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At least 1,657 records · Page 92

Evaluation of on-board hydrogen storage methods f or high-speed aircraft

Hydrogen is the fuel of choice for hypersonic vehicles. Its main disadvantage is its low liquid and solid density. This increases the vehicle volume and hence the drag losses during atmospheric flight. In addition, the dry mass of the vehicle is larger due to larger vehicle structure and fuel tankage. Therefore it is very desirable to find a fuel system with smaller fuel storage requirements without deteriorating the vehicle performance substantially. To evaluate various candidate fuel systems, they were first screened thermodynamically with respect to their energy content and cooling capacities. To evaluate the vehicle performance with different fuel systems, a simple computer model is developed to compute the vehicle parameters such as the vehicle volume, dry mass, effective specific impulse, and payload capacity. The results indicate that if the payload capacity (or the gross lift-off mass) is the most important criterion, only slush hydrogen and liquid hydrogen - liquid methane gel shows better performance than the liquid hydrogen vehicle. If all the advantages of a smaller vehicle are considered and a more accurate mass analysis can be performed, other systems using endothermic fuels such as cyclohexane, and some boranes may prove to be worthy of further consideration.

Akyurtlu, Ates↗

BOREAS TE-2 NSA Soil Lab Data

This data set contains the major soil properties of soil samples collected in 1994 at the tower flux sites in the Northern Study Area (NSA). The soil samples were collected by Hugo Veldhuis and his staff from the University of Manitoba. The mineral soil samples were largely analyzed by Barry Goetz, under the supervision of Dr. Harold Rostad at the University of Saskatchewan. The organic soil samples were largely analyzed by Peter Haluschak, under the supervision of Hugo Veldhuis at the Centre for Land and Biological Resources Research in Winnipeg, Manitoba. During the course of field investigation and mapping, selected surface and subsurface soil samples were collected for laboratory analysis. These samples were used as benchmark references for specific soil attributes in general soil characterization. Detailed soil sampling, description, and laboratory analysis were performed on selected modal soils to provide examples of common soil physical and chemical characteristics in the study area. The soil properties that were determined include soil horizon; dry soil color; pH; bulk density; total, organic, and inorganic carbon; electric conductivity; cation exchange capacity; exchangeable sodium, potassium, calcium, magnesium, and hydrogen; water content at 0.01, 0.033, and 1.5 MPascals; nitrogen; phosphorus: particle size distribution; texture; pH of the mineral soil and of the organic soil; extractable acid; and sulfur. These data are stored in ASCII text files. The data files are available on a CD-ROM (see document number 20010000884), or from the Oak Ridge National Laboratory (ORNL) Distributed Active Archive Center (DAAC).

Veldhuis, Hugo↗

Approximate Solution for Choked Flow in Gas Seal Pads

Previous analyses of high pressure seals have considered adiabatic flow with friction but neglected effects of seal rotation. Most of this work analyzed a one-dimensional flow field. This works well to calculate stiffness and leakage of full circular seals, either face seals or annular ring seals. However, it cannot provide accurate results for a rectangular seal pad with its strongly two-dimensional flow field and its reliance on hydrodynamic forces to maintain a full fluid film. On the other hand, solutions of Reynolds lubrication equation have been obtained for the two-dimensional flow in a seal pad. But these solutions do not account for choking which occurs at high seal pressure ratios, nor do they consider the pressure loss that occurs in the entrance region of the flow field. The aim of the present work is to build on the Reynolds equation solution by use of an approximate choked flow analysis. This will account for the pressure losses in the flow entrance region, ensure that fluid velocities remain subsonic, and enable fluid inertial effects within the pad film to be accounted for. Results show that, in general, fluid inertia acts to decrease pad film load capacity and leakage, and increase film stiffness.

