SEARCH · Engineering Papers

Results for “LAB”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,675 records · Page 93

All sources NASA NTRS DOE OSTI

DOE OSTI2025

UV + Damp Heat Induced Power Losses in Fielded Utility N-Type Si PV Modules

A recent trend in commercial PV modules is a transition to n-type silicon cells, including passivated emitter rear totally diffused (n-PERT), tunnel oxide passivated contact (TOPCon), and silicon heterojunction (SHJ). There is evidence via lab studies that some of these cells are more susceptible to UV induced degradation (UVID), yet there is a lack of confirmation that such degradation occurs in the field. Current IEC standards designed to screen for early module failures require only minimal UV exposure (15 kWh/m2 280-400 nm, ~2-3 months equivalent outdoor exposure). Here, we investigate fielded n-PERT silicon (Si) modules from a commercial utility that show power losses of ~2%/year. We present a comprehensive picture of the physics and chemistry of degradation supported by both module and cell electronic characterization (EL, PL, IV, EQE, and DLIT) and materials-level morphological and chemical analysis (SEM, EDS, XPS, FTIR, and HPLC). All sampled site modules show short circuit current (Isc) and open circuit voltage (Voc) losses when compared to unfielded spares, with the most severely degraded also having losses in fill factor (FF). We identify two different degradation modes contributing to overall power loss: (1) external quantum efficiency (EQE) measurements show losses in the blue range of the spectra, indicative of cell surface recombination losses, and (2) variations in high series resistance (Rs) at the cell level that are correlated with compositional differences in cell metallization. Using unfielded spares, we were able to reproduce Voc, Isc, and EQE losses via a minimum UV stress of 67.5 kWh/m2 (280-400 nm), 4.5x the exposure currently required in IEC 61215-2 (MQT 10). Degradation continued with additional UV dosage equivalent to the fielded modules (405 kWh/m2 total), with power loss leveling out at an average of 6.1%. Subsequent 1000 h of 85% RH/85degrees C damp heat testing showed that cells exposed to UV underwent additional severe series resistance degradation, even those without the susceptible paste composition seen in the field, whereas non-UV exposed cells saw little change. We attribute this to higher concentrations of acetic acid generated on the UV exposed area of the module, leading to degradation of the gridline/cell interface and high Rs. This study is unique in that it reproduces field observed utility scale UVID with an accelerated test and supports the need for standards development for longer UV exposure combined with other stress factors to catch materials interplay within a module package.

14 SOLAR ENERGY↗

DOE OSTI2025

Deep Neural Network Assisted Distributed Strain and Temperature Fiber Sensor System for Natural Gas Pipeline Monitoring

Natural gas pipeline integrity monitoring is crucial to detect potential leaks, find structural issues, and prevent environmental damage. This article presents a system of natural gas pipeline monitoring that uses a specialized double Brillouin peak sensing fiber along with the Brillouin optical time domain analysis (BOTDAs) technique. The calibrated sensing fiber coefficients for strain and temperature are 41.8 kHz/ με and 0.9 MHz/°C for peak 1; and 47.2 kHz/ με , and 1.11 MHz/°C for peak 2, respectively. Initially, lab tests were performed by installing a short section of double Brillouin peak fiber (DBPF) on a 1-in steel pipe under pressure up to 1000 per square inch (psi) at elevated temperatures. Simultaneous distributed measurements of temperature and pressure-induced hoop strain were successfully measured. Considering the long processing speed to extract Brillouin frequency shift (BFS), we employ a novel probabilistic deep neural network (PDNN) framework for rapid BFS prediction. Additionally, using the Finite Element Method, the effects of the pipeline pressure on hoop strain were modeled and compared to the experimental hoop strain under the same set of pipeline conditions. Finally, an actual 4-in outer diameter steel natural gas pipeline was used for pilot-scale tests, where hoop strain was measured at various pressure levels. Leaks were simulated to demonstrate accurate pipeline integrity monitoring. At an internal pipe pressure of 1000 psi, hoop strain of approximately 300 με was observed, and the sensitivity was calculated as 0.28 με /psi. The results of this pilot-scale study demonstrated that the system is capable of performing distributed monitoring sufficient to detect pipeline pressure and the presence of leaks to ensure the safe operation of gas pipelines in the field.

