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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,657 records · Page 92
All sourcesNASA NTRSDOE OSTI
NASA NTRS1974

Simulation of lunar carbon chemistry. I - Solar wind contribution

Simulation experiments were conducted to identify the role of solar and lunar winds in the evolution of lunar carbon chemistry. Major conclusions are that (1) implantation of solar wind C, D, and N ions in silicates synthesizes small molecules that can be released into vacuum either by ion sputtering or by heating; (2) this synthesis is highly specific when compared to other processes accounting for the formation of molecules in the solar nebula or in interstellar space; (3) the carbon injected by the solar wind in the crystalline component of mature soils should reach a saturation concentration of about 200 ppm; and (4) the carbon chemistry of the crystalline component of mature soils is dominated by solar wind implantation effects.

Bibring, J. P.↗
NASA NTRS1976

Oxidation of metals and alloys in controlled atmospheres using in situ transmission electron microscopy and Auger spectrography

Single-crystalline thin films of copper were oxidized at an isothermal temperature of 425 C and at an oxygen partial pressure of .005 Torr in situ in a high-resolution electron microscope. The specimens were prepared by epitaxial vapor deposition onto polished 100 and 110 faces of rocksalt and mounted in a hot stage inside an ultra-high-vacuum specimen chamber of the microscope. Large amounts of sulfur, carbon, and oxygen were detected by Auger electron spectroscopy on the surface of the as-received films and were removed in situ by ion-sputter etching immediately prior to the oxidation. The nucleation and growth characteristics of Cu2O on Cu were studied. Results show that neither stacking faults nor dislocations are associated with the Cu2O nucleation sites. The growth of Cu2O nuclei is linear with time. The experimental findings, including results from oxygen dissolution experiments and from repetitive oxidation-reduction-oxidation sequences, fit well into the framework of an oxidation process involving (a) the formation of a surface-charge layer, (b) oxygen saturation in the metal and (c) nucleation, followed by surface diffusion of oxygen and bulk diffusion of copper for lateral and vertical oxide growth, respectively.

Rao, D. B.↗
NASA NTRS1975

History of Boulder 1 at Station 2, Apollo 17 based on trace element interrelationships

Correlations among the trace and minor element pairs Cl and Br, Cl and P2O5, and Ru and Os, present in parent igneous rocks, generally survived the processes of boulder breccia formation. Fractions of Cl, Br, and Hg that are mobilized by water leaching or volatilization at moderate temperatures place constraints on the thermal history of Boulder 1 and its component breccias. Since, and possibly during, consolidation, the boulder has probably not been subjected to temperatures in excess of 450 C. The parent rocks of the Apollo 17 boulder and breccia samples studied could have been derived from two initial magmas. Vapor clouds from apparently external sources permeated the source regions of the boulders.

Jovanovic, S.↗
NASA NTRS1977

Explorer 33 entry layer observations

Low fluxes of stagnant or irregularly flowing plasma along the inside of the magnetopause labeled as the entry layer by Haerendel and Paschmann, are observed on Explorer 33 orbits which cross the dayside magnetopause and on one orbit which skims the dawn flank. The data indicate that the entry layer is a permanent magnetospheric feature which extends across the dayside and along the flanks to large distances down the tail on dipolelike field lines between extensions of the northern and southern polar cusps. Pressure anisotropies are present in the entry layer but are often weaker and less frequent than those in the adjacent magnetosheath. These anisotropies give clues about the process of entry layer formation. The sense of anisotropy when it is present on both sides of the magnetopause is the same for magnetosheath fields with a southward component and opposite for fields with a northward component. These correlations are consistent with entry layer filling by bulk flow along field lines opened by magnetic merging in the one case and by diffusion onto closed field lines in the other.

Crooker, N. U.↗
NASA NTRS1977

Intumescent-ablators as improved thermal protection materials

Nitroaromatic amine-based intumescent coatings were improved with regard to their thermal protection ability by adding endothermic decomposing fillers with endotherms at or near the exothermic reaction of the intumescent agent, since the effectiveness of the intumescent coatings without fillers is reduced by the exothermic behavior of the coatings during thermal activation. Fillers were dispersed directly in the base coating. Potassium fluoborate, ammonium fluoborate, zinc borate, and ammonium oxalate function as endothermic ablative materials at specific temperature regions, and also enhance the char formation during the intumescent process.

Sawko, P. M.↗
NASA NTRS1977

Use of thermal-infrared imagery in ground-water investigations in Montana

Thermal infrared imagery was used to locate ground-water inflow along three streams and one lake in Montana. The thermal scanner used in May 1972, March 1973, and November 1975 was mounted in a twin-engined aircraft. On the 1973 and 1975 flights, the data were recorded in an analog format on magnetic tape in flight, later were converted to digital format, and were computer processed using an assignment of patterns to indicate differences in water temperature. Output from the image processing program was converted to a temperature map having an isotherm spacing of 0.5 C. Computerization was found to be the most efficient method to manipulate data from lakes, large rivers, and narrow sinuous streams.

