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NASA NTRS1993

On the evaluation of air mass factors for atmospheric near-ultraviolet and visible absorption spectroscopy

The interpretation of UV-visible twilight absorption measurements of atmospheric chemical constituents is dependent on how well the optical path, or air mass factor, of light collected by the spectrometer is understood. A simple single scattering model and a Monte Carlo radiative transfer scheme have been developed to study the effects of multiple scattering, aerosol scattering, surface albedo and refraction on air mass factors for scattered light observations. At fairly short visible wavelengths (less than about 450 nm), stratospheric air mass factors are found to be relatively insensitive to multiple scattering, surface albedo and refraction, as well as aerosol scattering by background aerosols. Longer wavelengths display greater sensitivity to refraction and aerosol scattering. Tropospheric air mass factors are found to be highly dependent on aerosol scattering, surface albedo and, at long visible wavelengths (about 650 nm), refraction. Absorption measurements of NO2 and O4 are shown to support these conclusions.

Perliski, Lori M.↗
NASA NTRS1993

The Hubble Space Telescope quasar absorption line key project. I - First observational results, including Lyman-alpha and Lyman-limit systems

Spectra are presented for 37 quasars with small and moderate redshifts; the quasars were observed with the Faint Object Spectrograph of the HST. New higher resolution measurements of the absorption lines in the UV spectra of 11 quasars with emission-line redshifts that lie between 0.3 and 1.0 are reported. Calibrated spectra and continuum fits are shown for each object. A total of 104 extragalactic Ly-alpha systems are identified, nine of which are found at the same redshifts as metal-line systems. The local number density of Ly-alpha systems with rest equivalent widths larger than 0.32 A and without detected metal lines is about 15.1 +/- 4.3 Ly-alpha systems per unit redshift with gamma = 0.30 +/- 0.62 and W* = 0.22 +/- 0.02 A. A total of 10 Lyman-limit systems with an optical depth greater than 0.4 are identified. The paucity of damped Ly-alpha lines at small and moderate redshifts shows that the number density of damped absorption systems decreases with decreasing redshift.

Bahcall, John N.↗
NASA NTRS1993

Geometric model for nuclear absorption from microscopic theory

A parameter-free geometric model for nuclear absorption is derived from microscopic theory. The expression for the absorption cross section in the eikonal approximation taken in integral form is separated into a geometric contribution, described by an energy-dependent effective radius, and two surface terms which are shown to cancel in an asymptotic series expansion. For collisions of light nuclei, an expression for the effective radius is derived using harmonic-oscillator nuclear density functions. A direct extension to heavy nuclei with Woods-Saxon densities is made by identifying the equivalent half density radius for the harmonic-oscillator functions. Coulomb corrections are incorporated and a simplified geometric form of the Bradt-Peters type obtained. Results spanning the energy range of 1 MeV/nucleon to 1 GeV/nucleon are presented. Good agreement with experimental results are obtained.

John, S.↗
NASA NTRS1993

Ozone absorption cross section measurements in the Wulf bands

A tandem dual-beam spectrometer has been developed to determine ozone absorption cross sections for 13 selected wavelengths between 750 and 975 nm at room temperature. The increasingly pronounced structure in this region may interfere with atmospheric trace gas transitions that are useful for remote sensing and complicate the measurement of aerosols. Ozone concentrations were determined by absorption at the common HeNe laser transition near 632.8 nm using the absolute cross section reported previously. The overall accuracy of these room temperature measurements is generally better than 2 percent. A synoptic near-IR spectrum scaled to these measurements is employed for comparison with results of previous studies.

Anderson, Stuart M.↗
NASA NTRS1993

Coronal heating by the resonant absorption of Alfven waves - Importance of the global mode and scaling laws

Numerical simulations of the MHD equations for a fully compressible, low-beta, resistive plasma are used to study the resonance absorption process for the heating of coronal active region loops. Comparisons with more approximate analytic models show that the major predictions of the analytic theories are, to a large extent, confirmed by the numerical computations. The simulations demonstrate that the dissipation occurs primarily in a thin resonance layer. Some of the analytically predicted features verified by the simulations are (a) the position of the resonance layer within the initial inhomogeneity; (b) the importance of the global mode for a large range of loop densities; (c) the dependence of the resonance layer thickness and the steady-state heating rate on the dissipation coefficient; and (d) the time required for the resonance layer to form. In contrast with some previous analytic and simulation results, the time for the loop to reach a steady state is found to be the phase-mixing time rather than a dissipation time. This disagreement is shown to result from neglect of the existence of the global mode in some of the earlier analyses. The resonant absorption process is also shown to behave similar to a classical driven harmonic oscillator.