Fleming, David P.↗

Autoregulation of cerebral blood flow in orthostatic hypotension

BACKGROUND AND PURPOSE: We sought to evaluate cerebral autoregulation in patients with orthostatic hypotension (OH). METHODS: We studied 21 patients (aged 52 to 78 years) with neurogenic OH during 80 degrees head-up tilt. Blood flow velocities (BFV) from the middle cerebral artery were continuously monitored with transcranial Doppler sonography, as were heart rate, blood pressure (BP), cardiac output, stroke volume, CO2, total peripheral resistance, and cerebrovascular resistance. RESULTS: All OH patients had lower BP (P<.0001), BFV_diastolic (P<.05), CVR (P<.007), and TPR (P<.02) during head-up tilt than control subjects. In control subjects, no correlations between BFV and BP were found during head-up tilt, suggesting normal autoregulation. OH patients could be separated into those with normal or expanded autoregulation (OH_NA; n=16) and those with autoregulatory failure (OH_AF; n=5). The OH_NA group showed either no correlation between BFV and BP (n=8) or had a positive BFV/BP correlation (R2>.75) but with a flat slope. An expansion of the "autoregulated" range was seen in some patients. The OH_AF group was characterized by a profound fall in BFV in response to a small reduction in BP (mean deltaBP <40 mm Hg; R2>.75). CONCLUSIONS: The most common patterns of cerebral response to OH are autoregulatory failure with a flat flow-pressure relationship or intact autoregulation with an expanded autoregulated range. The least common pattern is autoregulatory failure with a steep flow-pressure relationship. Patients with patterns 1 and 2 have an enhanced capacity to cope with OH, while those with pattern 3 have reduced capacity.

Non-NASA Center↗

Application of Climate Impact Metrics to Rotorcraft Design

Multiple metrics are applied to the design of large civil rotorcraft, integrating minimum cost and minimum environmental impact. The design mission is passenger transport with similar range and capacity to a regional jet. Separate aircraft designs are generated for minimum empty weight, fuel burn, and environmental impact. A metric specifically developed for the design of aircraft is employed to evaluate emissions. The designs are generated using the NDARC rotorcraft sizing code, and rotor analysis is performed with the CAMRAD II aeromechanics code. Design and mission parameters such as wing loading, disk loading, and cruise altitude are varied to minimize both cost and environmental impact metrics. This paper presents the results of these parametric sweeps as well as the final aircraft designs.

Russell, Carl↗

Application of Climate Impact Metrics to Civil Tiltrotor Design

Multiple metrics are applied to the design of a large civil tiltrotor, integrating minimum cost and minimum environmental impact. The design mission is passenger transport with similar range and capacity to a regional jet. Separate aircraft designs are generated for minimum empty weight, fuel burn, and environmental impact. A metric specifically developed for the design of aircraft is employed to evaluate emissions. The designs are generated using the NDARC rotorcraft sizing code, and rotor analysis is performed with the CAMRAD II aeromechanics code. Design and mission parameters such as wing loading, disk loading, and cruise altitude are varied to minimize both cost and environmental impact metrics. This paper presents the results of these parametric sweeps as well as the final aircraft designs.

Russell, Carl R.↗

Strong detection of the CMB lensing and galaxy weak lensing cross-correlation from ACT-DR4, Planck Legacy, and KiDS-1000

We measured the cross-correlation between galaxy weak lensing data from the Kilo Degree Survey (KiDS-1000, DR4) and cosmic microwave background (CMB) lensing data from the Atacama Cosmology Telescope (ACT, DR4) and the Planck Legacy survey. We used two samples of source galaxies, selected with photometric redshifts, (0.1 < z(B) < 1.2) and (1.2 < z(B) < 2), which produce a combined detection significance of the CMB lensing and weak galaxy lensing cross-spectrum of 7.7σ. With the lower redshift galaxy sample, for which the cross-correlation was detected at a significance of 5.3σ, we present joint cosmological constraints on the matter density parameter, Ω(m), and the matter fluctuation amplitude parameter, σ(8), marginalising over three nuisance parameters that model our uncertainty in the redshift and shear calibration as well as the intrinsic alignment of galaxies. We find our measurement to be consistent with the best-fitting flat ΛCDM cosmological models from both Planck and KiDS-1000. We demonstrate the capacity of CMB weak lensing cross-correlations to set constraints on either the redshift or shear calibration by analysing a previously unused high-redshift KiDS galaxy sample (1.2 < z(B) < 2), with the cross-correlation detected at a significance of 7σ. This analysis provides an independent assessment for the accuracy of redshift measurements in a regime that is challenging to calibrate directly owing to known incompleteness in spectroscopic surveys.