03 NATURAL GAS↗

DOE OSTI2025

Particle Handling in Particle-Based Pumped Thermal Energy Storage

A particle-based pumped thermal electricity storage system stores high-temperature heat (~1000 degrees C) in low-cost silica sand and generates power through an efficient power cycle. Central to this system is a counterflow direct-contact gas/particle fluidized-bed heat exchanger, which can significantly improve the heat exchange process due to the large heat transfer surface area of particles. To showcase a lab-scale 10- to 20-kWe heat exchange process with particles heating up to 300 degrees C, a comprehensive hydrodynamic analysis of the fluidization condition inside the heat exchanger was conducted. The heat exchanger was designed to target for heat exchange process of 10-20 kW and accommodate an air mass flow rate of 0.3-0.7 kg/s. The fluidization condition was set to maintain stable bubbling fluidization, thereby maximizing the particle-to-air heat transfer. An air distributor was designed to equally distribute air over the bed, which can avoid defluidized zones in the heat exchanger. Additionally, particle handling systems including L-valves, screw conveyors, and pneumatic conveyors were developed for the prototype heat exchanger, efficiently conveying high-temperature particles at 0.2-0.5 kg/s. This work lays the foundation for scaling up the system and integrating it into larger energy storage applications, demonstrating its potential for efficient, high-temperature thermal energy storage and power generation.

25 ENERGY STORAGE↗

DOE OSTI2025

eLog Analysis for Accelerators: Status and Future Outlook

This work demonstrates electronic logbook (eLog) systems leveraging modern AI-driven information retrieval capabilities at the accelerator facilities of Fermilab, Jefferson Lab, Lawrence Berkeley National Laboratory (LBNL), SLAC National Accelerator Laboratory. We evaluate contemporary tools and methodologies for information retrieval with Retrieval Augmented Generation (RAGs), focusing on operational insights and integration with existing accelerator control systems. The study addresses challenges and proposes solutions for state-of-the-art eLog analysis through practical implementations, demonstrating applications and limitations. We present a framework for enhancing accelerator facility operations through improved information accessibility and knowledge management, which could potentially lead to more efficient operations.

Hellert, Thorsten [LBNL, ALS]↗

DOE OSTI2025

eLog analysis for accelerators: status and future outlook

Sulc, A. [LBL, Berkeley]↗

DOE OSTI2017

Simulating stick-slip failure in a sheared granular layer using a physics-based constitutive model

In this paper, we model laboratory earthquakes in a biaxial shear apparatus using the Shear-Transformation-Zone (STZ) theory of dense granular flow. The theory is based on the observation that slip events in a granular layer are attributed to grain rearrangement at soft spots called STZs, which can be characterized according to principles of statistical physics. We model lab data on granular shear using STZ theory and document direct connections between the STZ approach and rate-and-state friction. We discuss the stability transition from stable shear to stick-slip failure and show that stick slip is predicted by STZ when the applied shear load exceeds a threshold value that is modulated by elastic stiffness and frictional rheology. Finally, we also show that STZ theory mimics fault zone dilation during the stick phase, consistent with lab observations.

58 GEOSCIENCES↗

DOE OSTI2023

Atmospheric Humidity Underlies Irreproducibility of Formamidinium Lead Iodide Perovskites

Metal halide perovskite solar cells (PSCs) are infamous for their batch-to-batch and lab-to-lab irreproducibility in terms of stability and performance. Reproducible fabrication of PSCs is a critical requirement for market viability and practical commercialization. PSC irreproducibility plagues all levels of the community; from institutional research laboratories, start-up companies, to large established corporations. Here, in this work, the critical function of atmospheric humidity to regulate the crystallization and stabilization of formamidinium lead triiodide (FAPbI 3 ) perovskites is unraveled. It is demonstrated that the humidity content during processing induces profound variations in perovskite stoichiometry, thermodynamic stability, and optoelectronic quality. Almost counterintuitively, it is shown that the presence of humidity is perhaps indispensable to reproduce phase-stable and efficient FAPbI 3 -based PSCs.

