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At least 1,657 records · Page 92

Characterization of Oxygenaceous Species Formed by Exposure of Ag(111) to Atomic Oxygen

The uptake and chemical speciation of oxygen in and on Ag(111) surface is described herein. An Ag(111) surface was exposed to gas-phase oxygen atoms under ultrahigh vacuum compatible conditions at various surface temperatures. The O uptake was quantified using temperature-programmed desorption measurements and showed that oxygen exposures at temperatures above 500 K yielded only surface-adsorbed oxygen in a single surface reconstruction. At temperatures below 500 K, O uptake continued past O surface saturation, and a maximum in the uptake with respect to exposure temperature was observed at 450 K. A model where O atoms must diffuse out of subsurface absorption sites to free room for further O describes this observation. The chemical speciation of the oxygenaceous species formed under these conditions was achieved using X-ray photoelectron spectroscopy. These data show that a single O species initially formed on the surface, but at higher coverages, a new, three-dimensional oxygenaceous phase developed. Because of the importance of silver in heterogeneously catalyzed partial oxidation reactions, these results show that oxygen species embedded below the surface plane must be incorporated into accurate models of Ag-surface catalyzed reactions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Two-dimensional plasma density evolution local to the inversion layer during sawtooth crash events using Beam Emission Spectroscopy

Here, we present methods for analyzing Beam Emission Spectroscopy (BES) data to obtain the plasma density evolution associated with rapid sawtooth crash events at the DIII-D tokamak. BES allows coverage over a 2D spatial plane, inherently local measurements, with fast time responses, and, therefore, provides a valuable new channel for data during sawtooth events. A method is developed to remove sawtooth-induced edge-light pulses contained in the BES data. The edge light pulses appear to be from the D α emission produced by edge recycling during sawtooth events, and are large enough that traditional spectroscopic filtering and data analysis techniques are insufficient to deduce physically meaningful quantities. A cross-calibration of 64 BES channels is performed by using a novel method to ensure accurate measurements. For the large-amplitude density oscillations observed, we discuss and use the non-linear relationship between the BES signal δI/ I 0 and the plasma density variation δn e / n e0 . The 2D BES images cover an 8 × 20 cm 2 region around the sawtooth inversion layer and show large-amplitude density oscillations, with additional significant spatial variations across the inversion layer that grows and peaks near the time of the temperature crash. The edge light removal technique and method of converting large-amplitude δI/ I 0 to δn e / n e0 presented here may help analyze other impulsive MHD phenomena in tokamaks.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

A new generation of effective core potentials: Selected lanthanides and heavy elements

Here, we construct correlation-consistent effective core potentials (ccECPs) for a selected set of heavy atoms and ƒ-elements that are of significant current interest in materials and chemical applications, including Y, Zr, Nb, Rh, Ta, Re, Pt, Gd, and Tb. As is customary, ccECPs consist of spin orbit averaged relativistic effective potential (AREP) and effective spin-orbit (SO) terms. For the AREP part, our constructions are carried out within a relativistic coupled-cluster framework while also taking into account objective function one-particle characteristics for improved convergence in optimizations. The transferability is adjusted using binding curves of hydride and oxide molecules. We address the difficulties encountered with ƒ-elements, such as the presence of large cores and multiple near-degeneracies of excited levels. For these elements, we construct ccECPs with core valence partitioning that includes 4ƒ-subshell in the valence space. The developed ccECPs achieve an excellent balance between accuracy, size of the valence space, and transferability and are also suitable to be used in plane wave codes with reasonable energy cutoffs.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Pressure evolution equation for the particulate phase in inhomogeneous compressible disperse multiphase flows

