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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,675 records · Page 93
All sourcesNASA NTRSDOE OSTI
DOE OSTI2015

Galvanomagnetic properties and electronic structure of iron-doped PbTe

We synthesize an iron-doped PbTe single-crystal ingot and investigate the phase composition and distribution of the iron impurity along the ingot as well as galvanomagnetic properties in weak magnetic fields (4.2 K ≤ T ≤ 300 K, B ≤ 0.07 T) of Pb{sub 1−y}Fe{sub y}Te alloys. We find microscopic inclusions enriched with iron and regions with a chemical composition close to FeTe in the heavily doped samples, while the iron impurity content in the main phase rises only slightly along the length of the ingot reaching the impurity solubility limit at approximately 0.6 mol. %. Samples from the initial and the middle parts of the ingot are characterized by p-type metal conductivity. An increase of the iron impurity content leads to a decrease in the free hole concentration and to a stabilization of galvanomagnetic parameters due to the pinning of the Fermi level by the iron resonant impurity level E{sub Fe} lying under the bottom of the valence band (E{sub v} − E{sub Fe} ≈ 16 meV). In the samples from the end of the ingot, a p-n inversion of the conductivity type and an increase of the free electron concentration along the ingot are revealed despite the impurity solubility limit being reached. The kinetics of changes of charge carrier concentration and of the Fermi energy along the ingot is analyzed in the framework of the six-band Dimmock dispersion relation. A model is proposed for the electronic structure rearrangement of Pb{sub 1−y}Fe{sub y}Te with doping, which may also be used for PbTe doped with other transition metals.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2011

Study of the surface chemistry and morphology of single walled carbon nanotube-magnetite composites

The study of the morphologies of the single walled carbon nanotube (SWCNT), magnetite nanoparticles (MNP), and the composite based on them was carried with combined X-ray diffraction (XRD), Raman spectroscopy (RS), scanning electron microscopy (SEM), field emission scanning electron microscopy (FESEM) and high resolution transmission electron microscopy (HRTEM). These techniques together with thermogravimetric analyses (TGA) and diffuse reflectance infrared transform spectroscopy (DRIFTS) confirmed the production of pure single phases, and that the composite material consisted of MNP attached to the outer surface of the SWCNT. The Moessbauer spectroscopy (MS) research showed the presence of a large quantity of Lewis acid sites in the highly dispersed magnetite particles supported on the SWCNT outer surface. The DRIFTS carbon dioxide adsorption study of the composites revealed significant adsorption of carbon dioxide, fundamentally in the Lewis acid sites. Then, the Lewis acid sites were observed to be catalytically active. Further, the electron exchange between the Lewis acid sites and the basic or amphoteric adsorbed molecules could influence the magnetic properties of the magnetite. Consequently, together with this first ever use of MS in the study of Lewis acid sites, this investigation revealed the potential of the composites for catalytic and sensors applications. -- Graphical abstract: A large amount of Lewis acid sites were found in the highly dispersed magnetite which is supported on the SWCNT outer surface. Display Omitted Research highlights: {yields} The obtained materials were completely characterized with XRD, Raman and SEM-TEM. {yields} DRIFT, TGA and adsorption of the composites allowed understand the material formation. {yields} This is the first report of a study of Lewis sites by Moessbauer spectroscopy.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2014

Coupled ion acoustic and drift waves in magnetized superthermal electron-positron-ion plasmas

Linear and nonlinear coupled drift-ion acoustic waves are investigated in a nonuniform magnetoplasma having kappa distributed electrons and positrons. In the linear regime, the role of kappa distribution and positron content on the dispersion relation has been highlighted; it is found that strong superthermality (low value of κ) and addition of positrons lowers the phase velocity via decreasing the fundamental scalelengths of the plasmas. In the nonlinear regime, first, coherent nonlinear structure in the form of dipoles and monopoles are obtained and the boundary conditions (boundedness) in the context of superthermality and positron concentrations are discussed. Second, in case of scalar nonlinearity, a Korteweg–de Vries-type equation is obtained, which admit solitary wave solution. It is found that both compressive and rarefactive solitons are formed in the present model. The present work may be useful to understand the low frequency electrostatic modes in inhomogeneous electron positron ion plasmas, which exist in astrophysical plasma situations such as those found in the pulsar magnetosphere.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2016

