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At least 1,675 records · Page 93

Effect of Index of Refraction on Radiation Characteristics in a Heated Absorbing, Emitting, and Scattering Layer

The index of refraction can considerably influence the temperature distribution and radiative heat flow in semitransparent materials such as some ceramics. For external radiant heating, the refractive index influences the amount of energy transmitted into the interior of the material. Emission within a material depends on the square of its refractive index, and hence this emission can be many times that for a biackbody radiating into a vacuum. Since radiation exiting through an interface into a vacuum cannot exceed that of a blackbody, there is extensive reflection at the internal surface of an interface, mostly by total internal reflection. This redistributes energy within the layer and tends to make its temperature distribution more uniform. The purpose of the present analysis is to show that, for radiative equilibrium in a gray layer with diffuse interfaces, the temperature distribution and radiative heat flux for any index of refraction can be obtained very simply from the results for an index of refraction of unity. For the situation studied here, the layer is subjected to external radiative heating incident on each of its surfaces. The material emits, absorbs, and isotropically scatters radiation. For simplicity the index of refraction is unity in the medium surrounding the layer. The surfaces of the layer are assumed diffuse. This is probably a reasonable approximation for a ceramic layer that has not been polished. When transmitted radiation or radiation emitted from the interior reaches the inner surface of an interface, the radiation is diffused and some of it thereby placed into angular directions for which there is total internal reflection. This provides a trapping effect for retaining energy within the layer and tends to equalize its temperature distribution. An analysis of temperature distributions in absorbing-emitting layers, including index of refraction effects, was developed by Gardon (1958) to predict cooling and heat treating of glass plates. The interfaces were optically smooth; the resulting specular reflections were computed from the Fresnel reflection laws. This provides a somewhat different behavior than for diffuse interfaces. A similar application was for heating that occurs in a window of a re-entry vehicle (Fowle et al., 1969). A number of recent papers (Rokhsaz and Dougherty, 1989; Ping and Lallemand, 1989; Crosbie and Shieh, 1990) further examined the effects of Fresnel boundary reflections and nonunity refractive index. Other examples of analyses of both steady and transient heat transfer to single or multiple plane layers (Amlin and Korpela, 1979; Tarshis et al., 1969) have used diffuse assumptions at the interfaces as in the present study

Siegel, R.↗

A new ionospheric electron precipitation module coupled with RAM-SCB within the geospace general circulation model

Electron precipitation down to the atmosphere due to wave-particle scattering in the magnetosphere contributes significantly to the auroral ionospheric conductivity. In order to obtain the auroral conductivity in global MHD models that are incapable of capturing kinetic physics in the magnetosphere, MHD parameters are often used to estimate electron precipitation flux for the conductivity calculation. Such an MHD approach, however, lacks self-consistency in representing the magnetosphere-ionosphere coupling processes. In this study we improve the coupling processes in global models with a more physical method. We calculate the physics-based electron precipitation from the ring current and map it to the ionospheric altitude for solving the ionospheric electrodynamics. In particular, we use the BATS-R-US (Block Adaptive Tree Scheme-Roe type-Upstream) MHD model coupled with the kinetic ring current model RAM-SCB (Ring current-Atmosphere interaction Model with Self-Consistent Magnetic field (B)) that solves pitch angle-dependent electron distribution functions, to study the global circulation dynamics during the 25–26 January 2013 storm event. Since the electron precipitation loss is mostly governed by wave-particle resonant scattering in the magnetosphere, we further investigate two loss methods of specifying electron precipitation loss associated with wave-particle interactions: (1) using pitch angle diffusion coefficients D αα (E,α) determined from the quasi-linear theory, with wave spectral and plasma density obtained from statistical observations (named as “diffusion coefficient method”) and (2) using electron lifetimes τ(E) independent on pitch angles inferred from the above diffusion coefficients (named as “lifetime method”). We found that both loss methods demonstrate similar temporal evolution of the trapped ring current electrons, indicating that the impact of using different kinds of loss rates is small on the trapped electron population. Furthermore, for the precipitated electrons, the lifetime method hardly captures any precipitation in the large L shell (i.e., 4 < L < 6.5) region, while the diffusion coefficient method produces much better agreement with NOAA/POES measurements, including the spatial distribution and temporal evolution of electron precipitation in the region from the premidnight through the dawn to the dayside. Further comparisons of the precipitation energy flux to DMSP observations indicates that the new physics-based precipitation approach using diffusion coefficients for the ring current electron loss can explain the diffuse electron precipitation in the dawn sector, such as the enhanced precipitation flux at auroral latitudes and flux drop near the subauroral latitudes, but the traditional MHD approach largely overestimates the precipitation flux at lower latitudes.