Boettcher, A. J.↗
NASA NTRS1978

Nitric oxide production by Tunguska meteor

The nonequilibrium chemical processes of nitric oxide formation are computed for the wake of the Tunguska meteor of 1908. The wake characteristics are derived by carrying out an optically-thick radiation field analysis for ablation of the meteoroid. The wake flow field is approximated by a one-dimensional, well-stirred reactor model. Known characteristics of the Tunguska event are imposed as constraints, and three controlling parameters - chemical composition, density, and velocity - are varied over a range around the values derived by Korobeinikov et al. (1976) and Petrov and Stulov (1975). The calculation shows that at least 19 million tons of nitric oxide is produced between the altitudes of 10 and 50 km. The anomalous atmospheric phenomena following the event are attributed to the reactions involving nitric oxide thus produced and atmospheric ozone. It is speculated that the nitric oxide produced by the event fertilized the area near the fall, causing the observed rapid plant growth.

Park, C.↗
NASA NTRS1978

Lubrication and failure mechanisms of molybdenum disulfide films. 1: Effect of atmosphere

Friction, wear, and wear lives of rubbed molybdenum disulfide (MoS2 films applied to sanded 440C HT steel surfaces were evaluated in moist air, dry air, and dry argon. Optical microscope observations were made as a function of sliding distance to determine the effect of moisture and oxygen on the lubricating and failure mechanisms of MoS2 films. In general, the lubrication process consisted of the formation of a thin, metallic colored, coalesced film of MoS2 that flowed between the surfaces in relative motion. In air, failure was due to the transformation of the metallic colored, coalesced films to a black, powdery material. Water in the air appeared to accelerate the transformation rate. In argon, no transformation of MoS2 was observed with the microscope, but cracking and spalling of the coalesced film occurred and resulted in the gradual depletion of the film.

Fusaro, R. L.↗
NASA NTRS1978

Indium antimonide infrared CCD linear imaging arrays with on-chip preprocessing

A description is presented of the fabrication of a new InSb CCD chip based on an improved process which eliminates the limitations inherent with the earlier techniques. This process includes planar junction formation and an aluminum and SiO2 material system which is amenable to state-of-the-art chemical and plasma delineation techniques. Further, the new chip integrates for the first time in monolithic format InSb IR detectors with an InSb CCD. The reported experiments represent the first operation of an InSb infrared CCD array. In addition to fuller characterization of the 20-element charge-coupled infrared imaging device, several factors which influence device performance are currently being addressed. These include surface state density, the CCD output circuit, and storage time (dark current).

Thom, R. D.↗
NASA NTRS1979

Solar Mesosphere Explorer optical-mechanical systems engineering

Mission overview of the Solar Mesosphere Explorer is presented along with design analysis and summaries of results. The Solar Mesosphere Explorer is a spin stabilized satellite carrying a complement of four Ebert-Fastie spectrometers and a four-channel Mersenne radiometer. Description of the spectrometer is given including a telescope and its aberrations. The radiometer is also described with consideration given to isothermal and thermal design, a Winston paraboloid, and optical tolerances. These five instruments are for measuring the earth's ozone density and distribution and providing quantitative data about those processes which govern the formation and destruction of ozone.

Gause, K. A.↗
NASA NTRS1980

Endemic isotopic anomalies in titanium

Abundances of the titanium isotopes were determined using a new high-precision technique that shows terrestrial, lunar, and bulk meteorite samples to be indistinguishable. Ca-Al-Ti-rich inclusions in the Allende meteorite are found to contain Ti of widely varying isotopic composition reflecting the presence of at least three nucleosynthetic components. The anomalies in Ti appear to be relatively widespread and, when correlated with Ca data, provide a clue to nucleosynthesis in the neighborhood of the iron peak and to the late-stage nucleosynthetic processes which immediately preceded formation of the solar nebula.

Niederer, F. R.↗
NASA NTRS1980

Dropping stones in magma oceans - Effects of early lunar cratering

A new methodology is used to calculate the accumulation rate of megaregolith materials for two models of early lunar cratering, both with and without episodes of late cataclysmic cratering. Results show that the pulverization of early rock layers was an important process competing with the formation of a coherent rock lithosphere at the surface of the hypothetical lunar magma ocean. If a magma ocean existed, then its initial cooling was marked by a period of pre-lithospheric chaos in which impacts punched through the initially thin rocky skin, mixing rock fragments with splashed magma. Furthermore, the results show that intense brecciation and pulverization of rock materials must have occurred to a depth of at least tens of kilometers in the first few hundred years of lunar history regardless of whether a 'terminal lunar cataclysm' occurred around 4.0 G.y. ago. The predicted pattern of brecciation and the ages of surviving rock fragments is similar to that actually observed among lunar samples. More reliable dating of basin-forming events and models of rock exhumation and survival are needed in order to understand better the relation between the early intense bombardment of the moon and the samples collected on the moon today.

