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Saltstone 2QCY13 TCLP Results

A Saltstone waste form was prepared in the Savannah River National Laboratory (SRNL) from a Tank 50H sample and Z-Area premix material for the second quarter of calendar year 2013 (2QCY13). After a 49 day cure, samples of the saltstone were collected, and the waste form was shown to meet the South Carolina Hazardous Waste Management Regulations (SCHWMR) R.61-79.261.24 and R.61-79.268.48(a) requirements for a nonhazardous waste form with respect to RCRA metals and underlying hazardous constituents. These analyses met all quality assurance specifications of USEPA SW-846.

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Saltstone 3QCY13 TCLP Results

A Saltstone waste form was prepared in the Savannah River National Laboratory (SRNL) from a Tank 50H sample and Z-Area premix material for the third quarter of calendar year 2013 (3QCY13). After a 63 day cure, samples of the saltstone were collected, and the waste form was shown to meet the South Carolina Hazardous Waste Management Regulations (SCHWMR) R.61-79.261.24 and R.61-79.268.48(a) requirements for a nonhazardous waste form with respect to RCRA metals and underlying hazardous constituents. These analyses met all quality assurance specifications of USEPA SW-846.

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Saltstone 4QCY13 TCLP Results

A Saltstone waste form was prepared in the Savannah River National Laboratory (SRNL) from a Tank 50H sample and Z-Area premix material for the fourth quarter of calendar year 2013 (4QCY13). After a 62 day cure, samples of the saltstone were collected, and the waste form was shown to meet the South Carolina Hazardous Waste Management Regulations (SCHWMR) R.61-79.261.24 and R.61-79.268.48(a) requirements for a nonhazardous waste form with respect to RCRA metals and underlying hazardous constituents. These analyses met all quality assurance specifications of USEPA SW-846.

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Saltstone 1QCY14 TCLP Results

A Saltstone waste form was prepared in the Savannah River National Laboratory (SRNL) from a Tank 50H sample and Z-Area premix material for the first quarter of calendar year 2014 (1QCY14). After a 64 day cure, samples of the saltstone were collected, and the waste form was shown to meet the South Carolina Hazardous Waste Management Regulations (SCHWMR) R.61-79.261.24 and R.61-79.268.48(a) requirements for a nonhazardous waste form with respect to RCRA metals and underlying hazardous constituents. These analyses met all quality assurance specifications of USEPA SW-846.

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Saltstone 3QCY14 TCLP results

A saltstone waste form was prepared in the Savannah River National Laboratory (SRNL) from a Tank 50H sample and Z-Area premix material for the third quarter of calendar year 2014 (3QCY14). After a 78 day cure, samples of the saltstone were collected, and the waste form was shown to meet the South Carolina Hazardous Waste Management Regulations (SCHWMR) R.61-79.261.24 and R.61-79.268.48(a) requirements for a nonhazardous waste form with respect to RCRA metals and underlying hazardous constituents. These analyses met all quality assurance specifications of USEPA SW-846.

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Municipal solid waste composition: Sampling methodology, statistical analyses, and case study evaluation

Highlights: • Tiered approach to waste sorting ensures flexibility and facilitates comparison of solid waste composition data. • Food and miscellaneous wastes are the main fractions contributing to the residual household waste. • Separation of food packaging from food leftovers during sorting is not critical for determination of the solid waste composition. - Abstract: Sound waste management and optimisation of resource recovery require reliable data on solid waste generation and composition. In the absence of standardised and commonly accepted waste characterisation methodologies, various approaches have been reported in literature. This limits both comparability and applicability of the results. In this study, a waste sampling and sorting methodology for efficient and statistically robust characterisation of solid waste was introduced. The methodology was applied to residual waste collected from 1442 households distributed among 10 individual sub-areas in three Danish municipalities (both single and multi-family house areas). In total 17 tonnes of waste were sorted into 10–50 waste fractions, organised according to a three-level (tiered approach) facilitating comparison of the waste data between individual sub-areas with different fractionation (waste from one municipality was sorted at “Level III”, e.g. detailed, while the two others were sorted only at “Level I”). The results showed that residual household waste mainly contained food waste (42 ± 5%, mass per wet basis) and miscellaneous combustibles (18 ± 3%, mass per wet basis). The residual household waste generation rate in the study areas was 3–4 kg per person per week. Statistical analyses revealed that the waste composition was independent of variations in the waste generation rate. Both, waste composition and waste generation rates were statistically similar for each of the three municipalities. While the waste generation rates were similar for each of the two housing types (single-family and multi-family house areas), the individual percentage composition of food waste, paper, and glass was significantly different between the housing types. This indicates that housing type is a critical stratification parameter. Separating food leftovers from food packaging during manual sorting of the sampled waste did not have significant influence on the proportions of food waste and packaging materials, indicating that this step may not be required.