Elucidating the magnetic and superconducting phases in the alkali metal intercalated iron chalcogenides

Here, the complex interdigitated phases have greatly frustrated attempts to document the basic features of the superconductivity in the alkali metal intercalated iron chalcogenides. Here, using elastic neutron scattering, energy-dispersive x-ray spectroscopy, and resistivity measurements, we elucidate the relations of these phases in Rb x Fe y Se 2-z S z . We find (i) the iron content is crucial in stabilizing the stripe antiferromagnetic (AF) phase with rhombic iron vacancy order (y ≈ 1.5), the block AF phase with root 5 x root 5 iron vacancy order (y ≈ 1.6), and the iron vacancy-free phase (y ≈ 2); and (ii) the iron vacancy-free superconducting phase (z = 0) evolves into an iron vacancy-free metallic phase with sulfur substitution (z > 1.5) due to the progressive decrease of the electronic correlation strength. Both the stripe AF phase and the block AF phase are Mott insulators. The iron-rich compounds (y > 1.6) undergo a first order transition from an iron vacancy disordered phase at high temperatures into the √5 x √5 iron vacancy ordered phase and the iron vacancy-free phase below T s . Our data demonstrate that there are miscibility gaps between these three phases. The existence of the miscibility gaps in the iron content is a key to understanding the relationship between these complicated phases.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2014

Preparation and structural, optical, magnetic, and electrical characterization of Mn{sup 2+}/Co{sup 2+}/Cu{sup 2+} doped hematite nanocrystals

Pure and Mn{sup 2+} / Co{sup 2+} / Cu{sup 2+} doped (1 and 2 at.%) spherical hematite (α-Fe{sub 2}O{sub 3})nanocrystals have been synthesized by a simple solvothermal method using a domestic microwave oven. XRD measurements confirm that all the seven nanocrystals prepared consist of nanocrystalline hematite phase without any other phases. The energy dispersive X-ray and Fourier transform infrared spectral analyses confirm the phase purity of the nanocrystals prepared. TEM analysis shows the average particle sizes within the range 33–51 nm. Optical absorption measurements indicate that all the three dopants enhance the optical transmittance and reflectance. A red shift is observed in the bandgap energy values estimated from optical absorption and reflectance spectra. Results of magnetic measurements made at room temperature using a vibrating sample magnetometer indicate significant changes in the magnetic properties (coercivity, retentivity and saturationmagnetization) due to doping. Results of magnetic measurements indicate significant changes in the magnetic properties. Results of AC electrical measurements made at various temperatures in the range 40–130 °C and frequencies in the range 100 Hz –1 MHz indicate low dielectric constants and AC electrical conductivities and consequently show the occurrence of nanoconfined states. -- Graphical abstract: The indexed X-ray diffraction (XRD) patterns of all the seven nanocrystals indicate the rhombohedral structure of hematite (JCPDS card No.13-0534). No impurity phase like oxides of Mn or Co or Cu was detected above equipment limit. The average crystallite (grain) sizes estimated using the Scherrer's formula. Highlights: • Pure and Mn/Co/Cu-doped hematite nanocrystals have been prepared. • The method adopted for the preparation is simple, economical and scalable. • Prepared nanocrystals are spherical in shape with good crystallinity and phase purity. • Mn/Co/Cu-doping enhances the optical transmittance and ferromagnetic order. • Optical, magnetic and electrical properties tuned by Mn/Co/Cu-doping are explained.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2018

Magnetic Core/Shell Nanocomposites MgFe{sub 2}O{sub 4}/SiO{sub 2} for Biomedical Application: Synthesis and Properties