Naomi Clare Robertson↗

Inter-Individual Variability in Astronaut Strength Response to Long-Duration Spaceflight May Be Dictated by In-Flight Exercise

Deconditioning induced by prolonged microgravity exposure during spaceflight hinders physical capacity. Examination of pre- to post-flight isokinetic strength measures shows that strength decreases; however, considerable variability between crewmembers exists. As in-flight exercise differs between crew, an examination of exercise training variables contributing to strength preservation is necessary. The purpose of this analysis was to examine in-flight exercise of astronauts who maintain strength compared to those with the greatest decrements in strength from pre- to post-flight.

Alyssa N. Varanoske↗

Inter-Individual Variability in Astronaut Strength Response to Long-Duration Spaceflight May Be Dictated by In-Flight Exercise

BACKGROUND: Deconditioning induced by prolonged microgravity exposure during spaceflight hinders physical capacity. Examination of pre- to post-flight isokinetic strength measures shows that strength decreases; however, considerable variability between crewmembers exists. As in-flight exercise differs between crew, an examination of exercise training variables contributing to strength preservation is necessary. The purpose of this analysis was to examine in-flight exercise of astronauts who maintain strength compared to those with the greatest decrements in strength from pre- to post-flight. METHODS: The database of NASA International Space Station (ISS) crew who completed pre- and post-flight knee isokinetic testing (n = 87) was used to identify “responders” (R) and “non-responders” (NR) to in-flight exercise (≥ 90-day flight duration). R were those that maintained or improved strength (mean of knee extension and flexion at 60°/sec) (n = 14; 5.6 ± 7.8%), and NR were those with the most severe decrements (n = 14; -32.8 ± 4.1%) from pre- to post-flight. In-flight daily exercise records (cycle ergometer, treadmill, resistance exercise) were aggregated on a weekly basis. Independent t-tests or Mann-Whitney U tests were used to compare groups for in-flight exercise variables (i.e., frequency, time, intensity, volume). RESULTS: In-flight cycle ergometer frequency (2.4 ± 0.8 vs. 3.3 ± 1.0 days/wk; p = 0.021), total time (78.5 ± 20.4 vs. 114.0 ± 49.3 min/wk; p = 0.021), and active time (59.3 ± 17.2 vs. 86.9 ± 44.1 min/wk; p = 0.050) were greater in NR than R, but no differences for cycle intensity were observed. Treadmill distance traveled per session was greater in R than NR (4.6 ± 0.8 vs 3.6 ± 1.3 km/sess, p = 0.031), but no differences for treadmill frequency, total time, or active time were observed. Lower body resistance exercise intensity relative to pre-flight body weight was greater in R than NR (110.0 ± 16.5 vs 88.7 ± 25.0%; p = 0.012), but no differences in upper body or core resistance exercise intensity, volume, or frequency existed. CONCLUSIONS: The unique musculoskeletal loading provided by treadmill running at the expense of cycle ergometry, combined with using higher relative lower body loads during resistance training, may contribute to preserving strength in ISS crewmembers during long-duration spaceflight.

