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At least 1,657 records · Page 92

Upper limits for the ethyl-cyanide abundances in TMC-1 and L134N - Chemical implications

Interstellar ethyl-cyanide has been sought via its 2(02)-1(01) transition towards two cold, dark clouds, and upper limits of the total column densities of 3 x 10 to the 12th/sq cm and 2 x 10 to the 12th/sq cm for TMC-1 and L134N, respectively. The 2(02)-1(01) transition of vynil cyanide, previously identified in TMC-1 by Matthews and Sears (1983b), was also observed. The detection of vinyl cyanide and the nondetection of ethyl cyanide in TMC-1 are consistent with gas phase ion-molecule chemical models, and there is thus no necessity of invoking grain surface synthesis for vinyl cyanide in cold clouds.

Minh, Y. C.↗

Isolating the effect of biomass burning aerosol emissions on 20th century hydroclimate in South America and Southeast Asia

Abstract Biomass burning is a significant source of aerosol emissions in some regions and has a considerable impact on regional climate. Earth system model simulations indicate that increased biomass burning aerosol emissions contributed to statistically significant decreases in tropical precipitation over the 20th century. In this study, we use the Community Earth System Model version 1 Large Ensemble (CESM1-LENS) experiment to evaluate the mechanisms by which biomass burning aerosol contributed to decreased tropical precipitation, with a focus on South America and Southeast Asia. We analyze the all-but-one forcing simulations in which biomass burning aerosol emissions are held constant while other forcings (e.g., greenhouse gas concentrations) vary throughout the 20th century. This allows us to isolate the influence of biomass burning aerosol on processes that contribute to decreasing precipitation, including cloud microphysics, the radiative effects of absorbing aerosol particles, and alterations in regional circulation. We also show that the 20th century reduction in precipitation identified in the CESM1-LENS historical and biomass burning experiments is consistent across Coupled Model Intercomparison Project Phase 5 models with interactive aerosol schemes and the CESM2 single-forcing experiment. Our results demonstrate that higher concentrations of biomass burning aerosol increases the quantity of cloud condensation nuclei and cloud droplets, limiting cloud droplet size and precipitation formation. Additionally, absorbing aerosols (e.g., black carbon) contribute to a warmer cloud layer, which promotes cloud evaporation, increases atmospheric stability, and alters regional circulation patterns. Corresponding convectively coupled circulation responses, particularly over the tropical Andes, contribute to further reducing the flow of moisture and moisture convergence over tropical land. These results elucidate the processes that affect the water cycle in regions prone to biomass burning and inform our understanding of how future changes in aerosol emissions may impact tropical precipitation over the 21st century.

Environmental Sciences & Ecology↗

Remote sensing of the atmospheric aerosols and noctilucent clouds from space

The method for the determination of the optical density of tropospheric and mesospheric aerosols and for the estimation of the scattering phase function in the forward directions (0 to 30 deg) is proposed. The method is based on measurements of the brightness of the twilight horizon with the high resolution limb camera having five separated fields of view. In some detail the features of the camera are described and the mathematical aspects of remote sensing data inversion are discussed.

Avaste, O.↗

Org Areo Boreal Forest Sources, compositions and properties of newly formed and regional organic aerosol in a boreal forest during the Biogenic Aerosol: Effects on Clouds and Climate Campaign

The major goals of this project were to make unique measurements, as part of the DOE sponsored Biogenic Aerosol Effects on Clouds and Climate (BAECC) campaign, of the volatility and molecular composition of organic aerosol, as well as gas-phase concentrations of oxygenated organic compounds that interact and affect organic aerosol. In addition, we aimed to conduct a similar set of measurements as part of a collaborative set of environmental simulation chamber experiments at PNNL, the aim of which was to simulate the atmospheric oxidation of key biogenic volatile organic compounds (BVOC) and study the associated formation and evolution of secondary organic aerosol (SOA). The target BVOC were a set of monoterpenes, isoprene, and related intermediates such as IEPOX. The ultimate goal of such measurements are to develop a more detailed mechanistic understanding of the sensitivity of SOA mass formation and lifetime to precursor and environmental conditions. Molecular composition and direct volatility measurements provide robust tracers of chemical processing and properties. As such, meeting these goals will allow for stronger constraints on the types of processes and their fundamental descriptions needed to simulate aerosol particle number and size, and cloud nucleating ability in regional and global earth system models.

