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At least 1,675 records · Page 93

Carbon Dioxide Cycling, Climate, Impacts, and the Faint Young Sun

Evidence for relatively mild climates on ancient Earth and Mars has been a puzzle in light of the faint early sun. The geologic evidence, although far from conclusive, would appear to indicate that the surfaces of both planets were, if anything, warmer ca. 3-4 Ga than they are now. The astrophysical argument that the sun ought to have brightened approx. 30% since it reached the main sequence is hard to refute. There results a paradox between the icehouse we expect and the greenhouse we think we see. The usual fix has been to posit massive CO2 atmospheres, although reduced gases (e.g., NH3 or CH4 ) have had their partisans. Evidence against siderite in paleosols dated 2.2-2.75 Ga sets a rough upper limit of 30 PAL (present atmospheric levels) on pCO2 at that time. This is an order of magnitude short of what is needed to defeat the fainter sun. We present here an independent argument against high pCO2 on early Earth that applies not only to the Archean but yet more forcefully to the Hadean era. Additional information is contained in the original extended abstract.

Zahnle, K. J.↗

Carbon Dioxide Cycling And The Climate of Ancient Earth

The continental cycle of silicate weathering and metamorphism dynamically buffers atmospheric CO2 and climate. Feedback is provided by the strong temperature dependence of silicate weathering. Here we argue that hydrothermal alteration of oceanic basalts also dynamically buffers CO2. The oceanic cycle links with the mantle via subduction and the midocean ridges. Feedback is provided by the dependence of carbonatization on dissolved carbonates in seawater. Unlike the continental cycle, the oceanic cycle has no thermostat. Currently the continental cycle is more important, but earlier in Earth's history, especially if heat flow were higher than it is now, more vigorous plate tectonics would have made the oceanic cycle dominant. We find that CO2 greenhouses thick enough to defeat the faint early sun are implausible and that, if no other greenhouse gases are invoked, very cold climates are expected for much of the Proterozoic and the Archean. We echo current fashion and favor biogenic methane as the chief supplement to CO2. Fast weathering and probable subduction of abundant impact ejecta would have reduced CO2 levels still further in the Hadean. Despite its name, the Hadean would have been the coldest era in the history of the Earth.

Zahnle, Kevin↗

Carbon Dioxide Cycling and the Climate of Ancient Earth

The continental cycle of silicate weathering and metamorphism dynamically buffers atmospheric CO2 and climate. Feedback is provided by the strong temperature dependence of silicate weathering. Here we argue that hydrothermal alteration of oceanic basalts also dynamically buffers CO2. The oceanic cycle links with the mantle via subduction and the midocean ridges. Feedback is provided by the dependence of carbonatization on dissolved carbonates in seawater. Unlike the continental cycle, the oceanic cycle has no thermostat. Currently the continental cycle is more important, but earlier in Earth's history, especially if heat flow were higher than it is now, more vigorous plate tectonics would have made the oceanic cycle dominant. We find that CO2 greenhouses thick enough to defeat the faint early Sun are implausible and that, if no other greenhouse gases are invoked, very cold climates are expected for much of the Proterozoic and the Archean. We echo current fashion and favor biogenic methane as the chief supplement to CO2. Fast weathering and probable subduction of abundant impact ejecta would have reduced CO2 levels still further in the Hadean. Despite its name, the Hadean would have been the coldest era in the history of the Earth.