Alyssa N. Varanoske↗

Multidisciplinary Optimization of A Transonic Truss-Braced Wing Aircraft Using Aviary

The continuous push to decrease fuel burn of single-aisle commercial aircraft has led to interest in a Transonic Truss-Braced Wing (TTBW) concept vehicle. Sporting high-slung wings that are long and slender to increase aerodynamic efficiency, a TTBW can also accommodate higher-bypass turbine engines. The combination of these two changes potentially leads to an overall decrease in fuel consumption. In this paper, a TTBW concept vehicle is assembled in the Aviary open-source tool for conceptual aircraft design. The conceptual-level aerodynamics and propulsion systems that come prepackaged with Aviary are replaced with higher-fidelity vortex lattice method for aerodynamics (VSPAERO) and a one-dimensional cycle analysis tool for propulsion (pyCycle). The vehicle is then optimized to minimize fuel burn for a representative commercial mission. Design parameters for the vehicle include the electrified turbine size, the size of the electric motors which are used for takeoff and climb assist, and battery capacity. The TTBW concept vehicle presented in this paper represents the first application of Aviary to an aircraft design problem.

Optimization↗

Hybrid power plant design for low-carbon hydrogen in the United States

In this study, we provide a nationwide techno-economic analysis of clean hydrogen production powered by a hybrid renewable energy plant for over 50,000 locations in the United States. We leverage the open-source Hybrid Optimization Performance Platform (HOPP) tool to simulate the hourly performance of an off-grid wind-solar plant integrated with a 1-GW polymer exchange membrane electrolyzer system. The levelized cost of hydrogen is calculated for varying technology costs, and tax credits to explore cost sensitivities independent of plant design, performance, and site selection. Our findings suggest that strategies for cost reduction include selecting sites with abundant wind resources, complementary wind and solar resources, and optimizing the sizing of wind and solar assets to maximize the hybrid plant capacity factor. These strategies are linked to increased hydrogen production and reduced electrolyzer stack replacements, thereby lowering the overall cost of hydrogen.

08 HYDROGEN↗

Expandable Li Percolation Network: The Effects of Site Distortion in Cation-Disordered Rock-Salt Cathode Material

Cation-disordered rock-salt (DRX) materials receive intensive attention as a new class of cathode candidates for high-capacity lithium-ion batteries (LIBs). Unlike traditional layered cathode materials, DRX materials have a three-dimensional (3D) percolation network for Li + transportation. The disordered structure poses a grand challenge to a thorough understanding of the percolation network due to its multiscale complexity. In this work, we introduce the large supercell modeling for DRX material Li 1.16 Ti 0.37 Ni 0.37 Nb 0.10 O 2 (LTNNO) via the reverse Monte Carlo (RMC) method combined with neutron total scattering. Here, through a quantitative statistical analysis of the material’s local atomic environment, we experimentally verified the existence of short-range ordering (SRO) and uncovered an element-dependent behavior of transition metal (TM) site distortion. A displacement from the original octahedral site for Ti 4+ cations is pervasive throughout the DRX lattice. Density functional theory (DFT) calculations revealed that site distortions quantified by the centroid offsets could alter the migration barrier for Li + diffusion through the tetrahedral channels, which can expand the previously proposed theoretical percolating network of Li. The estimated accessible Li content is highly consistent with the observed charging capacity. The newly developed characterization method here uncovers the expandable nature of the Li percolation network in DRX materials, which may provide valuable guidelines for the design of superior DRX materials.

25 ENERGY STORAGE↗

Soil Respiration Response to Simulated Precipitation Change Depends on Ecosystem Type and Study Duration

Soil respiration—the flow of biologically-generated CO 2 from the soil surface to the atmosphere—is a major component of global carbon cycling, but the long-term response of this flux to altered precipitation regimes remains uncertain, due to different responses of soil respiration in distinct ecosystems with varying degrees of water limitation. We conducted a meta-analysis to determine the role of soil characteristics (organic carbon stock and clay content), study duration, and ecosystem type (e.g., forest, grassland, etc) in modifying the response of soil respiration to precipitation change. In general, decreased precipitation (N = 128 effect size pairs) decreased soil respiration rates. In contrast, increased precipitation (N = 141) had a more variable and on-average weak positive effect on this flux; significantly increasing soil respiration only in desert ecosystems. The long-term response of ecosystems varied, with those that are less constrained by water-availability (e.g., forests) showing acclimation over time to altered precipitation. Soil organic carbon stock strongly modified the response of soil respiration to decreased precipitation (p < 0.0001), but only weakly modified the response to increased precipitation (p < 0.01). Our results suggest that ecosystems with limited soil water-holding capacity and strong inherent water-limitation will show long-term dynamic change in soil respiration regardless of the direction of precipitation change.