An analytical expression describing the unsteady pressure evolution of the dispersed phase driven by variations in the carrier phase is presented. In this article, the term “dispersed phase” represents rigid particles, droplets, or bubbles. Letting both the dispersed and continuous phases be inhomogeneous, unsteady, and compressible, the developed pressure equation describes the particle response and its eventual equilibration with that of the carrier fluid. The study involves impingement of a plane traveling wave of a given frequency and subsequent volume-averaged particle pressure calculation due to a single wave. The ambient or continuous fluid's pressure and density-weighted normal velocity are identified as the source terms governing the particle pressure. Analogous to the generalized Faxén theorem, which is applicable to the particle equation of motion, the pressure expression is also written in terms of the surface average of time-varying incoming flow properties. The surface average allows the current formulation to be generalized for any complex incident flow, including situations where the particle size is comparable to that of the incoming flow. Further, the particle pressure is also found to depend on the dispersed-to-continuous fluid density ratio and speed of sound ratio in addition to dynamic viscosities of both fluids. The model is applied to predict the unsteady pressure variation inside an aluminum particle subjected to normal shock waves. The results are compared against numerical simulations and found to be in good agreement. Furthermore, it is shown that, although the analysis is conducted in the limit of negligible flow Reynolds and Mach numbers, it can be used to compute the density and volume of the dispersed phase to reasonable accuracy. Finally, analogous to the pressure evolution expression, an equation describing the time-dependent particle radius is deduced and is shown to reduce to the Rayleigh-Plesset equation in the linear limit.

42 ENGINEERING↗

Necessary and sufficient conditions for resonant mixing of plane waves in elastic solids with quadratic nonlinearity

This paper studies the interactions of two plane waves in elastic solids with quadratic nonlinearity. In particular, the necessary and sufficient conditions for resonant mixing of two plane waves are derived. It is shown that the conventional resonance condition for resonant mixing of plane waves is only a necessary condition, not sufficient. Based on the newly derived necessary and sufficient conditions, resonant mixing of various types of plane waves are investigated and specific conditions for generating a resonant mixed wave are obtained for each case. These results are useful for developing nonlinear ultrasonic nondestructive evaluation techniques using the wave mixing method.

Gao, Xiang↗

Results from the DarkSide-50 Dark Matter Experiment

While there is tremendous astrophysical and cosmological evidence for dark matter, its precise nature is one of the most significant open questions in modern physics. Weakly interacting massive particles (WIMPs) are a particularly compelling class of dark matter candidates with masses of the order 100 GeV and couplings to ordinary matter at the weak scale. Direct detection experiments are aiming to observe the low energy (<100 keV) scattering of dark matter off normal matter. With the liquid noble technology leading the way in WIMP sensitivity, no conclusive signals have been observed yet. The DarkSide experiment is looking for WIMP dark matter using a liquid argon target in a dual-phase time projection chamber located deep underground at Gran Sasso National Laboratory (LNGS) in Italy. Currently filled with argon obtained from underground sources, which is greatly reduced in radioactive 39Ar, DarkSide-50 recently made the most sensitive measurement of the 39Ar activity in underground argon and used it to set the strongest WIMP dark matter limit using liquid argon to date. This work describes the full chain of analysis used to produce the recent dark matter limit, from reconstruction of raw data to evaluation of the final exclusion curve. The DarkSide- 50 apparatus is described in detail, followed by discussion of the low level reconstruction algorithms. The algorithms are then used to arrive at three broad analysis results: The electroluminescence signals in DarkSide-50 are used to perform a precision measurement of ii longitudinal electron diffusion in liquid argon. A search is performed on the underground argon data to identify the delayed coincidence signature of 85Kr decays to the 85mRb state, a crucial ingredient in the measurement of the 39Ar activity in the underground argon. Finally, a full description of the WIMP search is given, including development of cuts, efficiencies, energy scale, and exclusion curve in the WIMP mass vs. spin-independent WIMP-nucleon scattering cross section plane. This work was supervised by Hanguo Wang and was completed in collaboration with members of the DarkSide collaboration.

79 ASTRONOMY AND ASTROPHYSICS↗

The Super Gaussian Laser Intensity Profile in HYDRA's 3D Laser Ray Trace Package

In this note, the laser focal plane intensity pro le for a beam modeled using the 3D ray trace package in HYDRA is determined. First, the analytical model is developed followed by a practical numerical model for evaluating the resulting computationally intensive normalization factor for all possible input parameters.

97 MATHEMATICS AND COMPUTING↗

Further comments on the application of the method of averaging to the study of the rotational motions of a triaxial rigid body, part 3

Variational equations were applied to the case of a rapidly spinning triaxial body moving in an elliptic orbit, in which the orbital plane is regressing at a constant rate. The explicit differential equations obtained in this application were integrated by the method of averaging to develop secular analytical expressions, which, to first-order in a small parameter, describe the complete space motions of the rigid body under the influence of nonresonant gravity-gradient perturbations. The effects of aerodynamic torque on the rotational motion of an orbiting satellite are studied, as another example of the application of the variational equations derived and the method of averaging.

