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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,657 records · Page 92
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

The influence of recent and future climate change on spring Arctic cyclones

In recent decades, the Arctic has experienced rapid atmospheric warming and sea ice loss, with an ice-free Arctic projected by the end of this century. Cyclones are synoptic weather events that transport heat and moisture into the Arctic, and have complex impacts on sea ice, and the local and global climate. However, the effect of a changing climate on Arctic cyclone behavior remains poorly understood. This study uses high resolution (4 km), regional modeling techniques and downscaled global climate reconstructions and projections to examine how recent and future climatic changes alter cyclone behavior. Results suggest that recent climate change has not yet had an appreciable effect on Arctic cyclone characteristics. However, future sea ice loss and increasing surface temperatures drive large increases in the near-surface temperature gradient, sensible and latent heat fluxes, and convection during cyclones. The future climate can alter cyclone trajectories and increase and prolong intensity with greatly augmented wind speeds, temperatures, and precipitation. Such changes in cyclone characteristics could exacerbate sea ice loss and Arctic warming through positive feedbacks. The increasing extreme nature of these weather events has implications for local ecosystems, communities, and socio-economic activities.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

Structural studies of the IFNλ4 receptor complex using cryoEM enabled by protein engineering

Abstract IFNλ4 has posed a conundrum in human immunology since its discovery in 2013, with its expression linked to complications with viral clearance. While genetic and cellular studies revealed the detrimental effects of IFNλ4 expression, extensive structural and functional characterization has been limited by the inability to express and purify the protein, complicating explanations of its paradoxical behavior. In this work, we report a method for robust production of IFNλ4. We then use yeast surface display to affinity-mature IL10Rβ and solve the 72 kilodalton structures of IFNλ4 (3.26 Å) and IFNλ3 (3.00 Å) in complex with their receptors IFNλR1 and IL10Rβ using cryogenic electron microscopy. Comparison of the structures highlights differences in receptor engagement and reveals a distinct 12-degree rotation in overall receptor geometry, providing a potential mechanistic explanation for differences in cell signaling, downstream gene induction, and antiviral activities. Further, we perform a structural analysis using molecular modeling and simulation to identify a unique region of IFNλ4 that, when replaced, enables secretion of the protein from cells. These findings provide a structural and functional understanding of the IFNλ4 protein and enable future comprehensive studies towards correcting IFNλ4 dysfunction in large populations of affected patients.

Science & Technology - Other Topics↗
DOE OSTI2020

Spontaneous and reversible hollowing of alloy anode nanocrystals for stable battery cycling

High-capacity alloy anode materials for Li-ion batteries have long been held back by limited cyclability caused by the large volume changes during lithium insertion and removal. Hollow and yolk-shell nanostructures have been used to increase the cycling stability by providing an inner void space to accommodate volume changes and a mechanically and dimensionally stable outer surface. These materials, however, require complex synthesis procedures. Here, using in situ transmission electron microscopy, we show that sufficiently small antimony nanocrystals spontaneously form uniform voids on the removal of lithium, which are then reversibly filled and vacated during cycling. This behaviour is found to arise from a resilient native oxide layer that allows for an initial expansion during lithiation but mechanically prevents shrinkage as antimony forms voids during delithiation. In this work, we developed a chemomechanical model that explains these observations, and we demonstrate that this behaviour is size dependent. Thus, antimony naturally evolves to form optimal nanostructures for alloy anodes, as we show through electrochemical experiments in a half-cell configuration in which 15-nm antimony nanocrystals have a consistently higher Coulombic efficiency than larger nanoparticles.

25 ENERGY STORAGE↗
DOE OSTI2022

Projected U.S. drought extremes through the twenty-first century with vapor pressure deficit

Global warming is expected to enhance drought extremes in the United States throughout the twenty-first century. Projecting these changes can be complex in regions with large variability in atmospheric and soil moisture on small spatial scales. Vapor Pressure Deficit (VPD) is a valuable measure of evaporative demand as moisture moves from the surface into the atmosphere and a dynamic measure of drought. Here, VPD is used to identify short-term drought with the Standardized VPD Drought Index (SVDI); and used to characterize future extreme droughts using grid dependent stationary and non-stationary generalized extreme value (GEV) models, and a random sampling technique is developed to quantify multimodel uncertainties. The GEV analysis was performed with projections using the Weather Research and Forecasting model, downscaled from three Global Climate Models based on the Representative Concentration Pathway 8.5 for present, mid-century and late-century. Results show the VPD based index (SVDI) accurately identifies the timing and magnitude short-term droughts, and extreme VPD is increasing across the United States and by the end of the twenty-first century. The number of days VPD is above 9 kPa increases by 10 days along California’s coastline, 30–40 days in the northwest and Midwest, and 100 days in California’s Central Valley.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1978

