Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “transient electronics”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,657 records · Page 92
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Reaction Discovery Using Spectroscopic Insights from an Enzymatic C–H Amination Intermediate

Engineered hemoproteins can selectively incorporate nitrogen from nitrene precursors like hydroxylamine, O-substituted hydroxylamines, and organic azides into organic molecules. Although iron-nitrenoids are often invoked as the reactive intermediates in these reactions, their innate reactivity and transient nature have made their characterization challenging. Here we characterize an iron-nitrosyl intermediate generated from NH 2 OH within a protoglobin active site that can undergo nitrogen-group transfer catalysis, using UV–vis, electron paramagnetic resonance (EPR) spectroscopy, and high-resolution electrospray ionization mass spectrometry (HR-ESI-MS) techniques. The mechanistic insights gained led to the discovery of aminating reagents—nitrite (NO 2 – ), nitric oxide (NO), and nitroxyl (HNO)—that are new to both nature and synthetic chemistry. Based on the findings, we propose a catalytic cycle for C–H amination inspired by the nitrite reductase pathway. Furthermore, this study highlights the potential of engineered hemoproteins to access natural nitrogen sources for sustainable chemical synthesis and offers a new perspective on the use of biological nitrogen cycle intermediates in biocatalysis.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2018

Photoinduced Heterocyclic Ring Opening of Furfural: Distinct Open-Chain Product Identification by Ultrafast X-ray Transient Absorption Spectroscopy

The ultraviolet-induced photochemistry of five-membered heterocyclic rings often involves ring opening as a prominent excited-state relaxation pathway. The identification of this particular photoinduced mechanism, however, presents a challenge for many experimental methods. We show that femtosecond X-ray transient absorption spectroscopy at the carbon K-edge (~284 eV) provides core-to-valence spectral fingerprints that enable the unambiguous identification of ring-opened isomers of organic heterocycles. The unique differences in the electronic structure between a carbon atom bonded to the oxygen in the ring versus a carbon atom set free of the oxygen in the ring-opened product are readily apparent in the X-ray spectra. Ultrafast ring opening via C-O bond fission occurs within ~350 fs in 266-nm photoexcited furfural, as evidenced by fingerprint core (carbon 1s) electronic transitions into a nonbonding orbital of the open-chain carbene intermediate at 283.3 eV. The lack of recovery of the 1sπ* ground-state depletion in furfural at 286.4 eV indicates that internal conversion to the ground state is a minor channel. These experimental results, augmented by recent advances in the generation of isolated attosecond pulses at the carbon K-edge, will pave the way for probing ring-opened conical intersection dynamics in the future.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2016

Attosecond science in atomic, molecular, and condensed matter physics

Attosecond science represents a new frontier in atomic, molecular, and condensed matter physics, enabling one to probe the exceedingly fast dynamics associated with purely electronic dynamics in a wide range of systems. This paper presents a brief discussion of the technology required to generate attosecond light pulses and gives representative examples of attosecond science carried out in several laboratories. Attosecond transient absorption, a very powerful method in attosecond science, is then reviewed and several examples of gas phase and condensed phase experiments that have been carried out in the Leone/Neumark laboratories are described.

Leone, Stephen R.↗
DOE OSTI2014

Ultrafast dynamics of the dielectric functions of ZnO and BaTiO{sub 3} thin films after intense femtosecond laser excitation

The ultrafast carrier dynamics of epitaxial ZnO and BaTiO{sub 3} thin films after intense excitation at 3.10 eV and 4.66 eV photon energy has been studied by femtosecond absorption spectroscopy. Modelling the transient transmission changes on the basis of spectroscopic ellipsometry data and pertinent equilibrium model dielectric functions extended by additional terms for the effects at high carrier density (P-band luminescence and stimulated emission from electron-hole-plasma), a self-consistent parameterized description was obtained for both materials. Excited carrier lifetimes in the range of ≈2 to ≈60 ps and long-lived thermal effects after several hundred ps have been identified in both materials. These findings form a reliable basis to quantitatively describe future femtosecond studies on ZnO/BaTiO{sub 3} heterolayer systems.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2019