14 SOLAR ENERGY↗

DOE OSTI2022

Scalable Direct Recycling of Cathode Black Mass from Spent Lithium‐Ion Batteries

Abstract End of life (EoL) lithium‐ion batteries (LIBs) are piling up at an intimidating rate, which is alarming for environmental health. With further expected rapid growth of LIB use, the magnitude of spent battery accumulation is also expected to grow. LiNi x Co y Mn z O 2 (NCM) cathode materials are a dominant chemistry in high energy LIBs, and make up a huge portion of this waste accumulation. Direct recycling is one of the most promising ways to turn this waste to wealth, but has been limited to lab‐scale, due to lack of robustness, namely the tedious pretreatment required that involves toxic organic solvents. Herein, a process that integrates the pretreatment and relithiation of the cathode black mass is demonstrated. Cathode material from EoL electric vehicle (EV) batteries is treated in a 100 g per batch operation and the regenerated cathode active material demonstrates 100% electrochemical performance recovery, with 91% yield rate, and shows promise for further scale up. This process has the advantages of integration, scalability, and universality, which clears the barricade for direct recycling to move from lab to industry scale with considerable profitability.

Chemistry↗

DOE OSTI2020

SERS and the scientific career of Richard P. Van Duyne (1945–2019)

This article describes the scientific career of our dear friend Richard P. Van Duyne. Rick was the discoverer of surface-enhanced Raman spectroscopy (SERS), and over the period from the mid-1970s until his death in 2019, he served as both the intellectual leader of the field, and the technical genius who pushed the field forward through his numerous inventions and discoveries. Rick's work went through many phases, and even involved a significant period of inactivity that Rick was able to break out of, but especially after 2000, there was a period of incredible creativity that ultimately led to a detailed understanding of what the SERS enhancement factor is all about and also led to fabrication techniques for making optimum SERS substrates such that applications of SERS to a wide variety of real-world problems in sensing became possible. In addition, Rick's SERS work spawned numerous related technologies, including index of refraction sensing based on localized surface plasmon resonance (LSPR) measurements, and the extension of SERS to its tip-enhanced cousin TERS, to electrochemical versions of SERS and TERS, and to ultrafast nonlinear techniques. The practical applications he pursued included diagnostics for diseases such as cancer, hand-held glucose sensing, and SERS studies related to art conservation. Furthermore, Rick's legacy will probably be best known through the numerous students, postdocs, and collaborators that passed through his lab and who are now active researchers in areas related to SERS at universities and industrial labs around the world.

47 OTHER INSTRUMENTATION↗

DOE OSTI2021

Carbonate clumped isotope analysis (Δ 47 ) of 21 carbonate standards determined via gas‐source isotope‐ratio mass spectrometry on four instrumental configurations using carbonate‐based standardization and multiyear data sets

Rationale Clumped isotope geochemistry examines the pairing or clumping of heavy isotopes in molecules and provides information about the thermodynamic and kinetic controls on their formation. The first clumped isotope measurements of carbonate minerals were first published 15 years ago, and since then, interlaboratory offsets have been observed, and laboratory and community practices for measurement, data analysis, and instrumentation have evolved. Here we briefly review historical and recent developments for measurements, share Tripati Lab practices for four different instrument configurations, test a recently published proposal for carbonate‐based standardization on multiple instruments using multi‐year data sets, and report values for 21 different carbonate standards that allow for recalculations of previously published data sets. Methods We examine data from 4628 standard measurements on Thermo MAT 253 and Nu Perspective IS mass spectrometers, using a common acid bath (90°C) and small‐sample (70°C) individual reaction vessels. Each configuration was investigated by treating some standards as anchors (working standards) and the remainder as unknowns (consistency standards). Results We show that different acid digestion systems and mass spectrometer models yield indistinguishable results when instrument drift is well characterized. For linearity correction, mixed gas‐and‐carbonate standardization or carbonate‐only standardization yields similar results. No difference is observed in the use of three or eight working standards for the construction of transfer functions. Conclusions We show that all configurations yield similar results if instrument drift is robustly characterized and validate a recent proposal for carbonate‐based standardization using large multiyear data sets. Δ 47 values are reported for 21 carbonate standards on both the absolute reference frame (ARF; also refered to as the Carbon Dioxide Equilibrated Scale or CDES) and the new InterCarb‐Carbon Dioxide Equilibrium Scale (I‐CDES) reference frame, facilitating intercomparison of data from a diversity of labs and instrument configurations and restandardization of a broad range of sample sets between 2006, when the first carbonate measurements were published, and the present.