54 ENVIRONMENTAL SCIENCES↗

Comparison of two droplet sizing systems in an icing wind tunnel

A comparison between the Phase Doppler Analyzer and the combined measurements from the Particle Measuring Systems Forward Scattering Spectrometer Probe and the Optical Array Probe was conducted in an icing wind tunnel using NASA Icing Research Tunnel spray nozzles to produce the icing cloud. Clouds with a range of volume median diameters from 10 to greater than 50 microns were used for the instrument comparisons. A comparison of the volume median diameter from the Phase Doppler Particle Analyzer and only the Forward Scattering Spectrometer Probe indicated agreement up to 18 microns. A combined volume median diameter was calculated from the droplet distribution of the Optical Array Probe and the Forward Scattering Spectrometer Probe. A comparison of the combined volume median diameters and the Phase Doppler Particle Analyzer volume median diameters showed agreement up to 30 microns with the agreement deteriorating rapidly above 30 microns. Droplet distributions from the Phase Doppler Particle Analyzer, the Forward Scattering Spectrometer Probe, and Optical Array Probe are presented.

Oldenburg, J. R.↗

Comparison of two droplet sizing systems in an icing wind tunnel

A comparison between the Phase Doppler Analyzer and the combined measurements from the Particle Measuring Systems Forward Scattering Spectrometer Probe and the Optical Array Probe was conducted in an icing wind tunnel using NASA Icing Research Tunnel spray nozzles to produce the icing cloud. Clouds with a range of volume median diameterss from 10 to greater than 50 microns were used for the instrument comparisons. A comparison of the volume median diameter from the Phase Doppler Particle Analyzer and only the Forward Scattering Spectrometer Probe indicated agreement up to 18 microns. A combined volume median diameter was calculated from the droplet distribution of the Optical Array Probe and the Forward Scattering Spectrometer Probe. A comparison of the combined volume median diameters and the Phase Doppler Particle Analyzer volume median diameters showed agreement up to 30 microns with the agreement deteriorating rapidly above 30 microns. Droplet distributions from the Phase Doppler Particle Analyzer, the Forward Scattering Spectrometer Probe, and Optical Array Probe are presented.

Oldenburg, John R.↗

Evolution of the Large Scale Circulation, Cloud Structure and Regional Water Cycle Associated with the South China Sea Monsoon During May-June, 1998

In this paper, changes in the large-scale circulation, cloud structures and regional water cycle associated with the evolution of the South China Sea (SCS) monsoon in May-June 1998 were investigated using data from the Tropical Rainfall Measuring Mission (TRMM) and field data from the South China Sea Monsoon Experiment (SCSMEX). Results showed that both tropical and extratropical processes strongly influenced the onset and evolution of the SCS monsoon. Prior to the onset of the SCS monsoon, enhanced convective activities associated with the Madden and Julian Oscillation were detected over the Indian Ocean, and the SCS was under the influence of the West Pacific Anticyclone (WPA) with prevailing low level easterlies and suppressed convection. Establishment of low-level westerlies across Indo-China, following the development of a Bay of Bengal depression played an important role in building up convective available potential energy over the SCS. The onset of SCS monsoon appeared to be triggered by the equatorward penetration of extratropical frontal system, which was established over the coastal region of southern China and Taiwan in early May. Convective activities over the SCS were found to vary inversely with those over the Yangtze River Valley (YRV). Analysis of TRMM microwave and precipitation radar data revealed that during the onset phase, convection over the northern SCS consisted of squall-type rain cell embedded in meso-scale complexes similar to extratropical systems. The radar Z-factor intensity indicated that SCS clouds possessed a bimodal distribution, with a pronounced signal (less than 30dBz) at a height of 2-3 km, and another one (less than 25 dBz) at the 8-10 km level, separated by a well-defined melting level indicated by a bright band at around 5-km level. The stratiform-to-convective cloud ratio was approximately 1:1 in the pre-onset phase, but increased to 5:1 in the active phase. Regional water budget calculations indicated that during the active phase, the SCS was a strong sink (E-P much less than 0) of atmospheric moisture, with the primary source of moisture coming from regions further west over Indo-China and the eastern Indian Ocean. Before onset and during the break, the SCS was a moisture source (E-P greater than ) to the overlying atmosphere. In particular, the SCS provided the bulk of moisture to the torrential rain over the YRV in mid-June 1998.