58 GEOSCIENCES↗

Interfacial Hydrogen-Bond Dynamics in Transition Metal Compounds

Understanding how water behaves when confined within atomic layers of active transition-metal carbides, nitrides, and carbonitrides is essential for uncovering the fundamental principles needed to engineer solid–liquid interfaces at the atomic scale. Yet, how lattice element chemistry and surface termination groups collectively regulate the structure and mobility of such interlayer water remains poorly understood. Here, we present a composition-controlled investigation of interlayer water dynamics in layered transition-metal nitride, carbide, and carbonitride systems using a systematic integration of quasi-elastic neutron scattering (QENS), ab initio molecular dynamics (AIMD) simulations, and density functional theory (DFT) calculations. QENS measurements show that nitride-rich systems host mobile, translationally diffusing water with thermally activated self-diffusion coefficients on the order of 10 –10 m 2 s –1 , whereas mixed C/N lattices confine water to localized, nontranslational motion that is insensitive to temperature. AIMD and DFT reveal that lattice C/N chemistry and surface functional group composition reshape the first hydration layer by modulating the surface electronic structure and termination-dependent hydrogen-bond networks, leading to pronounced differences in water ordering and thermal resilience. On the other hand, fully carbide systems exhibit intermediate behavior, highlighting that water mobility is not primarily controlled by the hydration level alone but by the coupling between lattice composition and surface chemistry. Overall, this study establishes how surface chemistry and lattice composition jointly control interfacial hydrogen bond dynamics, offering a mechanistic framework for designing transition-metal layered materials with tailored interfacial transport properties.

Hydration↗

Evidence for a spinon Fermi surface in a triangular-lattice quantum-spin-liquid candidate

A quantum spin liquid is an exotic quantum state of matter in which spins are highly entangled and remain disordered down to zero temperature. Such a state of matter is potentially relevant to high-temperature superconductivity and quantum-information applications, and experimental identification of a quantum spin liquid state is of fundamental importance for our understanding of quantum matter. Theoretical studies have proposed various quantum-spin-liquid ground states, most of which are characterized by exotic spin excitations with fractional quantum numbers (termed ‘spinons’). In this paper, we report neutron scattering measurements of the triangular-lattice antiferromagnet YbMgGaO 4 that reveal broad spin excitations covering a wide region of the Brillouin zone. The observed diffusive spin excitation persists at the lowest measured energy and shows a clear upper excitation edge, consistent with the particle–hole excitation of a spinon Fermi surface. Finally, our results therefore point to the existence of a quantum spin liquid state with a spinon Fermi surface in YbMgGaO 4 , which has a perfect spin-1/2 triangular lattice as in the original proposal of quantum spin liquids.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Planck intermediate results: XXXVII. Evidence of unbound gas from the kinetic Sunyaev-Zeldovich effect

By looking at the kinetic Sunyaev-Zeldovich effect (kSZ) in Planck nominal mission data, we present in this paper a significant detection of baryons participating in large-scale bulk flows around central galaxies (CGs) at redshift z ≈ 0.1. We estimate the pairwise momentum of the kSZ temperature fluctuations at the positions of the Central Galaxy Catalogue (CGC) samples extracted from Sloan Digital Sky Survey (SDSS-DR7) data. For the foreground-cleaned SEVEM, SMICA, NILC, and COMMANDER maps, we find 1.8–2.5σ detections of the kSZ signal, which are consistent with the kSZ evidence found in individualPlanck raw frequency maps, although lower than found in the WMAP-9yr W-band (3.3σ). We further reconstruct the peculiar velocity field from the CG density field, and compute for the first time the cross-correlation function between kSZ temperature fluctuations and estimates of CG radial peculiar velocities. This correlation function yields a 3.0–3.7σ detection of the peculiar motion of extended gas on Mpc scales in flows correlated up to distances of 80–100 h -1 Mpc. Both the pairwise momentum estimates and the kSZ temperature-velocity field correlation find evidence for kSZ signatures out to apertures of 8 arcmin and beyond, corresponding to a physical radius of >1 Mpc, more than twice the mean virial radius of halos. This is consistent with the predictions from hydrodynamical simulations that most of the baryons are outside the virialized halos. We fit a simple model, in which the temperature-velocity cross-correlation is proportional to the signal seen in a semi-analytic model built upon N-body simulations, and interpret the proportionality constant as an effective optical depth to Thomson scattering. Finally, we find τ T = (1.4 ± 0.5) × 10 -4 ; the simplest interpretation of this measurement is that much of the gas is in a diffuse phase, which contributes little signal to X-ray or thermal Sunyaev-Zeldovich observations.

