM). Excessive displacement between the tang and clevis, possibly unseating the O-ring seals, may have initiated the resulting accident. An effort was undertaken at NASA's Langley Research Center to design an alternative concept for mating the casing segments. A bolted flanged joint concept was designed and analyzed to determine if the concept would effectively maintain a seal while minimizing joint weight and controlling stress levels. It is shown that under the loading condition analyzed the seal area of the joint remains seated. The only potential stress problem is a stress concentration in the flange at the edge of the bolt hole, which is highly localized. While heavier than the existing joint, this concept does have some advantages which make the bolted joint an attractive alternative.

Lindell, Michael C.↗

DOE OSTI2026

Formation of 1 H -Phenalene (C 13 H 10 ) in the Taurus Molecular Cloud via Methylidyne Addition-Cyclization-Aromatization (MACA)

The formation of 1H-phenalene (C 13 H 10 ) in cold molecular clouds, such as the Taurus Molecular Cloud-1 (TMC-1), presents a significant challenge to traditional astrochemical models, which predominantly suggest high-temperature pathways for polycyclic aromatic hydrocarbon (PAH) formation. In this study, we explore computationally the Methylidyne Addition-Cyclization-Aromatization (MACA) mechanism as a viable, barrierless pathway for phenalene synthesis under low-temperature conditions. Through electronic structure calculations and Rice–Ramsperger–Kassel–Marcus (RRKM) statistical methods, we demonstrate that the reaction of 1-vinylnaphthalene (C 10 H 7 C 2 H 3 ) with the methylidyne radical (CH) leads to the formation of 1H-phenalene via a bimolecular reaction, a process that is exoergic and without entrance barrier. The MACA mechanism facilitates the growth of the aromatic carbon backbone via a [5 + 1] ring annulation, providing a new insight into PAH formation in cold molecular clouds. Notably, the MACA mechanism has previously been shown to form indene (C9H8), which was detected in TMC-1 as well, via a [4 + 1] annulation, demonstrating its potential to produce a variety of complex PAHs by addition of a five- and six-membered ring to a benzene moiety via [4 + 1] and [5 + 1] annulation, respectively. As a result, this work highlights the importance of barrierless, exoergic reactions involving MACA in the synthesis of complex aromatic molecules in space, expanding our physicochemical understanding of carbon-rich chemistry in cold molecular clouds.

Aromatic compounds↗

DOE OSTI2026

Anion-dependent phase behavior of methylimidazolium-based ionic liquids mixed with water: Correlation between local molecular structure and mesoscale behaviors

The mesoscopic phase behavior of decylmethylimidazolium (C 10 mim) ionic liquids (ILs) bearing three monovalent anions—thiocyanate (SCN − ), nitrate (NO 3 − ), and chloride (Cl − )—mixed with water at relatively high IL contents (50–95 wt%) was investigated. Small-angle and wide-angle X-ray scattering (SAXS/WAXS) were employed to follow the evolution of both local and mesoscale structures across this composition range. In the absence of water, C 10 mimSCN and C 10 mimCl behaved as disordered liquids, whereas C 10 mimNO 3 spontaneously formed a hexagonally ordered cylindrical mesophase and displayed a sticky-solid macroscopic appearance. Upon addition of water, C 10 mimSCN remained a viscous liquid and only weakly ordered lamellar domains were observed. This limited ordering is attributed to the lack of hydrogen bonding and weak interaction energy between SCN − anions and C 10 mim + cations. In contrast, the trigonal-planar NO 3 − and point-like Cl − anions promoted the formation of well-defined hexagonal mesophases up to 35–45 wt% water. The formation of hydrogen bonding of the two anions with imidazolium ring protons likely enabled the creation of compact ion clusters that effectively exclude water molecules from the immediate vicinity of the IL aggregates. These findings demonstrate that the interaction energy between ion pairs dictate IL-water interactions and therefore control the transition from disordered liquids to ordered mesophases in IL/water mixtures with high IL contents. In conclusion, the combined SAXS/WAXS analysis reveals a correlation between local intermolecular structure and the emergence of mesoscopic order, providing a systematic framework for tailoring mesoscale structures in alkylimidazolium-based IL/water systems.

