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At least 1,657 records · Page 92
All sourcesNASA NTRSDOE OSTI
DOE OSTI2019

A new method for in situ structural investigations of nano-sized amorphous and crystalline materials using mixed-flow reactors

Structural investigations of amorphous and nanocrystalline phases forming in solution are historically challenging. Few methods are capable of in situ atomic structural analysis and rigorous control of the system. A mixed-flow reactor (MFR) is used for total X-ray scattering experiments to examine the short- and long-range structure of phases in situ with pair distribution function (PDF) analysis. The adaptable experimental setup enables data collection for a range of different system chemistries, initial supersaturations and residence times. The age of the sample during analysis is controlled by adjusting the flow rate. Faster rates allow for younger samples to be examined, but if flow is too fast not enough data are acquired to average out excess signal noise. Slower flow rates form older samples, but at very slow speeds particles settle and block flow, clogging the system. Proper background collection and subtraction is critical for data optimization. Overall, this MFR method is an ideal scheme for analyzing the in situ structures of phases that form during crystal growth in solution. As a proof of concept, high-resolution total X-ray scattering data of amorphous and crystalline calcium phosphates and amorphous calcium carbonate were collected for PDF analysis.

36 MATERIALS SCIENCE↗
DOE OSTI2016

Tracking the distribution of {sup 26}Al and {sup 60}Fe during the early phases of star and disk evolution

The short-lived {sup 26}Al and {sup 60}Fe radionuclides are synthesized and expelled into the interstellar medium by core-collapse supernova events. The solar system’s first solids, calcium–aluminum refractory inclusions (CAIs), contain evidence for the former presence of the {sup 26} Al nuclide defining the canonical {sup 26}Al/{sup 27} Al ratio of ∼5×10{sup −5}. A different class of objects temporally related to canonical CAIs are CAIs with fractionation and unidentified nuclear effects (FUN CAIs), which record a low initial {sup 26}Al/{sup 27}Al of 10{sup −6}. The contrasting level of {sup 26}Al between these objects is often interpreted as reflecting the admixing of the {sup 26}Al nuclides during the early formative phase of the Sun. We use giant molecular cloud scale adaptive mesh-refinement numerical simulations to trace the abundance of {sup 26}Al and {sup 60}Fe in star-forming gas during the early stages of accretion of individual low-mass protostars. We find that the {sup 26}Al/{sup 27}Al and {sup 60}Fe/{sup 56}Fe ratios of accreting gas within a vicinity of 1000 au of the stars follow the predicted decay curves of the initial abundances at the time of star formation without evidence of spatial or temporal heterogeneities for the first 100 kyr of star formation. Therefore, the observed differences in {sup 26}Al/{sup 27}Al ratios between FUN and canonical CAIs are likely not caused by admixing of supernova material during the early evolution of the proto-Sun. Selective thermal processing of dust grains is a more viable scenario to account for the heterogeneity in {sup 26}Al/{sup 27}Al ratios at the time of solar system formation.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1991

An overview of the NASA electronic components information management system

The NASA Parts Project Office (NPPO) comprehensive data system to support all NASA Electric, Electronic, and Electromechanical (EEE) parts management and technical data requirements is described. A phase delivery approach is adopted, comprising four principal phases. Phases 1 and 2 support Space Station Freedom (SSF) and use a centralized architecture with all data and processing kept on a mainframe computer. Phases 3 and 4 support all NASA centers and projects and implement a distributed system architecture, in which data and processing are shared among networked database servers. The Phase 1 system, which became operational in February of 1990, implements a core set of functions. Phase 2, scheduled for release in 1991, adds functions to the Phase 1 system. Phase 3, to be prototyped beginning in 1991 and delivered in 1992, introduces a distributed system, separate from the Phase 1 and 2 system, with a refined semantic data model. Phase 4 extends the data model and functionality of the Phase 3 system to provide support for the NASA design community, including integration with Computer Aided Design (CAD) environments. Phase 4 is scheduled for prototyping in 1992 to 93 and delivery in 1994.