Lau, William K.-M.↗

Cloud Processing of Aerosol during SAIL Field Campaign Report

Globally, on average, the release rate of aerosols from clouds is estimated to be about 6,000 Tg/yr and an aerosol particle is estimated to experience about three cloud cycles. Cloud processing of aerosol produces aerosols that have dramatically different physicochemical properties compared to their original form. Cloud processing may transform particles to efficient cloud condensation nuclei (CCN) or ice nucleating particles (INP) that can further participate in cloud formation. We investigated cloud processing of aerosol during the U.S. Department of Energy (DOE)’s Atmospheric Radiation Measurement (ARM) Surface Atmosphere Integrated Field Laboratory (SAIL) field campaign using multi-modal offline analysis techniques available at DOE’s Environmental Molecular Sciences Laboratory (EMSL). The main scientific aim of this project was to understand the processes that transform aerosols (chemically, and physically), and influence aerosol-cloud interactions. Aerosol particles undergo significant modifications due to warm (cloud droplets) and cold cloud (ice crystals) processing. Cloud processing of aerosol has important effects on the atmospheric aerosol number and mass concentration, size distribution, phase separation, and chemical composition.

54 ENVIRONMENTAL SCIENCES↗

Evaluation of RMI Ejecta Sourcing from Reconstructed Interfaces in 2D FLAG Flyer-Plate Simulations

This study investigates the performance of RMI ejecta sourcing from a reconstructed interface in two-dimensional FLAG ejecta flyer-plate simulations. Enabling the RMI ejecta model to operate on reconstructed interfaces has been a longstanding challenge in FLAG, limiting its applicability to experiments in which interface reconstruction is not required. Addressing this limitation is therefore an important step toward expanding the model’s predictive capability. The first phase of this effort focused on identifying a flyer-plate/target configuration that produces large ejecta clouds from two distinct shocks using the standard RMI ejecta model. A series of simulations examined the effects of flyer composition, layer thickness, and mesh resolution on shock structure and ejecta formation. VISAR traces were used to evaluate shock timing and identify configurations that produced a clear double-shock response. A copper middle-layer flyer with a doubled tin layer yielded the most favorable shock characteristics and was selected as the baseline configuration. After confirming this configuration performed as expected when running a reference FLAG version, it became the basis for three simulations: (1) a standard two-dimensional ejecta flyer-plate calculation using a reference FLAG version, (2) the same calculation with the reconstructed interface option enabled, and (3) a calculation employing ALE strategies to force the ejecta model to operate on the reconstructed interface. While the baseline simulation produced the expected ejecta response, the reconstructed interface approach did not result in measurable ejecta, indicating that this capability remains under development. These results highlight both the progress made and the remaining challenges in extending the RMI ejecta model to reconstructed interfaces.