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Municipal solid waste source-separated collection in China: A comparative analysis

A pilot program focusing on municipal solid waste (MSW) source-separated collection was launched in eight major cities throughout China in 2000. Detailed investigations were carried out and a comprehensive system was constructed to evaluate the effects of the eight-year implementation in those cities. This paper provides an overview of different methods of collection, transportation, and treatment of MSW in the eight cities; as well as making a comparative analysis of MSW source-separated collection in China. Information about the quantity and composition of MSW shows that the characteristics of MSW are similar, which are low calorific value, high moisture content and high proportion of organisms. Differences which exist among the eight cities in municipal solid waste management (MSWM) are presented in this paper. Only Beijing and Shanghai demonstrated a relatively effective result in the implementation of MSW source-separated collection. While the six remaining cities result in poor performance. Considering the current status of MSWM, source-separated collection should be a key priority. Thus, a wider range of cities should participate in this program instead of merely the eight pilot cities. It is evident that an integrated MSWM system is urgently needed. Kitchen waste and recyclables are encouraged to be separated at the source. Stakeholders involved play an important role in MSWM, thus their responsibilities should be clearly identified. Improvement in legislation, coordination mechanisms and public education are problematic issues that need to be addressed.

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Transportation of Low-Level Radioactive Waste from KAERI to the Final Repository - 18179

The Korea Atomic Energy Research Institute (KAERI) collects the radioactive wastes generated during the operation of nuclear facilities and R and D processes. Radioactive wastes are treated and repackaged according to the national radioactive waste management policy, and then transferred to the final disposal site at the Korea Radioactive Waste Agency (KORAD). After 2015, the wastes delivered to the final disposal site have consisted of spent filters and combustible wastes such as clothes and gloves generated during R and D or facility operation processes at KAERI. The wastes generated by each facility are collected at the radioactive waste treatment facility, then treated and repackaged in 200 L drums according to their generation characteristics, i.e. each drum contains waste of the same type from the same facility, and with the same date of generation. Then, a radionuclide inventory is obtained for the repackaged drum by using a direct measurement method such as the drum assay system, radiochemical analysis through random sampling or an indirect measurement method such as applying a scaling factor. When performing sampling of the radioactive waste drums, the waste samples with a high contamination are selected in a conservative approach as representative. The radioactive waste drums are inspected and checked for acceptability by the Quality Management Division of KAERI, and a preliminary inspection is carried out on-site by KORAD. At this time, the acceptability of the radioactive waste drums is assessed through visual inspection, the appropriateness of their nuclide analysis value is confirmed, and a survey or smear test of sample drums is performed. Drums that meet the acceptance criteria are transferred to KORAD after a radiation environmental impact assessment of the transportation. Since 2015, 1,084 low-level operational radioactive wastes have been transferred from KAERI to the final disposal site, and further preparation work is now being made for the transportation of additional drums. (authors)

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Optimal management program for asbestos containing building materials to be available in the event of a disaster

