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At least 1,657 records · Page 92
All sourcesNASA NTRSDOE OSTI
NASA NTRS2011

Production of Organic Grain Coatings by Surface-Mediated Reactions and the Consequences of This Process for Meteoritic Constituents

When hydrogen, nitrogen and CO are exposed to amorphous iron silicate surfaces at temperatures between 500 - 900K, a carbonaceous coating forms via Fischer-Tropsch type reactions. Under normal circumstances such a catalytic coating would impede or stop further reaction. However, we find that this coating is a better catalyst than the amorphous iron silicates that initiate these reactions. The formation of a self-perpetuating catalytic coating on grain surfaces could explain the rich deposits of macromolecular carbon found in primitive meteorites and would imply that protostellar nebulae should be rich in organic material. Many more experiments are needed to understand this chemical system and its application to protostellar nebulae.

Nuth, Joseph A., III↗
NASA NTRS2011

Ion-Ice Astrochemistry: Barrierless Low-Energy Deposition Pathways to HCOOH, CH3OH, and CO2 on Icy Grain Mantles from Precursor Cations

A new family of very favorable reaction pathways is explored involving the deposition of ions on icy grain mantles with very low energies. Quantum chemical cluster calculations at the MP2/6-31+G** level in 4H2O clusters and at the B3LYP/6-31+G** level in 17H2O clusters indicate that HCO+ and CH3 + are able to react spontaneously with one of the water molecules in the cluster to form protonated formic acid (HCOOH2 +) and protonated methanol (CH3OH2 +), respectively. It is furthermore found that these initial adducts spontaneously transfer their excess protons to the cluster to form neutral formic acid and methanol, plus solvated hydronium, H3O+. In the final case, if a CO molecule is bound to the surface of the cluster, OH+ may react with it to form protonated carbon dioxide (HCO2 +), which then loses its proton to yield CO2 and H3O+. In the present model, all of these processes were found to occur with no barriers. Discussion includes the analogous gas phase processes, which have been considered in previous studies, as well as the competitive abstraction pathway for HCO(+) + H2O.

Woon, David E.↗
NASA NTRS2012

Will Organic Synthesis Within Icy Grains or on Dust Surfaces in the Primitive Solar Nebula Completely Erase the Effects of Photochemical Self Shielding?

There are at least 3 separate photochemical self-shielding models with different degrees of commonality. All of these models rely on the selective absorption of (12))C(16)O dissociative photons as the radiation source penetrates through the gas allowing the production of reactive O-17 and O-18 atoms within a specific volume. Each model also assumes that the undissociated C(16)O is stable and does not participate in the chemistry of nebular dust grains. In what follows we will argue that this last, very important assumption is simply not true despite the very high energy of the CO molecular bond.

Nuth, Joseph A., III↗
NASA NTRS2012

Multiscale Modeling of Grain Boundaries in ZrB2: Structure, Energetics, and Thermal Resistance

A combination of ab initio, atomistic and finite element methods (FEM) were used to investigate the structures, energetics and lattice thermal conductance of grain boundaries for the ultra high temperature ceramic ZrB2. Atomic models of idealized boundaries were relaxed using density functional theory. Information about bonding across the interfaces was determined from the electron localization function. The Kapitza conductance of larger scale versions of the boundary models were computed using non-equilibrium molecular dynamics. The interfacial thermal parameters together with single crystal thermal conductivities were used as parameters in microstructural computations. FEM meshes were constructed on top of microstructural images. From these computations, the effective thermal conductivity of the polycrystalline structure was determined.

Lawson, John W.↗
NASA NTRS2013

A Microanalytical (TEM) Study of Fine-grained Chondrule Rims in NWA 5717

Northwest Africa (NWA) 5717 is a highly primitive ordinary chondrite of petrologic type 3.05 with ubiquitous fine-grained chondrule rims [1, 2]. Rims appear around approximately 60% of chondrules and are comprised of micron-sized mineral and lithic fragments and microchondrules that are embdedded in an FeO-rich submicron groundmass that compositionally resembles fayalitic olivine. Some rim clasts appear overprinted with FeO-rich material, suggesting secondary alteration that postdates rim formation. Here we present a microanalytical (TEM) study of the submicron component (i.e. the groundmass) of the rims in order to determine the crystal structures and compositions of their constituent phases and decipher the accretion and alteration history recorded in rims.