Zahnle, Kevin↗

Stratospheric Age Spectra and Mean Ages From In Situ Observations of Carbon Dioxide

Tropospheric CO2 mixing ratios exhibit latitudinally varying seasonal and interannual oscillations superimposed on the long-term positive trend due to fossil fuel combustion. In situ observations of CO2 obtained from 1992-2000 using the NASA ER-2 aircraft and high-altitude balloons show that these time-varying signals propagate into the stratosphere, providing information about the transport history of sampled air. We have used these data to derive age spectra and mean ages that can be compared with results from models of the stratospheric circulation. Age spectra have been derived for altitudes below approximately 20 km for the tropics and for northern midlatitudes, where there is sufficient data and where the amplitudes of the seasonal and interannual oscillations are large enough to be detected. The midlatitude CO2 data are consistent with bimodal age spectra, which may result from a subtropical "barrier" to horizontal exchange. Seasonally resolved mean ages are available with nearly pole-to-pole coverage below 20 km and in the tropics and at middle and high northern latitudes up to the maximum altitude reached by the balloons (approximately 30 km). The oldest air sampled was in the Arctic polar vortex with a mean age of 6.5 +/- 0.5 years.

Andrews, Arlyn E.↗

Sources of Variability in the Stratospheric Column of Nitrogen Dioxide

Instruments such as the Global Ozone Monitoring Experiment (GOME, on the European Remote Sensing Satellite (ERS-2), launched 1995), the Scanning Imaging Absorption Spectrometer for Atmospheric Chartography (SCIAMACHY, on ENVISAT, to be launched July 2001) and the Ozone Monitoring Instrument (OMI on EOS Aura, to be launched 2003) make measurements of the total column of NO2. There is interest in separating the stratospheric and tropospheric contributions to the column, as the tropospheric column provides a measure of pollution. We are using a 3D chemistry and transport model driven by winds from the Goddard Space Flight Center Data Assimilation System to examine variability in the stratospheric NO2 column. Model results for NOx = NO + NO2 + 2N2O5 will be shown to compare well with sunset observations from the Halogen Occultation Experiment on the Upper Atmosphere Research Satellite, and to exhibit similar temporal and spatial dependence. Partitioning between NO, NO2, and N2O5 is also shown to compare well with observations. This good agreement supports the use of simulated fields in the stratosphere to derive the tropospheric column from the total column. Preliminary comparisons of the tropospheric column with model simulations for the troposphere will also be shown.

Douglass, Anne↗

Stratospheric Age Spectra and Mean Ages from In Situ Observations of Carbon Dioxide

In situ observations of CO2 obtained from 1992 through 2000 using the NASA ER-2 aircraft and high-altitude balloons show that seasonal and interannual variations in CO2 mixing ratios propagate from the troposphere into the lower stratosphere via the tropical tropopause, along with the long-term trend due to fossil fuel combustion. These signals spread laterally and vertically, providing detailed quantitative information about the transport history of sampled air. We have used these data to derive age spectra and mean ages that can be compared with results from models of the stratospheric circulation. For an air parcel at a point in the stratosphere, the age spectrum is defined as the probability distribution function for transit times from the tropical tropopause for each fluid element comprising the parcel. The mean age is the average transit time, corresponding to the first moment of the age spectrum. Age spectra have been derived for altitudes below approximately 20 km for the tropics and for northern midlatitudes where there is sufficient data and where the amplitudes of the seasonal and interannual oscillations in CO2 mixing ratios are large enough to be detected. Tropical age spectra are narrow, with seasonal variation indicating faster ascent during northern winter, consistent with a circulation driven by breaking of extratropical waves. The midlatitude CO2 data are consistent with bimodal age spectra, which could result from a subtropical "barrier" to horizontal exchange over a substantial altitude region. Seasonally resolved mean ages are available with nearly pole-to-pole coverage below 20 km and in the tropics and at middle and high northern latitudes up to the maximum altitude reached by the balloons (approximately 30 km). At ER-2 altitudes, steep meridional gradients in mean age are observed in the subtropics. Between 20 and 30 km, midlatitude air is approximately 2 years older than tropical air at the same altitude. The oldest air sampled was in the Arctic polar vortex with a mean age of .5 plus or minus 0.5 years. This value is much younger than mean ages inferred from simultaneous and previous observations of SF6 in the Arctic vortex, providing evidence for a mesospheric sink for SF6. The mean age in the midlatitude middle stratosphere (approximately 25-32 km) is nearly constant with respect to altitude at 5 plus or minus 0.5 years. Comparison with earlier balloon observations of CO2 dating back to the 1970s shows that the mean age of air in this region has been relatively invariant over the last 25 years.