Kramer, G.↗
DOE OSTI2016

Three-Phase 3D Reconstruction of a LiCoO2 Cathode via FIB-SEM Tomography

Abstract Three-phase three-dimensional (3D) microstructural reconstructions of lithium-ion battery electrodes are critical input for 3D simulations of electrode lithiation/delithiation, which provide a detailed understanding of battery operation. In this report, 3D images of a LiCoO 2 electrode are achieved using focused ion beam-scanning electron microscopy (FIB-SEM), with clear contrast among the three phases: LiCoO 2 particles, carbonaceous phases (carbon and binder) and the electrolyte space. The good contrast was achieved by utilizing an improved FIB-SEM sample preparation method that combined infiltration of the electrolyte space with a low-viscosity silicone resin and triple ion-beam polishing. Morphological parameters quantified include phase volume fraction, surface area, feature size distribution, connectivity, and tortuosity. Electrolyte tortuosity was determined using two different geometric calculations that were in good agreement. The electrolyte tortuosity distribution versus position within the electrode was found to be highly inhomogeneous; this will lead to inhomogeneous electrode lithiation/delithiation at high C-rates that could potentially cause battery degradation.

Liu, Zhao (ORCID:0000000303702406)↗
NASA NTRS1996

Internal loading of an inhomogeneous compressible Earth with phase boundaries

The geoid and the boundary topography caused by mass loads inside the earth were estimated. It is shown that the estimates are affected by compressibility, by a radially varying density distribution, and by the presence of phase boundaries with density discontinuities. The geoid predicted in the chemical boundary case is 30 to 40 percent smaller than that predicted in the phase case. The effects of compressibility and radially varying density are likely to be small. The inner core-outer core topography for loading inside the mantle and for loading inside the inner core were computed.

Defraigne, P.↗
DOE OSTI2013

Ion Exchange Column Tests Supporting Technetium Removal Resin Maturation

The primary treatment of the tank waste at the DOE Hanford site will be done in the Waste Treatment and Immobilization Plant, currently under construction. The baseline plan for this facility is to treat the waste, splitting it into High Level Waste (HLW) and Low Activity Waste (LAW). Both waste streams are then separately vitrified as glass and sealed in canisters. The LAW glass will be disposed on site. There are currently no plans to treat the waste to remove technetium, so its disposition path is the LAW glass. Due to the soluble properties of pertechnetate and long half-life of 99 Tc, effective management of 99 Tc is important. Options are being explored to immobilize the supplemental LAW portion of the tank waste, as well as to examine the volatility of 99 Tc during the vitrification process. Removal of 99 Tc, followed by off-site disposal has potential to reduce treatment and disposal costs. A conceptual flow sheets for supplemental LAW treatment and disposal that could benefit from technetium removal will specifically examine removing 99 Tc from the LAW feed stream to supplemental immobilization. SuperLig® 639 is an elutable ion exchange resin. In the tank waste, 99 Tc is predominantly found in the tank supernate as pertechnetate (TcO 4 - ). Perrhenate (ReO 4 - ) has been shown to be a good non-radioactive surrogate for pertechnetate in laboratory testing for this ion exchange resin. This report contains results of experimental ion exchange distribution coefficient and column resin maturation kinetics testing using the resin SuperLig® 639a to selectively remove perrhenate from simulated LAW. This revision includes results from testing to determine effective resin operating temperature range. Loading tests were performed at 45°C, and the computer modeling was updated to include the temperature effects. Equilibrium contact testing indicated that this batch of SuperLig® 639 resin has good performance, with an average perrhenate distribution coefficient of 291 mL/g at a 100:1 phase ratio. This slightly exceeds the computer-modeled equilibrium distribution. The modeling agreed well with the experimental data for perrhenate removal with minor adjustments. Predicted breakthrough performance was on average within about 20% of measured values.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
NASA NTRS1993

