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At least 1,657 records · Page 92

Pore-Selective Fullerene Loading in a Porphyrin-Based Metal–Organic Framework Controls Photoinduced Charge-Transfer Dynamics

Building porous donor−acceptor networks based on host−guest interactions in metal organic frameworks (MOFs) provides unique opportunities for tuning charge separation in highly tailorable materials. Here we focus on installing electron-rich porphyrins and electron-deficient fullerene derivatives in the PCN-222 MOF using a solvent assisted ligand insertion (SALI) method. The fullerene is primarily bound in the large pore, where it is subject to distinct dielectric environments through dimethylformamide (DMF) and 1,4-dioxane solvent exchange. Following photoexcitation, sub-picosecond charge transfer involving initial exciplex population is observed, with different charge recombination pathways and lifetimes depending on solvent polarity through modulation of charge-transfer state energies. While the 1,4-dioxane environment yields charge recombination within 1 ns via local fullerene and porphyrin triplet state population, DMF results in charge recombination directly to the ground state on much longer time scales, including some lifetime components in the microsecond range. Fullerene loading influences these kinetics, and the potential for charge delocalization due to fullerene aggregation within the pores is evaluated by using molecular dynamics simulations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A comprehensive analytical model of rotorcraft aerodynamics and dynamics. Part 2: User's manual

The use of a computer program for a comprehensive analytical model of rotorcraft aerodynamics and dynamics is described. The program calculates the loads and motion of helicopter rotors and airframe. First the trim solution is obtained, then the flutter, flight dynamics, and/or transient behavior can be calculated. Either a new job can be initiated or further calculations can be performed for an old job.

Johnson, W.↗

Response of laminated composite flat panels to sonic boom and explosive blast loadings

This paper deals with a theoretical analysis of the dynamic response of shear deformable symmetrically laminated rectangular composite flat panels exposed to sonic boom and explosive blast loadings. The pertinent governing equations incorporating transverse shear deformation, transverse normal stress, as well as the higher-order effects are solved by using the integral-transform technique. The obtained results are compared with their counterparts obtained within the framework of the first-order transverse shear deformation and the classical plate theories and some conclusions concerning their range of applicability are outlined. The paper also contains a detailed analysis of the influence played by the various parameters characterizing the considered pressure pulses as well as the material and geometry of the plate.

Librescu, L.↗

An Investigation of the Effect of Downwash from a VTOL Aircraft and a Helicopter in the Ground Environment

Dynamic-pressure measurement, in ground effect, have been obtained about a single-rotor helicopter and a dual-propeller VTOL (Vertical Take-Off and Landing) aircraft. The results indicate that the slipstream dynamic pressure along the ground, some distance from the center of rotation, is not a function of disk loading but merely a function of the gross weight or thrust of the aircraft. Furthermore, for a given gross weight the thickness of this outward flowing sheet of air is less for a small-diameter propeller (higher disk loading propeller). The variation of the dynamic-pressure flow field for single and dual propellers or rotors is significantly different in the plane of symmetry between the two rotors than in a direction normal to this plane. The interaction of the two flows produces a region of upflow in this plane where the fuselage is located, and the decay of the maximum dynamic pressure with distance ahead of the fuselage is slower.

O'Bryan, Thomas C.↗

Enhanced simulation software for rocket turbopump, turbulent, annular liquid seals

One of the main objectives of this work is to develop a new dynamic analysis for liquid annular seals with arbitrary profile and to analyze a general distorted interstage seal of the space shuttle main engine high pressure oxygen turbopump (SSME-ATD-HPOTP). The dynamic analysis developed is based on a method originally proposed by Nelson and Nguyen. A simpler scheme based on cubic splines is found to be computationally more efficient and has better convergence properties at higher eccentricities. The first order solution of the original analysis is modified by including a more exact solution that takes into account the variation of perturbed variables along the circumference. A new set of equations for dynamic analysis are derived based on this more general model. A unified solution procedure that is valid for both Moody's and Hirs' friction models is presented. Dynamic analysis is developed for three different models: constant properties, variable properties, and thermal effects with variable properties. Arbitrarily varying seal profiles in both axial and circumferential directions are considered. An example case of an elliptical seal with varying degrees of axial curvature is analyzed in detail. A case study based on predicted clearances of an interstage seal of the SSME-ATD-HPOTP is presented. Dynamic coefficients based on external specified load are introduced to analyze seals that support a preload. The other objective of this work is to study the effect of large rotor displacements of SSME-ATD-HPOTP on the dynamics of the annular seal and the resulting transient motion. One task is to identify the magnitude of motion of the rotor about the centered position and establish limits of effectiveness of using current linear models. This task is accomplished by solving the bulk flow model seal governing equations directly for transient seal forces for any given type of motion, including motion with large eccentricities. Based on the above study, an equivalence is established between linearized coefficients based transient motion and the same motion as predicted by the original governing equations. An innovative method is developed to model nonlinearities in an annular seal based on dynamic coefficients computed at various static eccentricities. This method is thoroughly tested for various types of transient motion using bulk flow model results as a benchmark.

