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In reduced deformation experiments on an ordinary H6 chondrite, we observe niningerite and oldhamite, which are found only in enstatite chondrites. The association of the reduced metal in shear zones suggests that deformation can enhance reaction. Additional information is contained in the original extended abstract.
The paper develops a general theory for finite rubber viscoelasticity, and specifies it in the form, convenient for solving problems important for rubber, tire and space industries. Based on the quasi-linear approach of non-equilibrium thermodynamics, a general nonlinear theory has been developed for arbitrary nonisothermal deformations of viscoelastic solids. In this theory, the constitutive equations are presented as the sum of known equilibrium (rubber elastic) and non-equilibrium (liquid polymer viscoelastic) terms. These equations are then simplified using several modeling arguments. Stability constraints for the proposed constitutive equations are also discussed. It is shown that only strong ellipticity criteria are applicable for assessing stability of the equations governing viscoelastic solids.
Molecular-level synergism between the silica nanoparticles of pre-formed monoliths and molecular cross-linkers inverts the relative host-guest roles in glass-polymer composites, leading to new strong low-density materials. Attempts to load gels with variable amounts of polyurethane precursors such as di-ISO and diol end-capped polybutylene adipate followed by heat treatment, washing, and supercritical drying led to opaque materials, somewhat stronger than silica but still quite brittle and much inferior to the materials described above. Direct mixing of a diisocyanate and an alcohol-free sol has been attempted recently by Yim et al. Reportedly, that procedure leads to week-long gelation times and requires an at least equally long aging period. In our attempt to add various amounts of di-ISO in a base-catalyzed sol in PC, we also noticed a week-long gelation time. The resulting aerogels were translucent but no less brittle than native silica. According to more recent studies, if propylene carbonate is replaced with acetone, it leads not only to shorter processing times, but also to much stronger gels that can tolerate loads in excess of 40 kg in the arrangement presented. We attribute that behavior to the lower viscosity of acetone, that allows faster diffusion of the di-ISO solution within the pores before di-ISO has time to react with the surface of silica. Further studies are underway to vary the chemical identity of the diisocyanate, as well as the composition and density of silica.
The horizontal and vertical transport of biomass fire emissions in West Africa during November 1998 through February 1999, are examined using all available data including wind, fire, aerosol, precipitation, lightning and outgoing longwave radiation. Ozonesonde data from the Aerosols99 Trans-Atlantic cruise are also included with rain and wind analyses. The results here support earlier studies that ozone and ozone precursors associated with biomass burning are confined to the lower troposphere primarily due to the lack of deep convection over land areas. Ozone and its precursors are horizontally transported equatorward or towards the west by winds in the 1000-700 hPa layers. However, rising adiabatic motions associated with the diurnal evolution of the West African n can transport ozone and its precursors vertically into the free troposphere above the marine boundary layer. Moreover, lightning from South America, Central Africa and mesoscale convective systems in the Gulf of Guinea can lead to elevated ozone mixing ratios in the middle and upper troposphere.
Although the primary focus of the Jupiter Icy Moons Orbiter (JIMO) mission will be the characterization and study of Jupiter's icy moons, there will be opportunities throughout the mission for unprecendented observations of Jupiter. With an adaptable suite of payload instruments, the atmospheric data collected by JIMO can help to answer fundamental questions about the largest planet in our solar system that remain after (or were generated by) previous spacecraft reconnaissance (e.g. Voyager, Galileo, and Cassini). Near-IR (0.7-4 micron) spectral imaging will most likely be used to identify mineralogies and ices on the Jovian satellites by virtue of their spectral signatures. This same capability is very well tailored for studies of Jovian atmospheric dynamics and structure. Near-IR methane absorption bands allow 2-D mapping of the horizontal wind field at size scales to tens of kms, as well as the height dependence of this field above the ammonia cloud deck (700 to a few mbar), constraining current models of atmospheric vertical structure. Likewise, atmospheric ice aerosols with unique spectroscopic signatures (ammonia ice near 1.5, 2.0, and 2.8 microns and water ice between 3.0 - 3.5 microns) can be detected and mapped using spectral difference imaging or spectrally inclusive principal-component methods. Spectral imaging of the Jovian aurora via (3)H(+) emission lines between 3 - 4 microns can be used to spatially map the interplay between the satellites) Jupiter's magnetosphere, and Jupiter's atmosphere. Each of these measurements addresses one or more fundamental questions related to the energy balance in Jupiter's atmosphere. All of these tunable imaging objectives can be achieved using acousto-optic tunable filters (AOTF's), which have been used for years in ground-based observing instruments and which have been proposed for numerous planetary missions. The application of this technology to the science objectives of both the icy satellites and Jovian atmospheric components of the JIMO mission will be discussed.