Bigolski, J. N.↗
NASA NTRS2014

Grain Destruction in a Supernova Remnant Shock Wave

Dust grains are sputtered away in the hot gas behind shock fronts in supernova remnants, gradually enriching the gas phase with refractory elements. We have measured emission in C IV (lambda)1550 from C atoms sputtered from dust in the gas behind a non-radiative shock wave in the northern Cygnus Loop. Overall, the intensity observed behind the shock agrees approximately with predictions from model calculations that match the Spitzer 24 micron and the X-ray intensity profiles. Thus these observations confirm the overall picture of dust destruction in SNR shocks and the sputtering rates used in models. However, there is a discrepancy in that the CIV intensity 10'' behind the shock is too high compared to the intensities at the shock and 25'' behind it. Variations in the density, hydrogen neutral fraction and the dust properties over parsec scales in the pre- shock medium limit our ability to test dust destruction models in detail.

dust↗
NASA NTRS2014

Method of Creating Micro-scale Silver Telluride Grains Covered with Bismuth Nanoparticles

Provided is a method of enhancing thermoelectric performance by surrounding crystalline semiconductors with nanoparticles by contacting a bismuth telluride material with a silver salt under a substantially inert atmosphere and a temperature approximately near the silver salt decomposition temperature; and recovering a metallic bismuth decorated material comprising silver telluride crystal grains.

Kim, Hyun-Jung↗
NASA NTRS2015

Surface Exposure Ages of Space-Weathered Grains from Asteroid 25143 Itokawa

We use the observed effects of solar wind ion irradiation and the accumulation of solar flare particle tracks recorded in Itokawa grains to constrain the rates of space weathering and yield information about regolith dynamics. The track densities are consistent with exposure at mm depths for 104-105 years. The solar wind damaged rims form on a much faster timescale, <10(exp 3) years.

Keller, L. P.↗
NASA NTRS2016

Macrosegregation and Grain Formation Caused by Convection Associated with Directional Solidification Through Cross-Section Increase

Cylindrical Al-7 wt% Silicon, Al-19 wt% Copper and Lead-6 wt% Antimony alloy samples were directionally solidified (DS) with liquid above, solid below, and gravity pointing down, in graphite crucibles having an abrupt cross-sectional increase. These alloys have similar solidification shrinkage but are expected to have different degrees of thermosolutal convection during solidification. Microstructures in the DS samples in the vicinity of the section change have been studied in order to examine the effect of convection associated with the combined influence of thermosolutal effects and solidification shrinkage. Extensive radial and axial macrosegregation associated with cross-section change is observed. It also appears that steepling and local primary alpha-phase remelting resulting from convection are responsible for stray grain formation at the reentrant corners. Preliminary results from a numerical model, which includes solidification shrinkage and thermosolutal convection in the mushy zone, indicate that these regions are prone to solutal remelting of dendrites.

Ghods, Masoud↗
NASA NTRS2016

Direct Numerical Simulation of an Airfoil with Sand Grain Roughness on the Leading Edge

As part of a computational study of acoustic radiation due to the passage of turbulent boundary layer eddies over the trailing edge of an airfoil, the Lattice-Boltzmann method is used to perform direct numerical simulations of compressible, low Mach number flow past an NACA 0012 airfoil at zero degrees angle of attack. The chord Reynolds number of approximately 0.657 million models one of the test conditions from a previous experiment by Brooks, Pope, and Marcolini at NASA Langley Research Center. A unique feature of these simulations involves direct modeling of the sand grain roughness on the leading edge, which was used in the abovementioned experiment to trip the boundary layer to fully turbulent flow. This report documents the findings of preliminary, proof-of-concept simulations based on a narrow spanwise domain and a limited time interval. The inclusion of fully-resolved leading edge roughness in this simulation leads to significantly earlier transition than that in the absence of any roughness. The simulation data is used in conjunction with both the Ffowcs Williams-Hawkings acoustic analogy and a semi-analytical model by Roger and Moreau to predict the farfield noise. The encouraging agreement between the computed noise spectrum and that measured in the experiment indicates the potential payoff from a full-fledged numerical investigation based on the current approach. Analysis of the computed data is used to identify the required improvements to the preliminary simulations described herein.

Ribeiro, Andre F. P.↗
NASA NTRS2018

Toolbox for Research and Exploration (TREX): Investigations of Fine-Grained Materials on Small Bodies

The Toolbox for Research and Exploration (TREX) is a NASA SSERVI (Solar System Exploration Research Virtual Institute) node. TREX (trex.psi.edu) aims to decrease risk to future missions, specifically to the Moon, the Martian moons, and near- Earth asteroids, by improving mission success and assuring the safety of astronauts, their instruments, and spacecraft. TREX studies will focus on characteristics of the fine grains that cover the surfaces of these target bodies - their spectral characteristics and the potential resources (such as H2O) they may harbor. TREX studies are organized into four Themes (Laboratory- Studies, Moon-Studies, Small-Bodies Studies, and Field-Work). In this presentation, we focus on the work targeted by the Small-Bodies Theme. The Small-Bodies' Theme delves into several topics, many which overlap or are synergistic with the other TREX Themes. The main topics include photometry, spectral modeling, laboratory simulations of space weathering processes relevant to asteroids, the assembly of an asteroid regolith database, the dichotomy between nuclear and reflectance spectroscopy, and the dynamical evolution of asteroids and the implications for the retention of volatiles.