Decay of equatorial ring current ions and associated aeronomical consequences

The decay of the major ion species which constitute the ring current is studied by solving the time evolution of their distribution functions during the recovery phase of a moderate geomagnetic storm. In this work, only equatorially mirroring particles are considered. Particles are assumed to move subject to E x B and gradient drifts. They also experience loses along their drift paths. Two loss mechanisms are considered: charge exchange with neutral hydrogen atoms and Coulomb collisions with thermal plasma in the plasmasphere. Thermal plasma densities are calculated with a plasmaspheric model employing a time-dependent convection electric field model. The drift-loss model successfully reproduces a number of important and observable features in the distribution function. Charge exchange is found to be the major loss mechanism for the ring current ions; however the important effects of Coulomb collisions on both the ring current and thermal populations are also presented. The model predicts the formation of a low-energy (less than 500 eV) ion population as a result of energy degradation caused by Coulomb collision of the ring current ions with the plasmaspheric electrons; this population may be one source of the low-energy ions observed during active and quiet periods in the inner magnetosphere. The energy transferred to plasmaspheric electrons through Coulomb collisions with ring current ions is believed to be the energy source for the electron temperature enhancement and the associated 6300 A (stable auroral red (SAR) arc) emission in the subauroral region. The calculated energy deposition rate is sufficient to produce a subauroral electron temperature enhancement and SAR arc emissions that are consistent with observations of these quantities during moderate magnetic activity levels.

Fok, M.-C.↗
NASA NTRS1988

Particle-laden weakly swirling free jets: Measurements and predictions

A theoretical and experimental investigation of particle-laden, weakly swirling, turbulent free jets was conducted. Glass particles, having a Sauter mean diameter of 39 microns with a standard deviation of 15 microns, were used. A single loading ratio of 0.2 was used in the experiments. Measurements are reported for three swirl numbers, ranging from 0.0 to 0.3. The measurements included mean and fluctuating velocities of both phases, and particle mass flux distributions. Measurements were compared with predictions from three types of multiphase flow analysis: locally homogeneous flow (LHF); deterministic separated flow (DSF); and stochastic separated flow (SSF). For the particle-laden jets, the LHF and DSF models did not provide very satisfactory predictions. The LHF model generally overestimated the rate of decay of particle mean axial and angular velocities with streamwise distance, due to the neglect of particle inertia. The LHF model predictions of particle mass flux also showed poor agreement with measurements due to the assumption of no-slip between phases. The DSF model also performed quite poorly for predictions of particle mass flux, because turbulent dispersion of the particles was neglected. The SSF model, which accounts for both particle inertia and turbulent dispersion of the particles, yielded reasonably good predictions throughout the flow field for the particle-laden jets.

Bulzan, Daniel L.↗
NASA NTRS1988

Particle-laden weakly swirling free jets - Measurements and predictions

A theoretical and experimental investigation of particle-laden, weakly swirling, turbulent free jets was conducted. Glass particles, having a Sauter mean diameter of 39 microns with a standard deviation of 15 microns, were used. A single loading ratio of 0.2 was used in the experiments. Measurements are reported for three swirl numbers, ranging from 0.0 to 0.3. The measurements included mean and fluctuating velocities of both phases, and particle mass flux distributions. Measurements were compared with predictions from three types of multiphase flow analysis: locally homogeneous flow (LHF); deterministic separated flow (DSF); and stochastic separated flow (SSF). For the particle-laden jets, the LHF and DSF models did not provide very satisfactory predictions. The LHF model generally overestimated the rate of decay of particle mean axial and angular velocities with streamwise distance, due to the neglect of particle inertia. The LHF model predictions of particle mass flux also showed poor agreement with measurements due to the assumption of no-slip between phases. The DSF model also performed quite poorly for predictions of particle mass flux, because turbulent dispersion of the particles was neglected. The SSF model, which accounts for both particle inertia and turbulent disperison of the particles, yielded reasonably good predictions throughout the flow field for the particle-laden jets.

Bulzan, Daniel L.↗
DOE OSTI2016

Deformation induced dynamic recrystallization and precipitation strengthening in an Mg−Zn−Mn alloy processed by high strain rate rolling