Magnetic core/shell (CS) nanocomposites (MNCs) are synthesized using a simple method, in which a magnesium ferrite nanoparticle (MgFe{sub 2}O{sub 4}) is a core, and an amorphous silicon dioxide (silica SiO{sub 2}) layer is a shell. The composition, morphology, and structure of synthesized particles are studied using X-ray diffraction, field emission electron microscopy, transmission electron microscopy (TEM), energy-dispersive spectroscopy (EDS), scattering electrophoretic photometer, thermogravimetric analysis (TGA), and Mössbauer spectroscopy. It is found that the MgFe{sub 2}O{sub 4}/SiO{sub 2} MNC has the core/shell structure formed by the Fe‒O–Si chemical bond. After coating with silica, the MgFe{sub 2}O{sub 4}/SiO{sub 2} MNC saturation magnetization significantly decreases in comparison with MgFe{sub 2}O{sub 4} particles without a SiO{sub 2} shell. Spherical particles agglomerated from MgFe{sub 2}O{sub 4} nanocrystallites ∼9.6 and ∼11.5 nm in size function as cores coated with SiO{sub 2} shells ∼30 and ∼50 nm thick, respectively. The total size of obtained CS MNCs is ∼200 and 300 nm, respectively. Synthesized CS MgFe{sub 2}O{sub 4}/SiO{sub 2} MNCs are very promising for biomedical applications, due to the biological compatibility of silicon dioxide, its sizes, and the fact that the Curie temperature is in the region required for hyperthermal therapy, 320 K.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2022

Anisotropic magnon damping by zero-temperature quantum fluctuations in ferromagnetic CrGeTe 3

Spin and lattice are two fundamental degrees of freedom in a solid, and their fluctuations about the equilibrium values in a magnetic ordered crystalline lattice form quasiparticles termed magnons (spin waves) and phonons (lattice waves), respectively. In most materials with strong spin-lattice coupling (SLC), the interaction of spin and lattice induces energy gaps in the spin wave dispersion at the nominal intersections of magnon and phonon modes. Here we use neutron scattering to show that in the two-dimensional (2D) van der Waals honeycomb lattice ferromagnetic CrGeTe 3 , spin waves propagating within the 2D plane exhibit an anomalous dispersion, damping, and breakdown of quasiparticle conservation, while magnons along the c axis behave as expected for a local moment ferromagnet. These results indicate the presence of dynamical SLC arising from the zero-temperature quantum fluctuations in CrGeTe 3 , suggesting that the observed in-plane spin waves are mixed spin and lattice quasiparticles fundamentally different from pure magnons and phonons.

36 MATERIALS SCIENCE↗
DOE OSTI2011

Magnetic correlations in Ho{sub x}Tb{sub 2-x}Ti{sub 2}O{sub 7}

Polycrystalline samples of Ho{sub x}Tb{sub 2-x}Ti{sub 2}O{sub 7} (0 < x < 2) have been prepared and characterized for their structural and magnetic properties. The parent compounds of this solid solution are the spin ice Ho{sub 2}Ti{sub 2}O{sub 7} and the spin liquid Tb{sub 2}Ti{sub 2}O{sub 7}. Specific-heat measurements on HoTbTi{sub 2}O{sub 7} (x = 1.0) reveal the absence of a long-range order state above 0.5 K. The integrated entropies of all Ho{sub x}Tb{sub 2-x}Ti{sub 2}O{sub 7} specimens up to 30 K scale well with the ratio of spin ice and spin liquid in the composition. The neutron diffraction spectrum of HoTbTi{sub 2}O{sub 7} exhibits a dipolar spin-ice pattern and can be well described by mean-field theory for <111> Ising spins, nearest-neighbor exchange, and dipolar interactions. Inelastic neutron scattering on HoTbTi{sub 2}O{sub 7} reveals two dispersionless excitations, one of {approx}2.5 meV out of the ground state, and a 4-meV transition out of an excited state. We argue that these data suggest that the very strong single-ion effects of Ho{sub 2}Ti{sub 2}O{sub 7} and Tb{sub 2}Ti{sub 2}O{sub 7} persist in the Ho{sub x}Tb{sub 2-x}Ti{sub 2}O{sub 7}(0 < x < 2) solid solution, whereas the Tb-Ho correlations are weak, resulting in small shifts in the energy scales but with no dramatic effect on the bulk properties.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Laboratory Measurement of Large-Amplitude Whistler Pulses Generated by Fast Magnetic Reconnection