54 ENVIRONMENTAL SCIENCES↗

Analysis of Trajectory Flexibility Preservation Impact on Traffic Complexity

The growing demand for air travel is increasing the need for mitigation of air traffic congestion and complexity problems, which are already at high levels. At the same time new information and automation technologies are enabling the distribution of tasks and decisions from the service providers to the users of the air traffic system, with potential capacity and cost benefits. This distribution of tasks and decisions raises the concern that independent user actions will decrease the predictability and increase the complexity of the traffic system, hence inhibiting and possibly reversing any potential benefits. In answer to this concern, the authors proposed the introduction of decision-making metrics for preserving user trajectory flexibility. The hypothesis is that such metrics will make user actions naturally mitigate traffic complexity. In this paper, the impact of using these metrics on traffic complexity is investigated. The scenarios analyzed include aircraft in en route airspace with each aircraft meeting a required time of arrival in a one-hour time horizon while mitigating the risk of loss of separation with the other aircraft, thus preserving its trajectory flexibility. The experiments showed promising results in that the individual trajectory flexibility preservation induced self-separation and self-organization effects in the overall traffic situation. The effects were quantified using traffic complexity metrics, namely dynamic density indicators, which indicated that using the flexibility metrics reduced aircraft density and the potential of loss of separation.

Idris, Husni↗

Geothermal Power Systems Analysis: Outcome of Industry Stakeholders Workshop: Preprint

Geothermal cost and performance evaluation implemented via technoeconomic assessment (TEA) modeling is critical for the Department of Energy (DOE) and other geothermal industry stakeholders in assessing the current state of geothermal technologies and to identify existing hurdles to commercially viable geothermal development. The Geothermal Electricity Technology Evaluation Model (GETEM) is a major TEA tool used in estimating the economic feasibility and levelized cost of energy (LCOE) of conventional hydrothermal systems and enhanced geothermal systems (EGS). Since 2021, GETEM has been transitioning from an intricate spreadsheet model to a user-friendly tool within the System Advisor Model (SAM) developed by the National Renewable Energy Laboratory (NREL). Apart from enabling an expanded visibility of the geothermal model among other renewable resources, having GETEM in SAM has the advantage of simulation automation, better usability, updates tracking, active user inputs/feedback, and extended financial modeling. GETEM is used in developing supply curves for the Annual Technology Baseline (ATB). The ATB data are inputs to the Renewable Energy Potential (reV) and the Regional Energy Deployment System (ReEDS) models. The geothermal module in NREL’s reV model assesses the geothermal energy potential in the conterminous United States by defining the geospatial intersection of geothermal resources with existing grid infrastructure within the constraint of land use characteristics. The ReEDS model is a capacity expansion model used for simulating the long-term build-out and operation of the US generation and transmission system based on current energy costs and policies. To ensure enhanced representation of current industry trends in our model transitions and development, we organized a two-day virtual workshop to elicit geothermal industry stakeholder input and recommendations on our current approaches and assumptions on technoeconomic, resource assessment, and deployment scenarios modeling of geothermal technologies. Participants included developers, operators, investors, regulatory agencies, system modelers, national laboratory researchers, consultants, and other stakeholders. In this workshop, we gained stakeholder insights on current geothermal plant performance (i.e., capacity factors), updated drilling costs and learning curves, and next generation technologies such as closed loop and superhot rock geothermal. Other outcomes from this workshop and its impact on future geothermal development feasibility, resource availability, and capacity expansion studies are compiled and discussed.

