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At least 1,657 records · Page 92

Dynamics of coupled thermoacoustic modes: Noise and frequency spacing effects

Practical combustion systems consist of multiple thermoacoustic modes that are linearly stable or unstable at a wide range of frequencies. When coupled, the modal interactions are a strong function of the frequency spacing between them – having very significant implications on interpretation of linear stability or instability of modes from experimental data. Frequency spacing between the modes particularly influences the stability and existence of potential limit cycle solutions. In this paper, we extend earlier deterministic studies to include the effects of noise, studying how deterministic dynamics change with the addition of noise and the simultaneous impact of frequency spacing (i.e., closely, or widely spaced). Specifically, this paper characterizes three key effects of noise, which are (1) distribution of limit cycle amplitudes (“diffusion”), (2) shift in the average limit cycle amplitudes (“noise induced drift”), and (3) introduction of new bifurcations that are not present in the deterministic system. Key conclusions from this work are that in highly noisy practical environments, a deterministic/ low noise analysis will not be sufficient to explain even critical qualitative features of the system – such as existence of stable limit cycles or their amplitudes. Furthermore, the nature of noise-induced effects on nonlinear modal interactions can be fundamentally different for degenerate, closely spaced, and widely spaced modes.

42 ENGINEERING↗

Fabrication of Large-Area Metal-on-Carbon Catalytic Condensers for Programmable Catalysis

Catalytic condensers stabilize charge on either side of a high-k dielectric film to modulate the electronic states of a catalytic layer for the electronic control of surface reactions. Here, carbon sputtering provided for fast, large-scale fabrication of metal–carbon catalytic condensers required for industrial application. Carbon films were sputtered on HfO 2 dielectric/p-type Si with different thicknesses (1, 3, 6, and 10 nm), and the enhancement of conductance and capacitance of carbon films was observed upon increasing the carbon thickness following thermal treatment at 400 °C. After Pt deposition on the carbon films, the Pt catalytic condenser exhibited a high capacitance of ∼210 nF/cm 2 that was maintained at a frequency ∼1000 Hz, satisfying the requirement for a dynamic catalyst to implement catalytic resonance. Temperature-programmed desorption of carbon monoxide yielded CO desorption peaks that shifted in temperature with the varying potential applied to the condenser (−6 or +6 V), indicating a shift in the binding energy of carbon monoxide on the Pt condenser surface. A substantial increase in capacitance (∼2000 nF/cm 2 ) of the Pt-on-carbon devices was observed at elevated temperatures of 400 °C that can modulate ∼10% of charge per metal atom when 10 V potential was applied. A large catalytic condenser of 42 cm 2 area Pt/C/HfO 2 /Si exhibited a high capacitance of 9393 nF with a low leakage current/capacitive current ratio (<0.1), demonstrating the practicality and versatility of the facile, large-scale fabrication method for metal–carbon catalytic condensers.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A metastable tetragonal phase in two-dimensional halide perovskite lattices driven by a coherent Higgs mode

The optoelectronic properties of metal halide perovskites are defined by their coupled structural and photophysical properties, yet their lattice behaviour remains underexplored. Here, using impulsive stimulated Raman spectroscopy, we study light-induced phonon dynamics of two-dimensional butylammonium lead iodide ((BA) 2 PbI 4 ) films under varying excitation intensities, photon energies and temperatures. We reveal that, whereas (BA) 2 PbI 4 exhibits two thermally accessible orthorhombic phases, optically excited phonons transiently direct the lattice to a distinct, higher symmetry tetragonal phase. We show that bandgap oscillations arise from simultaneous distortions of in-plane and out-of-plane octahedral tilt angles with oscillations following a low-to-high symmetry pathway, marked by two vibrational frequencies independent of intensity—a signature of an optically excited Higgs mode. Notably, the Higgs mode at below-bandgap excitation induces a fourfold larger spectral shift than above-bandgap, where photogenerated charge carriers drive the system away from the optically induced tetragonal phase. This study illustrates how optomechanical coupling influences the optical properties of two-dimensional perovskites.