79 ASTRONOMY AND ASTROPHYSICS↗

Inertial and anisotropic pressure effects on cross-field electron transport in low-temperature magnetized plasmas

In this paper, a one-dimensional (1D) particle-in-cell Monte Carlo collision (PIC-MCC) model is developed to investigate the effects of anisotropic pressure and inertial terms due to non-Maxwellian velocity distribution functions on cross-field electron transport. The conservation of momentum is evaluated by taking the moments of the first-principles gas-kinetic equation. A steady-state discharge is obtained without any low-frequency ionization oscillations by considering an anomalous electron scattering profile. Further, the results obtained from the 1D PIC-MCC model are compared with fluid models, including the quasi-neutral drift-diffusion (DD), non-neutral DD, and full fluid moment models. The discharge current obtained from the PIC-MCC model is in good agreement with the fluid models. The cross-field electron transport due to the inertial terms, i.e. the gradient of axial and azimuthal drift, is evaluated. Moreover, PIC-MCC simulation results show non-zero, anisotropic, off-diagonal pressure tensor terms due to asymmetric non-Maxwellian electron velocity distribution function, potentially contributing to cross-field electron transport.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Diffuse gamma-ray constraints on dark matter revisited I: the impact of subhalos

We make a detailed analysis of the indirect diffuse gamma-ray signals from dark matter annihilation in the Galaxy. We include the prompt emission, as well as the emission from inverse Compton scattering whenever the annihilation products contain light leptons. We consider both the contribution from the smooth dark matter halo and that from substructures. The main parameters for the latter are the mass function index and the minimal subhalo mass. We use recent results from N-body simulations to set the most reasonable range of parameters, and find that the signal can be boosted by a factor ranging from 2 to 15 towards the Galactic poles, slightly more towards the Galactic anticenter, with an important dependence on the subhalo mass index. This uncertainty is however much less than that of the extragalactic signal studied in the literature. We derive upper bounds on the dark matter annihilation cross section using the isotropic gamma-ray emission measured by Fermi-LAT, for two directions in the sky, the Galactic anticenter and the Galactic pole(s). The former represents the lowest irreducible signal from dark matter annihilation, and the latter is robust as the astrophysical background, dominated by the hadronic contribution, is rather well established in that direction. Finally, we show how the knowledge of the minimal subhalo mass, which formally depends on the dark matter particle interactions with normal matter, can be used to derive the mass function index.

79 ASTRONOMY AND ASTROPHYSICS↗

Measurement of Ehrlich-Schwoebel barrier contribution to the self-organized formation of ordered surface patterns on Ge(001)

Normal-incidence 1-keV Ar + ion bombardment leads to amorphization and ultrasmoothing of Ge at room temperature, but at elevated temperatures the Ge surface remains crystalline and is unstable to the formation of self-organized nanoscale patterns of ordered pyramid-shaped pits. The physical phenomenon distinguishing the high-temperature patterning from room-temperature ultrasmoothing is believed to be a surface instability due to the Ehrlich-Schwoebel barrier for diffusing vacancies and adatoms, which is not present on the amorphous material. This real-time grazing-incidence small-angle x-ray scattering study compares smoothing of a prepatterned Ge sample at room temperature with patterning of an initially flat Ge sample at an elevated temperature. In both experiments, when the nanoscale structures are relatively small in height, the average kinetics can be explained by a linear theory. Furthermore, the linear theory coefficients, indicating surface stability or instability, were extracted for both experiments. A comparison between the two measurements allows estimation of the contribution of the Ehrlich-Schwoebel barrier to the self-organized formation of ordered nanoscale patterns on crystalline Ge surfaces.