Highlights: • The safe management of asbestos is a matter of considerable importance. • There is a lack of literature concerning the development of a program for ACBMs. •A management program for the optimal disposal of ACBMs has been developed. • This program is also available in the event of a post-disaster. - Abstract: The safe management and disposal of asbestos is a matter of considerable importance. A large number of studies have been undertaken to quantify the issue of waste management following a disaster. Nevertheless, there have been few (if any) studies concerning asbestos waste, covering the amount generated, the cost of disposal, and the degree of hazard incurred. Thus, the current study focuses on developing a program for the management of Asbestos Containing Building Materials (ACBMs), which form the source of asbestos waste in the event of a disaster. The study will also discuss a case study undertaken in a specific region in Korea in terms of: (1) the location of ACBM-containing buildings; (2) types and quantities of ACBMs; (3) the cost of ACBM disposal; (4) the amount of asbestos fiber present during normal times and during post-disaster periods; (5) the required order in which ACBM-containing buildings should be dismantled; and (6) additional greenhouse gases generated during ACBM removal. The case study will focus on a specific building, with an area of 35.34 m{sup 2}, and will analyze information concerning the abovementioned points. In addition, the case study will focus on a selected area (108 buildings) and the administrative district (21,063 buildings). The significance of the program can be established by the fact that it visibly transmits information concerning ACBM management. It is a highly promising program, with a widespread application for the safe management and optimal disposal of asbestos in terms of technology, policy, and methodology.

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3rd Quarter Transportation Report FY 2014: Radioactive Waste Shipments to and from the Nevada National Security Site (NNSS)

This report satisfies the U.S. Department of Energy (DOE), National Nuclear Security Administration Nevada Field Office (NNSA/NFO) commitment to prepare a quarterly summary report of radioactive waste shipments to the Nevada National Security Site (NNSS) Radioactive Waste Management Complex (RWMC) at Area 5. There were no shipments sent for offsite treatment and returned to the NNSS this quarter. This report summarizes the 3rd quarter of Fiscal Year (FY) 2014 low-level radioactive waste (LLW) and mixed low-level radioactive waste (MLLW) shipments. This report also includes annual summaries for FY 2014 in Tables 4 and 5. Tabular summaries are provided which include the following: Sources of and carriers for LLW and MLLW shipments to and from the NNSS; Number and external volume of LLW and MLLW shipments; Highway routes used by carriers; and Incident/accident data applicable to LLW and MLLW shipments. In this report shipments are accounted for upon arrival at the NNSS, while disposal volumes are accounted for upon waste burial. The disposal volumes presented in this report do not include minor volumes of non-radioactive materials that were approved for disposal. Volume reports showing cubic feet generated using the Low-Level Waste Information System may vary slightly due to differing rounding conventions.

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Performance Assessment Results for the Hanford Integrated Disposal Facility - 19134

In 2014, the US DOE Office of River Protection and its contractors began to develop a performance assessment for the near-surface disposal of low-level and mixed low-level waste at the Hanford Integrated Disposal Facility. The Hanford Integrated Disposal Facility is a doubly-lined landfill that was constructed between 2004 and 2006 to be the disposal facility for the vitrified low-activity waste containers that will be produced at the Hanford Waste Treatment and Immobilization Plant. The disposal facility is also expected to receive solid secondary waste produced at the Hanford Waste Treatment and Immobilization Plant and other solid wastes from site activities. The constructed facility is awaiting authorization to receive waste. Although no waste destined for the facility is currently being generated, operations cannot begin until the facility has received a Disposal Authorization Statement from US DOE and a permit modification from the State of Washington Department of Ecology. Both the Disposal Authorization Statement and permit modification require a demonstration that the system of engineered and natural features of the disposal facility will limit releases from the facility and be protective of human health and the environment for the next 1,000 to 10,000 years. Based on the analyses presented in the Integrated Disposal Facility Performance Assessment, US DOE issued a conditional Disposal Authorization Statement for the facility in June 2018. Demonstrating the long-term performance of the facility to be protective of human health and the environment was evaluated under the requirements of US DOE Order 435.1, Radioactive Waste Management. Computer simulations were performed to evaluate whether or not the disposal facility would comply with the performance objectives specified in the order. The evaluation was performed using numerical models to simulate source term releases from vitrified and cement-based waste forms. Source term releases were subsequently transported through an air pathway and a groundwater pathway to a point of compliance 100 meters from the disposed of waste. In addition, an analysis evaluating the consequences of an inadvertent intrusion into the waste was also performed. In accordance with US DoE's technical standard for performance assessments, deterministic and probabilistic analyses were performed to demonstrate that the Hanford Integrated Disposal Facility, together with the engineered features of the waste forms and natural features of the selected site, provides a reasonable expectation that the low-level waste and mixed low-level waste disposal will meet the radiological performance objectives established by US DOE. Post-closure doses to future members of the public were evaluated after the time of closure and included a 100-year period of institutional controls that limited exposure immediately following closure of the facility. Calculated doses to a future member of the public from the air pathway were below the 100 μSv/yr dose performance objective. Calculated doses to a future member of the public from all exposure pathways, including the air pathway and the groundwater pathway, were below the 250 μSv/yr dose performance objective. Doses following an inadvertent intrusion into the facility after the institutional control period were below the 5 mSv acute dose performance measure and the 1 mSv/yr chronic dose performance measure. (authors)