36 MATERIALS SCIENCE↗

NASA NTRS2001

ALEXIS Observations of the Monogem Ring Supernova Remnant

The subject grant is for the analysis of ALEXIS observations of the Monogem Ring supernova remnant using the diffuse all-sky maps produced from the ALEXIS all-sky survey. The work is to produce ratio maps of the three energy bands provided by ALEXIS, analyze the ratio data to constrain the intervening neutral hydrogen column density and the temperature and elemental abundances of the X-ray emitting gas, compare the structure to that observed in the ROSAT maps, and incorporate the results into current supenova remnant evolution models. The work outlined above has been significantly delayed since the ALEXIS diffuse all-sky maps took longer to produce than anticipated. Unfortunately, the ALEXIS satellite suffered a failure of the Pegasus launch vehicle which left the satellite in a partially functioning condition. The attitude control system of the spacecraft was unable to operate as planned and this has greatly increased the complexity of the aspect solution. Our colleagues at Los Alamos have made progress in producing these maps and are nearing completion of the final maps. However, the quality of the data have been significantly compromised by the overall lower exposure due to the spacecraft problems and the higher background of the micro-channel plate detectors. We have compared the ALEXIS and ROSAT maps of this region of the sky and there is no obvious signal in the ALEXIS maps of the Monogem Ring. We are now exploring correlation techniques to determine if there is indeed a faint signal in the ALEXIS maps. Although, the project has been a disappointment so far, the data may still provide a valuable lower limit on the neutral hydrogen column density. This is a far cry from our original intentions, but would still be valuable science. Given the large delays in producing the ALEXIS sky maps, this work will continue past the end of the grant period.

Plucinsky, Paul↗

DOE OSTI2025

Visualizing the Three-Dimensional Arrangement of Hydrogen Atoms in Organic Molecules by Coulomb Explosion Imaging

Structure-sensitive methods based on femtosecond light or electron pulses are now making it possible to measure how molecular structures change during light-induced processes. Despite significant progress, high-fidelity imaging of nuclear positions remains a challenge even for relatively small molecular systems and, notably, regarding the positions of hydrogen atoms. As demonstrated in recent work, X-ray-induced Coulomb explosion imaging (CEI) may overcome this obstacle, as its sensitivity does not depend on the mass of the imaged atoms. The photoinduced ring opening of the heterocyclic molecule 2(5 H )-thiophenone has attracted recent interest. Here, in this work, we show that CEI offers a powerful route to imaging the peripheral H atoms in this molecule and thus, more generally, to tracking detailed nuclear motions (e.g., isomerizations) in organic molecules on ultrafast time scales. Specifically, we record momentum-space Coulomb explosion images that report on the three-dimensional positioning of all nuclei within the molecule, for instance, distinguishing H atoms in C–H bonds that lie within or are directed out of the plane defined by the heavy atoms. The prospect of imaging peripheral H atoms to probe photochemical dynamics is explored by coupling ab initio molecular dynamics with classical Coulomb explosion simulations, thereby differentiating potential photoproduct isomers, including those whose structures primarily differ in the position of the hydrogens.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2024

Experimental Verification of Integrability in a Danilov-Nagaitsev Lattice using Machine Learning

In non-linear optics, achieving integrability can enhance the dynamic aperture in storage rings. We analyze turn-by-turn phase-space data from our Danilov-Nagaitsev lattice implementation at Fermilab's Integrable Optics Test Accelerator using machine learning. \textit{AI Poincar\'e} estimates conserved quantities from experimental data without prior knowledge of the invariant structure, showing qualitative agreement with theoretical predictions. Additionally, one of the two learned invariants exhibits comparable or better conservation compared to known theoretical expressions.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