Avoidance of impurity-induced current quench using lower hybrid current drive

This work reports observations of a tokamak plasma that experienced a thermal quench due to a large, transient high-Z influx but avoided a current quench. This is argued to be caused by the presence of lower hybrid range of frequency (LHRF) waves that sustain a non-thermal, current-carrying electron population. In Alcator C-Mod L-mode plasmas at I p = 450 kA, n¯ e = 0.5 x 10 20 m –3 , nearly all of the current can be sustained non-inductively by injecting ≃700 kW of LHRF power at 4.6 GHz and n ∥ = 1.9. A sudden influx of a large amount of tungsten, n z /n e ≃ 0.0044, triggers a cooling wave that propagates at 2–3 m s –1 all the way into the core, dropping on-axis T e from 3 keV to temperatures less than measurement floor of 50 eV. An off-axis reheat begins after 100 ms, but T e profiles remain hollow for 300–350 ms after the injection. Throughout this temperature evolution, the plasma density, current and shape remain unchanged to within 10%. Following the expulsion of the tungsten, the plasma returns to its baseline conditions and the plasma ends as planned with a controlled current ramp-down. Energy balance analysis shows the LHRF power continues to be absorbed in the plasma after the thermal quench, as a significant fraction of it is needed to be consistent with radiated power measurements. Examination of current relaxation time, τ R , and fast-electron slowing down time, τ s , indicate the LHRF must contribute to driving current, despite the low temperatures, as the current remains nominally stationary despite τ R < 5 ms and τ s < 50 ms for relativistic electrons. Furthermore, these measurements represent an important existence proof of a possible technique for avoidance of disruptions caused by sudden, unplanned influx of impurities in the form of dust or flakes of high-Z wall material. Implications and suggestions for future experimental and modeling and simulation work are summarized.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2022

State-selective probing of CO 2 autoionizing inner valence Rydberg states with attosecond extreme ultraviolet four-wave-mixing spectroscopy

Nonlinear spectroscopies can disentangle spectra that are congested due to inhomogeneous broadening. Here, in conjunction with theoretical calculations, attosecond extreme ultraviolet (XUV) four-wave-mixing (FWM) spectroscopy is utilized to probe the dynamics of autoionizing inner valence excited Rydberg states of the polyatomic molecule, CO 2 . This tabletop nonlinear technique employs a short attosecond XUV pulse train and two noncollinear, few-cycle near-infrared pulses to generate background-free XUV wave-mixing signals. FWM emission is observed from the n=5-7 states of the Henning sharp ndσ g Rydberg series that converges to the ionic $\widetilde{B}$ 2 Σ$^{+}_{u}$ state. However, these transient emission signals decay with lifetimes of 33 ± 6, 53 ± 2, and 94 ± 2 fs, respectively, which calculations show are consistent with the lifetimes of the short-lived n=6-8 members of the nsσ g character Henning diffuse Rydberg series. The oscillator strengths of transitions between states involved in all possible resonant FWM processes are calculated, verifying that the nonlinear spectra are dominated by pathways described by an initial excitation to the diffuse nsσ g Rydberg series and emission from the sharp ndσ g Rydberg series. The results substantiate not only that attosecond XUV FWM spectroscopy produces rigorous and meaningful measurements of ultrafast dynamics in polyatomic systems, but also that nonlinear spectroscopic techniques are versatile tools to selectively probe dynamics that are otherwise difficult to access.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Multistability of isolated and hydrogenated Ga–O divacancies in β–Ga 2 O 3

This work systematically explores 19 unique configurations of the close-associate Ga–O divacancies (V Ga V O ) in β–Ga 2 O 3 , including their complexes with H impurities, using hybrid functional calculations. Interestingly, most configurations are found to retain the negative-U behavior of V O , as they exhibit a thermodynamic (–/3–) charge-state transition level energetically located in the upper part of the band gap, where the 3– charge state is associated with the formation of a Ga–Ga dimer. The energy positions of the thermodynamic (–/3–) charge-state transition levels divide the divacancy configurations into three different groups, which can be understood from the three possible Ga–Ga dimerizations resulting from the tetrahedral and octahedral Ga sites. The relative formation energies of the different divacancy configurations, and hence the electrical activity of the divacancies, is found to depend on the Fermi-level position, and the energy barriers for transformation between different divacancy configurations are explored from nudged elastic band calculations. Hydrogenation of the divacancies is found to either passivate their negative-U charge-state transition levels or shift them down in Fermi level position, depending on whether the H resides at V O or forms an O–H bond at V Ga , respectively. Finally, the divacancy is discussed as a potential origin of the so-called E$^{*}_{2}$ center previously observed by deep-level transient spectroscopy.