36 MATERIALS SCIENCE↗

Observed properties of interstellar dust

Recent information on the observed properties of interstellar dust is reviewed, with an attempt made to clarify some of the observational uncertainties associated with obtaining dust parameters. Attention is given to interstellar extinction, the interstellar dust distribution, the dust-to-gas ratio, and light scattering by dust grains. Interstellar polarization is also examined, along with heavy-element depletion in the interstellar medium, thermal emission from interstellar dust grains, diffuse interstellar features, and the composition and origin of interstellar grains.

Savage, B. D.↗

An improved method for determining the vertical ozone distribution using satellite measurements

A procedure was developed for determining vertical ozone distributions from spectral measurements of UV radiances diffusely reflected from the terrestrial atmosphere. In this procedure, the inversion method of Aruga and Igarashi (1976) is improved by incorporating the effects of multiple scattering and the lower boundary of the atmosphere. The improved inversion algorithm was tested using data of NIMBUS-4 backscattered UV experiments. The results indicate that by using this method, the vertical distributions of atmospheric ozone can be obtained with high accuracy over a wide range of altitude.

Aruga, Tadashi↗

Electron-positron heating and the eclipsing millisecond pulsar PSR 1957 + 20

The companion in the eclipsing millisecond PSR 1957 + 20 appears to be strongly heated by the pulsar and may also be rapidly losing mass due to that heating. A new mechanism is presented by which the heating may be accomplished: diffusion of mildly relativistic electron-positron pairs from the pulsar's relativistic wind through a thermal wind issuing from the companion. Wave-particle scattering regulates the depth at which the pairs deposit their energy; requirements of self-consistency place bounds on the wave spectrum and pair distribution function. If the pairs carry over about 10 percent of the pulsar spin-down luminosity, and the companion's heavy element abundance is subsolar, the heating rate can be adequate to drive a wind with sufficient momentum flux to explain the eclipse geometry. Annihilation photons then heat the companion beneath its photosphere and supply a significant part of the power for the optical luminosity. This model also suggests that the eclipse duration decreases sharply above a critical photon frequency.

Krolik, Julian H.↗

Diffuse Galactic low energy gamma ray continuum emission

We investigate the origin of diffuse low-energy Galactic gamma-ray continuum down to about 30 keV. We calculate gamma-ray emission via bremsstrahlung and inverse Compton scattering by propagating an unbroken electron power law injection spectrum and employing a Galactic emmissivity model derived from COSB observations. To maintain the low energy electron population capable of producing the observed continuum via bremsstrahlung, a total power input of 4 x 10 exp 41 erg/s is required. This exceeds the total power supplied to the nuclear cosmic rays by about an order of magnitude.

Skibo, J. G.↗

Effects of water on the stochastic motions of propane confined in MCM-41-S pores

Hydrocarbons confined in porous media find applications in a wide variety of industries and therefore their diffusive behavior is widely studied. Most of the porous media found in natural environments are laden with water, which might affect the confined hydrocarbons. To quantify the effect of hydration, we report here a combined quasielastic neutron scattering (QENS) and molecular dynamics (MD) simulation study on the dynamics of propane confined in the 1.5 nm-wide micropores of MCM-41-S in the presence of water at 230 and 250 K. To eliminate the strong incoherent signal from water and emphasize the propane signal we have used heavy water (D 2 O). QENS data show two dynamically different populations of propane in MCM-41-S and suggest that the presence of water hinders the diffusion of propane. Weak elastic contributions to the QENS spectra suggest that only long-range translational motion of propane molecules contributes to the quasielastic broadening. MD simulations carried out using a model cylindrical silica pore of 1.6 nm diameter filled with water and propane agree with the experimental finding of water hindering the diffusion of propane. Further, the simulation results suggest that the slowing down of propane motions is a function of the water content within the pore and is stronger at higher water contents. At high water content, the structure and the dynamics, both translational and rotational, of propane are severely impacted. Simulation data suggest that the rotational motion of the propane molecule occurs on time scales much faster than those accessible with the QENS instrument used, and thus explain the weak elastic contribution to the QENS spectra measured in the experiments. This study shows the effects of hydration on the structure and dynamics of volatiles in porous media, which are of interest for fundamental understanding and applied studies of confined fluids.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Thermophysical Properties of Ti3SiC2 MAX Phase Composites with SiC Reinforcement