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Development of an Integrated Natural Barrier Database System for Site Evaluation of a Deep Geologic Repository in Korea - 13527

Korea Radioactive-waste Management Corporation (KRMC) established in 2009 has started a new project to collect information on long-term stability of deep geological environments on the Korean Peninsula. The information has been built up in the integrated natural barrier database system available on web (www.deepgeodisposal.kr). The database system also includes socially and economically important information, such as land use, mining area, natural conservation area, population density, and industrial complex, because some of this information is used as exclusionary criteria during the site selection process for a deep geological repository for safe and secure containment and isolation of spent nuclear fuel and other long-lived radioactive waste in Korea. Although the official site selection process has not been started yet in Korea, current integrated natural barrier database system and socio-economic database is believed that the database system will be effectively utilized to narrow down the number of sites where future investigation is most promising in the site selection process for a deep geological repository and to enhance public acceptance by providing readily-available relevant scientific information on deep geological environments in Korea. (authors)

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Modeling the growth dynamics of four candidate crops for Controlled Ecological Life Support Systems (CELSS)

The production of food for human life support for advanced space missions will require the management of many different crops. The research to design these food production capabilities along with the waste management to recycle human metabolic wastes and inedible plant components are parts of Controlled Ecological Life Support Systems (CELSS). Since complete operating CELSS were not yet built, a useful adjunct to the research developing the various pieces of a CELSS are system simulation models that can examine what is currently known about the possible assembly of subsystems into a full CELSS. The growth dynamics of four crops (wheat, soybeans, potatoes, and lettuce) are examined for their general similarities and differences within the context of their important effects upon the dynamics of the gases, liquids, and solids in the CELSS. Data for the four crops currently under active research in the CELSS program using high-production hydroponics are presented. Two differential equations are developed and applied to the general characteristics of each crop growth pattern. Model parameters are determined by closely approximating each crop's data.

Volk, Tyler↗

Development of a multi-purpose container system for the storage, transport and disposal of PWR spent fuel in the UK - 15466

Radioactive Waste Management Limited (RWM) is a wholly owned subsidiary of UK's Nuclear Decommissioning Authority, and is responsible for implementing UK Government policy on geological disposal of higher activity radioactive waste. An aspect of the generic work programme that underpins the current generic disposal concepts includes the development of the associated disposal containers. To date RWM has focused on the development of a range of disposal container designs that fulfil the requirements for transport and disposal in a Geological Disposal Facility (GDF) for legacy high heat generating wastes, one of which includes legacy Pressurised Water Reactor (PWR) spent nuclear fuel (SF). In line with a number of European countries exploring deep geological disposal, the conceptual disposal container solution developed for this waste type has a capacity of 4 PWR fuel assemblies. Since 2013, the feasibility of developing an alternative higher capacity disposal container design based around the Multi-Purpose Container (MPC) concept has been explored. In general terms, MPCs are containers that are designed to meet requirements for safe containment of radioactive waste during storage, transport and disposal. The fundamental design philosophy of the MPC is that once the waste is packaged in an MPC, it would not need to be handled again. That is, after a period of initial cooling in a fuel pond, the SF could be packaged for long term dry storage and would not require direct handling for its eventual transport to, and disposal in, a GDF. The novel feature of the MPC system design considered is the inclusion of an additional overpack specifically for the final deep geological disposal phase. The conceptual MPC and its associated storage, transfer, transport and thick walled carbon steel disposal overpack have been developed to a conceptual level of design detail to demonstrate concept feasibility, with the final design solution confirming a MPC system with a capacity of 12 PWR SF assembles. This represents the highest capacity PWR MPC system that complies with the mass and rail gauge limits of the UK W6a rail gauge. Such a capacity realises a contents loading three times that of the standard PWR disposal container and presented technical challenges from both a structural performance and thermal perspective; necessitating the need for the inclusion of features to enhance heat transfer from the central fuel assemblies within the MPC and novel lid features on the transport container overpack to maintain structural integrity and containment during the hypothetical accident conditions of transport tests. In developing the MPC system conceptual design it is recognised that, depending upon the safety functions of the MPC disposal overpack, the choice of carbon steel material may not be suitable for all geological environments. Consequently, the MPC system design and its materials of construction will require further evaluation once detailed knowledge of the disposal concept to be implemented, its safety functions and geological environment are known. (authors)

