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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,657 records · Page 92
All sourcesNASA NTRSDOE OSTI
DOE OSTI2017

Bidirectional low temperature district energy systems with agent-based control: Performance comparison and operation optimization

Bidirectional low temperature networks are a novel concept that promises more efficient heating and cooling of buildings. Early research shows theoretical benefits in terms of exergy efficiency over other technologies. Pilot projects indicate that the concept delivers good performance if heating and cooling demands are diverse. However, the operation of these networks is not yet optimized and there is no quantification of the benefits over other technologies in various scenarios. Moreover, there is a lack of understanding of how to integrate and control multiple distributed heat and cold sources in such networks. Thus, this paper develops a control concept based on a temperature set point optimization and agent-based control which allows the modular integration of an arbitrary number of sources and consumers. Afterwards, the concept is applied to two scenarios representing neighborhoods in San Francisco and Cologne with different heating and cooling demands and boundary conditions. The performance of the system is then compared to other state-of-the-art heating and cooling solutions using dynamic simulations with Modelica. The results show that bidirectional low temperature networks without optimization produce 26% less emissions in the San Francisco scenario and 63% in the Cologne scenario in comparison to the other heating and cooling solutions. Savings of energy costs are 46% and 27%, and reductions of primary energy consumption 52% and 72%, respectively. The presented operation optimization leads to electricity use reductions of 13% and 41% when compared to networks with free-floating temperature control and the results indicate further potential for improvement. The study demonstrates the advantage of low temperature networks in different situations and introduces a control concept that is extendable for real implementation.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2017

Global land carbon sink response to temperature and precipitation varies with ENSO phase

Climate variability associated with the El Niño-Southern Oscillation (ENSO) and its consequent impacts on land carbon sink interannual variability have been used as a basis for investigating carbon cycle responses to climate variability more broadly, and to inform the sensitivity of the tropical carbon budget to climate change. Past studies have presented opposing views about whether temperature or precipitation is the primary factor driving the response of the land carbon sink to ENSO. We show that the dominant driver varies with ENSO phase. And whereas tropical temperature explains sink dynamics following El Niño conditions (r TG,P = 0.59, p < 0.01), the post La Niña sink is driven largely by tropical precipitation (r PG,T= -0.46, p = 0.04). This finding points to an ENSO-phase-dependent interplay between water availability and temperature in controlling the carbon uptake response to climate variations in tropical ecosystems. Furthermore, we find that none of a suite of ten contemporary terrestrial biosphere models captures these ENSO-phase-dependent responses, highlighting a key uncertainty in modeling climate impacts on the future of the global land carbon sink.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1977

Liquid rocket engine self-cooled combustion chambers

Self-cooled combustion chambers are chambers in which the chamber wall temperature is controlled by methods other than fluid flow within the chamber wall supplied from an external source. In such chambers, adiabatic wall temperature may be controlled by use of upstream fluid components such as the injector or a film-coolant ring, or by internal flow of self-contained materials; e.g. pyrolysis gas flow in charring ablators, and the flow of infiltrated liquid metals in porous matrices. Five types of self-cooled chambers are considered in this monograph. The name identifying the chamber is indicative of the method (mechanism) by which the chamber is cooled, as follows: ablative; radiation cooled; internally regenerative (Interegen); heat sink; adiabatic wall. Except for the Interegen and heat sink concepts, each chamber type is discussed separately. A separate and final section of the monograph deals with heat transfer to the chamber wall and treats Stanton number evaluation, film cooling, and film-coolant injection techniques, since these subjects are common to all chamber types. Techniques for analysis of gas film cooling and liquid film cooling are presented.