NASA NTRS1979

Load concentration due to missing members in planar faces of a large space truss

A large space structure with members missing was investigated using a finite element analysis. The particular structural configuration was the tetrahedral truss, with attention restricted to one of its planar faces. Initially the finite element model of a complete face was verified by comparing it with known results for some basic loadings. Then an analysis was made of the structure with members near the center removed. Some calculations were made on the influence of the mesh size of a structure containing a hexagonal hole, and an analysis was also made of a structure with a rigid hexagonal insert. In general, load concentration effects in these trusses were significantly lower than classical stress concentration effects in an infinitely wide isotropic plate with a circular rigid inclusion, although larger effects were obtained when a hole extended over several rings of elements.

Waltz, J. E.↗

NASA NTRS1980

Collapse and equilibrium of rotating, adiabatic clouds

A numerical hydrodynamics computer code analysis of the collapse and establishment of equilibrium of adiabatic gas clouds restricted to axial symmetry found that the clouds are originally uniform in density and rotation. The method can compare the dynamic collapse and approach to equilibrium with the data on incompressible uniformly rotating equilibrium clouds and on equilibrium structures of differentially rotating polytropes. It is concluded that the stellar formation theory indicates that the low alpha fragments produced at the termination of the dynamic isothermal collapse phase of interstellar clouds may undergo significant dynamic collapse in an adiabatic regime leading to transitory ring formation and additional fragmentation on a smaller scale.

Boss, A. P.↗

NASA NTRS1990

High-velocity interstellar gas in the lines of sight to the Wolf-Rayet stars HD 97152 and HD 96548

The interstellar medium was studied in the direction to the WR stars HD 96548 and HD 97152, and the results are reported. New observational data on the UV spectra of several field stars near both these WR stars are presented. The high-velocity gas seen in the spectra of these stars suggests that the detected expanding interstellar gas structure consists of two OB cluster supershells. The presence of high-velocity absorption components in one of five field star spectra in the direction of the more isolated WR star HD 96548 suggests that this expanding gas does not originate from the optical ring nebula RCW 58 surrounding HD 96548, as previously believed, but instead indicates the detection of a previously unknown expanding interstellar shell in this line of sight.

Nichols-Bohlin, Joy↗

NASA NTRS1995

Saturn's central flash from the 3 July 1989 occultation of 28 Sgr

We present observations of Saturn's central flash obtained from Palomar and McDonald Observatories during the 3 July 1989 occultation of 28 Sgr. As the star passed close to the geometric center of Saturn's shadow, the focusing of the incident starlight by the planet's atmosphere formed multiple stellar images along the limb which were detected in infrared images obtained at wavelengths of 3.9 (Palomar) and 2.1 microns (McDonald). These are the first reported observations of a central flash due to Saturn, and the first of any planet in which the signal flash from each stellar image could be determined separately, permitting a comparison of both intensity and position for each image with model predictions. Four separate flashes were observed from each observatory, corresponding to points on the limb where the starlight passed through the Cassini Division and the relatively transparent C Ring, with maximum brightness reaching 1-2% of the unocculted stellar intensity. The timing of the flashes is quite sensitive to the shape of Saturn's limb, which depends in turn on the planet's zonal gravity harmonics and on the zonal wind profile in the lower stratosphere, near the 2.5-mbar pressure level. The locations of the images along the limb, as well as the timing, shapes, and amplitudes of the individual flash light curves, are well matched by a smoothed model based on a tropospheric zonal wind profile obtained from tracking cloud features in Voyager images and the Saturn ring optical depth profile obtained from the Voyager Photopolarimeter experiment. The smoothing required to give the best match to the data exceeds that attributable to the finite angular extent of the occulted star and may be due to refractive scattering by turbulence or wave structure in Saturn's atmosphere. There is no evidence of significant atmospheric absorption at the observed wavelengths, which correspond to spectral regions of weak methane absorption.

Nicholson, Philip D.↗