Andrews, Arlyn E.↗

Cold Spots in the Martian Polar Regions: Evidence of Carbon Dioxide Depletion?

Regions of very low, rapidly varying brightness temperatures have been observed near the martian winter poles by several spacecraft. One possibility is that the CO2 condensation temperature is lowered by depletion of CO2 in the air at the surface. We estimate the rate at which this low-molecular-weight air would disperse into the high-molecular-weight air above and show that it is generally faster than the rate of supply. This dispersal could be prevented if there is a strong temperature inversion (warm air above colder air) near the surface. Without an inversion, the entire atmospheric column could become depleted. However, depleted columns take a long time to form, and they are inconsistent with the rapid fluctuations in the cold spot locations and temperatures. Because low-altitude temperature inversions cannot be ruled out by existing observations, CO2 depletion is still a viable explanation for the martian cold spots.

Weiss, Benjamin P.↗

Detecting a Terrestrial Biosphere Sink for Carbon Dioxide: Interannual Ecosystem Modeling for the Mid-1980s

There is considerable uncertainty as to whether interannual variability in climate and terrestrial ecosystem production is sufficient to explain observed variation in atmospheric carbon content over the past 20-30 years. In this paper, we investigated the response of net CO2 exchange in terrestrial ecosystems to interannual climate variability (1983 to 1988) using global satellite observations as drivers for the NASA-CASA (Carnegie-Ames-Stanford Approach) simulation model. This computer model of net ecosystem production (NEP) is calibrated for interannual simulations driven by monthly satellite vegetation index data (NDVI) from the NOAA Advanced Very High Resolution Radiometer (AVHRR) at 1 degree spatial resolution. Major results from NASA-CASA simulations suggest that from 1985 to 1988, the northern middle-latitude zone (between 30 and 60 degrees N) was the principal region driving progressive annual increases in global net primary production (NPP; i.e., the terrestrial biosphere sink for carbon). The average annual increase in NPP over this predominantly northern forest zone was on the order of +0.4 Pg (10 (exp 15) g) C per year. This increase resulted mainly from notable expansion of the growing season for plant carbon fixation toward the zonal latitude extremes, a pattern uniquely demonstrated in our regional visualization results. A net biosphere source flux of CO2 in 1983-1984, coinciding with an El Nino event, was followed by a major recovery of global NEP in 1985 which lasted through 1987 as a net carbon sink of between 0.4 and 2.6 Avg C per year. Analysis of model controls on NPP and soil heterotrophic CO2 fluxes (Rh) suggests that regional warming in northern forests can enhance ecosystem production significantly. In seasonally dry tropical zones, periodic drought and temperature drying effects may carry over with at least a two-year lag time to adversely impact ecosystem production. These yearly patterns in our model-predicted NEP are consistent in magnitude with the estimated exchange of CO2 by the terrestrial biosphere with the atmosphere, as determined by previous isotopic (delta (sup 13 C) convolution analysis. Ecosystem simulation results can help further target locations where net carbon sink fluxes have occurred in the past or may be verified in subsequent field studies.

Potter, Christopher S.↗

Retrieval of Kinetic Temperature and Carbon Dioxide Abundance from Non-Local Thermodynamic Equilibrium Limb Emission Measurements made by the SABER Experiment on the TIMED Satellite