Padavala, Satya↗

The thermal environment of transatmospheric vehicles

A transatmospheric vehicle using primarily air-breathing propulsion must fly in the denser part of the atmosphere to achieve adequate acceleration to reach orbital speed. The potentially long ascent times, combined with the need for a low-drag configuration, result in a severe aerothermodynamics environment. To achieve low drag, the vehicle must have a relatively sharp nose and wing leading edges. The ascent peak stagnation point and equilibrium wall temperatures for the wing leading edge can reach values of 4000 K and 3000 K, respectively, for high dynamic pressure trajectories, making some form of mass addition cooling mandatory. The corresponding temperatures during entry are about 1500 K lower. The vehicle windward centerline temperatures are more moderate, however, with values peaking around 1500 K. Therefore, radiative cooling should be effective over large areas of the vehicle. The windward, centerline heat loads are relatively insensitive to the dynamic pressure of the ascent trajectory, in contrast to the stagnation point and wing leading edge. The windward surface entry heat loads are much lower, but depend strongly on the flightpath.

Tauber, Michael E.↗

Robot arm dynamics and control

Variations in total inertia and gravity loads at the joint outputs are treated along with the relative importance of gravity and acceleration-generated reaction torques or forces versus inertia torques or forces. The relation between the dynamical state equations in explicit terms and servoing the manipulator is briefly discussed in the framework of state variable feedback control which also forms the basis of adaptive manipulator control. Exact state equations were determined for total inertia and gravity loads at the joint outputs as a function of joint variables, using the constant inertial and geometric parameters of the individual links defined in the respective link coordinate frames. The range of maximum variations in total inertia and gravity loads at the joint outputs was calculated for both no load and load in the hand. The main result is the construction of a set of greatly simplified state equations which describe the total inertia and gravity load variations at the output of the six joints with an average error of less than 5%.

Bejczy, A. K.↗

Understanding early HIV-1 rebound dynamics following antiretroviral therapy interruption: The importance of effector cell expansion

Most people living with HIV-1 experience rapid viral rebound once antiretroviral therapy is interrupted; however, a small fraction remain in viral remission for an extended duration. Understanding the factors that determine whether viral rebound is likely after treatment interruption can enable the development of optimal treatment regimens and therapeutic interventions to potentially achieve a functional cure for HIV-1. We built upon the theoretical framework proposed by Conway and Perelson to construct dynamic models of virus-immune interactions to study factors that influence viral rebound dynamics. We evaluated these models using viral load data from 24 individuals following antiretroviral therapy interruption. The best-performing model accurately captures the heterogeneity of viral dynamics and highlights the importance of the effector cell expansion rate. Our results show that post-treatment controllers and non-controllers can be distinguished based on the effector cell expansion rate in our models. Furthermore, these results demonstrate the potential of using dynamic models incorporating an effector cell response to understand early viral rebound dynamics post-antiretroviral therapy interruption.

60 APPLIED LIFE SCIENCES↗

Wind Loading on Parabolic Trough Collectors: Wind and Structural Loads Measurements at an Operational Powerplant