Steinolfson, Richard S.↗
NASA NTRS1993

Absorption heat pump for space applications

In the first part, the performance of the Absorption Heat Pump (AHP) with water-sulfuric acid and water-magnesium chloride as two new refrigerant-absorbent fluid pairs was investigated. A model was proposed for the analysis of the new working pairs in a heat pump system, subject to different temperature lifts. Computer codes were developed to calculate the Coefficient of Performance (COP) of the system with the thermodynamic properties of the working fluids obtained from the literature. The study shows the potential of water-sulfuric acid as a satisfactory replacement for water-lithium bromide in the targeted temperature range. The performance of the AHP using water-magnesium chloride as refrigerant-absorbent pair does not compare well with those obtained using water-lithium bromide. The second part concentrated on the design and testing of a simple ElectroHydrodynamic (EHD) Pump. A theoretical design model based on continuum electromechanics was analyzed to predict the performance characteristics of the EHD pump to circulate the fluid in the absorption heat pump. A numerical method of solving the governing equations was established to predict the velocity profile, pressure - flow rate relationship and efficiency of the pump. The predicted operational characteristics of the EHD pump is comparable to that of turbomachinery hardware; however, the overall efficiency of the electromagnetic pump is much lower. An experimental investigation to verify the numerical results was conducted. The pressure - flow rate performance characteristics and overall efficiency of the pump obtained experimentally agree well with the theoretical model.

Nguyen, Tuan↗
NASA NTRS1993

Applications of x ray absorption fine structure to the in situ study of the effect of cobalt in nickel hydrous oxide electrodes for fuel cells and rechargeable batteries

Electronic and structural aspects of composite nickel-cobalt hydrous oxides have been examined in alkaline solutions using in situ X-ray absorption fine structure (XAFS). The results obtained have indicated that cobalt in this material is present as cobaltic ions regardless of the oxidation state of nickel in the lattice. Furthermore, careful analysis of the Co K-edge Extended X-ray absorption fine structure data reveals that the co-electrodeposition procedure generates a single phase, mixed metal hydrous oxide, in which cobaltic ions occupy nickel sites in the NiO2 sheet-like layers and not two intermixed phases each consisting of a single metal hydrous oxide.

Kim, Sunghyun↗
NASA NTRS1994

HO2 detection by near infrared absorption using tunable diode lasers

The strongest absorption lines are in the v sub 2 vibrational band around 1400/cm; several near-coincident line pairs in this region provide max linestrengths of 1.2 x 10 exp -20 sq. cm/(molecule*cm). High Frequency wavelength modulation coupled with sweep integration were used to minimize noise and maintain spectral discrimination. Reduced pressure sampling was performed using supersonic nozzle and an aerodynamic flow cell to minimize residence time and wall losses of radicals. The astigmatic mirror design provides pathlengths up to 200 m in volume of 3 liters with minimal optical interference fringes; longer pathlengths are possible. The detection limit depends on pathlength and minimum fractional absorptions.

Nelson, David↗
NASA NTRS1994

Wavelength calibration techniques and subtle surface and atmospheric absorption features in the Mariner 6, 7 IRS reflectance data

1994 marks the 25th anniversary of the Mariner 6 and 7 flyby missions to Mars. Despite its age, the Mariner 6,7 Infrared Spectrometer (IRS) data are a unique set of measurements that can provide important information about the Martian surface, atmospheric, and atmospheric aerosol composition. For certain mid-IR wavelengths, the IRS spectra are the only such spacecraft data obtained for Mars. At other wavelengths, IRS measured surface regions different from those measured by Mariner 9 or Phobos 2 and under different dust opacity conditions. We are interested in examining the IRS reflectance data in the 1.8 to 3.0 micron region because there are numerous diagnostic absorption features at these wavelengths that could be indicative of hydrated silicate minerals or of carbonate- or sulfate-bearing minerals. Groundbased telescopic data and recent Phobos ISM measurements have provided controversial and somewhat contradictory evidence for the existence of mineralogic absorption features at these wavelengths. Our goal is to determine whether any such features can be seen in the IRS data and to use their presence or absence to re-assess the quality and interpretations of previous telescopic and spacecraft measurements.