36 MATERIALS SCIENCE↗

Increasing precipitation whiplash in climate change hotspots

Abstract Throughout the world, the hydrologic cycle is projected to become more variable due to climate change, posing challenges in semi-arid regions with high water resource vulnerability. Precipitation whiplash results from hydrologic variability, and refers to interannual shifts between wet (⩾80th historical percentile) and dry (⩽20th historical percentile) years. Using five model large ensembles, we show that whiplash is projected to increase in frequency (25%–60%) and intensity (30%–100%) by 2100 across several semi-arid regions of the globe, including Western North America and the Mediterranean. These changes can be driven by increases in the frequency of wet years or dry years, or both, depending on the region. Moisture budget calculations in these regions illuminate the physical mechanisms behind increased whiplash. Thermodynamic changes generally dominate, with modulations by dynamics, evaporation, and eddies on regional or global scales. These findings highlight increasingly volatile hydrology in semi-arid regions as the 21st Century progresses.

54 ENVIRONMENTAL SCIENCES↗

Social Unit Organization in Three Wild Pig Populations

Wild pig (Sus scrofa) social unit organization was compared in three introduced populations in the southeastern United States. Group size, age and sex composition and types of social unit were recorded from field observations. Groups of two or more individuals were significantly more frequent than solitary animals in all three populations. Mixed adult/immature groups were the largest social unit of two or more individuals, followed by groups of immature animals and the various types of adult groups. In two of the populations, this same trend among these groups types was seen for the frequency of occurrence (i.e., with the adult/immature group being the most common). In the third population, the frequency of the adult/immature and immature-only groups were reversed. Size variation within all except the mixed-sex adult group type was similar among the three field sites. Adult males were the most frequently observed solitary category. Increased percentage of hardwood forest was significantly correlated with a decrease in the percent frequency of immature-only groups and an increase in adult/immature groups. Increasing annual harvest by man was significantly correlated with an increase in the frequency of immature-only groups and a decrease in those of adults/immatures. The biased removal of females through trapping would be consistent with the apparent shift from adult/immature groups to immature-only groups among the three field sites.

59 BASIC BIOLOGICAL SCIENCES↗

First results of a study on turbulent boundary layers in oscillating flow with a mean adverse pressure gradient

The development of a turbulent unsteady boundary layer with a mean pressure gradient strong enough to induce separation, in order to complete the extend results obtained for the flat plate configuration is presented. The longitudinal component of the velocity is measured using constant temperature hot wire anemometer. The region where negative velocities exist is investigated with a laser Doppler velocimeter system with BRAGG cells. The boundary layer responds by forced pulsation to the perturbation of potential flow. The unsteady effects observed are very important. The average location of the zero skin friction point moves periodically at the perturbation frequency. Average velocity profiles from different instants in the cycle are compared. The existence of a logarithmic region enables a simple calculation of the maximum phase shift of the velocity in the boundary layer. An attempt of calculation by an integral method of boundary layer development is presented, up to the point where reverse flow starts appearing.

Houdeville, R.↗

Self broadening in the nu-1 band of NH3

Self-broadening coefficients, pressure shifts, and integrated intensities have been measured for Q- and R-branch transitions in the nu-1 fundamental band of ammonia using a difference-frequency laser spectrometer. A strong, systematic J and K dependence of the broadening coefficients, reminiscent of the ground-state inversion transitions, is observed and compared with semiclassical line broadening calculations. Dicke narrowing is evident at intermediate pressures for the sharpest lines, primarily the R(J, 0) transitions. Incipient line mixing is apparent in the Q branch at pressures above about 0.1 bar.

Markov, V. N.↗

Mixing noise reduction for rectangular supersonic jets by nozzle shaping and induced screech mixing

Two methods of mixing noise modification were studied for supersonic jets flowing from rectangular nozzles with an aspect ratio of about five and a small dimension of about 1.4 cm. The first involves nozzle geometry variation using either single (unsymmetrical) or double bevelled (symmetrical) thirty degree cutbacks of the nozzle exit. Both converging (C) and converging-diverging (C-D) versions were tested. The double bevelled C-D nozzle produced a jet mixing noise reduction of about 4 dB compared to a standard rectangular C-D nozzle. In addition all bevelled nozzles produced an upstream shift in peak mixing noise which is conducive to improved attenuation when the nozzle is used in an acoustically treated duct. A large increase in high frequency noise also occurred near the plane of the nozzle exit. Because of near normal incidence, this noise can be easily attenuated with wall treatment. The second approach uses paddles inserted on the edge of the two sides of the jet to induce screech and greatly enhance the jet mixing. Although screech and mixing noise levels are increased, the enhanced mixing moves the source locations upstream and may make an enclosed system more amenable to noise reduction using wall acoustic treatment.