Here, we introduce observations of large-amplitude (δB/B~ 0.01) oblique whistler wave pulses generated by a spontaneous, 3-D localized magnetic reconnection event in the Caltech jet experiment. The wave pulses are measured more than 50 ion skin depths from the reconnection location by a tetrahedron array of three-axis B-dot probes that mimic the pyramid flight formations of the Cluster and Magnetospheric Multiscale Mission spacecraft. Measurements of background parameters, wave polarization, and wave dispersion confirm that the pulses are whistler modes. These findings demonstrate that localized impulsive reconnection events can generate large-amplitude, oblique whistler wave pulses that propagate far outside the reconnection region. This offers a new pathway for the generation of magnetospheric whistler pulses and may help explain relativistic particle acceleration in phenomena such as solar flares that incorporate 3-D localized impulsive magnetic reconnection.

3‐D magnetic reconnection↗
DOE OSTI2014

A tale of two anomalies: Depletion, dispersion, and the connection between the stellar lithium spread and inflated radii on the pre-main sequence

We investigate lithium depletion in standard stellar models (SSMs) and main sequence (MS) open clusters, and explore the origin of the Li dispersion in young, cool stars of equal mass, age, and composition. We first demonstrate that SSMs accurately predict the Li abundances of solar analogs at the zero-age main sequence (ZAMS) within theoretical uncertainties. We then measure the rate of MS Li depletion by removing the [Fe/H]-dependent ZAMS Li pattern from three well-studied clusters, and comparing the detrended data. MS depletion is found to be mass-dependent, in the sense of more depletion at low mass. A dispersion in Li abundance at fixed T{sub eff} is nearly universal, and sets in by ∼200 Myr. We discuss mass and age dispersion trends, and the pattern is mixed. We argue that metallicity impacts the ZAMS Li pattern, in agreement with theoretical expectations but contrary to the findings of some previous studies, and suggest Li as a test of cluster metallicity. Finally, we argue that a radius dispersion in stars of fixed mass and age, during the epoch of pre-MS Li destruction, is responsible for the spread in Li abundances and the correlation between rotation and Li in young cool stars, most well known in the Pleiades. We calculate stellar models, inflated to match observed radius anomalies in magnetically active systems, and the resulting range of Li abundances reproduces the observed patterns of young clusters. We discuss ramifications for pre-MS evolutionary tracks and age measurements of young clusters, and suggest an observational test.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2025

A scalable multidimensional fully implicit solver for Hall magnetohydrodynamics

We propose an optimally performant fully implicit algorithm for the Hall magnetohydrodynamics (HMHD) equations based on multigrid-preconditioned Jacobian-free Newton-Krylov methods. HMHD is a challenging system to solve numerically because it supports stiff fast dispersive waves. The preconditioner is formulated using an operator-split approximate block factorization (Schur complement), informed by physics insight. We use a vector-potential formulation (instead of a magnetic field one) to allow a clean segregation of the problematic $\nabla$ x $\nabla$ x operator in the electron Ohm's law subsystem. This segregation allows the formulation of an effective damped block-Jacobi smoother for multigrid. We demonstrate by analysis that our proposed block-Jacobi iteration is convergent and has the smoothing property. The resulting HMHD solver is verified linearly with wave propagation examples, and nonlinearly with the GEM challenge reconnection problem by comparison against another HMHD code. We demonstrate the excellent algorithmic and parallel performance of the algorithm up to 16384 MPI tasks in two dimensions.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2014

An optically modulated zero-field atomic magnetometer with suppressed spin-exchange broadening

We demonstrate an optically pumped {sup 87}Rb magnetometer in a microfabricated vapor cell based on a zero-field dispersive resonance generated by optical modulation of the {sup 87}Rb ground state energy levels. The magnetometer is operated in the spin-exchange relaxation-free regime where high magnetic field sensitivities can be achieved. This device can be useful in applications requiring array-based magnetometers where radio frequency magnetic fields can induce cross-talk among adjacent sensors or affect the source of the magnetic field being measured.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2014