The Sounding of the Atmosphere using Broadband Emission Radiometry (SABER) experiment was launched onboard the TIMED satellite in December, 2001. SABER is designed to provide measurements of the key radiative and chemical sources and sinks of energy in the mesosphere and lower thermosphere (MLT). SABER measures Earth limb emission in 10 broadband radiometer channels ranging from 1.27 micrometers to 17 micrometers. Measurements are made both day and night over the latitude range from 54 deg. S to 87 deg. N with alternating hemisphere coverage every 60 days. In this paper we concentrate on retrieved profiles of kinetic temperature (T(sub k)) and CO2 volume mixing ratio (vmr), inferred from SABER-observed 15 micrometer and 4.3 micrometer limb emissions, respectively. SABER-measured limb radiances are in non-local thermodynamic equilibrium (non-LTE) in the MLT region. The complexity of non-LTE radiation transfer combined with the large volume of data measured by SABER requires new retrieval approaches and radiative transfer techniques to accurately and efficiently retrieve the data products. In this paper we present the salient features of the coupled non-LTE T(sub k)/CO2 retrieval algorithm, along with preliminary results.

Mertens, Christopher J.↗

Comparison of Carbon Dioxide and Helium as Fire Extinguishing Agents for Spacecraft

The effects of radiation heat transfer in microgravity compared to convection heat transfer in earth gravity for opposed-flow (downward) over thermally-thick fuel using low density foam fuel were investigated. Microgravity experiments on flame spread over thermally-thick fuels were conducted using foam fuels to obtain low density and thermal conductivity, and thus large flame spread rate compared to dense fuels such as PMMA. And thereby valid microgravity results were obtained even in 2.2 second drop-tower experiments not to mention for the longer duration tests in Zero Gravity Facility. Contrast to the conventional understanding, it was found that steady flame spread can occur over thick fuels in quiescent microgravity environments, especially when radiatively-active diluent gases such as CO2 were employed. This is proposed to result from radiative heat transfer from the flame to the fuel surface, which could lead to steady spread even when the amount of the heat transfer via conduction from the flame to the fuel bed is negligible. Radiative effects are more significant at microgravity conditions because the flame is thicker and thus the volume of radiating combustion products is larger as well. These results suggested that helium may be a better inert or extinguishment agent on both a mass and a mole bases at microgravity even though CO2 is much better on a mole bases at earth gravity, and these are relevant to studies of fire safety in manned spacecraft, particularly the International Space Station that uses CO2 fire extinguishers. CO2 may not be as effective as an extinguishing agent at g as it is at earth gravity in some conditions because of the differences in spread mechanisms between the two cases. In particular, the difference between conduction-dominated heat transport to the fuel bed at earth gravity and radiation-dominated heat transport at g indicates that radiatively-inert diluent such as helium could be preferable in g applications. Helium may be a superior fire suppression agent at g on several bases. First, helium is more effective than CO2 on a mole basis (thus pressure times storage volume basis) at g, meaning that the size and weight of storage bottles would be smaller for the same fire-fighting capability. Second; helium is much more effective on a mass basis (by about 11 times) at g. Third; helium has no physiological activity, unlike CO2 that affects human respiration. Fourth, as compared to N2 or CO2, is not very soluble in water and thus has fewer tendencies to cause bloodstream bubble formation following rapid spacecraft cabin depressurization.

Gokoglu, Suleyman↗

A multiple chamber, semicontinuous, crop carbon dioxide exchange system: design, calibration, and data interpretation

Long-term, whole crop CO2 exchange measurements can be used to study factors affecting crop growth. These factors include daily carbon gain, cumulative carbon gain, and carbon use efficiency, which cannot be determined from short-term measurements. We describe a system that measures semicontinuously crop CO2 exchange in 10 chambers over a period of weeks or months. Exchange of CO2 in every chamber can be measured at 5 min intervals. The system was designed to be placed inside a growth chamber, with additional environmental control provided by the individual gas exchange chambers. The system was calibrated by generating CO2 from NaHCO3 inside the chambers, which indicated that accuracy of the measurements was good (102% and 98% recovery for two separate photosynthesis systems). Since the systems measure net photosynthesis (P-net, positive) and dark respiration(R-dark, negative), the data can be used to estimate gross photosynthesis, daily carbon gain, cumulative carbon gain, and carbon use efficiency. Continuous whole-crop measurements are a valuable tool that complements leaf photosynthesis measurements. Multiple chambers allow for replication and comparison among several environmental or cultural treatments that may affect crop growth. Example data from a 2 week study with petunia (Petunia x hybrida Hort. Vilm.-Andr.) are presented to illustrate some of the capabilities of this system.