The most recent studies by the Federal Aviation Administration (FAA) and the aviation industry have indicated that it has become increasingly difficult to make new VHF frequency or channel assignments to meet the aviation needs for air-ground communications. FAA has planned for several aggressive improvement measures to the existing systems, but these measures would not meet the projected voice communications needs beyond 2009. FAA found that since 1974 there has been, on the average, a 4 percent annual increase in the number of channel assignments needed to satisfy the air-ground communication traffic (approximately 300 new channel assignments per year). With the planned improvement measures, the channel assignments are expected to reach a maximum number of 16615 channels by about 2010. Hence, the FAA proposed the use of VDL Mode 3 as a new integrated digital voice and data communications systems to meet the future air traffic demand. This paper presents analytical results of frequency reuse; cell separation and capacity estimation of VDL Mode 3 TDMA systems that FAA has planned to implement the future VHF air-ground communications system by the year 2010. For TDMA, it is well understood that the frequency reuse factor is a crucial parameter for capacity estimation. Formulation of this frequency reuse factor is shown, taking into account the limitation imposed by the requirement to have a sufficient Signal to Co-Channel Interference Ratio. Several different values for the Signal to Co-Channel Interference Ratio were utilized corresponding to the current analog VHF DSB-AM systems, and the future digital VDL Mode 3. The required separation of Co-Channel cells is computed for most of the Frequency Protected Service Volumes (FPSV's) currently in use by the FAA. Additionally, the ideal cell capacity for each FPSV is presented. Also, using actual traffic for the Detroit air space, a FPSV traffic distribution model is used to generate a typical cell for channel capacity prediction. Such prediction is useful for evaluating the improvement of future VDL Mode 3 deployment and capacity planning.
We describe a broad resolution of the "Atlantic Paradox" concerning the seasonal and geographic distribution of tropical tropospheric ozone. We describe periods of significant maximum tropospheric O3 for Jan.-April, 1999, exploiting satellite estimates and SHADOZ (Southern Hemisphere Additional Ozonesondes). Trajectory analyses connecting sondes and Total Tropospheric Ozone (TTO)O3 maps suggest a complex influence from the Indian Ocean: beginning with mixed combustion sources, then low level transport, cumulonimbus venting, and finally high-level transport to the west, with possible mixing over Africa. For the Jan.- March highest column-O3 periods in the Atlantic, distinct sounding peaks trace to specific NO sources, especially lightning, while in the same episodes, recurring every 30 or 60 days, more diffuse buildups of Indian-to-Atlantic pollution make important contributions.
The PITS Modification Script has been under development. Testing, debugging, and optimization of the script are in progress. MSIS has begun population of ODC values from historic issue data. Design of the Linker Tool is also continuing. The quarterly review meeting held on December 17,2003, allowed for a venue to discuss installing the PITS Modification Script to the production version of PITS upon completion and incorporation of ODC into an IV&V project s issue tracking process. Feedback from NASA was positive although any global implementation will likely be timed to coordinate with other activities such as establishment of an IV&V Work Breakdown Structure.
This work presents a short report on the routing tests of the Ku band satcom and VHF line-of-sight communications systems on the Advanced Air Transportation Technologies (AATT) Aero/Mobile van. The first section is a description of the equipment used, followed by descriptions of the tests, the theoretical results, and finally, conclusions and the actual data.
The NASA ADS Abstract Service is a NASA-funded project which provides FREE World Wide Web abstract search services. We currently have over 3.6 million references in four databases: 1) Astronomy and Planetary Sciences; 2) Physics and Geophysics; 3) Space Instrumentation; and 4) Astronomy Preprints. Our eleven mirror sites in France, Germany, Japan, Chile, Great Britain, India, Russia, Brazil, Argentina, Korea and China help to provide better global access. Each database contains abstracts from hundreds of journals, publications, colloquia, symposia, proceedings, PhD Theses, and NASA reports. All abstracts can be searched by author, title, or abstract text words.