Concentrated Solar Power (CSP) is a promising method for using solar power for electricity generation with thermal energy storage for industrial applications. Solar collectors constitute almost 1/3 of the total cost of the power plant. One of the primary drivers of unrealiability of these collectors is wind-driven loading of mirrors, support structures, and drives. To date, the design of the solar collector structures has relied on data from wind tunnels that do not adequately capture the dynamic effects observed at scale. NREL initiated a field measurement campaign at the operational Nevada Solar One (NSO) parabolic trough powerplant. At this plant, parabolic trough solar collectors track the sun from east to west in the course of a day and face varying wind loads depending on the wind properties and the angle of the troughs. The aim of the project is a detailed characterization of prevailing wind and turbulence conditions and resulting operational loads on parabolic troughs, providing insights into structural dynamic response, and generating a comprehensive wind-loading dataset for validating simulations of wind loading on collector structures. The measurements at NSO consist of sonic anemometers on masts at different heights to characterize the incoming flow and conditions at four trough rows at the edge of the trough field. In addition, a Doppler Lidar scans the horizontal plane above the troughs. The wind measurements at NSO have been continuously collecting data since October 2021 and are combined with structural load measurements that started in November 2022. The load measurements were installed on the same four outermost trough rows and include support structure bending moments, drive torque moments, dynamic accelerations of the spaceframe, mirror displacement, and tilt angles. Measurements are planned to continue until May 2023, providing a first-of-a-kind, high-resolution multi-month dataset of combined wind and load measurements. In this presentation, we show first results of the measurement campaign. Based on the measurements, we identified three main factors altering the flow over the parabolic troughs: Wind speed, wind direction, and the angle of the parabolic troughs. Most interactions between incoming wind and the trough field are observed when the wind blows perpendicular to the trough rows. In this case, the first rows experience the highest wind speed and block the downwind rows, creating conditions with decreased wind speed and enhanced turbulence within the trough field. Also, turbulent length scales are smaller after the first row. This leads to the highest static loads (bending and torque moments) at the first row but potentially increased dynamic loads within the field. We illustrate our findings with case studies focused on different wind conditions and will present fatigue analysis to highlight the impact of wind-driven loads on collector structures.

CSP collectors↗

A summary of current research in rotor unsteady aerodynamics with emphasis on work at Langley Research Center

The basic unsteady aerodynamic environment of the rotary wing is summarized. Some of the observed trends in the state of the art are discussed. Some of the research needs that will require attention are reported. A review of a number of research investigations as a part of a joint NASA/Army rotorcraft project is presented. The research is directed toward achieving a better understanding of rotor unsteady airfoils. The investigations include: (1) rotor maneuver loads; (2) level flight and maneuver wake prediction; (3) tip-vortex flow; (4) blade-vortex interactions; (5) dynamic stall; (6) transient Mach number air loads; and (7) development of variable geometry rotors.

Ward, J. F.↗

On the track of practical forward-swept wings

Structural laminates which comprise wing-cover skins for forward swept winged aircraft are examined. The laminates are themselves composed of lamina arranged in a symmetrical and unbalanced fashion. The fibers are oriented so that no fiber has a counterpart in the same ply which is at an exact anti-angle to itself. The laminate orientation creates a wash-out in a forward swept wing and alleviates aeroelastic loading. Further discussion is devoted to center-of-pressure movement, flutter behavior, aeroelasticity and aeroelastic divergence, and wind tunnel testing of aerodynamically tailored wings. It is found that rotating the laminate to increase the divergence dynamic pressure decreases strain under aerodynamic loading. Flight tests with three models are reported, and it is concluded that divergence can be avoided by the use of an efficient composite structure.

Hertz, T. J.↗

Tank Investigation of a Powered Dynamic Model of a Large Long-Range Flying Boat

Principles for designing the optimum hull for a large long-range flying boat to meet the requirements of seaworthiness, minimum drag, and ability to take off and land at all operational gross loads were incorporated in a 1/12-size powered dynamic model of a four-engine transport flying boat having a design gross load of 165,000 pounds. These design principles included the selection of a moderate beam loading, ample forebody length, sufficient depth of step, and close adherence to the form of a streamline body. The aerodynamic and hydrodynamic characteristics of the model were investigated in Langley tank no. 1. Tests were made to determine the minimum allowable depth of step for adequate landing stability, the suitability of the fore-and-aft location of the step, the take-off performance, the spray characteristics, and the effects of simple spray-control devices. The application of the design criterions used and test results should be useful in the preliminary design of similar large flying boats.