Liu, J. J. F.↗

Reflection of a shock wave from a thermally accommodating wall - Molecular simulation.

Reflection of a plane shock wave from a wall has been simulated on a microscopic scale using a direct simulation Monte Carlo technique of the type developed by Bird. A monatomic gas model representing argon was used to describe the fluid medium and a simple one-parameter accommodation coefficient model was used to describe the gas-surface interaction. The influence of surface accommodation was studied parametrically by varying the accommodation coefficient from zero to one. Results are presented showing the temporal variations of flow field density, and mass, momentum, and energy fluxes to the wall during the shock wave reflection process. The energy flux was used to determine the wall temperature history. Comparisons with experiment are found to be satisfactory where data are available.

Deiwert, G. S.↗

Finite-difference theory for sound propagation in a lined duct with uniform flow using the wave envelope concept

Finite difference equations are derived for sound propagation in a two dimensional, straight, soft wall duct with a uniform flow by using the wave envelope concept. This concept reduces the required number of finite difference grid points by one to two orders of magnitude depending on the length of the duct and the frequency of the sound. The governing acoustic difference equations in complex notation are derived. An exit condition is developed that allows a duct of finite length to simulate the wave propagation in an infinitely long duct. Sample calculations presented for a plane wave incident upon the acoustic liner show the numerical theory to be in good agreement with closed form analytical theory. Complete pressure and velocity printouts are given to some sample problems and can be used to debug and check future computer programs.

Baumeister, K. J.↗

Recent high energy gamma-ray results from SAS-2

Recent developments in gamma-ray astronomy due to the results from SAS-2 have focused on two areas. First, the emission from the plane of the Galaxy is the dominant feature in the gamma-ray sky. The galactic latitude and longitude distributions are consistent with the concept that the high-energy radiation originates from cosmic rays interacting with interstellar matter, and the measurements support a galactic origin for cosmic rays. Second, searches of the SAS-2 data for emission from localized sources have shown three strong discrete gamma-ray sources: the Crab nebula and PSR 0531 + 21, the Vela supernova remnant and PSR 0833-45, and a source near galactic coordinates 193 deg longitude, +3 deg latitude, which does not appear to be associated with other known celestial objects. Evidence has also been found for pulsed gamma-ray emission from two other radio pulsars, PSR 1818-04 and PSR 1747-46. A localized source near longitudes 76-80 deg may be associated with the X-ray source Cyg X-3.

Thompson, D. J.↗

Developing flow in S-shaped ducts. 1: Square cross-section duct

Laser-Doppler velocimetry was used to measure the laminar and turbulent flow in an S-duct formed with two 22.5 deg sectors of a bend with ratio of mean radius of curvature to hydraulic diameter of 7.0. The boundary layers at the inlet to the bend were about 25% and 15% of the hydraulic diameter for the laminar and turbulent flows, respectively. Pressure-driven secondary flows develop in the first half of the S-duct and persist into the second half but are largely reversed by the exit plane as a consequence of the change in the sense of curvature. There is, however, a region near the outer wall of the second bend where the redistribution of the streamwise isotachs results in a reinforcement of the secondary flow which was established in the first half of the S-duct. The net redistribution of the streamwise isotachs is comparable to that occurring in unidirectional bends of stronger curvature. The wall pressure distribution was also measured for the turbulent flow and quantifies the expected large variations in the longitudinal pressure gradient distributions which occur at different radial locations.

Taylor, A. M. K. P.↗

High frequency scattering by a thin dielectric slab

The geometrical theory of diffraction (GTD) is applied to the problem of a source in the presence of a three-dimensional thin dielectric slab. It is assumed that the reflection and transmission properties of the slab are known, and the slab is not lossy and/or multilayered. Two-dimensional thin dielectric layer scattering is analyzed when diffraction emanates from a single point, the source is not near the slab, and random energy approaching tangentially due to transmission is negligible. Coefficients are obtained for the scattering and the GTD solution is extended to the three dimensional case after development of a ray fixed coordinate system. The results are applied to a half wavelength dipole mounted above a square polystyrene covered ground plane.