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Opportunities for Cost Effective Disposal of Radioactively Contaminated Solid Waste on the Oak Ridge Reservation, Oak Ridge, TN - 13045

Department of Energy (DOE) requirements for the release of non-real property, including solid waste, containing low levels of residual radioactive materials are specified in DOE Order 458.1 and associated guidance. Authorized limits have been approved under the requirements of DOE Order 5400.5, predecessor to DOE Order 458.1, to permit disposal of solid waste containing low levels of residual radioactive materials at solid waste landfills located within the DOE Oak Ridge Reservation (ORR). Specifically, volumetric concentration limits for disposal of solid waste at Industrial Landfill V and at Construction/Demolition Landfill VII were established in 2003 and 2007, respectively, based on the requirements in effect at that time, which included: an evaluation to ensure that radiation doses to the public would not exceed 25 mrem/year and would be as low as reasonably achievable (ALARA), with a goal of a few mrem/year or less (in fact, these authorized limits actually were derived to meet a dose constraint of 1 mrem/year); an evaluation of compliance with groundwater protection requirements; and reasonable assurance that the proposed disposal is not likely to result in a future requirement for remediation of the landfill. Prior to approval as DOE authorized limits, these volumetric concentration limits were coordinated with the Tennessee Department of Environment and Conservation (TDEC) and documented in a Memorandum of Understanding (MOU) between the TDEC Division of Radiological Health and the TDEC Division of Solid Waste Management. These limits apply to the disposal of soil and debris waste generated from construction, maintenance, environmental restoration, and decontamination and decommissioning (D and D) activities on the DOE Oak Ridge Reservation. The approved site-specific authorized limits were incorporated in the URS/CH2M Oak Ridge LLC (UCOR) waste profile system that authorizes disposal of special wastes at either of the RCRA Subtitle D landfills. However, a recent DOE assessment found that implementation of the site-specific authorized limits for volumetrically contaminated waste was potentially limited due in part to confusion regarding the applicability of volumetric concentration limits and/or surface activity limits to specific wastes. This paper describes recent efforts to update the authorized limits for Industrial Landfill V and Construction/Demolition Landfill VII and to improve the procedures for implementation of these criteria. The approved authorized limits have been evaluated and confirmed to meet the current requirements of DOE Order 458.1, which superseded DOE Order 5400.5 in February 2011. In addition, volumetric concentration limits have been developed for additional radionuclides, and site-specific authorized limits for wastes with surface contamination have been developed. Implementing procedures have been revised to clarify the applicability of volumetric concentration limits and surface activity limits, and to allow the use of non-destructive waste characterization methods. These changes have been designed to promote improved utilization of available disposal capacity of the onsite disposal facilities within the DOE Oak Ridge Reservation. In addition, these changes serve to bring the waste acceptance requirements at these DOE onsite landfills into greater consistency with the requirements for commercial/ public landfills under the TDEC Bulk Survey for Release (BSFR) program, including two public RCRA Subtitle D landfills in close proximity to the DOE Oak Ridge Reservation. (authors)

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The Evaluation of Chemical Decontamination for Contaminated Carbon Steel Scrap by Multiphase Treatment Process - 20249