Bell, James F., III↗
NASA NTRS1994

Landing gear energy absorption system

A landing pad system is described for absorbing horizontal and vertical impact forces upon engagement with a landing surface where circumferentially arranged landing struts respectively have a clevis which receives a slidable rod member and where the upper portion of a slidable rod member is coupled to the clevis by friction washers which are force fit onto the rod member to provide for controlled constant force energy absorption when the rod member moves relative to the clevis. The lower end of the friction rod is pivotally attached by a ball and socket to a support plate where the support plate is arranged to slide in a transverse direction relative to a housing which contains an energy absorption material for absorbing energy in a transverse direction.

Hansen, Christopher P.↗
NASA NTRS1993

Investigations on the 1.7 micron residual absorption feature in the vegetation reflection spectrum

The detection and interpretation of the weak absorption features associated with the biochemical components of vegetation is of great potential interest to a variety of applications ranging from classification to global change studies. This recent subject is also challenging because the spectral signature of the biochemicals is only detectable as a small distortion of the infrared spectrum which is mainly governed by water. Furthermore, the interpretation is complicated by complexity of the molecules (lignin, cellulose, starch, proteins) which contain a large number of different and common chemical bonds. In this paper, we present investigations on the absorption feature centered at 1.7 micron; these were conducted both on AVIRIS data and laboratory reflectance spectra of leaves.

Verdebout, J.↗
NASA NTRS1995

Determination of the in-flight spectral calibration of AVIRIS using atmospheric absorption features

Spectral calibration of the Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) as data are acquired in flight is essential to quantitative analysis of the measured upwelling spectral radiance. In each spectrum measured by AVIRIS in flight, there are numerous atmospheric gas absorption bands that drive this requirement for accurate spectral calibration. If the surface and atmospheric properties are measured independently, these atmospheric absorption bands may be used to deduce the in-flight spectral calibration of an imaging spectrometer. Both the surface and atmospheric characteristics were measured for a calibration target during an in-flight calibration experiment held at Lunar Lake, Nevada on April 5, 1994. This paper uses upwelling spectral radiance predicted for the calibration target with the MODTRAN radiative transfer code to validate the spectral calibration of AVIRIS in flight.

Green, Robert O.↗
NASA NTRS1994

Ultraviolet interstellar absorption lines in the LMC: Searching for hidden SNRs

Strong x-ray emission detected in Large Magellanic Cloud (LMC) superbubbles has been explained as the result of interior supernova remnants (SNRs) hitting the dense superbubble shell. Such SNRs cannot be found using conventional criteria. We thus investigate the possibility of using the interstellar absorption properties in the ultraviolet (UV) as a diagnostic of hidden SNR shocks. The International Ultraviolet Explorer (IUE) archives provide the database for this pilot study. They contain high-dispersion spectra of several stars in x-ray bright superbubbles. To distinguish the effects of SNR shocks from those of local stellar winds and a global hot halo around the LMC, we included control objects in different environments. We find that almost all interstellar absorption properties can be explained by the interstellar environment associated with the objects. Summarizing the two most important results of this study: (1) a large velocity shift between the high-ionization species (C IV and Si IV) and the low-ionization species (S II, Si II, and C II*) is a diagnostic of hidden SNR shocks; however, the absence of a velocity shift does not preclude the existence of SNR shocks; (2) there is no evidence that the LMC is uniformly surrounded by hot gas; hot gas is preferentially found associated with large interstellar structures like superbubbles and supergiant shells, which may extend to large distances from the plane.