Burnside, W. D.↗

Near-infrared linear array spectrometer for space applications

A 128-element InSb linear detector array read out with a field effect transistor (FET) multiplexing scheme has been developed at the Jet Propulsion Laboratory. State-of-the-art NEP, uniform response, on-detector charge integration, and very low focal plane heat load compared to that of discrete detector arrays allows this type of array to open new possibilities for spaceborne near-infrared imaging spectrometers. Large number of cooled detector elements are feasible with the new technology, making it practical to design sensitive spectrometers even for spinning spacecraft where simultaneous wavelength coverage is necessary to avoid confusion of spatial with spectral variations.

Apt, J.↗

Large-scale Bubble Structure of the Intersteller Medium (ISM) and Properties of the Local Spiral Arm (LSA)

Bubbles which are very common structure units in the Galaxy and galaxies were examined. Collection of radio, optical, infrared and X-ray observations of the Cyg superbubble (CSB) region of the sky show that the CSB is not a single bubble object. Between 50 to 75 percent of its X-ray emission is ascribed to discrete sources. The other 25 to 50% X-ray emission, probably originates from bubbles around 8 OB associations of the region. All bubbles located within the spiral structure of Galaxy, M31 and M33 have diameter 300 pc. The large distance of stellar association from the galactic plane (GP) combined with picture of the gas distribution within the LSA shows that a Reyleigh-Taylor instability in the LSA can develop and give use to the formation of compact stellar clusters, such as the Cyg OB2 association. Development stages of the Reyleigh-Taylor instability, some peculiarities of the dust distribution and departures of the local structure from the galactic grand design suggest the absence of a spiral shockwave in the LSA.

Bochkarev, N. G.↗

Three-Dimensional Radiative-Transfer Equation

Progress made toward interpretation of radiometric observations. Paper discusses equation of radiative transfer in three-dimensional, inhomogeneous, scattering medium illuminated from above and bounded below by laterallyinhomogeneous, reflective plane. Representation of radiation field with full three-dimensional variability derived by use of spatial Fourier transform and matrix-operator techniques developed previously for one-dimensional version of problem. Equations useful for radiometric measurements from aircraft and spacecraft. Although derivations and resulting equations complicated, use of Fourier-transform, matrix-operator approach to solve practical problems simpler than direct solution of complete three-dimensional, linear wave equations.

Martonchik, J. V.↗

Experiments on supersonic turbulent flow development in a square duct

The nature of supersonic, turbulent, adiabatic-wall flow in a square duct is investigated experimentally over a development length of x/D between 0 and 20 for a uniform flow, Mach 3.9 condition at the duct inlet. Initial discussion centers on the duct configuration itself, which was designed specifically to minimize wave effects and nozzle-induced distortion in the flow. Total pressure contours and local skin friction coefficient distributions are presented which show that the flow develops in a manner similar to that observed for the incompressible case. In particular, undulations exist in total pressure contours within the cross plane and in transverse skin friction coefficient distributions, which are indicative of the presence of a well-defined secondary flow superimposed upon the primary flow. The results are analyzed to show that local law-of-the-wall behavior extends well into the corner region, which implies that wall functions conventionally applied in two-equation type turbulence models, when suitably defined for compressible flow, may also be applied to supersonic streamwise corner flows.

Gessner, F. B.↗

Large-scale wind turbine structures

The purpose of this presentation is to show how structural technology was applied in the design of modern wind turbines, which were recently brought to an advanced stage of development as sources of renewable power. Wind turbine structures present many difficult problems because they are relatively slender and flexible; subject to vibration and aeroelastic instabilities; acted upon by loads which are often nondeterministic; operated continuously with little maintenance in all weather; and dominated by life-cycle cost considerations. Progress in horizontal-axis wind turbines (HAWT) development was paced by progress in the understanding of structural loads, modeling of structural dynamic response, and designing of innovative structural response. During the past 15 years a series of large HAWTs was developed. This has culminated in the recent completion of the world's largest operating wind turbine, the 3.2 MW Mod-5B power plane installed on the island of Oahu, Hawaii. Some of the applications of structures technology to wind turbine will be illustrated by referring to the Mod-5B design. First, a video overview will be presented to provide familiarization with the Mod-5B project and the important components of the wind turbine system. Next, the structural requirements for large-scale wind turbines will be discussed, emphasizing the difficult fatigue-life requirements. Finally, the procedures used to design the structure will be presented, including the use of the fracture mechanics approach for determining allowable fatigue stresses.

Spera, David A.↗