NASA Discipline Life Support Systems↗

Yield and seed oil content response of dwarf, rapid-cycling Brassica to nitrogen treatments, planting density, and carbon dioxide enrichment

Effects of N level (15 to 30 mM), time of N increase (14 to 28 days after planting), and planting density (1163 to 2093 plants/m2) were determined for crop yield responses of dwarf, rapid-cycling brassica (Brassica napus L., CrGC 5-2, Genome: ACaacc). Crops were grown in solid-matrix hydroponic systems and under controlled-environment conditions, including nonsupplemented (ambient) or elevated CO2 concentrations (998 +/- 12 micromoles mol-1). The highest seed yield rate obtained (4.4 g m-2 day-1) occurred with the lowest N level (15 mM) applied at the latest treatment time (day 28). In all trials, CO2 enrichment reduced seed yield rate and harvest index by delaying the onset of flowering and senescence and stimulating vegetative shoot growth. The highest shoot biomass accumulation rate (55.5 g m-2 day-1) occurred with the highest N level (30 mM) applied at the earliest time (day 14). Seed oil content was not significantly affected by CO2 enrichment. Maximum seed oil content (30% to 34%, dry weight basis) was obtained using the lowest N level (15 mM) initiated at the latest treatment time (day 28). In general, an increase in seed oil content was accompanied by a decrease in seed protein. Seed carbohydrate, moisture, and ash contents did not vary significantly in response to experimental treatments. Effects of N level and time of N increase were consistently significant for most crop responses. Planting density was significant only under elevated CO2 conditions.

Non-NASA Center↗

Seafloor hydrothermal activity and spreading rates: the Eocene carbon dioxide greenhouse revisted

A suggestion has been made that enhanced rates of hydrothermal activity during the Eocene could have caused a global warming by adding calcium to the ocean and pumping CO2 into the atmosphere (Owen and Rea, 1984). This phenomenon was purported to be consistent with the predictions of the CO2 geochemical cycle model of Berner, Lasaga and Garrels (1983) (henceforth BLAG). In fact, however, the BLAG model predicts only a weak connection between hydrothermal activity and atmospheric CO2 levels. By contrast, it predicts a strong correlation between seafloor spreading rates and pCO2, since the release rate of CO2 from carbonate metamorphism is assumed to be proportional to the mean spreading rate. The Ecocene warming can be conveniently explained if the BLAG model is extended by assuming that the rate of carbonate metamorphism is also proportional to the total length of the midocean ridges from which the spreading originates.

Seawater/chemistry↗

Carbon dioxide exchange of lettuce plants under hypobaric conditions

Growth of plants in a Controlled Ecological Life Support System (CELSS) may involve the use of hypobaric pressures enabling lower mass requirements for atmospheres and possible enhancement of crop productivity. A controlled environment plant growth chamber with hypobaric capability designed and built at Ames Research Center was used to determine if reduced pressures influence the rates of photosynthesis (Ps) and dark respiration (DR) of hydroponically grown lettuce plants. The chamber, referred to as a plant volatiles chamber (PVC), has a growing area of about 0.2 m2, a total gas volume of about 0.7 m3, and a leak rate at 50 kPa of <0.1%/day. When the pressure in the chamber was reduced from ambient to 51 kPa, the rate of net Ps increased by 25% and the rate of DR decreased by 40%. The rate of Ps increased linearly with decreasing pressure. There was a greater effect of reduced pressure at 41 Pa CO2 than at 81 Pa CO2. This is consistent with reports showing greater inhibition of photorespiration (Pr) in reduced O2 at low CO2 concentrations. When the partial pressure of O2 was held constant but the total pressure was varied between 51 and 101 kPa, the rate of CO2 uptake was nearly constant, suggesting that low pressure enhancement of Ps may be mainly attributable to lowered partial pressure of O2 and the accompanying reduction in Pr. The effects of lowered partial pressure of O2 on Ps and DR could result in substantial increases in the rates of biomass production, enabling rapid throughput of crops or allowing flexibility in the use of mass and energy resources for a CELSS.