Chu, You-Hua↗
NASA NTRS1994

An IUE survey of interstellar H I Ly alpha absorption. 2: Interpretations

We present an analysis of interstellar neutral hydrogen column densities obtained from archival Ly alpha absorption line data toward the complete sample of B2 and hotter stars observed at high spectral resolution with the IUE satellite. The full sample includes 554 stars and more than doubles the number of lines of sight previously observed. Many of the B2 and B1.5 stars exhibit contamination from stellar Ly alpha absorption, and were excluded from the subsequent analysis. The final working sample includes 393 stars. We present statistical averages for a number of quantities derived for the sample. The stars range in distance from 0.12 to 11 kpc with an average distance of 2.1 kpc. Values for average sight-line density range from 0.017 to 8.62 atoms cm(exp -3), with an overall average of 0.23 atoms cm(exp -3). Neutral hydrogen and dust are well correlated, with N(H I)/E(B - V) = 4.93 x 10(exp 21) cm(exp -2) mag(exp -1), and N(H I)/E(Bump) = 2.17 x 10(exp 21) cm(exp -2) mag(exp -1). There is an increase in the H I to dust ratios for the densest sight lines. Evidently, the H I to dust ratios in dense clouds are higher than in the lower density medium between the clouds and in interarm directions. The effect is probably an indication of dust modification in the dense clouds. The H I to dust ratios are approx. 17% smaller for the sight lines to O stars compared to the ratios found toward B stars. We have identified sight lines with anomalously large and small values of N(H I)/E(B - V) and H(H I)/E(Bump). Some of these sight lines are well-known examples of peculiar extinction (i.e., HD 147933 and HD 37061 (NU Ori)). Others are less well known and may provide important new examples of regions with highly modified dust. The number of stars with anomalously low H I to dust ratios is disproportionately larger than the number of stars with anomalously high H I to dust ratios. The distribution of the gas away form the Galactic plane for the sample of objects is complex. For the subset of 375 stars whose lines of sight have a statistically low probablility of intersecting a large cloud, the distribution may be roughly approximated by an exponential density distribution, with a midplane density of 0.366 atoms cm(exp -3), a scale height of 195 pc, and a random logarithmic scattering parameter sigma (sub p) of 0.159 dex. For the same sample of stars, interstellar dust is found to be confined closer to the plane than the H I, with (E(B - V)/r)(sub 0) = 0.257 mag kpc(exp -1), scale height h = 152 pc, and sigma(sub p) = 0.263 dex. The dust distribution is more inhomogeneous than the gas distribution. The observed distribution of H I away from the Galactic plane can also be fitted with a two-component exponential model including the effects of patchiness. Unfortunately, the foreground contamination produced by the cloudy and more confined component of H I makes it difficult to estimate the scale height of the extended component without invoking an independent estimate of its midplane density. Assuming n(sub 2)(0) = 0.16 cm(exp -3) from the Copernicus satellite H I/H(sub 2) survey, we obtain n(sub 1)(0) = 0.247 cm(exp -3), h(sub 1) = 73 PC, and h(sub 2) + 357 pc.

Diplas, Athanassios↗
NASA NTRS1994

Evidence for X-ray flux and spectral modulation by absorption in NGC 6814. 1: The nature of the most rapid variability

The Seyfert 1 galaxy NGC 6814 was observed using the Japanese X-ray astronomy satellite Ginga in 1990 April and October. The rapid variability characteristically associated with this source was reconfirmed. Specifically, three dips were found in the April observation in which the flux dropped to nearly zero in approximately 300 s. The doubling timescale was approximately 50 s. A similar but separated drop and rise in flux was observed in the October data, different in that the flux did not decrease completely to zero. A detailed analysis of the data around the structures of most rapid variability found spectral variability and lags in flux between different energy bands. Lags were on the order of a few to tens of seconds for the April data, and on the order of tens to a couple of hundred seconds for the October data. The sense of the lags was such that during flux decreases the hard flux lagged, while during flux increases the soft flux lagged. Associated significant apparent hardening of the spectrum at low flux was observed in the April data. Apparent hardening of the spectrum also occurred in the October flux decrease, to a photon index of GAMMA = 0.85; however, the spectrum softened at lowest flux to the index of the predecrease level, GAMMA = 1.54. In the April dips, the line flux was found to decrease significantly. A marginal decrease in line flux was also observed in the October data. The variability of the line flux reconfirmed the result of Kunieda et al. (1990), who found that the line production region must be within approximately 300 light-seconds from the source. To explain the observational results, a variable-absorption model was proposed, in which the column density was assumed to vary as a function of time. Other physical processes, including intrinsic spectral changes and warm absorber models, which could account for the fastest variability, could be ruled out by the results of the data analysis. A primary constraint found for geometrical models is that the material which is doing the absorption must have relatively low ionization (xi less than 100). This result leads to severe constraints on a general orbiting cloud model, requiring high densities (n approximately 10(exp 16)/cu cm) and sheetlike geometry.