Analytical study of STOL Aircraft in ground effect. Part 1: Nonplanar, nonlinear wing/jet lifting surface method

A nonlinear, nonplanar three dimensional jet flap analysis, applicable to the ground effect problem, is presented. Lifting surface methodology is developed for a wing with arbitrary planform operating in an inviscid and incompressible fluid. The classical, infintely thin jet flap model is employed to simulate power induced effects. An iterative solution procedure is applied within the analysis to successively approximate the jet shape until a converged solution is obtained which closely satisfies jet and wing boundary conditions. Solution characteristics of the method are discussed and example results are presented for unpowered, basic powered and complex powered configurations. Comparisons between predictions of the present method and experimental measurements indicate that the improvement of the jet with the ground plane is important in the analyses of powered lift systems operating in ground proximity. Further development of the method is suggested in the areas of improved solution convergence, more realistic modeling of jet impingement and calculation efficiency enhancements.

Shollenberger, C. A.↗
NASA NTRS1984

Bidirectional Reflectance Modeling of Non-homogeneous Plant Canopies

Efforts to develop a three dimensional model to predict canopy, bidirectional reflectance for heterogenous plant stands using incident radiation and canopy structural descriptions as inputs are described. Utility programs were developed to cope with the complex output from the 3 dimensional model. In addition an attempt was made to define leaf and soil properties, which are appropriate to the mode, by measuring leaf and soil bidirectional reflectance distribution functions; since almost no data exist on these distributions. In the process it was realized that most models probably are using the wrong leaf spectral properties, and that off-nadir reflectance measurements are difficult to make because of non-Lambertian properties of reference surfaces. Also, in the visible wavebands, rough soil may not be distinguishable from canopies when viewed from above.

Norman, J. M.↗
NASA NTRS1986

Steady and unsteady transonic pressure measurements on a clipped delta wing for pitching and control-surface oscillations

Steady and unsteady pressures were measured on a clipped delta wing with a 6-percent circular-arc airfoil section and a leading-edge sweep angle of 50.40 deg. The model was oscillated in pitch and had an oscillating trailing-edge control surface. Measurements were concentrated over a Mach number range from 0.88 to 0.94; less extensive measurements were made at Mach numbers of 0.40, 0.96, and 1.12. The Reynolds number based on mean chord was approximately 10 x 10 to the 6th power. The interaction of wing or control-surface deflection with the formation of shock waves and with a leading-edge vortex generated complex pressure distributions that were sensitive to frequency and to small changes in Mach number at transonic speeds.

Hess, Robert W.↗
NASA NTRS1991

3-D CFD in a day - The laser digitizer project

The computation of airflow over complex configurations requires a complete description of the geometry. This can be obtained from CAD data, from blueprints, or from actual models. In any case, the time required is currently estimated at 4 to 6 months. It is proposed to shorten this time by a factor of 10 to 100 through the use of automated software, a fast, highly parallel computer and a three-dimensional laser digitizer. This device can provide (x,y,z) coordinates of surface points at rates exceeding 14,500/sec. Thus, it is possible to digitize an entire model in a few minutes. The accuracy of measurement on a flat white surface is better than 0.005 inches. Higher accuracy is available at higher cost. This work discusses the challenges which remain to be addressed. In particular, the surface point data need to be converted into a surface description, the surface description needs to be made into a surface grid, and the surface grid used to make a volume grid for the flow solver. Algorithms are kept in place or in mind for all of these problems. Integration of the more mature flow solution and visualization algorithms then allows generation of solution graphics directly from a wind tunnel model.

Merriam, Marshal↗
NASA NTRS2001

Spectroscopic diagnostics of organic chemistry in the protostellar environment

A combination of astronomical observations, laboratory studies, and theoretical modelling is necessary to determine the organic chemistry of dense molecular clouds. We present spectroscopic evidence for the composition and evolution of organic molecules in protostellar environments. The principal reaction pathways to complex molecule formation by catalysis on dust grains and by reactions in the interstellar gas are described. Protostellar cores, where warming of dust has induced evaporation of icy grain mantles, are excellent sites in which to study the interaction between gas phase and grain-surface chemistries. We investigate the link between organics that are observed as direct products of grain surface reactions and those which are formed by secondary gas phase reactions of evaporated surface products. Theory predicts observable correlations between specific interstellar molecules, and also which new organics are viable for detection. We discuss recent infrared observations obtained with the Infrared Space Observatory, laboratory studies of organic molecules, theories of molecule formation, and summarise recent radioastronomical searches for various complex molecules such as ethers, azaheterocyclic compounds, and amino acids.