In the present work, dense (∼100%) Ti 3 SiC 2 composites (TSC) are processed along with 20 vol% of SiC reinforcement (TSC20) via spark plasma sintering at 1400°C, 40 MPa, 15 min, and dynamic vacuum environment. Thermal expansion of both the composites increases from RT to 1273 K and linear fitting of data yields coefficient of thermal expansion (CTE) of 9.4 × 10 −6 K −1 for TSC which decreases to 8.3 × 10 −6 K −1 for TSC20. With increase in temperature from RT to 773 K, specific heat for both TSC and TSC20 composites is observed to increase from 598-850 J.kg −1 .K −1 , whereas thermal diffusivity and thermal conductivity values decrease with testing temperature. SiC reinforcement in Ti 3 SiC 2 resulted in improved thermal diffusivity from 12.7 to 18.7 mm 2 .s −1 and thermal conductivity from ∼57 to ∼79 W.m −1 .K −1 at RT. However, with increase in temperature (773 K), thermal diffusivity and conductivity decrease, and values get closer for both TSC and TSC20 composites. Further extrapolation of thermal conductivity data showed cross-over at ∼973 K due to domination of phonon-phonon scattering and thus lower values of thermal conductivity for TSC20 than TSC. Therefore, reduced CTE and higher thermal conductivity of TSC20 make it a viable choice for applications in high temperatures.

36 MATERIALS SCIENCE↗

Carrier Diffusion Lengths Exceeding 1 μm Despite Trap-Limited Transport in Halide Double Perovskites

In this work we image charge carrier transport over nanometers–micrometers and picoseconds–microseconds in halide double perovskites Cs 2 AgBiBr 6 and Cs 2 AgTlBr 6 single crystals using stroboscopic scattering microscopy. Both materials exhibit long, microsecond carrier lifetimes because of their indirect or symmetry-forbidden direct bandgaps. We extract free-charge and trap-limited mobilities near the surface and in the crystal bulk. The free-charge mobilities for both materials (~10–50 cm 2 /(V s)) can reach those reported for archetypal lead halide perovskites. We measure trap densities exceeding 10 17 cm –3 within ~20 nm of the crystal surface. Measurements on freshly cleaved or thermally annealed crystals suggest the traps are primarily halide vacancies that likely form through surface bromine degassing. Although these traps considerably slow charge transport, they are energetically shallow, enabling thermally induced detrapping and mobile carriers over microseconds at room temperature. This defect tolerance yields carrier diffusion lengths exceeding 1 μm even in the presence of large trap densities and under solar excitation conditions where traps are not saturated. These results suggest that halide double perovskites could rival the best lead-based perovskites for photovoltaic and optoelectronic applications.

36 MATERIALS SCIENCE↗

Finite range and upper branch effects on itinerant ferromagnetism in repulsive Fermi gases: Bethe–Goldstone ladder resummation approach