Y980459 was found near the Minami-Yamato Nunataks, Antarctica in 1998 and was recently classified as an olivine-bearing shergottite. It petrographically resembles many other olivine-phyric shergottites mostly found in hot deserts, e.g. DaG476/489, SaU005/094, Dohfar 019, NWA 1068/1110, NWA 1195 and EETA 79001 lith.A. However, Y980459 is unique among these meteorites in several respects. It is apparently very fresh and only weakly shocked. Also, it completely lacks plagioclase, but contains abundant residual volcanic glass. This group of olivine-phyric shergottites is characterized by variable crystallization ages from approx.172 Ma to approx.575 Ma and ejection ages from approx.1 Ma to approx.20 Ma. They probably represent volcanic melts originated from the deep Martian mantle. We performed Rb-Sr and Sm-Nd isotopic analyses on Y980459 to determine its crystallization age and compared its age and isotopic signatures with those obtained from other olivine-phyric shergottites and QUE 94201, the other Antarctic olivine-free shergottite. QUE 94201 and some olivine-phyric shergottites e.g. DaG, SaU, Doh and EETA lith A have similar depleted-LREE patterns and are herein referred to as depleted shergottites. A petrogenetic model correlating depleted shergottites and nakhlites is also proposed. Preliminary Rb-Sr and Sm-Nd isotopic data for Y980459 were presented earlier at the NIPR, Japan, in 2003.
A number of studies have addressed responses of leaf spectral reflectance, transmittance, or absorptance to physiological stress. Stressors included dehydration, ozone, herbicides, disease, insufficient mycorrhizae and N fertilization, flooding and insects. Species included conifers, grasses, and broadleaved trees. Increased reflectance with maximum responses near 700 nm wavelength occurred in all cases. Varying the chlorophyll content in leaves or pigment extracts can simulate this effect. Thus, common optical responses to stress result from decreases in leaf chlorophyll contents or the capacity of chloroplasts to absorb light. Leaf optic can be quite sensitive to any stressor that alters soil-plant-atmosphere processes.
The goal of this session is to bring together scientists from interdisciplinary backgrounds to discuss the data, scientific approaches and recent results focusing on the impact of urbanization on the climate. The discussion will highlight current observational and modeling capabilities being employed for investigating the urban environment and its linkage to the change in the Earth's climate system. The goal of the session is to identify our current stand and the future direction on the topic. Urbanization is one of the extreme cases of land use change. Most of population of the world has moved to urban areas. By 1995, more than 70% of population of North America and Europe were living in cities. By 2025, the United Nations estimates that 60% of the worlds population will live in cities. Although currently only 1.2% of the land is urban, better understanding of how the atmosphere-ocean-land-biosphere components interact as a coupled system and the influence of human activities on this system is critical. Our understanding of urbanization effect is incomplete, partly because human activities induce new changes on climate in addition to the original natural variations, and partly because previously few data available for study urban effect globally. Urban construction changes surface roughness, albedo, heat capacity and vegetation coverage. Traffic and industry increase atmospheric aerosol. It is suggested that urbanization may modify rainfall processes through aerosol-cloud interactions or dynamic feedbacks. Because urbanization effect on climate is determined by many factors including land cover, the city's microscale features, population density, and human lifestyle patterns, it is necessary to study urban areas over globe.
This communication provides an update of our understanding of the neurological bases for the close association between balance control and anxiety. New data suggest that a vestibulo-recipient region of the parabrachial nucleus (PBN) contains cells that respond to body rotation and position relative to gravity. The PBN, with its reciprocal relationships with the extended central amygdaloid nucleus, infralimbic cortex, and hypothalamus, appears to be an important node in a primary network that processes convergent vestibular, somatic, and visceral information processing to mediate avoidance conditioning, anxiety, and conditioned fear responses. Noradrenergic and serotonergic projections to the vestibular nuclei also have parallel connections with anxiety pathways. The coeruleo-vestibular pathway originates in caudal locus coeruleus (LC) and provides regionally specialized noradrenergic input to the vestibular nuclei, which likely mediate effects of alerting and vigilance on the sensitivity of vestibulo-motor circuits. Both serotonergic and nonserotonergic pathways from the dorsal raphe nucleus and the nucleus raphe obscurus also project differentially to the vestibular nuclei, and 5-HT(2A) receptors are expressed in amygdaloid and cortical targets of the PBN. It is proposed that the dorsal raphe nucleus pathway contributes to both (a) a tradeoff between motor and sensory (information gathering) aspects of responses to self-motion and (b) a calibration of the sensitivity of affective responses to aversive aspects of motion. This updated neurologic model continues to be a synthetic schema for investigating the neurological and neurochemical bases for comorbidity of balance disorders and anxiety disorders.