Rice, Edward J.↗

Spectral indices of cardiovascular adaptations to short-term simulated microgravity exposure

We investigated the effects of exposure to microgravity on the baseline autonomic balance in cardiovascular regulation using spectral analysis of cardiovascular variables measured during supine rest. Heart rate, arterial pressure, radial flow, thoracic fluid impedance and central venous pressure were recorded from nine volunteers before and after simulated microgravity, produced by 20 hours of 6 degrees head down bedrest plus furosemide. Spectral powers increased after simulated microgravity in the low frequency region (centered at about 0.03 Hz) in arterial pressure, heart rate and radial flow, and decreased in the respiratory frequency region (centered at about 0.25 Hz) in heart rate. Reduced heart rate power in the respiratory frequency region indicates reduced parasympathetic influence on the heart. A concurrent increase in the low frequency power in arterial pressure, heart rate, and radial flow indicates increased sympathetic influence. These results suggest that the baseline autonomic balance in cardiovascular regulation is shifted towards increased sympathetic and decreased parasympathetic influence after exposure to short-term simulated microgravity.

NASA Discipline Cardiopulmonary↗

Spectroscopic methods and systems for isotopic analysis

Disclosed are spectroscopy systems and methods. A spectroscopy system can include a reference cell and a multi-pass sample cell. The reference arm can include an etalon and a reference cavity containing a reference gas. A system can include a fractional sublimation cold trap. Detectors of the reference and sample arms can detect both intensity and absorption spectra of impinging beams. A frequency calibration based on a reference absorption spectra can be used to analyze a sample absorption spectrum. The analysis can provide information regarding an absorption band shift of the sample absorption spectrum, said shift being related to the isotope concentration of the sample.

O'Rourke, Patrick E.↗

First observation of RMP ELM mitigation on MAST Upgrade

Abstract The first experimental attempts at controlling edge localised modes (ELMs) via the application of resonant magnetic perturbations on the MAST Upgrade tokamak are reported. Using the linear MHD model MARS-F, the phase shift between the upper and lower coil rows ΔΦ was optimised for toroidal mode number n = 1 and n = 2 fields, to provide forward guidance to experiments. In low β N discharges, the application of n = 1 3D fields caused the ELM frequency f E L M to increase by over a factor 20 relative to the reference, and also induced a locked mode, which did not cause a plasma termination nor an H-L back transition. However when β N was raised, this induced locked mode caused plasma termination which precluded mitigation access. Initially, applying a numerically optimised n = 2 field had no effect. However applying a rigid toroidal shift to this field caused a locked mode disruption, demonstrating the presence of a substantial n = 2 error field. Coil current ramps were conducted with ΔΦ set at 6 different values, resulting in either locked mode disruptions or no effect, but mitigation with n = 2 fields was not established.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Broadband cross polarization for ultra-wideline magic-angle spinning NMR

Over the past decade, there has been a sustained interest in using frequency-swept (FS) pulses for the efficient acquisition of wideline and ultra-wideline (UW) NMR powder patterns. Such experiments are typically conducted under static conditions, employing both direct- and indirect-excitation methods (i.e., WCPMG and BRAIN-CP/WCPMG, respectively). Recently, Koppe et al. demonstrated that the WCPMG pulse sequence can be used to efficiently acquire wideline and UW NMR spectra with spinning sideband (SSB) manifolds under magic-angle spinning (MAS) conditions, capitalizing on the increased signal-to-noise ratios (SNR) afforded by MAS. To date, there have been only a few instances of broadband cross-polarization (CP) experiments using FS pulses under MAS conditions and no applications to systems exhibiting wideline and/or ultra-wideline powder patterns, despite the clear advantages these experiments could offer. Herein, we demonstrate that FS pulses selectively applied to a single sideband of the S spin can be used for efficient 1 H-S polarization transfer to S = 1/2 nuclides with large anisotropic chemical shift interactions at slow to moderate MAS rates. The Hartmann–Hahn matching conditions in BRAIN-CP/WCPMG-MAS experiments bear similarity to those of standard CP sequences, yet operate over UW frequency ranges and only require low-amplitude RF pulses on the S channel. Crucial to the success of the BRAIN-CP/WCPMG-MAS experiment is careful calibration of the RF amplitude, transmitter offset, and effective frequency sweep of the FS pulse applied to the S spins at a given MAS rate. Thus, by means of numerical simulations and experimental testing, we provide recommendations for the parameterization and setup of BRAIN-CP/WCPMG-MAS experiments for their most efficient use. Results showcasing the capability of the BRAIN-CP/WCPMG-MAS pulse sequence are presented, including applications to 119 Sn, 195 Pt, and 103 Rh NMR.