36 MATERIALS SCIENCE↗
DOE OSTI2025

High-resolution X-ray structure of Gln143Asn manganese superoxide dismutase captures multiple hydrogen peroxide-binding sites

Human mitochondrial manganese superoxide dismutase (MnSOD) converts superoxide into hydrogen peroxide and molecular oxygen, serving as a key defence against oxidative damage. Despite extensive studies, the full structural characterization of H 2 O 2 -binding sites in MnSOD remains largely unexplored. Previous H 2 O 2 -soaked MnSOD structures have identified two distinct H 2 O 2 -binding sites: one directly ligated to the catalytic manganese (LIG position) and another at the active-site gateway (PEO position) between the second-shell residues Tyr34 and His30. In this study, a kinetically impaired Gln143Asn MnSOD variant is used to trap and explore additional H 2 O 2 -binding sites beyond the second-shell solvent gate. In the wild-type enzyme, Gln143 mediates proton transfers with the manganese-bound solvent (WAT1) to drive redox cycling of the metal, which is necessary for effective superoxide dismutation. Substitution with Asn stalls catalysis because the increased distance from WAT1 disrupts critical proton-coupled electron-transfer (PCET) events, and the redox cycling of the active-site metal is impaired. This, in turn, stalls the electrostatic cycling of positive charge on the enzyme surface and enhances the likelihood of trapping transient H 2 O 2 -bound states in this variant. The results reveal several H 2 O 2 molecules leading up to the active site, in addition to the canonical LIG and PEO positions.

Dasgupta, Medhanjali [University of Nebraska Medic↗
DOE OSTI2025

Electrodynamics of photo-carriers in multiferroic Eu 0.75 Y 0.25 MnO 3

Understanding and controlling the antiferromagnetic order in multiferroic materials on an ultrafast time scale is a long standing area of interest, due to their potential applications in spintronics and ultrafast magnetoelectric switching. We present an optical pump-terahertz (THz) probe study on multiferroic Eu 0.75 Y 0.25 MnO 3 . The optical pump predominantly excites the d-d transitions of the Mn 3+ ions, and the temporal evolution of the pump-induced transient conductivity is measured with a subsequent THz pulse. Two distinct, temperature-dependent decay times are revealed. The shorter relaxation time corresponds to spin-lattice thermalization, while the longer one is ascribed to electron-hole recombination. A spin-selection rule in the relaxation process is proposed in the magnetic phase. Slight suppression of the electromagnons was observed after the optical pump pulse within the spin-lattice thermalization time scale. These observed fundamental magnetic processes can shed light on ultrafast control of magnetism and photoinduced phase transitions in multiferroics.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
NASA NTRS1976

Gamma-ray astronomy: Nuclear transition region

This monograph reviews the major theoretical and experimental efforts made during the past 12 years in gamma-ray astronomy over the energy range from 10 keV to about 100 MeV, where nuclear-transition lines are expected. Early attempts to detect celestial gamma rays are recounted, mechanisms of gamma-ray line and continuum production are examined, and formulas giving the various possible differential gamma-ray spectral shapes are provided. Predicted fluxes are discussed for solar gamma rays as well as for gamma emission from supernova remnants, supernovae, neutron stars, flare stars, the galactic core and disk, black holes, and diffuse sources. Gamma-ray interactions with matter are analyzed, particularly the photoelectric effect, Compton scattering from free electrons, and pair production in nuclear fields. Significant results are summarized for observations of gamma rays from the sun as well as from point and extended sources within and beyond the Galaxy, including diffuse fluxes and transient gamma-ray bursts. Factors pertaining to the design of gamma-ray astronomy experiments are considered, especially detector background limitations, gamma-ray production within instruments, and present-day detection methods.

