IRRADIATION OF ETHYLENE DILUTED IN SOLID NITROGEN WITH VACUUM ULTRAVIOLET LIGHT AND ELECTRONS: ITS IMPLICATIONS FOR THE FORMATION OF HCN AND HNC
Chemical reactions of C{sub 2}H{sub 4} dispersed in solid nitrogen at 10 K that occur upon irradiation with Lyα light at a wavelength of 121.6 nm and 500 eV electrons were investigated by measuring the infrared absorption spectra. Photolysis of the matrix samples with 121.6 nm light yielded products, including C{sub 2}H{sub 2}, CN, and isomers of C{sub 2}N{sub 2}, as well as a pair of HCN and HNC. In contrast, electron bombardment of similar matrix samples mainly resulted in the generation of N{sub 3}, C{sub 2}H{sub 2}, C{sub 2}H{sub 3}, C{sub 3}H{sub 2}, and C{sub 3}N{sup −}. Mechanisms of the reactions that occur during the photolysis and electron-radiation of the matrix samples are discussed. The results of the study provide insights into the formation of HNC and HCN, as well as nitriles, in N{sub 2}-rich ice samples containing a small proportion of C{sub 2}H{sub 4}.