Ethers/analysis/chemical synthesis/chemistry↗
NASA NTRS2009

The International Space Station and the Space Debris Environment: 10 Years On

For just over a decade the International Space Station (ISS), the most heavily protected vehicle in Earth orbit, has weathered the space debris environment well. Numerous hypervelocity impact features on the surface of ISS caused by small orbital debris and meteoroids have been observed. In addition to typical impacts seen on the large solar arrays, craters have been discovered on windows, hand rails, thermal blankets, radiators, and even a visiting logistics module. None of these impacts have resulted in any degradation of the operation or mission of the ISS. Validating the rate of small particle impacts on the ISS as predicted by space debris environment models is extremely complex. First, the ISS has been an evolving structure, from its original 20 metric tons to nearly 300 metric tons (excluding logistics vehicles) ten years later. Hence, the anticipated space debris impact rate has grown with the increasing size of ISS. Secondly, a comprehensive visual or photographic examination of the complete exterior of ISS has never been accomplished. In fact, most impact features have been discovered serendipitously. Further complications include the estimation of the size of an impacting particle without knowing its mass, velocity, and angle of impact and the effect of shadowing by some ISS components. Inadvertently and deliberately, the ISS has also been the source of space debris. The U.S. Space Surveillance Network officially cataloged 65 debris from ISS from November 1998 to November 2008: from lost cameras, sockets, and tool bags to intentionally discarded equipment and an old space suit. Fortunately, the majority of these objects fall back to Earth quickly with an average orbital lifetime of less than two months and a maximum orbital lifetime of a little more than 15 months. The cumulative total number of debris object-years is almost exactly 10, the equivalent of one piece of debris remaining in orbit for 10 years. An unknown number of debris too small to be tracked and cataloged have also been generated, but normally with even shorter orbital lifetimes. Finally, eight collision avoidance maneuvers have been performed to avoid potential collisions between ISS and large, tracked space debris. The most recent such maneuver was accomplished by ESA's Automated Transfer Vehicle, the Jules Verne, just three months before the 10th anniversary of the launch of ISS's first element.

Johnson, Nicholas↗
NASA NTRS2012

Remote Sensing and Modeling of Landslides: Detection, Monitoring and Risk Evaluation

Landslides are one of the most pervasive hazards in the world, resulting in more fatalities and economic damage than is generally recognized_ Occurring over an extensive range of lithologies, morphologies, hydrologies, and climates, mass movements can be triggered by intense or prolonged rainfall, seismicity, freeze/thaw processes, and antbropogertic activities, among other factors. The location, size, and timing of these processes are characteristically difficult to predict and assess because of their localized spatial scales, distribution, and complex interactions between rainfall infiltration, hydromechanical properties of the soil, and the underlying surface composition. However, the increased availability, accessibility, and resolution of remote sensing data offer a new opportunity to explore issues of landslide susceptibility, hazard, and risk over a variety of spatial scales. This special issue presents a series of papers that investigate the sources, behavior, and impacts of different mass movement types using a diverse set of data sources and evaluation methodologies.

Kirschbaum, Dalia↗
NASA NTRS2022

The Influence of Recent and Future Climate Change on Spring Arctic Cyclones

In recent decades, the Arctic has experienced rapid atmospheric warming and sea ice loss, with an ice-free Arctic projected by the end of this century. Cyclones are synoptic weather events that transport heat and moisture into the Arctic, and have complex impacts on sea ice, and the local and global climate. However, the effect of a changing climate on Arctic cyclone behavior remains poorly understood. This study uses high resolution (4 km), regional modeling techniques and downscaled global climate reconstructions and projections to examine how recent and future climatic changes alter cyclone behavior. Results suggest that recent climate change has not yet had an appreciable effect on Arctic cyclone characteristics. However, future sea ice loss and increasing surface temperatures drive large increases in the near-surface temperature gradient, sensible and latent heat fluxes, and convection during cyclones. The future climate can alter cyclone trajectories and increase and prolong intensity with greatly augmented wind speeds, temperatures, and precipitation. Such changes in cyclone characteristics could exacerbate sea ice loss and Arctic warming through positive feedbacks. The increasing extreme nature of these weather events has implications for local ecosystems, communities, and socio-economic activities.