We investigate the ferromagnetic transition in repulsive Fermi gases at zero temperature with upper branch and effective range effects. Based on a general effective Lagrangian that reproduces precisely the two-body s-wave scattering phase shift, we obtain a nonperturbative expression of the energy density as a function of the polarization by using the Bethe–Goldstone ladder resummation. For hard sphere potential, the predicted critical gas parameter k{sub F}a=0.816 and the spin susceptibility agree well with the results from fixed-node diffusion Monte Carlo calculations. In general, positive and negative effective ranges have opposite effects on the critical gas parameter k{sub F}a: While a positive effective range reduces the critical gas parameter, a negative effective range increases it. For attractive potential or Feshbach resonance model, the many-body upper branch exhibits an energy maximum at k{sub F}a=α with α=1.34 from the Bethe–Goldstone ladder resummation, which is qualitatively consistent with experimental results. The many-body T-matrix has a positive-energy pole for k{sub F}a>α and it becomes impossible to distinguish the bound state and the scattering state. These positive-energy bound states become occupied and therefore the upper branch reaches an energy maximum at k{sub F}a=α. In the zero range limit, there exists a narrow window (0.86<k{sub F}a<1.56) for the ferromagnetic phase. At sufficiently large negative effective range, the ferromagnetic phase disappears. On the other hand, the appearance of positive-energy bound state resonantly enhances the two-body decay rate around k{sub F}a=α and may prevent the study of equilibrium phases and ferromagnetism of the upper branch Fermi gas. - Highlights: • Nonperturbative interaction energy is obtained within the Bethe–Goldstone ladder resummation approach. • Positive and negative effective ranges have opposite effects on the critical gas parameter. • The upper branch Fermi gas exhibits an energy maximum and reentrant ferromagnetic transition. • The ferromagnetic phase disappears for large and negative effective ranges.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Dynamics of water in prussian blue analogues: Neutron scattering study

Dynamics of crystal water in Prussian blue (PB), Fe(III){sub 4}[Fe(II)(CN){sub 6}]{sub 3}.14H{sub 2}O and its analogue Prussian green (PG), ferriferricynaide, Fe(III){sub 4}[Fe(III)(CN){sub 6}]{sub 4}.16H{sub 2}O have been investigated using Quasielastic Neutron Scattering (QENS) technique. PB and its analogue compounds are important materials for their various interesting multifunctional properties. It is known that crystal water plays a crucial role towards the multifunctional properties of Prussian blue analogue compounds. Three structurally distinguishable water molecules: (i) coordinated water molecules at empty nitrogen sites, (ii) non-coordinated water molecules in the spherical cavities, and (iii) at interstitial sites exist in PB. Here spherical cavities are created due to the vacant sites of Fe(CN){sub 6} units. However, PG does not have any such vacant N or Fe(CN){sub 6} units, and only one kind of water molecules, exists only at interstitial sites. QENS experiments have been carried out on both the compounds in the temperature range of 260–360 K to elucidate the dynamical behavior of different kinds of water molecules. Dynamics is found to be much more pronounced in case of PB, compared to PG. A detailed data analysis showed that localized translational diffusion model could describe the observed data for both PB and PG systems. The average diffusion coefficient is found to be much larger in the PB than PG. The obtained domain of dynamics is found to be consistent with the geometry of the structure of the two systems. Combining the data of the two systems, a quantitative estimate of the dynamics, corresponding to the water molecules at different locations is made.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Reconstructing WIMP properties through an interplay of signal measurements in direct detection, Fermi-LAT, and CTA searches for dark matter

We examine the projected ability to reconstruct the mass, scattering, and annihilation cross section of dark matter in the new generation of large underground detectors, XENON-1T, SuperCDMS, and DarkSide-G2, in combination with diffuse gamma radiation from expected 15 years of data from Fermi-LAT observation of 46 local spiral dwarf galaxies and projected CTA sensitivity to a signal from the Galactic Center. To this end we consider several benchmark points spanning a wide range of WIMP mass, different annihilation final states, and large enough event rates to warrant detection in one or more experiments. As previously shown, below some 100 GeV only direct detection experiments will in principle be able to reconstruct WIMP mass well. This may, in case a signal at Fermi-LAT is also detected, additionally help restricting σ v and the allowed decay branching rates. In the intermediate range between some 100 GeV and up a few hundred GeV, direct and indirect detection experiments can be used in complementarity to ameliorate the respective determinations, which in individual experiments can at best be rather poor, thus making the WIMP reconstruction in this mass range very challenging. At large WIMP mass, ∼ 1 TeV, CTA will have the ability to reconstruct mass, annihilation cross section, and the allowed decay branching rates to very good precision for the τ{sup +}τ{sup -} or purely leptonic final state, good for the W {sup +} W {sup -} case, and rather poor for b b-bar . A substantial improvement can potentially be achieved by reducing the systematic uncertainties, increasing exposure, or by an additional measurement at Fermi-LAT that would help reconstruct the annihilation cross section and the allowed branching fractions to different final states.

79 ASTRONOMY AND ASTROPHYSICS↗