36 MATERIALS SCIENCE↗

A hot gaseous galaxy halo candidate with Mg X absorption

The hot gas in galaxy halos may account for a significant fraction of missing baryons in galaxies, and some of these gases can be traced by high ionization absorption systems in QSO UV spectra. Using high S/N Hubble Space Telescope/Cosmic Origins Spectrograph spectra, we discovered a high ionization state system at z = 1.1912 in the sightline toward LBQS 1435-0134, and two-component absorption lines are matched for Mg x, Ne viii, Ne vi, O vi, Ne v, O v, Ne iv, O iv, N iv, O iii, and H i. Mg x, detected for the first time (5.8σ), is a particularly direct tracer of hot galactic halos, as its peak ion fraction occurs near 10{sup 6.1} K, about the temperature of a virialized hot galaxy halo of mass ∼0.5M{sup ∗}. With Mg x and Ne viii, a photoionization model cannot reproduce the observed column densities with path lengths of galaxy halos. For collisional ionization models, one or two-temperature models do not produce acceptable fits, but a three-temperature model or a power-law model can produce the observed results. In the power-law model, dN/dT=10{sup 4.4±2.2−[Z/X]}T{sup 1.55±0.41} with temperatures in the range of 10{sup 4.39±0.13} K<T<10{sup 6.04±0.05} K, the total hydrogen column density is 8.2×10{sup 19}(0.3 Z{sub ⊙}/Z) cm{sup −2} and the positive power-law index indicates most of the mass is at the high temperature end. We suggest that this absorption system is a hot volume-filled galaxy halo rather than interaction layers between the hot halo and cool clouds. The temperature dependence of the column density is likely due to the local mixture of multiple phase gases.

79 ASTRONOMY AND ASTROPHYSICS↗

The TESS Phase Curve of KELT-1b Suggests a High Dayside Albedo

We measured the optical phase curve of the transiting brown dwarf KELT-1b (TOI 1476) using data from the TESS spacecraft. We found that KELT-1b shows significant phase variation in the TESS bandpass, with a relatively large phase amplitude of 234{sub −44}{sup +43} ppm and a secondary eclipse depth of 371{sub −49}{sup +47} ppm. We also measured a marginal eastward offset in the dayside hot spot of 18.°3 ± 7.°4 relative to the substellar point. We detected a strong phase-curve signal attributed to ellipsoidal distortion of the host star with an amplitude of 399 ± 19 ppm. Our results are roughly consistent with the Spitzer phase curves of KELT-1b, but the TESS eclipse depth is deeper than expected. Our cloud-free 1D models of KELT-1b’s dayside emission are unable to fit the full combined eclipse spectrum. Instead, the large TESS eclipse depth suggests that KELT-1b may have a significant dayside geometric albedo of A {sub g} ∼ 0.5 in the TESS bandpass, which would agree with the tentative trend between equilibrium temperature and geometric albedo recently suggested by Wong et al. We posit that if KELT-1b has a high dayside albedo, it is likely due to silicate clouds that form on KELT-1b’s nightside and are subsequently transported onto the western side of KELT-1b’s dayside hemisphere before breaking up.

79 ASTRONOMY AND ASTROPHYSICS↗

Spatial distribution of polarization over the disks of Venus, Jupiter, Saturn, and the moon

The method of photographic subtraction, which superposes positive and negative photographs taken with the analyzer rotated through 90 deg, is used to analyze polarization photographs of Venus, Jupiter, Saturn, and the moon. For Venus, near 90 deg phase angle, variation in polarization in ultraviolet light appears to correspond generally with the position of the cloud markings. The northern hemisphere of Saturn shows higher polarization in blue light than does the rest of the planet. The polarization of the moon is shown to deviate significantly from Umov's law for reciprocity of polarization and reflectivity in certain regions.

Fountain, J. W.↗

Polarimetry of satellite surfaces

Available polarization observations of the satellites are reviewed, and the question of what information about satellite surfaces such observations contain is discussed critically. For satellites with negligible atmospheres, polarization measurements should provide useful information on surface texture and on the opacity of the surface materials. However, they are unlikely to yield specific compositional information. For Titan, the only satellite known to have an extensive atmosphere, polarimetry indicates the presence of optically thick clouds; it should be possible to deduce the cloud particle characteristics from such data, especially if more extensive observations, covering the full range of available phase angles and wavelengths, are obtained.