Methyladenine and adenine N-phosphoryl derivatives of adenosine 5'-monophosphate (5'-AMP) and uridine 5'-monophosphate (5'-UMP) are synthesized, and their structures are elucidated. The oligomerization reactions of the adenine derivatives of 5'-phosphoramidates of adenosine on montmorillonite are investigated. 1-Methyladenine and 3-methyladenine derivatives on montmorillonite yielded oligoadenylates as long as undecamer, and the 2-methyladenine and adenine derivatives on montmorillonite yielded oligomers up to hexamers and pentamers, respectively. The 1-methyladenine derivative yielded linear, cyclic, and A5'ppA-derived oligonucleotides with a regioselectivity for the 3',5'-phosphodiester linkages averaging 84%. The effect of pKa and amine structure of phosphate-activating groups on the montmorillonite-catalyzed oligomerization of the 5'-phosphoramidate of adenosine are discussed. The binding and reaction of methyladenine and adenine N-phosphoryl derivatives of adenosine are described.
The formation of the internucleotide bond in diguanylate synthesis was studied in aqueous solution at pH 8 and 0.2 M Mg2+ in the presence and absence of polycytidylate, poly(C). The investigation was simplified by using guanosine 5'-phosphorylmorpholinamide, mor-pG, which can act only as a nucleophile, and deoxyguanosine 5'-phosphoryl-2-methylimidazolide, 2-MeImpdG, which can act only as an electrophile. The time-dependent product distribution was monitored by high-performance liquid chromatography (HPLC) and liquid chromatography mass spectrometry (LC/MS). In the absence of poly(C) the reaction between mor-pG and 2-MeImpdG yielded small amounts of the dimer mor-pGpdG with a regioselectivity of 2'-5':3'-5' = 3.5. In the presence of poly(C) dimer yields increased and a reversal in regioselectivity occurred; both effects were in proportion to the concentration of the polymer. The results can be quantitatively explained with the proposition that poly(C), acting as the template, catalyzes the reaction between template-bound monomers by about a factor of 4-5 over the reaction in solution and yields dimers with a regioselectivity of 2'-5':3'-5' approximately 0.33. These findings illustrate the intrinsic preference of guanosine monomers to correctly self-assemble on the appropriate template.
The effects of amine structure on the montmorillonite-catalyzed oligomerization of the 5'-phosphoramidates of adenosine are investigated. 4-Aminopyridine derivatives yielded oligoadenylates as long as dodecamers with a regioselectivity for 3',5'-phosphodiester bond formation averaging 88%. Linear and cyclic oligomers are obtained and no A5'ppA-containing products are detected. Oligomers as long as the hexanucleotide are obtained using 2-aminobenzimidazole as the activating group. A predominance of pA2'pA is detected in the dimer fraction along with cyclic 3',5'-trimer; no A5'ppA-containing oligomers were detected. Little or no oligomer formation was observed when morpholine, piperidine, pyrazole, 1,2,4-triazole, and 2-pyridone are used as phosphate-activating groups. The effects of the structure of the phosphate activating group on the oligomer structure and chain lengths are discussed.
Transduction of a signal from an extracellular peptide hormone to produce an intracellular response is often mediated by a cell surface receptor, which is usually a glycoprotein. The secondary intracellular signal(s) generated after hormone binding to the receptor have been intensively studied. The nature of the primary signal generated by ligand binding to the receptor is understood less well in most cases. The particular case of the epidermal growth factor (EGF) receptor is analyzed, and evidence for or against two dissimilar models of primary signal transduction is reviewed. Evidence for the most widely accepted current model is found to be unconvincing. Evidence for the other model is substantial but indirect; a direct test of this model remains to be done.