58 GEOSCIENCES↗

DOE OSTI2016

From Desire to Data: How JLab’s Experimental Program Evolved

Measurements of the EMC effect in the tritium and helium-3 mirror nuclei are reported. The data were obtained by the MARATHON Jefferson Lab experiment, which performed deep inelastic electron scattering from deuterium and the three-body nuclei, using a cryogenic gas target system and the High Resolution Spectrometers of the Hall A Facility of the Lab. The data cover the Bjorken x range from 0.20 to 0.83, corresponding to a squared four-momentum transfer Q2 range from 2.7 to 11.9 (GeV/c)2, and to an invariant mass W of the final hadronic state greater than 1.84 GeV/c2. The tritium EMC effect measurement is the first of its kind. The MARATHON experimental results are compared to results from previous measurements by DESY-HERMES and JLab-Hall C experiments, as well as with few-body theoretical predictions.

Westfall, Catherine↗

DOE OSTI2022

Reference surface excess isotherms for carbon dioxide adsorption on ammonium ZSM-5 at various temperatures

Abstract This work is part of the effort at the Facility for Adsorbent Characterization and Testing (FACT lab) at the National Institute of Standards and Technology (NIST) to develop reference materials, reference data, and measurement best practices for adsorption metrology. High-pressure surface excess isotherms for CO 2 adsorption on NIST Reference Material 8852 (ammonium ZSM-5) at 15 °C, 25 °C, and 35 °C are reported, expanding on a FACT Lab-organized international interlaboratory study on this sorbent/sorbate pair at 20 °C. The range of temperatures of the present study is of interest for many CO 2 adsorption measurements and applications. Measurements were made using five different adsorption instruments, both manometric and gravimetric. Excellent agreement in the measured isotherms among the instruments was found. An empirical reference equation of the form, $${n}_{ex,ref}({P}_{eq})=\frac{c}{\{{1+\mathrm{exp}[\left(-\mathrm{ln}\left(P\right)+a\right)/b ]\}}^{b }} ,$$ n e x , r e f ( P eq ) = c { 1 + exp [ - ln P + a / b ] } b , [ n ex,ref is surface excess uptake (mmol/g); P eq is equilibrium pressure (MPa); P is ( P eq )/(1 MPa)]; a , b , c are constants] and the 95% uncertainty interval were determined for the isotherms at each of the temperatures. Lastly, the isosteric heat of adsorption is estimated from absolute isotherms derived from the surface excess reference data.

Nguyen, Huong Giang T. (ORCID:0000000210527565)↗

DOE OSTI2017

The Millennial model: in search of measurable pools and transformations for modeling soil carbon in the new century

Soil organic carbon (SOC) can be defined by measurable chemical and physical pools, such as mineral-associated carbon, carbon physically entrapped in aggregates, dissolved carbon, and fragments of plant detritus. Yet, most soil models use conceptual rather than measurable SOC pools. What would the traditional pool-based soil model look like if it were built today, reflecting the latest understanding of biological, chemical, and physical transformations in soils? We propose a conceptual model-the Millennial model-that defines pools as measurable entities. First, we discuss relevant pool definitions conceptually and in terms of the measurements that can be used to quantify pool size, formation, and destabilization. Then, we develop a numerical model following the Millennial model conceptual framework to evaluate against the Century model, a widely-used standard for estimating SOC stocks across space and through time. The Millennial model predicts qualitatively similar changes in total SOC in response to single factor perturbations when compared to Century, but different responses to multiple factor perturbations. We review important conceptual and behavioral differences between the Millennial and Century modeling approaches, and the field and lab measurements needed to constrain parameter values. We propose the Millennial model as a simple but comprehensive framework to model SOC pools and guide measurements for further model development.