Kimball, James J. [Florida State University, Talla↗

Analysis and Control of a Three-Port Converter with High-Frequency AC Link for Hybrid Unmanned/Autonomous Aerial Vehicles

In this study, a three-port resonant converter with a high-frequency isolation link for hybrid unmanned/autonomous aerial vehicle (UAV/AAV) applications is analyzed. The rectified engine-generator set output supplies the first input ports while the other is connected to a battery energy storage system. Input ports consist of half-bridge high-frequency inverters, whereas output port utilizes a semi-bridgeless active rectifier. This rectifier is formed by replacing rectifier low-side diodes with active switching devices. A phase-shift duty-cycle control is implemented for switching signals to regulate the power share and flow between ports. The proposed control system implemented achieves zero voltage switching (ZVS), reduces switching losses, and minimum current flow optimization ensures regulation in a wide range of output power. Compared to the existing bidirectional pulse width modulation (PWM) converters, the proposed system decreases the number of power conversion stages and provides centralized control without needing communications between the ports. The proposed control technique operating in closed-loop control achieves the power flow between ports under various load conditions. Finally, theoretical analysis demonstrates the proposed converter’s viability and laboratory experimental validations at 500 W full power.

33 ADVANCED PROPULSION SYSTEMS↗

Determining Locations by Use of Networks of Passive Beacons

Networks of passive radio beacons spanning moderate-sized terrain areas have been proposed to aid navigation of small robotic aircraft that would be used to explore Saturn s moon Titan. Such networks could also be used on Earth to aid navigation of robotic aircraft, land vehicles, or vessels engaged in exploration or reconnaissance in situations or locations (e.g., underwater locations) in which Global Positioning System (GPS) signals are unreliable or unavailable. Prior to use, it would be necessary to pre-position the beacons at known locations that would be determined by use of one or more precise independent global navigation system(s). Thereafter, while navigating over the area spanned by a given network of passive beacons, an exploratory robot would use the beacons to determine its position precisely relative to the known beacon positions (see figure). If it were necessary for the robot to explore multiple, separated terrain areas spanned by different networks of beacons, the robot could use a long-haul, relatively coarse global navigation system for the lower-precision position determination needed during transit between such areas. The proposed method of precise determination of position of an exploratory robot relative to the positions of passive radio beacons is based partly on the principles of radar and partly on the principles of radio-frequency identification (RFID) tags. The robot would transmit radar-like signals that would be modified and reflected by the passive beacons. The distance to each beacon would be determined from the roundtrip propagation time and/or round-trip phase shift of the signal returning from that beacon. Signals returned from different beacons could be distinguished by means of their RFID characteristics. Alternatively or in addition, the antenna of each beacon could be designed to radiate in a unique pattern that could be identified by the navigation system. Also, alternatively or in addition, sets of identical beacons could be deployed in unique configurations such that the navigation system could identify their unique combinations of radio-frequency reflections as an alternative to leveraging the uniqueness of the RFID tags. The degree of dimensional accuracy would depend not only on the locations of the beacons but also on the number of beacon signals received, the number of samples of each signal, the motion of the robot, and the time intervals between samples. At one extreme, a single sample of the return signal from a single beacon could be used to determine the distance from that beacon and hence to determine that the robot is located somewhere on a sphere, the radius of which equals that distance and the center of which lies at the beacon. In a less extreme example, the three-dimensional position of the robot could be determined with fair precision from a single sample of the signal from each of three beacons. In intermediate cases, position estimates could be refined and/or position ambiguities could be resolved by use of supplementary readings of an altimeter and other instruments aboard the robot.

Okino, Clayton↗

Modeling of frequency-sweeping Alfvén modes in the TJ-II stellarator

Alfvénic activity has been observed in the TJ-II stellarator which resembles the frequency sweeping demonstrated by Alfvén cascade modes in tokamaks. A numerical validation study was conducted using a reduced magnetohydrodynamic (MHD) model to show that such modes could only have been observed in discharges where the rotational transform profile was non-monotonic. During experiments, coil current was varied which resulted in shifting of the minimum value of the rotational transform profile. To mimic this effect, we study the Alfvénic activity predicted by the reduced MHD model for a set of input rotational transform profiles with varying minima. A mode is found whose toroidal and poloidal mode numbers match those predicted in experiments which sweeps downward/upward in frequency as the minimum value of the rotational transform profile is increased/decreased. The results serve as a demonstration of the validity and utility of MHD spectroscopy.