Chelsea L Parker↗
DOE OSTI2021

Design of Efficient Molecular Electrocatalysts for Water and Carbon Dioxide Reduction Using Predictive Models of Thermodynamic Properties

Objectives: 1) To design and synthesize water soluble transition metal complexes that function as electrocatalysts for the reduction of water to hydrogen or carbon dioxide to formate 2) To experimentally measure thermochemical properties, such as hydride donor ability, and use these quantities to optimize catalyst performance in solutions of varying pH 3) To incorporate results from detailed mechanistic and kinetic studies to direct improvements in catalyst design 4) To use thermochemical data from objective 2 to generate predictive models for the properties of new complexes to apply to the development of catalysts for other reductive reactions, with an emphasis on carbon dioxide reduction to methanol Description: Wide-spread implementation of renewable but intermittent energy sources, such as solar, requires the development of efficient methods for energy storage. The high energy density of chemical bonds makes chemical fuels an ideal solution for energy storage. Hydrogen and reduced carbon compounds have been proposed as ideal candidates for chemical fuels. However, the generation of chemical fuels from electricity requires competent electrocatalysts. The proposed research focuses on developing electrocatalysts for the reduction of water to hydrogen, and carbon dioxide to formate. Both products can be used directly as an energy carrier in fuel cells, or as a reductant for more saturated chemical fuels. Hydrogen is the most common fuel used in current commercial fuel cells. Additionally, there is interest in formic acid as a liquid carrier for hydrogen because of its increased storage density and ease of dehydrogenation. Formate is also an intermediate in the sequential reduction of CO 2 to methanol, another potential chemical fuel with high energy storage density. Despite the utility of formate as a chemical fuel or precursor, there are very few examples of electrocatalysts for its production from CO 2 , and even fewer demonstrate high product selectivity. In heterogeneous catalysis, the Sabatier principle is used to generate volcano curves that describe optimal thermochemical properties for key intermediates that result in peak catalytic activity. In most cases, such as hydrogen production and oxidation, the most favorable metals (Pt, Re, Rh, and Ir) are rare and expensive. Molecular inorganic complexes provide an opportunity to use electronic and steric ligand effects to tune the critical thermodynamic parameters of abundant metals to values comparable to key surface intermediates on precious metals. This principle will be applied to the design of aqueous homogeneous catalysts for the reduction of H 2 O and CO 2 optimized to function at specific pH ranges. The critical intermediate in both of these reactions is a metal hydride. The strength of this bond, or hydricity (ΔGH - ) dictates the overall thermodynamics of the reduction of H + to H 2 and the sequential reduction of C1 substrates, such as CO 2 , CO, and H 2 CO (the latter to CH 3 OH). ΔGH - will be systematically measured for a series of first row metal complexes to form predictive models for metal and ligand electronic effects. Benefits and Outcomes: This approach addresses thermodynamic requirements essential for energy-efficient catalyst design and transition state barrier considerations for faster catalysis. The advancements made from this research will include the discovery of efficient, stable, and fast catalysts for hydrogen and formate generation from electricity. The ability to store energy efficiently is critical to the widespread use of renewable energy schemes. This provides a viable solution to produce high energy density fuels for stationary and mobile energy applications. The fundamental research conducted is also directly applicable to the design of catalysts for the generation of further reduced products such as methanol.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1992

Search for evidence of a clock related to the solar 154 day complex of periodicities

Evidence that has recently been compiled (Bai and Sturrock 1991) indicates that the enigmatic 154-day periodicity in solar activity may be viewed as part of a complex of periodicities that are approximate multiples of 25.8 days, suggesting that the Sun contains a 'clock' with frequency in the range 440 to 463 nano Hz. The clock may comprise either an oscillator or a rotator, each of which may be either real or virtual. We have reconsidered a previous spectrum analysis of the Zurich sunspot-number sequence by Knight, Schatten, and Sturrock (1979) which revealed a sharp, persistent and significant periodicity with a period of 12.072 days, corresponding to a frequency of about 958.8 nano Hz. This periodicity may be regarded as the (second) upper sideband of the second harmonic (2nu(sub R) + 2nu(sub E)) of a fundamental frequency of 447.7 nano Hz that is clearly within the search band. In this expression, nu(sub R) is the sidereal frequency of the hypothetical rotator and nu(sub E) is the frequency (31.69 nano Hz) of the Earth in its orbital motion around the Sun. In analyzing sunspot area data derived from the Greenwich data set, and on noting that any frequency is defined only to within the Nyquist frequency, we find clear evidence not only for the upper sideband of the second harmonic, but also for the second harmonic (2nu(sub R)) and the lower sideband of the second harmonic (2nu(sub R) - 2nu(sub E)). There is no strong peak at the fundamental frequency in the Greenwich data, but there is in the Zurich sunspot data. The effect of a linear oscillator is, to the lowest order in the amplitude, the same as the combined effect of two rotators of opposite polarities. A rotator that has arbitrary orientation with respect to the ecliptic may influence the outer layers of the Sun and thereby modulate the occurrence of solar activity such as sunspots. By analyzing a simple model, we find that such a rotator would influence surface activity in such a way that the spectrum of a 'signal' (such as the record of sunspots), as seen from the Earth, would contain components with frequencies that are certain integral combinations of nu(sub R) and nu(sub E). The amplitudes of the various components depend sensitively on theta, the angle between the axis of the rotator and the axis of the Earth's orbital motion. This simple model therefore offers a kinematical (but not dynamical) interpretation of the sunspot spectrum. The present analysis, while offering support of our conjectures that the Sun contains a clock that regulates the 154-day complex of periodicities, cannot distinguish between an osillator or a rotator (that might be a traveling wave), nor between a real rotator or a virtual rotator (that might be an apparent traveling wave due to the aliasing effect of an oscillator in a rotating system). Further analysis of sunspot and other data sets will be required to confirm the existence of such clock and (if it is real) to determine its physical nature.