Ultrafast dark-field surface inspection with hybrid-dispersion laser scanning

High-speed surface inspection plays an important role in industrial manufacturing, safety monitoring, and quality control. It is desirable to go beyond the speed limitation of current technologies for reducing manufacturing costs and opening a new window onto a class of applications that require high-throughput sensing. Here, we report a high-speed dark-field surface inspector for detection of micrometer-sized surface defects that can travel at a record high speed as high as a few kilometers per second. This method is based on a modified time-stretch microscope that illuminates temporally and spatially dispersed laser pulses on the surface of a fast-moving object and detects scattered light from defects on the surface with a sensitive photodetector in a dark-field configuration. The inspector's ability to perform ultrafast dark-field surface inspection enables real-time identification of difficult-to-detect features on weakly reflecting surfaces and hence renders the method much more practical than in the previously demonstrated bright-field configuration. Consequently, our inspector provides nearly 1000 times higher scanning speed than conventional inspectors. To show our method's broad utility, we demonstrate real-time inspection of the surface of various objects (a non-reflective black film, transparent flexible film, and reflective hard disk) for detection of 10 μm or smaller defects on a moving target at 20 m/s within a scan width of 25 mm at a scan rate of 90.9 MHz. Our method holds promise for improving the cost and performance of organic light-emitting diode displays for next-generation smart phones, lithium-ion batteries for green electronics, and high-efficiency solar cells.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2015

The analysis of Raman scattering in a free-electron laser with a rectangular hybrid wiggler

A one dimensional theory of the stimulated Raman backscattering process in a free electron laser with rectangular hybrid wiggler (RHW) is analyzed. The dispersion relation in the rest frame of the electron beam and also a formula for the lab-frame spatial growth rate are derived. A numerical computation of the growth rate for RHW is conducted and a comparison with that for coaxial hybrid wiggler is made away from the resonance. The growth rate is found larger for the rectangular wiggler than for the coaxial wiggler. A much narrower magnetoresonance associated with the third spatial harmonic is also obtained compared to the first one.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2011

ASSIGNMENT OF 5069 A DIFFUSE INTERSTELLAR BAND TO HC{sub 4}H{sup +}: DISAGREEMENT WITH LABORATORY ABSORPTION BAND

Krelowski et al. have reported a weak, diffuse interstellar band (DIB) at 5069 A which appears to match in both mid-wavelength and width the A {sup 2}{Pi}{sub u}-X {sup 2}{Pi}{sub g} gas-phase origin absorption band of HC{sub 4}H{sup +}. Here, we present laboratory rotational profiles at low temperatures which are then compared with the 5069 A DIB using {approx}0.1 and 0.3 A line widths based on a realistic line-of-sight interstellar velocity dispersion. Neither the band shape nor the wavelength of the maximum absorption match, which makes the association of the 5069 A DIB with HC{sub 4}H{sup +} unlikely. The magnetic dipole transition X {sup 2}{Pi}{sub g} {Omega} = 1/2{yields}X {sup 2}{Pi}{sub g} {Omega} = 3/2 within the ground electronic state which competes with collisional excitation is also considered. In addition, we present the laboratory gas-phase spectrum of the A {sup 2}{Pi}{sub u}-X {sup 2}{Pi}{sub g} transition of HC{sub 4}H{sup +} measured at 25 K in an ion trap and identify further absorption bands at shorter wavelengths for comparison with future DIB data.

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2017

Direct observation of magnon-phonon coupling in yttrium iron garnet

The magnetic insulator yttrium iron garnet (YIG) with a ferrimagnetic transition temperature of ~ 560 K has been widely used in microwave and spintronic devices. Anomalous features in spin Seeback effect (SSE) voltages have been observed in Pt/YIG and attributed to magnon-phonon coupling. Here, we use inelastic neutron scattering to map out low-energy spin waves and acoustic phonons of YIG at 100 K as a function of increasing magnetic field. In this work, by comparing the zero and 9.1 T data, we find that instead of splitting and opening up gaps at the spin wave and acoustic phonon dispersion intersecting points, magnon-phonon coupling in YIG enhances the hybridized scattering intensity. These results are different from expectations of conventional spin-lattice coupling, calling for different paradigms to understand the scattering process of magnon-phonon interactions and the resulting magnon polarons.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