Source record↗
DOE OSTI2015

Oxide scale formation on 316L and FeCrAl steels exposed to oxygen controlled static LBE at temperatures up to 800 °C

The corrosion behavior of three stainless steels (316L, Alkrothal 720 and Kanthal-APM) in static LBE with oxygen concentration of 10 –5 wt% at temperatures of 700 °C for 230 h and 800 °C for 360 h was studied. The steel surface morphology of the oxide scales formed was investigated by SEM, XRD and Raman spectroscopy and the cross-section by SEM and EDX. Here, a transitional inner-layer of Fe–Cr–Al oxides was found at the substrate interface and an Al-oxide outer layer on the Fe–Cr–Al alloys. Fast growing nonprotective oxide scale with underlying dissolution was observed on the 316L alloy

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
NASA NTRS2014

CFD Analysis of Thermal Control System Using NX Thermal and Flow

The Thermal Control Subsystem (TCS) is a key part of the Advanced Plant Habitat (APH) for the International Space Station (ISS). The purpose of this subsystem is to provide thermal control, mainly cooling, to the other APH subsystems. One of these subsystems, the Environmental Control Subsystem (ECS), controls the temperature and humidity of the growth chamber (GC) air to optimize the growth of plants in the habitat. The TCS provides thermal control to the ECS with three cold plates, which use Thermoelectric Coolers (TECs) to heat or cool water as needed to control the air temperature in the ECS system. In order to optimize the TCS design, pressure drop and heat transfer analyses were needed. The analysis for this system was performed in Siemens NX Thermal/Flow software (Version 8.5). NX Thermal/Flow has the ability to perform 1D or 3D flow solutions. The 1D flow solver can be used to represent simple geometries, such as pipes and tubes. The 1D flow method also has the ability to simulate either fluid only or fluid and wall regions. The 3D flow solver is similar to other Computational Fluid Dynamic (CFD) software. TCS performance was analyzed using both the 1D and 3D solvers. Each method produced different results, which will be evaluated and discussed.

CFD↗
DOE OSTI2020

An Open-Cell Environmental Transmission Electron Microscopy Technique for In Situ Characterization of Samples in Aqueous Liquid Solutions

The desire to image specimens in liquids has led to the development of open-cell and closed-cell techniques in transmission electron microscopy (TEM). The closed-cell approach is currently more common in TEM and has yielded new insights into a number of biological and materials processes in liquid environments. The open-cell approach, which requires an environmental TEM (ETEM), is technically challenging but may be advantageous in certain circumstances due to fewer restrictions on specimen and detector geometry. Here, we demonstrate a novel approach to open-cell liquid TEM, in which we use salt particles to facilitate the in situ formation of droplets of aqueous solution that envelope specimen particles coloaded with the salt. This is achieved by controlling sample temperature between 1 and 10°C and introducing water vapor to the ETEM chamber above the critical pressure for the formation of liquid water on the salt particles. Our use of in situ hydration enables specimens to be loaded into a microscope in a dry state using standard 3 mm TEM grids, allowing specimens to be prepared using trivial sample preparation techniques. Furthermore, our future aim will be to combine this technique with an in situ light source to study photocorrosion in aqueous environments.

47 OTHER INSTRUMENTATION↗
DOE OSTI2026

Hidden Spin-Valley Locking Stabilizes Nanosecond Spin Polarization in 2D Perovskites

Room-temperature spin control in semiconductors is fundamental to spin-optoelectronics. Although inversion symmetry breaking offers one path for spin control in semiconductors, strong spin dephasing at elevated temperatures remains a persistent limitation. Hidden spin polarization without global symmetry breaking provides another promising material design strategy, but robust spin stabilization from this effect has yet to be experimentally realized. Here we show spin stabilization at room temperature in two-dimensional hybrid organic-inorganic perovskites through hidden spin-valley locking. We use functional non-primary ammonium cations to induce symmetry-breaking distortions in the metal-halide layers, producing giant local spin splitting while preserving global inversion symmetry. Time-resolved circular dichroism measurements reveal optically generated spin-polarized carriers that persist for 686 ps in (AzOH)2PbI4 and 4.7 ns in the lead-free analogue (AzOH)2SnI4 at room temperature, without an external magnetic field. First-principles calculations suggest that these long lifetimes arise from hidden spin valleys, enhanced dielectric screening and reduced spin-orbit-induced scattering in the Sn-based compound. Our design paradigm unlocks inversion-symmetric semiconductors with ultralong spin lifetimes, broadening the materials options for light-driven spin control.