There is a significant growth in the field of decommissioning of nuclear facilities due the fact that for a lot of them their end of life is nearing. In Taiwan, the government plans to steadily reduce the dependence on nuclear power and moves gradually towards a nuclear-free homeland. Therefore, the development of decommissioning technology becomes the significant issue for the next coming years. The decommissioning of a nuclear power plant is a long process and practical work including radiological surveys, decontamination, dismantling, and the subsequent waste management. Chemical decontamination is an important task in the decommissioning of nuclear power plants and is usually performed by circulating the chemical solution in selected systems or full systems in order to reduce dose levels. However, the decontamination of segmented metal parts is also considered to reduce the contamination to such levels that they may be disposed of at a lower classification or be unconditionally released, and it helps to achieve the goal of waste minimization and provide a more economical cost for disposal management. Chemical decontamination technology is used to remove the contaminated oxides deposited on the surface of metals by dissolving them with chemical mechanisms, such as chelation, acidic or alkaline dissolution, redox reaction and so on. Carbon steel is the major material used in systems and pipelines in the nuclear power plant, thus it is also commonly selected as the target to be decontaminated in the decommissioning process. In this study, the effectiveness of chemical decontamination is evaluated by using multiphase treatment process including the reduction and the oxidation steps. In the step of redox reaction, the oxidation state of the substance is very important. Especially metals of some oxidation states show solubility in water, which has a decisive influence on the chemical decontamination. The experiment of decontamination of metal scraps is carried out by the immersion method within a chemical solution. The relative operation parameters such as temperature, pH, and concentration of the chemical solution are recorded to demonstrate the effect of the decontamination process. (authors)

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Waste-Incidental-to-Reprocessing Evaluation for the West Valley Demonstration Project Vitrification Melter - 12167

The Department of Energy (DOE) has determined that the vitrification melter used in the West Valley Demonstration Project can be disposed of as low-level waste (LLW) after completion of a waste-incidental-to-reprocessing evaluation performed in accordance with the evaluation process of DOE Manual 435.1-1, Radioactive Waste Management Manual. The vitrification melter - which consists of a ceramic lined, electrically heated box structure - was operated for more than 5 years melting and fusing high-level waste (HLW) slurry and glass formers and pouring the molten glass into 275 stainless steel canisters. Prior to shutdown, the melter was decontaminated by processing low-activity decontamination flush solutions and by extracting molten glass from the melter cavity. Because it could not be completely emptied, residual radioactivity conservatively estimated at approximately 170 TBq (4,600 Ci) remained in the vitrification melter. To establish whether the melter was incidental to reprocessing, DOE prepared an evaluation to demonstrate that the vitrification melter: (1) had been processed to remove key radionuclides to the maximum extent technically and economically practical; (2) would be managed to meet safety requirements comparable to the performance objectives for LLW established by the Nuclear Regulatory Commission (NRC); and (3) would be managed by DOE in accordance with DOE's requirements for LLW after it had been incorporated in a solid physical form with radionuclide concentrations that do not exceed the NRC concentration limits for Class C LLW. DOE consulted with the NRC on the draft evaluation and gave other stakeholders an opportunity to submit comments before the determination was made. The NRC submitted a request for additional information in connection with staff review of the draft evaluation; DOE provided the additional information and made improvements to the evaluation, which was issued in January 2012. DOE considered the NRC Technical Evaluation Report as well as comments received from other stakeholders prior to making its determination that the vitrification melter is not HLW, does not require permanent isolation in a geologic repository, and can be disposed of as LLW. (authors)

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ERM 593 Applied Project_Guidance for Reviewing and Approving a Waste Stream Profile in the Waste Compliance and Tracking System_Final_05-05-15

My ERM 593 applied project will provide guidance for the Los Alamos National Laboratory Waste Stream Profile reviewer (i.e. RCRA reviewer) in regards to Reviewing and Approving a Waste Stream Profile in the Waste Compliance and Tracking System. The Waste Compliance and Tracking system is called WCATS. WCATS is a web-based application that “supports the generation, characterization, processing and shipment of LANL radioactive, hazardous, and industrial waste.” The LANL generator must characterize their waste via electronically by filling out a waste stream profile (WSP) in WCATS. Once this process is completed, the designated waste management coordinator (WMC) will perform a review of the waste stream profile to ensure the generator has completed their waste stream characterization in accordance with applicable state, federal and LANL directives particularly P930-1, “LANL Waste Acceptance Criteria,” and the “Waste Compliance and Tracking System User's Manual, MAN-5004, R2,” as applicable. My guidance/applied project will describe the purpose, scope, acronyms, definitions, responsibilities, assumptions and guidance for the WSP reviewer as it pertains to each panel and subpanel of a waste stream profile.

54 ENVIRONMENTAL SCIENCES↗