decomposition↗

DOE OSTI2018

A Feature-Based Stochastic Permeability of Shale: Part 2–Predicting Field-Scale Permeability

We report that in a recent numerical study, it was demonstrated that characterizing reservoir permeability in terms of rock’s quality, as observed in lab and field, is the most important step before implementing an enhanced oil recovery operation or drilling a new well in a tight formation. In that study, it was shown that permeable features in shale-like organic matter (OM) and fractures were the only regions that allowed some reasonable movement of fluid, whereas inorganic matter (iOM) that occupies larger pore volume with significant saturation of hydrocarbons has extremely low permeability that did not allow any reasonable fluid movement to affect production. That study demonstrated the importance of characterizing reservoir heterogeneity in shale in order to economically exploit the shale resource. This study proposes a method to predict spatially heterogeneous field-scale permeability of shale in terms of natural fractures, and matrix (iOM and OM). The method developed in Part 1 is combined with a history-matching process that uses only readily available information from lab-scale and outcrop (information from geologists) to predict field-scale permeability. The method also ensures consistency between the underlying fracture distribution and optimally matched fracture lengths and their apertures, in addition to accounting for random distribution of fractures and their abundance. Optimized parameters of fracture distribution are used to generate multiple realizations of geological model, and the “best-fitting” (most-likely) permeability scenario is chosen by generating production response of each realization of the geological model and comparing them against the observed field production history. Finally, the novelty of the proposed to predict field-scale permeability is that it uses only readily available information while also ensuring consistency between the underlying fracture distribution and optimally matched fracture lengths and their apertures, in addition to accounting for random distribution of fractures and their abundance.

58 GEOSCIENCES↗

DOE OSTI2022

Interlaboratory Reproducibility of Contour Method Data in a High Strength Aluminum Alloy

The contour method for residual stress measurement has seen significant development, but an experimental reproducibility study utilizing physical samples has not been published. A double-blind reproducibly study is reported, having scope beginning with EDM cutting and ending with residual stress calculation. A reinforced I-beam sample geometry is identified for its unique residual stress profile when extracted from residual stress bearing quenched aluminum bar (7050-T74). Contour measurements are prescribed on a midplane of symmetry with dimensions 24.0 mm by 50.0 mm. Fourteen identically prepared samples are fabricated from a single long bar with well characterized and uniform residual stress. Five samples throughout the bar are identified for planning measurements to validate sample uniformity and overall suitability of the residual stress field. The planning measurements employ a range of techniques: contour method, neutron diffraction, and hole-drilling. Eight samples are distributed to an international group of participants to execute their standard measurement practice. A double-blind process is followed to provide anonymity. Results are provided by eight participants: six being self-similar and two being quite different, the latter set aside as outliers. An average residual stress field is established from non-outlying results and the spatial distribution of reproducibility standard deviation is determined. The average stress field ranges from -60 to 70 MPa and the reproducibility standard deviation averages 8.1 MPa on the measurement plane. The average reproducibility standard deviation is about 3 × larger for points within 1.0 mm of plane boundaries (17.6 MPa) than for the remaining points (6.1 MPa). Reproducibility standard deviation (among different labs) for contour method residual stress measurement is found to be very similar to repeatability standard deviation (in a single lab) reported in prior work. The reproducibility observed here, for the entire measurement process, is also similar to that found in a prior reproducibility study limited to contour method data analysis.