Leighly, Karen↗
NASA NTRS1994

Mg II absorption in a sample of 56 steep-spectrum quasars

We present an analysis of the statistical properties of Mg II absorbers found in the spectra of 56 intrinsically faint, steep-spectrum radio quasars. We observe for the first time a significant excess of associated Mg II absorbers over the number expected from cosmologically distributed absorbers. This result is in contrast to previous Mg II surveys in which the QSOs were optically selected. This distinction is similar to the result for associated C IV absorbers, in which intrinsically faint, steep-spectrum quasars show excess associated absorption and intrinsically bright QSOs (both radio-loud and radio-quiet) do not show an excess. From our spectra a statistically complete list of absorption lines is derived, and we find 29 Mg II absorbers, 18 of which have not been previously reported. We also determine several characteristics of the quasar emission lines in our spectra. The Mg II absorber distribution as a function of redshift and equivalent width is calculated both for our sample alone and from our sample combined with spectra from other surveys. For the redshift distribution n(z) = n(1 + z)(exp gamma), we obtain, using the combined sample, the values gamma = 1.11 +/- 0.46 for W(min) = 0.6 A and gamma = 2.47 +/- 0.68 for W(min) = 1.0 A. We find that the distribution fo strong absorbers is inconsistent with no evolution at a confindence level between 2.2 and 2.9 sigma, depending on the deceleration parameter q(sub 0). The deviation from no evolution is similar to what had been previously reported.

Aldcroft, Thomas L.↗
NASA NTRS1994

An IUE survey of interstellar H I Ly alpha absorption. 1: Column densities

We measure Galactic interstellar neutral hydrogen column densities by analyzing archival interstellar Ly alpha absorption line data toward 554 B2 and hotter stars observed at high resolution with the IUE satellite. This study more than doubles the number of lines of sight with measures of N(H I) based on Ly alpha. We have included the scattered light background correction algorithm of Bianchi and Bohlin in our data reduction. We use the correlation between the Balmer discontinuity (c sub 1) index and the stellar Ly alpha absorption in order to assess the effects of stellar Ly alpha contamination. Approximately 40% of the B stars with measured (c sub 1) index, exhibit serious stellar Ly alpha contamination. One table contains the derived values of the interstellar N(H I) for 393 stars with at most small amounts of stellar contamination. Another lists the observed values of total N(H I) for 161 stars with suspected stellar Ly alpha contamination and/or uncertain stellar parameters.

Diplas, Athanassios↗
NASA NTRS1995

The soft gamma-ray spectrum of A0535+26: Detection of an absorption feature at 110 keV by OSSE

We present soft gamma-ray observations by the Oriented Scintillation Spectrometer Experiment (OSSE) on the Compton Gamma Ray Observatory (GRO) of the transient X-ray binary pulsar A0535+26. The observations were made 1994 February 8-17, immediately prior to the peak of a giant outburst. The phase averaged spectrum is complex and cannot be described by a single-component model. We find that structure in the spectrum above 100 keV can best be modeled by an absorption feature near 110 keV, which we interepret as the signature of cyclotron resonant scattering. Because of OSSE's 45 keV threshold, we are unable to make a definitive statement on the presence of a 55 keV absorption line; however, we can conclude that if this line does exist, it must have a smaller optical depth than the line at 110 keV. A first harmonic (=fundamental) cyclotron resonance at 110 keV corresponds to a magnetic field strength at the surface of the neutron star of approximately 1 x 10(exp 13) G (approximately 5 x 10(exp 12) G if the first harmonic is at 55 keV).

Grove, J. E.↗