Annual Technology Baseline↗

Unraveling Na and F coupling effects in stabilizing Li, Mn-rich layered oxide cathodes via local ordering modification

Regardless of the prevailing capacity and energy density of lithium, manganese-rich layered oxide (LMR-NMC) cathodes, continuous decay of voltage and overall energy density during cycling hinders this material from commercialization in Li-ion batteries. Although significant work focuses on single doping of Na and F, analysis in portraying the benefit of these ions in diminishing the structural distortion during activation cycle is in doubt. In this study, the effects of co-doping Na and F into the LMR-NMC structure in stabilizing the structure and mitigating oxygen loss during the first cycle are closely examined via in situ x-ray measurements. Na and F co-doping shows a 30% lower degree of Li + /Ni 2+ mixing in the Li layer (C2/m structure), 50% reduced Debye-Waller factor of Mn-O bonding, increase reversible TM migration, and faster Li diffusion relative to the pristine material. Due to the utilization of Ni redox chemistry below 4.4 V, less oxygen redox is required for charge compensation at high voltage. This study offers the first instance to quantitatively evaluate the effects of co-doping Na and F in LMR-NMC cathode in order to minimize voltage degradation by altering the local ordering of O3-type structure, which may rationalize strategies to overcome the issues of the material.

25 ENERGY STORAGE↗

An organic bifunctional redox active material for symmetric aqueous redox flow battery

Symmetric redox flow batteries utilizing a single redox active material as catholyte and anolyte, offer a plausible and unique strategy to alleviate cross-contamination issues during cycling, making them an ideal energy storage device for large scale applications. In this work, a low-cost riboflavin organic molecule is coupled with a 2,2,6,6-Tetramethylpiperidinyl-N-oxyl (TEMPO) radical molecule to form a single Riboflavin-TEMPO (RIBOTEMPO) bifunctional redox active material, which is used in both aqueous anolyte and catholyte. Cyclic voltammetry analysis of the combined molecule displays electrochemically reversible reactions for the redox couples at 0.72 V and 0.51 V versus Hg/Hg2SO4, leading to a theoretical cell voltage of 1.23 V. A symmetric cell testing demonstrated over 100 consecutive charge/discharge cycles with nearly 80% coulombic efficiency and capacity retention of 44.7% at a current density of 2.5 mA cm(-2). By utilizing a pH neutral supporting electrolyte, a lowcost, safe, and environmental-friendly redox flow battery is achieved. This work provides a pathway for the design and development of bifunctional redox active molecules for symmetric battery applications.

25 ENERGY STORAGE↗

Cs absorption capacity and selectivity of crystalline and amorphous Hf and Zr phosphates

Removal of radioactive Cs from sodium-rich solutions is a technical challenge that goes back to post World War II nuclear waste storage and treatment; and interest in this topic was reinvigorated by the Fukushima-Daiichi nuclear power plant disaster, 10 years ago. Since the 1960's there has been considerable focus on layered Zr phosphates as robust inorganic sorbents for separation of radionuclides such as Cs. Here we present synthesis and characterization, and direct comparison of Cs sorption capacity and selectivity of four related materials: 1) crystalline α-Zr phosphate and α-Hf phosphate, and 2) amorphous analogues of these. Powder X-ray diffraction, thermogravimetry, solid-state 31P magic angle spinning nuclear magnetic resonance (MAS-NMR) spectroscopy, and compositional analysis (inductively coupled plasma optical emission spectroscopy and mass spectroscopy, ICP OES and ICP MS) provided formulae; respectively M(HPO4)2∙1H2O and M(HPO4)2∙4H2O (M = Hf, Zr) for crystalline and amorphous analogues. Maximum Cs loading, competitive Cs-Na selectivity and maximum Cs-Na loading followed by the above characterizations plus 133Cs MAS-NMR spectroscopy revealed that amorphous analogues are considerably better Cs-sorbents (based on maximum Cs-loading and selectivity over Na) than the well-studied crystalline Zr-analogue. Additionally, crystalline α-Hf phosphate is better Cs-sorbent than crystalline α-Zr phosphate. All these studies consistently show that Hf phosphate is less crystallize than Zr phosphate, when obtained under similar or identical synthesis conditions. We attribute this to lower solubility of Hf phosphate compared to Zr phosphate, preventing ‘defect healing’ during the synthesis process.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