The microstructure of a high strain-rate rolled Mg−Zn−Mn alloy was investigated by transmission electron microscopy to understand the relationship between the microstructure and mechanical properties. The results indicate that: (1) a bimodal microstructure consisting of the fine dynamic recrystallized grains and the largely deformed grains was formed; (2) a large number of dynamic precipitates including plate-like MgZn{sub 2} phase, spherical MgZn{sub 2} phase and spherical Mn particles distribute uniformly in the grains; (3) the major facets of many plate-like MgZn{sub 2} precipitates deviated several to tens of degrees (3°–30°) from the matrix basal plane. It has been shown that the high strength of the alloy is attributed to the formation of the bimodal microstructure, dynamic precipitation, and the interaction between the dislocations and the dynamic precipitates. - Highlights: •A bimodal microstructure was formed in a high strain-rate rolled Mg−Zn−Mn alloy. •Plate-like MgZn{sub 2}, spherical MgZn{sub 2} and spherical Mn phases were observed. •The major facet of the plate-like MgZn{sub 2} deviated from the matrix basal plane.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Local Sn Dipolar-Character Displacements behind the Low Thermal Conductivity in SnSe Thermoelectric

The local atomic structure of SnSe was characterized across its orthorhmbic-to-orthorhombic structural phase transition using x-ray pair distribution function analysis. Substantial Sn displacements with a dipolar character persist in the high symmetry high temperature phase, albeit with a symmetry different from that of the ordered displacements below the transition. The analysis implies that the transition is neither order-disorder nor displacive, but rather a complex crossover. Robust ferro-coupled SnSe intra-layer distortions suggest a ferroelectric-like instability as the driving force. Furthermore, these local symmetry-lowering Sn displacements are likely integral to the ultra-low lattice thermal conductivity mechanism in SnSe.

36 MATERIALS SCIENCE↗
NASA NTRS1993

Optoelectronic Control Of Phased-Array Antenna

Radiation patterns switched within microseconds. According to concept, digital beam-steering information destined for number of phased antenna elements transmitted in serial multiplex along optical fiber to optoelectronic integrated circuit (OEIC), demultiplexing information into parallel electronic channels to phase shifters associated with various elements. Because of small distances between elements of such arrays, compactness of optical fibers makes them attractive for distribution of beam-steering (phase-shifting) control signals. Also offers advantages of light weight, low attenuation, mechanical flexibility, large bandwidth, and immunity to both crosstalk and electromagnetic interference.

Bhasin, K. B.↗
NASA NTRS2000

Glass/Jamming Transition in Colloidal Aggregation

We have studied colloidal aggregation in a model colloid plus polymer system with short-range attractive interactions. By varying the colloid concentration and the strength of the attraction, we explored regions where the equilibrium phase is expected to consist of colloidal crystallites in coexistance with colloidal gas (i.e. monomers). This occurs for moderate values of the potential depth, U approximately equal to 2-5 kT. Crystallization was not always observed. Rather, over an extended sub-region two new metastable phases appear, one fluid-like and one solid-like. These were examined in detail with light scattering and microscopy techniques. Both phases consist of a near uniform distribution of small irregular shaped clusters of colloidal particles. The dynamical and structural characteristics of the ergodic-nonergodic transition between the two phases share much in common with the colloidal hard sphere glass transition.

Segre, Philip N.↗
NASA NTRS2003

GPS-Like Phasing Control of the Space Solar Power System Transmission Array

The problem of phasing of the Space Solar Power System's transmission array has been addressed by developing a GPS-like radio navigation system. The goal of this system is to provide power transmission phasing control for each node of the array that causes the power signals to add constructively at the ground reception station. The phasing control system operates in a distributed manner, which makes it practical to implement. A leader node and two radio navigation beacons are used to control the power transmission phasing of multiple follower nodes. The necessary one-way communications to the follower nodes are implemented using the RF beacon signals. The phasing control system uses differential carrier phase relative navigation/timing techniques. A special feature of the system is an integer ambiguity resolution procedure that periodically resolves carrier phase cycle count ambiguities via encoding of pseudo-random number codes on the power transmission signals. The system is capable of achieving phasing accuracies on the order of 3 mm down to 0.4 mm depending on whether the radio navigation beacons operate in the L or C bands.