14 SOLAR ENERGY↗
NASA NTRS2018

Evaluating the Calibration of Aqua MODIS Bands 33, 35, and 36 During Blackbody Warm-Up Cool-Down Events

Aqua MODIS is the second MODIS instrument of NASA's Earth Observation System and has operated for over sixteen years since its launch in 2002. MODIS has sixteen thermal emissive bands (TEBs) located on two separate cold focal plane assemblies (CFPA). The TEBs are calibrated every scan using observations of an onboard blackbody (BB) and a space view port. Low saturation temperatures (Tsat) of Aqua MODIS bands 33, 35, and 36 cause these bands to saturate when the BB temperature is higher than their Tsat values during a BB warm-up cool-down (WUCD) cycle, therefore impacting the ability to perform nominal calibration. In addition, starting from around 2006, the CFPA temperature showed gradual variation from its nominally-controlled operating temperature due to a loss of its radiative cooler margin and the magnitude of its fluctuation reaching a maximum in 2013. The MODIS Characterization Support Team currently uses a correction that is dependent on the CFPA temperature to provide a gain estimate for the saturated scans during the BB WUCD. This gain estimation has been implemented in the Aqua MODIS Collection 6 (C6) and C6.1 L1B products. This paper evaluates the quality of the calibrated radiance of Aqua MODIS bands 33, 35, and 36 using simultaneous nadir observations from the Atmospheric Infrared Sounder (AIRS), which is also onboard the Aqua satellite. Our analysis results show that the differences between AIRS and Aqua MODIS can be controlled well within the fluctuation range compared to the periods when the BB signals for these bands are not saturated.

Li, Yonghong↗
DOE OSTI2017

Compact low power infrared tube furnace for in situ X-ray powder diffraction.

We describe the development and implementation of a compact, low power, infrared heated tube furnace for in situ powder X-ray diffraction experiments. Our silicon carbide (SiC) based furnace design exhibits outstanding thermal performance in terms of accuracy control and temperature ramping rates while simultaneously being easy to use, robust to abuse and, due to its small size and low power, producing minimal impact on surrounding equipment. Temperatures in air in excess of 1100 °C can be controlled at an accuracy of better than 1%, with temperature ramping rates up to 100 °C/s. The complete "add-in" device, minus power supply, fits in a cylindrical volume approximately 15 cm long and 6 cm in diameter and resides as close as 1 cm from other sensitive components of our experimental synchrotron endstation without adverse effects.

47 OTHER INSTRUMENTATION↗
DOE OSTI2020

Toward the Prediction and Control of Glass Transition Temperature for Donor–Acceptor Polymers

Semiconducting donor–acceptor (D–A) polymers have attracted considerable attention toward the application of organic electronic and optoelectronic devices. However, a rational design rule for making semiconducting polymers with desired thermal and mechanical properties is currently lacking, which greatly limits the development of new polymers for advanced applications. Here, polydiketopyrrolopyrrole (PDPP)-based D–A polymers with varied alkyl side-chain lengths and backbone moieties are systematically designed, followed by investigating their thermal and thin film mechanical responses. The experimental results show a reduction in both elastic modulus and glass transition temperature (Tg) with increasing side-chain length, which is further verified through coarse-grained molecular dynamics simulations. Informed from experimental results, a mass-per-flexible bond model is developed to capture such observation through a linear correlation between Tg and polymer chain flexibility. Using this model, a wide range of backbone Tg over 80 °C and elastic modulus over 400 MPa can be predicted for PDPP-based polymers. This study highlights the important role of side-chain structure in influencing the thermomechanical performance of conjugated polymers, and provides an effective strategy to design and predict Tg and elastic modulus of future new D–A polymers.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Control of High-Temperature Static and Transient Thermomechanical Behavior of SiMo Ductile Iron by Al Alloying