NASA Program CELSS↗

Reducing uncertainty about carbon dioxide as a climate driver

The lack of an adequate ancient analogue for future climates means that we ultimately must use and trust climate models, evaluated against modern observation and our best geologic records of warm and cold climates of the past. Armed with an elevated confidence in the models, we will then be able to make reliable predictions of the Earth's response to our risky experiment with the climate system.

Climate↗

Nitrogen nutrition and temporal effects of enhanced carbon dioxide on soybean growth

Plants grown on porous media at elevated CO2 levels generally have low concentrations of tissue N and often appear to require increased levels of external N to maximize growth response. This study determines if soybean [Glycine max (L.) Merr. Ransom'] grown hydroponically at elevated CO2 requires increases in external NO3- concentrations beyond levels that are optimal at ambient CO2 to maintain tissue N concentrations and maximize the growth response. This study also investigates temporal influences of elevated CO2 on growth responses by soybean. Plants were grown vegetatively for 34 d in hydroponic culture at atmospheric CO2 concentrations of 400, 650, and 900 microliters L-1 and during the final 18 d at NO3- concentrations of 0.5, 1.0, 5.0 and 10.0 mM in the culture solution. At 650 and 900 microliters L-1 CO2, plants had maximum increases of 31 and 45% in dry weight during the experimental period. Plant growth at 900 microliters L-1 CO2 was stimulated earlier than at 650 microliters L-1. During the final 18 d of the experiment, the relative growth rates (RGR) of plants grown at elevated CO2 declined. Elevated CO2 caused increases in total N and total NO3(-)-N content and leaf area but not leaf number. Enhancing CO2 levels also caused a decrease in root:shoot ratios. Stomatal resistance increased by 2.1- and 2.8-fold for plants at the 650 and 900 microliters L-1 CO2, respectively. Nitrate level in the culture solutions had no effect on growth or on C:N ratios of tissues, nor did increases in CO2 levels cause a decrease in N concentration of plant tissues. Hence, increases in NO3- concentration of the hydroponic solution were not necessary to maintain the N status of the plants or to maximize the growth response to elevated CO2.

NASA Program CELSS↗

Elevated carbon dioxide influences yield and photosynthetic responses of hydroponically-grown sweetpotato

The response of 'TI-155' and 'Georgia Jet' sweetpotato cultivars to elevated CO2 concentrations of 400 (ambient), 750 and 1000 micromoles mol-1 were evaluated under controlled environment conditions using the nutrient film technique (NFT). Growth chamber conditions included photosynthetic photon flux (PPF) of 600 micromoles m-2 s-1, 14/10 light/dark period, and 70% +/- 5% RH. Plants were grown using a modified half-Hoagland nutrient solution with a pH range of 5.5-6.0 and an electrical conductivity of 0.12 S m-1. Gas exchange measurements were made using infrared gas analysis, an open-flow gas exchange system, and a controlled-climate cuvette. Photosynthetic (Pn) measurements were made at CO2 ranges of 50 to 1000 micromoles mol-1. Storage root yield/plant increased with CO2 up to 750 but declined at 1000 micromoles mol-1. Storage root dry matter (DM) and foliage dry weight increased with increasing CO2. Harvest index (HI) for both cultivars was highest at 750 micromoles mol-1. The PPF vs Pn curves were typical for C3 plants with saturation occurring at approximately 600 micromoles m-2 s-1. CO2 concentration did not significantly influence net Pn, transpiration, water-use-efficiency (WUE), and stomatal conductance. As measurement CO2 concentration increased, net Pn and WUE increased while transpiration and stomatal conductance decreased.

Solanaceae/drug effects/growth & development↗