Psiaki, Mark L.↗
NASA NTRS2010

Directivity of a Sparse Array in the Presence of Atmospheric-Induced Phase Fluctuations for Deep Space Communications

Widely distributed (sparse) ground-based arrays have been utilized for decades in the radio science community for imaging celestial objects, but have only recently become an option for deep space communications applications with the advent of the proposed Next Generation Deep Space Network (DSN) array. But whereas in astronomical imaging, observations (receive-mode only) are made on the order of minutes to hours and atmospheric-induced aberrations can be mostly corrected for in post-processing, communications applications require transmit capabilities and real-time corrections over time scales as short as fractions of a second. This presents an unavoidable problem with the use of sparse arrays for deep space communications at Ka-band which has yet to be successfully resolved, particularly for uplink arraying. In this paper, an analysis of the performance of a sparse antenna array, in terms of its directivity, is performed to derive a closed form solution to the expected array loss in the presence of atmospheric-induced phase fluctuations. The theoretical derivation for array directivity degradation is validated with interferometric measurements for a two-element array taken at Goldstone, California. With the validity of the model established, an arbitrary 27-element array geometry is defined at Goldstone, California, to ascertain its performance in the presence of phase fluctuations. It is concluded that a combination of compact array geometry and atmospheric compensation is necessary to ensure high levels of availability.

Nessel, James A.↗
DOE OSTI2018

Power Hardware-in-the-Loop Testing of a Smart Distribution System

This paper presents the results of the third and final phase of the National Renewable Energy Lab (NREL) INTEGRATE demonstration: Smart Distribution. For this demonstration, high penetrations of solar PV and wind energy systems were simulated in a power hardware-in-the-loop set-up using a smart distribution test feeder. Simulated and real DERs were controlled by a real-time control platform, which manages grid constraints under high clean energy deployment levels. The power HIL testing, conducted at NREL's ESIF smart power lab, demonstrated how dynamically managing DER increases the grid's hosting capacity by leveraging active network management's (ANM) safe and reliable control framework. Results are presented for how ANM's real-time monitoring, automation, and control can be used to manage multiple DERs and multiple constraints associated with high penetrations of DER on a distribution grid. The project also successfully demonstrated the importance of escalating control actions given how ANM enables operation of grid equipment closer to their actual physical limit in the presence of very high levels of intermittent DER.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2021

Distributed Thermal Response Multi-Source Modeling to Evaluate Heterogeneous Subsurface Properties

A thorough assessment of thermal properties in heterogeneous subsurface is necessary in design of low-temperature borehole heat exchangers (BHEs). For this study, a distributed thermal response test (DTRT), which combines distributed temperature sensing (DTS) with a conventional thermal response test (TRT), was conducted in a U-bend geothermal loop installed in an open borehole at the University of Illinois at Urbana-Champaign to estimate thermal properties by analyzing the thermal response of different geologic materials while applying a constant heat input rate. Fiber-optic cables in the DTRT were deployed both inside the U-bend geothermal loop and in the center of the borehole to improve the accuracy of calculated heat-loss rates and borehole temperature profile measurements. To assess the subsurface thermal conductivity during the heating phase of the DTRT, a single-source model and a multi-source model, both based on the infinite line source method, were developed using the borehole temperature data and temperatures inside and along the outside of the loop, separately. The two models returned similar thermal conductivity values. The multi-source modeling has the advantage of predicting the thermal conductivity of heterogeneous geologic materials from borehole temperature profiles during the DTRT heating phase. Additionally, based on the distributed thermal conductivity measured in the borehole, estimates were made for both radial thermal impacts and the rate of heat loss in the BHE.

58 GEOSCIENCES↗
DOE OSTI2019

Microstructural Analysis of Powder Metallurgy Tool Steels in the Context of Abrasive Wear Behavior: A New Computerized Approach to Stereology

The present work describes a new methodology designed to characterize the microstructures of tool steels containing carbide hard phases, with the focus set on their abrasive wear resistance. A series of algorithms were designed and implemented in MATLAB® to (i) recognize each of the features of interest, (ii) measure relevant quantities and (iii) characterize each of the phases and the alloy in function of attributes usually neglected in wear description applications: size distribution, shape and contiguity of the hard phases. The new framework incorporates new parameters to describe each one of these attributes, as observed in SEM micrographs. All three aforementioned stages contain novel contributions that can be potentially beneficial to the field of materials design in general and to the field of alloy design for severely abrasive environments in particular. Models of known geometry and micrographs of different powder metallurgy steels were analyzed, and the obtained results were compared with the obtained by the linear intercept method. The relation between the new parameters and the ones available in the scientific literature is also discussed.

36 MATERIALS SCIENCE↗