Veverka, J.↗

Studies of proton-irradiated cometary-type ice mixtures

Cometary ice mixtures are studied in a laboratory experiment designed to simulate the temperature, pressure and radiation environments of the interstellar Oort cloud region, in order to test the hypothesized radiation synthesis mechanism for changing the characteristics of the outer few meters of a comet stored in the Oort cloud for 4.6 billion years. All experiments conducted confirm the synthesis of new molecular species in solid phase mixtures at 20 K. When CH4 is present in the irradiated ice mixture, long chained, voltaile hydrocarbon and CO2 are synthesized together with high molecular weight C compounds present in the room temperature residue. Due to radiation synthesis, about 1 percent of the ice was converted into a nonvolatile residue containing complicated C compounds not present in the blank samples. These results suggest that initial molecular abundances can be altered, and new species created, as a result of radiation synthesis. Irradiated mixtures exhibited thermoluminescence and pressure enhancements during warming, showing the synthesis of reactive species. Outbursts in new comets resulting from similar irradiation-induced exothermic activity would be expected to begin occurring at distances of the order of 100 AU.

Moore, M. H.↗

Lidar observations of mixed layer dynamics - Tests of parameterized entrainment models of mixed layer growth rate

Ground based lidar measurements of the atmospheric mixed layer depth, the entrainment zone depth and the wind speed and wind direction were used to test various parameterized entrainment models of mixed layer growth rate. Six case studies under clear air convective conditions over flat terrain in central Illinois are presented. It is shown that surface heating alone accounts for a major portion of the rise of the mixed layer on all days. A new set of entrainment model constants was determined which optimized height predictions for the dataset. Under convective conditions, the shape of the mixed layer height prediction curves closely resembled the observed shapes. Under conditions when significant wind shear was present, the shape of the height prediction curve departed from the data suggesting deficiencies in the parameterization of shear production. Development of small cumulus clouds on top of the layer is shown to affect mixed layer depths in the afternoon growth phase.

Boers, R.↗

Low energy antiprotons from supernova exploding in dense clouds

The antiproton spectrum resulting from a supernova, which exploded inside a dense cloud, is calculated by taking into account all energy loss processes including adiabatic deceleration during the expansion phase. The influence of various energy loss processes on the evolution of the spectrum as the supernova expands is investigated. It is shown that if about 25 percent of the cosmic ray nucleons are from such sources, the observed low energy antiprotons can be explained, provided the effect of solar modulation is not very large. The possibility of obtaining enhanced low energy spectrum by this process is also examined.

Stephens, S. A.↗

Estimates of the bolometric albedos and radiation balance of Uranus and Neptune

Models possessing an upper haze layer of finite optical depth and a lower cloud layer of infinite optical depth at discrete altitudes are used to bound the wavelength-averaged phase integrals and bolometric albedos of Uranus and Neptune. The models differ in the assumed value of the particles' single scattering phase function and the wavelength dependence of the haze optical depth. A range of phase functions, from the isotropic to those characterizing Titan, Jupiter, and Saturn atmosphere particles, are discussed. The results obtained imply that the meteorological regimes in the observable atmospheres of Uranus and Neptune may differ considerably; internal heat flux could play a much more important role for Neptune than for Uranus.

Pollack, J. B.↗

Vertical structure of aerosols and clouds in the atmospheres of Uranus and Neptune: Implications for their heat budgets

Models possessing an upper haze layer of finite optical depth and a lower cloud layer of infinite optical depth at discrete altitudes are used to bound the wavelength-averaged phase integrals and bolometric albedos of Uranus and Neptune. The models differ in the assumed value of the particles single scattering phase function and the wavelength dependence of the haze optical depth. A range of phase functions, from the isotropic to those characterizing Titan, Jupiter, and Saturn atmosphere particles, are discussed. The results obtained imply that the meteorological regimes in the observable atmospheres of Uranus and Neptune may differ considerably; internal heat flux could play a much more important role for Neptune than for Uranus.

Pollack, James B.↗