Hartmann, W. K.↗
NASA NTRS1980

Geochemical anomalies on the eastern limb and farside of the moon

A variety of orbital geochemistry and photogeologic data was used to investigate major geochemical anomalies on the east limb and farside of the moon and to determine the processes responsible for their formation. These anomalies are located in the following regions: (1) near Langemak crater, (2) Mare Marginis, (3) Balmer crater, (4) terrain north of Taruntius crater, and (5) Van de Graaff. It was concluded that these anomalies are related to episodes of extrusive igneous activity which produced deposits with a variety of ages and compositions. Some of the associated volcanic deposits exhibit albedos and surface morphologies similar to those of the nearside maria, while others are now thinly covered by highland debris and are commonly represented by light plains units which exhibit clusters of dark-haloed craters. Little evidence was found for a genuine episode of highland volcanism (e.g., Apollo 15 KREEP basalt, highland basalt, etc.). The existence of intermediate basalts on the eastern limb and farside supports previous suggestions that KREEP-like volcanism was not limited to a small area of the lunar nearside. Eastern limb and farside volcanic activity has been more extensive in both space and time and has produced a greater variety of compositions than has previously been thought. Since thinly covered basaltic units can exert a strong influence on regional surface chemistry as determined from orbit, caution is urged in interpreting the surface compositions of highland terrains which exhibit a high density of dark-haloed impact craters.

Hawke, B. R.↗
NASA NTRS1981

A turbulent origin for the rotation of molecular clouds

The observed rotational properties of dark clouds are shown to be consistent with the turbulent character of the interstellar medium. The turbulent flow is easily maintained by the shearing action of differential galactic rotation. The size distribution of molecular clouds inferred from observations is found to closely resemble a Kolmogorov turbulent spectrum. These findings suggest that the processes leading to the formation and evolution of such clouds may depend strongly on the properties and characteristics of interstellar turbulence.

Fleck, R. C., Jr.↗
NASA NTRS1981

Nucleation and growth of stratospheric aerosols

Formation mechanisms and nucleation processes are examined, and nucleation in the stratosphere is considered, taking into account binary nucleation, ternary nucleation, binary heterogeneous nucleation, and heteromolecular nucleation. Attention is also given to the growth of aerosol particles, nucleation and growth in models, and the role of aerosols in the upper atmosphere. It is pointed out that various sampling studies and numerical models have provided evidence that the in situ oxidation of sulfur-bearing gases is responsible for the sulfate mass of the stratospheric aerosol. Data obtained by Castleman et al. (1974) suggest that there is a common source of sulfur compounds for the stratosphere of both the northern and southern hemispheres.

Castleman, A. W., Jr.↗
NASA NTRS1982

Ion beam microtexturing and enhanced surface diffusion

Ion beam interactions with solid surfaces are discussed with particular emphasis on microtexturing induced by the deliberate deposition of controllable amounts of an impurity material onto a solid surface while simultaneously sputtering the surface with an ion beam. Experimental study of the optical properties of microtextured surfaces is described. Measurements of both absorptance as a function of wavelength and emissivity are presented. A computer code is described that models the sputtering and ion reflection processes involved in microtexture formation.

Robinson, R. S.↗
NASA NTRS1980

Control of crater morphology by gravity and target type - Mars, earth, moon

The process involved in the formation of impact craters on solid planets and satellites in the solar system is thought to be essentially the same everywhere. However, the resulting landforms are not all alike. The possible reasons for the differences in crater morphology are investigated. The obtained results suggest that both gravitational acceleration and target characteristics have affected the morphology of impact craters across the solar system. Neither of these important influences alone can explain all of the many observations on craters. The relative importance of gravity and target type differs from planet to planet. Intraplanetary contrasts in crater shape which reflect differences in target materials appear to be large on earth, significant but minor on Mars and the moon, and minimal on Mercury. Whole-planet differences in crater shape between earth and the moon, on the other hand, seem to be entirely dependent on g.

Pike, R. J.↗
NASA NTRS1982

Temperature dependence of the formation of sulfate aerosols in the stratosphere

Classical nucleation theory is used in calculations of the temperature dependence of the characteristics and nucleation rates of sulfate aerosols in the binary H2SO4-H2O vapor mixture, in order to assess the influence of temperature on the formation of sulfate aerosols in the stratosphere, and to explore the possibility of new particle formation through homogeneous nucleation processes at regions where temperature is as low as -75 C, rather than the often-assumed -50 or -55 C. Calculation results indicate that the number of particles formed at a lower temperature is larger by several orders of magnitude than at higher temperatures, when water and sulfuric acid vapor concentrations are kept constant, and that large quantities of ultrafine particles which cannot be detected by conventional methods may exist at low-temperature stratospheric regions.

Yue, G. K.↗