Sturrock, P. A.↗
DOE OSTI2024

ELM-Wet: Inclusion of a wetland landunit with sub-grid representation of eco-hydrological patches and hydrological forcing in E3SM Land Model (ELM)

Wetlands emit the most biogenic methane (CH4) and present the greatest uncertainty in the global CH4 budget. Modeling these emissions is challenging due to the temporal and spatial variability in wetland structure and CH4 flux rates, along with complex interactions among hydrological, ecological, meteorological, and microbial processes that govern CH4 dynamics. To address these issues, we aim to enhance the accuracy of wetland representation in the U.S. Department of Energy’s Exascale Earth System Model (E3SM) Land Model, ELM. This effort led to the development of ELM-Wet, which incorporates a dedicated wetland landunit with subgrid representation of eco-hydrological patch types. We implement wetland-specific hydrology by imposing site-specific constraints on surface water levels, thereby allowing different patches to sustain varying depths of inundation. Additionally, we refined the calculation of aerenchyma transport diffusivity based on observed conductance across different vegetation types. We validated these enhancements through site-specific simulations of a coastal freshwater wetland, the Salvador WMA Freshwater Marsh (Ameriflux, site ID US-LA2), located in the coast of Louisiana (29.85N,90.29W) at an elevation of 0 m. The site was simulated with ELM-Wet and the default version ELMv1. We use Bayesian Optimization to parameterize CO2 and CH4 fluxes. Eddy covariance observations of CO2 and CH4 fluxes from 2012-2013 were used to train the model and data from 2021 were used for validation. In this repository, we include all the output of all the simulations performed using different versions of ELMv1 and ELM-Wet, all input required to the model, and the Matlab scripts we used to processed the output data. ELM-Wet_flmd.csv includes a detailed description of the datasets files.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

Simultaneous mitigation of density and energy errors in approximate DFT for transition metal chemistry (Final Technical Report)

There were three major goals and objectives of this project: 1) Develop tools to understand density-driven errors in transition metal complexes, 2) Evaluate and minimize energy delocalization error and static correlation error through judicious functional choice, and 3) applying this workflow to machine-learning accelerated screening of redox couples. Over the reporting period, we developed a framework for eliminating flat plane errors. We introduced fully non-empirical coefficients. We demonstrated the approach on both molecules and solids. We investigated and eliminated density driven errors and demonstrated their impact on potential energy surfaces. We trained machine learning models both in a method-dependent fashion and to predict errors in method accuracy. We built large data sets of small molecule energetics and multi-reference character.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
NASA NTRS1981

Influence of friction forces on the motion of VTOL aircraft during landing operations on ships at sea

Equations describing the friction forces generated during landing operations on ships at sea were formulated. These forces depend on the platform reaction and the coefficient of friction. The platform reaction depends on the relative sink rate and the shock absorbing capability of the landing gear. The friction coefficient varies with the surface condition of the landing platform and the angle of yaw of the aircraft relative to the landing platform. Landings by VTOL aircraft, equipped with conventional oleopneumatic landing gears are discussed. Simplifications are introduced to reduce the complexity of the mathematical description of the tire and shock strut characteristics. Approximating the actual complicated force deflection characteristic of the tire by linear relationship is adequate. The internal friction forces in the shock strut are included in the landing gear model. A set of relatively simple equations was obtained by including only those tire and shock strut characteristics that contribute significantly to the generation of landing gear forces.

Howard, J. C.↗