Domingue, D. L.↗
NASA NTRS2018

Outgas and Vacuum Storage Testing for MAV Hybrid Fuel Grain

As a part of the Mars Ascent Vehicle mission, NASA MSFC has formulated a new hybrid fuel grain from a paraffin blend, named SP-7. As a part of the necessary preparation for the mission, this material must be tested for any outgassing behavior or other property changes due to vacuum exposure. This type of testing had not yet been conducted for this material. The goal of this project was to set up and begin automated analysis of this material, which would then run over the course of a year. To accomplish this goal, a few primary objectives were necessary-construction of a vacuum chamber to house the test, implementation of an automated gas analyzer system, preparation of SP-7 samples, and test initialization.

Mars Ascent Vehicle↗
NASA NTRS2018

Where are the Shocked Grains in the Hadean Zircon Record? Insights on the Preservation of Shocked Zircon and Their U-Pb Systematics

While the earliest history of many planetary bodies within the inner Solar System is dominated by intense bombardment, this record is missing from Earth due to active tectonics and erosion. Where-as rocks from the earliest history of Earth are absent, mineral relics, such as ancient detrital zircon concentrated in sediments within the Jack Hills, Narryer, Illara and Maynard Hills greenstone belts of the Yilgarn Craton in Western Australia preserve a record of this time.Shock in zircon: During shock deformation, resulting from hyper-velocity impact, zircon can be modified in crystallographically-controlled ways. This includes the development of planar and subplanar low-angle grain boundaries, the formation of mechanical twins, transformation to the high pressure polymorph reidite, development of polycrystalline microtexture, and dissociation to its dioxide constituents SiO2 and ZrO2.

Erickson, T. M.↗
NASA NTRS2020

Dust from Mars-Analog Plains (Iceland): Physico-Compositional Properties as a Function of Grain-Size Fraction

Dust is a key component of the geological and climatic systems of Earth and Mars. On Mars, dust is ubiquitous. It coats rocks and soils, and, in the atmosphere, it interacts strongly with solar and thermal radiation. Yet, key questions remain about the genesis and fate of martian dust, as well as its sources, composition, and properties. We collected wind-blown dust from basaltic plains in SW Iceland at Skjaldbreiðauhraun that represent a geologic Mars-analog environment. Icelandic dust differs from the typical continental sources (e.g. Sahara, Asia) because of its basaltic volcanogenic origin, which is similar to Mars. Dust collection took place in July of 2019 as a complementary project to the SAND-E: Semi-Autonomous Navigation for Detrital Environments project. Here we report preliminary analyses of this Mars-analog dust material, with the goal of understanding the processes that control the physico-chemical proper-ties of the different grain-size fractions.

Nachon, Marion↗
NASA NTRS1996

Subpixel Snow-Covered-Area and Snow Grain Size from Mixture Analysis with Aviris Data

Snow-covered-area (SCA) and snow grain size are crucial inputs to hydrologic and climatologic modeling of alpine and other seasonally snow-covered regions. SCA is necessary to parameterize energy budget calculations in climate models, to determine in which regions point snowmelt models are to be run for distributed snowmelt modeling efforts and to provide a basis from which estimates of snow water equivalent (SWE) may be made.

hydrologic↗
NASA NTRSDate not supplied

Al-Mg Isotopic Constraints on the Condensation Age of Fine-Grained Refractory Inclusions in Reduced Cv3 Chondrites

Fine-grained Ca-Al-rich inclusions (FGIs) in carbonaceous chondrites are interpreted as aggregates of direct condensates from the solar nebula that escaped extensive melting. Thus far, a few high-precision SIMS Al-Mg chronology studies of FGIs from CV3 chondrites have been reported. Argued that (26Al/27Al)0 of all FGIs are close to the bulk refractory inclusion value of ~5.2×10−5 which may define a time zero for the FGI condensation. A similar (26Al/27Al)0 value was also inferred from an amoeboid olivine aggregate (AOA), which also represents a direct condensate from the solar nebula. In contrast, reported significant variations in (26Al/27Al)0 of FGIs, ranging from ~5.2×10−5 to ~3.4×10−5, and concluded that their formation continued over at least ~0.4 Ma after the canonical value. These contrasting results suggest that the chronological significance for the formation age spread of FGIs in CV3 chondrites is still poorly constrained.

J. Han↗