Chupp, E. L.↗
NASA NTRS1981

On the shape and orientation control of an orbiting shallow spherical shell structure

A proposed method for controlling the shape and orientation of very large shallow dish type receiver/reflectors to be used in communication, radiometry and in electronic orbital based mail systems involves connecting a rigid light weight dumbell with heavy tip masses to the shell at its apex by a spring loaded double gimballed joint with dampling. To completely damp the system transient motion in all of the important lower frequency modes, an active control system is required. A mathematical model is extended to include the effects of point actuators located at preselected positions on the shell surface. The formulation of the uncontrolled dynamics assumes an a priori knowledge of the frequencies of all the elastic modes to be incorporated within the system model. As an example, three rigid body modes and six elastic modes are included in the model and six actuators are assumed, none of which lies on a nodal line or circle.

Bainum, P. M.↗
NASA NTRS1984

A model for equatorial explosive spread F

Explosive spread F was first described by Woodman and LaHoz (1976). In such events the 50 MHz radar signal rises at Jicamarca to 10-20 dB above the noise level within a few milliseconds but then disappears within 100 ms or less. It has been suggested that electric fields from thunderstorms might drive a plasma instability which could cause these echoes, and recent observations (Woodman and Kudeki, 1984) provide convincing evidence for this triggering. Here, the instability mechanism is discussed and it is shown that transient thunderstorm electric fields comparable to those recently observed by rockets in the midlatitude ionosphere could excite a rapidly growing two-stream plasma instability that is driven by the ExB drift of the F region electrons in the short period (less than the ion gyroperiod) before the ions reach the same velocity.

Kelley, M. C.↗
NASA NTRS1987

Frequency domain laser velocimeter signal processor: A new signal processing scheme

A new scheme for processing signals from laser velocimeter systems is described. The technique utilizes the capabilities of advanced digital electronics to yield a smart instrument that is able to configure itself, based on the characteristics of the input signals, for optimum measurement accuracy. The signal processor is composed of a high-speed 2-bit transient recorder for signal capture and a combination of adaptive digital filters with energy and/or zero crossing detection signal processing. The system is designed to accept signals with frequencies up to 100 MHz with standard deviations up to 20 percent of the average signal frequency. Results from comparative simulation studies indicate measurement accuracies 2.5 times better than with a high-speed burst counter, from signals with as few as 150 photons per burst.

Meyers, James F.↗
NASA NTRS1991

Urodynamic pressure sensor

A transducer system was developed for measuring the closing pressure profile along the female urethra, which provides up to five sensors within the functional length of the urethra. This new development is an improvement over an earlier measurement method that has a smaller sensor area and was unable to respond to transient events. Three sensors were constructed; one of them was subjected to approximately eight hours of use in a clinical setting during which 576 data points were obtained. The complete instrument system, including the signal conditioning electronics, data acquisition unit, and the computer with its display and printer is described and illustrated.

Moore, Thomas↗
NASA NTRS1991

A study of ignition and simulation circuits for arcjet thrusters, part 1

A 1 kW electronic load was programmed to simulate the nonlinear i-v (volt-ampere) characteristics of an arcjet, both ignited and unignited. The simulator was tested and found to closely resemble an arcjet both for large transients and small perturbances up to about 40 kHz. No attempt was made to simulate the ignition process itself. The dynamic behavior of the arcjet (and the simulator) was shown to differ significantly from that of a resistor bank. Previous research led to the design and construction of a 1 kW arcjet power supply. A high voltage ignition circuit was added to this hardware, and tests on a 1 kW arcjet were performed at NASA-Lewis. All tests were successful and no ignition failures were observed. Circuit documentation and test results are included.

Stuart, Thomas A.↗
NASA NTRS1992

A model for nonlinear collisionless reconnection

The time dependence and scaling of the electric and magnetic field components during the nonlinear phase of reconnection of 'thin' unstable neutral layers (thickness approximately equals electron gyroradius) are investigated. Solutions to model equations show an initial interval of rapid growth and subsequent large-amplitude fluctuations of the trapped magnetic flux and the ion kinetic energy. The fluctuations arise from the transient formation, merging, and dissolution of magnetic islands.