Alfvén cascades↗

Sub-daily virus sampling at the Bermuda Atlantic Time Series reveals diel and depth-structured population dynamics without community-level shifts

Ocean microbes contribute to biogeochemical cycles and ecosystem function, but they do so under top-down pressure imposed by viruses. While viruses are increasingly understood spatially and beginning to be incorporated into predictive modeling, high-frequency ocean virus dynamics remain understudied due to methodological challenges. Here we sampled stratified Bermuda Atlantic Time Series (BATS) waters for 112 hours at sub-daily 4- (surface) or 12- (deep chlorophyll maximum) hour intervals, purified viral particles from these samples, sequenced their metagenomes, and used the resulting data to characterize high-frequency virus community dynamics. Aggregated community diversity metrics changed with depth, but were not statistically significant temporally at a fixed location. However, finer-scale population-level analyses revealed both depth and temporal change, including physicochemical depth-driven differences and, in surface waters, thousands of viral populations that exhibited statistically significant diel rhythms. Statistical analyses revealed three main archetypes of temporal dynamics that themselves differed in abundance patterns, host predictions, viral taxonomy, and gene functions. Among these, highlights include viruses resembling an archetype with a night peaking pattern in activity that include an over-representation of viruses that putatively infect Prochlorococcus, a phototrophic cyanobacteria. Together, these efforts provide baseline community- and population-scale short-time-frame observations relevant to future climate state modeling.

Carrillo, Alfonso [The Ohio State University, Colu↗

622-Mbps Orthogonal Frequency Division Multiplexing (OFDM) Digital Modem Implemented

Future generation space communications systems feature significantly higher data rates and relatively smaller frequency spectrum allocations than systems currently deployed. This requires the application of bandwidth- and power-efficient signal transmission techniques. There are a number of approaches to implementing such techniques, including analog, digital, mixed-signal, single-channel, or multichannel systems. In general, the digital implementations offer more advantages; however, a fully digital implementation is very difficult because of the very high clock speeds required. Multichannel techniques are used to reduce the sampling rate. One such technique, multicarrier modulation, divides the data into a number of low-rate channels that are stacked in frequency. Orthogonal frequency division multiplexing (OFDM), a form of multicarrier modulation, is being proposed for numerous systems, including mobile wireless and digital subscriber link communication systems. In response to this challenge, NASA Glenn Research Center's Communication Technology Division has developed an OFDM digital modem (modulator and demodulator) with an aggregate information throughput of 622 Mbps. The basic OFDM waveform is constructed by dividing an incoming data stream into four channels, each using either 16- ary quadrature amplitude modulation (16-QAM) or 8-phase shift keying (8-PSK). An efficient implementation for an OFDM architecture is being achieved using the combination of a discrete Fourier transform (DFT) at the transmitter to digitally stack the individual carriers, inverse DFT at the receiver to perform the frequency translations, and a polyphase filter to facilitate the pulse shaping.

Kifle, Muli↗

Influence of African Easterly Wave Suppression on Atlantic Tropical Cyclone Activity in a Convection-Permitting Model

African easterly waves (AEWs) are strongly linked to Atlantic tropical cyclones (TCs) on the synoptic timescale by serving as seedling disturbances for TC genesis. However, it is unclear whether climatological TC frequency is limited by AEWs. We investigated the impact of suppressing AEWs using a 3-member ensemble of convection-permitting regional model simulations, in which AEWs were either retained or removed through the lateral boundary conditions. Suppressing AEWs did not substantially change seasonal TC number, but did influence TC intensity, genesis time and location. Suppressing AEWs produced stronger TCs, shifted peak TC genesis from September to August, and reduced (increased) TC genesis in the eastern Atlantic (Gulf of Mexico). Without AEWs, TCs generated under more favorable large-scale atmospheric conditions. Furthermore, these results indicate that AEWs may not be reliable predictors of basin-wide seasonal TC frequency. However, simulations provide evidence that AEWs could influence the large-scale environment that is important for TCs.

54 ENVIRONMENTAL SCIENCES↗