36 MATERIALS SCIENCE↗

DOE OSTI2026

An International Round-Robin Study on Thermoelectric Module Testing and Development of Standard Power Generation Modules

An international round-robin study on thermoelectric power generation modules was conducted with nine participating laboratories. Two types of commercially available bismuth telluride modules, 30 mm × 30 mm and 40 mm × 40 mm, were used. A test protocol was followed with five temperature set points from 50°C to 150°C. Graphite sheets were used as thermal interface materials with test pressure at 100 psi (0.69 MPa). The results showed large lab-to-lab variations and the key source of uncertainty for module efficiency was identified as the heat flux measurement. In the meantime, significant uncertainty was also found in maximum electrical power (P max ) measurements. As a result of the round-robin, a “standard module” with 4 × 4 legs on a 20 mm × 20 mm platform was suggested. A skutterudite module and a half-Heusler module were produced with identical geometry and 4 mm × 4 mm × 8 mm legs. All transport properties to calculate the figure-of-merit, zT, were measured from ambient temperature to 500°C. Module performance was measured by two laboratories. Two finite-element-analysis (FEA)-based models were developed independently to simulate and predict the module performance. In conclusion, the standard modules eliminated significant test uncertainties and are aimed at assisting device design and achieving more accurate performance predictions.

Round-robin↗

DOE OSTI2025

PERCEPTIVE: an R shiny $\underline{p}$ipelin$\underline{e}$ for the p$\underline{r}$edi$\underline{c}$tion of $\underline{ep}$igenetic modula$\underline{t}$ors $\underline{i}$n no$\underline{v}$el sp$\underline{e}$cies

Epigenetic processes are central to regulating gene expression, genome stability, and metabolic function across the tree of life; yet, their roles remain underexplored in microalgae, especially as new species continue to be identified and characterized. This is likely due to the cumbersome nature and species-dependent attributes of epigenetic wet-lab methodologies, which preclude the rapid identification of epigenetic modifications and modulators. However, there is high conservation of epigenetic processes from budding yeast to humans; in many cases, one may infer how behavior and function are epigenetically regulated in novel species by identifying epigenetic modulators, or the proteins responsible for conferring epigenetic modifications. Here, to this end, we have developed a graphical software package, titled PERCEPTIVE (pipeline for the prediction of epigenetic modulators in novel species). This platform solely uses the genomic sequence of an algal species, and preexisting information from other model organisms, to predict the epigenetic modulators and associated modifications in algae. Predictions are presented to the user in a graphical interface, which provides literature-based interpretation of results, enabling users to quickly understand potential epigenetic processes in their algal species of interest and plan follow-up experiments. To test PERCEPTIVE, we predicted epigenetic modulators in several feedstock candidate algae species. To validate these predictions, wet-lab studies were performed, including mass spectrometry; these results underscore the high accuracy of PERCEPTIVE predictions. Overall, PERCEPTIVE represents a powerful in silico tool for the research and manipulation of algal species, which does not require a priori knowledge of epigenetics and is accessible to a broad set of investigators.

59 BASIC BIOLOGICAL SCIENCES↗

DOE OSTI2019

Radiation reaction of classical hyperbolic oscillator: Experimental signatures

When accelerated by a constant force in the lab frame, a classical charge experiences no self force. In this case, the particle radiates without dissipating its kinetic and potential energy. But what happens when the particle enters another region with equal and opposite acceleration? Does the oscillating charge lose its mechanical energy similar to a radiating dipole, even though it seems to lose no mechanical energy within each region of constant acceleration? In this paper, I will show how mechanical energy is transferred to radiation energy via the Schott energy when the particle crosses the boundary between the two regions. In particular, I will show how preacceleration, which is usually regarded as an unphysical effect of the Lorentz–Abraham–Dirac self force, is essential for the energy transfer. Moreover, I will show that the commonly adopted Landau–Lifshitz approximation, which removes preacceleration, introduces second-order secular energy error. On a more fundamental level, the validity of classical electrodynamics is in fact questionable because quantum effects are likely important. The classical prediction can be tested experimentally by observing frequency chirping of radiation, whereby micro physics leaves signatures on macroscopic scales. The required experimental accuracy is estimated. Trap experiments of this type is complementary to collider experiments that endeavor to observe radiation reaction for elementary particles.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