Lovelace, R. V. E.↗
NASA NTRS2002

Discovery of Cyclotron Resonance Features in the Soft Gamma Repeater SGR 1806-20

We report evidence for cyclotron resonance features from the Soft Gamma Repeater SCR 1806-20 in outburst, detected with the Rossi X-ray Timing Explorer in the spectrum of a long, complex precursor that preceded a strong burst. The features consist of a narrow 5.0 keV absorption line with modulation near its second and third harmonics (at 11.2 keV and 17.5 keV respectively). The line features are transient and are detected in the harder part of the precursor. The 5.0 keV feature is strong, with an equivalent width of approx. 500 eV, and a narrow width of < 0.4 keV. Interpreting the features as electron cyclotron lines in the context of accretion models leads to a large mass-radius ratio (M/R > 0.3 Solar Mass/km) that is inconsistent with neutron stars, or requires a low (5 - 7) x 10(exp 11) G magnetic field that is unlikely for SGRs. The line widths are also narrow compared to those of electron cyclotron resonances observed so far in X-ray pulsars. In the magnetar picture, the features are plausibly explained as ion cyclotron resonances in an ultra-strong magnetic field, which have recently been predicted from magnetar candidates. In this view, the 5.0 keV feature is consistent with a proton cyclotron fundamental whose energy and width are close to model predictions. The line energy would correspond to a surface magnetic field of 1.0 x 10(exp 15) G for SGR 1806-20, in good agreement with that inferred from the spin-down measure in the source.

Ibrahim, A. I.↗
NASA NTRS2018

Behavior of Langmuir Probes in Non-Equilibrium Plasmas

Langmuir probes are diagnostic tools used to determine electron temperature, number density, and plasma potential. Irving Langmuir first used an electrostatic probe in the 1920s to find these characteristics in ionized gases. Single, double, and triple Langmuir probes are commonly used in plasma diagnostics because of their relative simplicity. In the single probe, a swept voltage is applied between the probe tip and circuit common to acquire a waveform showing the collected current as a function of applied voltage. A double Langmuir probe consists of two tips, both inserted into the plasma, with a voltage applied between them. As this voltage is swept, a current-voltage characteristic is measured. In a triple probe three probe tips are electrically coupled to each other with constant non-swept voltages applied between each of the tips. The voltages are selected to represent three points on the single Langmuir probe I-V curve. Elimination of the voltage sweep makes it possible to measure time-varying plasma properties in transient plasmas. Triple Langmuir probe measurements have been widely employed for various types of plasmas, including pulsed and time-varying plasmas such as those seen in pulsed plasma thrusters (PPTs), dense plasma focus devices, plasma flows, and fusion experiments. The typical Langmuir probe analysis for determining electron temperature and number density of the plasma (for a single, double, or triple Langmuir probe) includes an assumption that the plasma is in thermal equilibrium. While the this assumption may be justified for some applications, it is unlikely that it is fully justifiable for pulsed and time-varying plasmas or for the entire time a plasma device is in use. In the present work, we model the responses of Langmuir probes as they are inserted into a range of simple equilibrium and non-equilibrium plasmas. We return to basic governing equations of probe current collection and compute the current to the probes for a distribution function consisting of two Maxwellian distributions with different temperatures (the two-temperature Maxwellian). A variation of this method is also employed, where one of the Maxwellians is offset from zero (in velocity space) to add a suprathermal beam of electrons to the tail of the main Maxwellian distribution (the bump-on-the-tail distribution function). For a range of parameters in these non-Maxwellian distributions, we compute the current collection to the probes. Comparing the distribution function that was assumed a priori with the plasma density and temperature one would infer when applying standard probe theory to analyze the collected currents serves to illustrate the effect a non- Maxwellian plasma would have on results interpreted using the equilibrium probe current collection theory, allowing us to state the magnitudes of these deviations as a function of the assumed distribution function properties.

Polzin, Kurt A.↗