Abstract Silicon and molybdenum ( SiMo ) ductile iron is commonly used for exhaust manifolds because these components experience thermal cycling in oxidizing environment, which requires resistance to fatigue during transient thermomechanical loads. Previous studies have demonstrated that alloying elements, such as Al , to SiMo ductile iron reduces the amount of surface degradation during static high-temperature exposure. However, deterioration of sphericity of the graphite nodules and a decrease in ductility could affect the tendency of cracking during thermal cycling. In this article, the effect of Al alloying on static and transient thermomechanical behavior of SiMo ductile iron was investigated to optimize the amount of Al alloying. A thermodynamic approach was used to confirm the effect of the Al alloying on the phase transformations in two SiMo cast irons, alloyed by 1.8% Al and 3% Al . These two alloys were cast in a laboratory along with the baseline SiMo ductile iron. Several experimental methods were used to evaluate the dimensional stability, physical properties, static oxidation, and failure resistance during constrained thermal cycling testing to compare their high-temperature capability. Experimental results verified that Al alloying increases the temperature range and decreases volume change during eutectoid transformation, which together with enhancement of oxidation protection improved the dimensional stability. Thermocycling tests showed that the number of cycles to failure depends on the amount of Al alloying and the applied high-temperature exposure during each cycle. SEM/EDX, high-resolution TEM and µCT analysis were used to verify the mechanism resulting from the Al alloying protection. It was shown that an optimal level of Al alloying for balancing oxidation and thermal cracking resistance depends on thermomechanical conditions of application.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Row spacing as a controller of solar module temperature and power output in solar farms

We report that when the temperature of solar photovoltaic modules rises, efficiency drops and module degradation accelerates. The spatial arrangement of solar modules can affect convective cooling and, consequently, module temperatures. However, the impact of row spacing on convective cooling in realistic solar farms has not yet been studied. Here, we develop six solar farm arrangements consisting of a fixed number of rows with varying streamwise row spacing. We model the flow and heat transfer of each solar farm using high-resolution large-eddy simulations. Results indicate that increasing row spacing can enhance convective cooling by 14.8%, which reduces module temperature by 6.6 °C and increases power output by 4.0% on average.

14 SOLAR ENERGY↗
DOE OSTI2022

Demand Driven Energy Management for PIPO Auxiliary Power Supply Architecture

In this paper, a demand driven energy management (DDEM) technique is implemented on modular parallel input parallel output DC/DC auxiliary power supply (APS) structure. In this method, modules are brought in/out of the operation making them operate under high loading conditions, avoiding low efficiency under light load. Such a method finds its application in power conservative systems with variable load. Implementation of DDEM and the energy saved is shown using APS comprised of two 15W commercially off-the-shelf DC-DC modules, with 100–1000 VDC input and 24 V output voltage. Along with the DDEM, the lifetime of the power stage devices is controlled minimizing their junction temperature swing through control of cooling system. This control method uses digital twin as interface to virtualize the power devices loading operation/ health condition. Accordingly, no extra sensor or closed loop control required to measure the junction temperature of the devices or feedback the losses to the cooling flow.

Azadeh, Yalda↗
DOE OSTI2023

Impact of Irradiation-Induced Filter Heating on Calibration of NIR-Longpass-Filtered Reference Solar Cells

Reference solar cells play a crucial role in determining the performance of photovoltaic (PV) devices. In the performance calibration chain of mainstream single-junction PV technologies, common reference cell types include Si, KG-filtered Si, and GaAs cells. For emerging multijunction (MJ) PV technologies, such as CdTe/Si and perovskite/Si, Si reference cells with colored glass near-infrared-longpass (LP) filters like Schott RG-715 and 850 glass have been proposed. They offer a better spectral response that matches the bottom junctions of the emerging MJs, which could lead to lower uncertainties in performance measurements. However, this article reveals a prominent decrease in short-circuit current (ISC) during National Renewable Energy Laboratory's primary calibration over the course of minutes when using this type of LP-filtered reference cell, which could result in unacceptable measurement errors. Unlike quartz or KG filter glasses, LP colored glass filters demonstrate temperature-sensitive cut-on wavelength. When incident irradiance reaches these LP-filtered reference cells, the increased temperature due to light absorption causes a shift of the cut-on to longer wavelength. As a result, the device I SC exhibits a continuous decrease (approximately a 2.5% drop with RG850 LP filter in a 5-min duration) even when the device temperature is controlled at 25 degrees C. To address the temperature gradient issue between colored glass LP filter and the reference cell, we propose the direct integration of thin-film LP semiconductor layer on reference cells. This type of LP-filter-integrated cell has shown minimal temperature-related I SC variation and can serve as a more reliable reference cell source for accurate performance measurements.

14 SOLAR ENERGY↗