Parkinson, John B↗

An improved CAMRAD model for aeroelastic stability analysis of the XV-15 with advanced technology blades

In pursuit of higher performance, the XV-15 Tiltrotor Research Aircraft was modified by the installation of new composite rotor blades. Initial flights with the Advanced Technology Blades (ATB's) revealed excessive rotor control loads that were traced to a dynamic mismatch between the blades and the aircraft control system. The analytical models of both the blades and the mechanical controls were extensively revised for use by the CAMRAD computer program to better predict aeroelastic stability and loads. This report documents the most important revisions and discusses their effects on aeroelastic stability predictions for airplane-mode flight. The ATB's may be flown in several different configurations for research, including changes in blade sweep and tip twist. The effects on stability of 1 deg and 0 deg sweep are illustrated, as are those of twisted and zero-twist tips. This report also discusses the effects of stiffening the rotor control system, which was done by locking out lateral cyclic swashplate motion with shims.

Acree, C. W., Jr.↗

Effects of state recovery on creep buckling under variable loading

Structural alloys embody internal mechanisms that allow recovery of state with varying stress and elevated temperature, i.e., they can return to a softer state following periods of hardening. Such material behavior is known to strongly influence structural response under some important thermomechanical loadings, for example, that involving thermal ratchetting. The influence of dynamic and thermal recovery on the creep buckling of a column under variable loading is investigated. The column is taken as the idealized (Shanley) sandwich column. The constitutive model, unlike the commonly employed Norton creep model, incorporates a representation of both dynamic and thermal (state) recovery. The material parameters of the constitutive model are chosen to characterize Narloy Z, a representative copper alloy used in thrust nozzle liners of reusable rocket engines. Variable loading histories include rapid cyclic unloading/reloading sequences and intermittent reductions of load for extended periods of time; these are superimposed on a constant load. The calculated results show that state recovery significantly affects creep buckling under variable loading. Structural alloys embody internal mechanisms that allow recovery of state with varying stress and time.

Robinson, D. N.↗

Effects of state recovery on creep buckling under variable loading

Structural alloys embody internal mechanisms that allow recovery of state with varying stress and elevated temperature, i.e., they can return to a softer state following periods of hardening. Such material behavior is known to strongly influence structural response under some important thermomechanical loadings, for example, that involving thermal ratchetting. The influence of dynamic and thermal recovery on the creep buckling of a column under variable loading is investigated. The column is taken as the idealized (Shanley) sandwich column. The constitutive model, unlike the commonly employed Norton creep model, incorporates a representation of both dynamic and thermal (state) recovery. The material parameters of the constitutive model are chosen to characterize Narloy Z, a representative copper alloy used in thrust nozzle liners of reusable rocket engines. Variable loading histories include rapid cyclic unloading/reloading sequences and intermittent reductions of load for extended periods of time; these are superimposed on a constant load. The calculated results show that state recovery significantly affects creep buckling under variable loading.

Robinson, D. N.↗

Effects of state recovery on creep buckling under variable loading

Structural alloys embody internal mechanisms that allow recovery of state with varying stress and elevated temperature, i.e., they can return to a softer state following periods of hardening. Such material behavior is known to strongly influence structural response under some important thermomechanical loadings, for example, that involving thermal ratchetting. The influence of dynamic and thermal recovery on the creep buckling of a column under variable loading is investigated. The column is taken as the idealized (Shanley) sandwich column. The constitutive model, unlike the commonly employed Norton creep model, incorporates a representation of both dynamic and thermal (state) recovery. The material parameters of the constitutive model are chosen to characterize Narloy Z, a representative copper alloy used in thrust nozzle liners of reusable rocket engines. Variable loading histories include rapid cyclic unloading/reloading sequences and intermittent reductions of load for extended periods of time; these are superimposed on a constant load. The calculated results show that state recovery significantly affects creep buckling under variable loading.

Robinson, D. N.↗

Steady-state and dynamic evaluation of the electric propulsion system test bed vehicle on a road load simulator

The propulsion system of the Lewis Research Center's electric propulsion system test bed vehicle was tested on the road load simulator under the DOE Electric and Hybrid Vehicle Program. This propulsion system, consisting of a series-wound dc motor controlled by an infinitely variable SCR chopper and an 84-V battery pack, is typical of those used in electric vehicles made in 1976. Steady-state tests were conducted over a wide range of differential output torques and vehicle speeds. Efficiencies of all of the components were determined. Effects of temperature and voltage variations on the motor and the effect of voltage changes on the controller were examined. Energy consumption and energy efficiency for the system were determined over the B and C driving schedules of the SAE J227a test procedure.

Dustin, M. O.↗