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At least 1,657 records · Page 92

International Symposium on Combustion, 14th, Pennsylvania State University, University Park, Pa., August 20-25, 1972, Proceedings.

Some elementary steps for the formation and destruction of nitric oxide in the H-N-O system, high-temperature oxidation of hydrogen by nitrous oxide in shock waves, and high-temperature fast-flow reactor studies of metal-atom oxidation kinetics are among the topics covered in papers concerned with elementary reactions in combustion. Other areas covered include oscillatory, turbulent, and supersonic combustion; flames in furnaces and combustors; and pollutant formation and destruction in flames. Individual items are announced in this issue.

Source record↗

Thermodynamic and transport properties of air and its products of combustion with ASTMA-A-1 fuel and natural gas at 20, 30, and 40 atmospheres

The isentropic exponent, molecular weight, viscosity, specific heat at constant pressure, thermal conductivity, Prandtl number, and enthalpy were calculated for air, the combustion products of ASTM-A-1 jet fuel and air, and the combustion products of natural gas and air. The properties were calculated over a temperature range from 300 to 2800 K in 100 K increments and for pressures of 20, 30 and 40 atmospheres. The data for natural gas and ASTM-A-1 were calculated for fuel-air ratios from zero to stoichiometric in 0.01 increments.

Poferl, D. J.↗

The hard start phenomena in hypergolic engines. Volume 2: Combustion characteristics of propellants and propellant combinations

The combustion characteristics of hypergolic propellants are described. A research project was conducted to determine if the reaction control system engine propellants on Apollo spacecraft undergo explosive reaction when subjected to conditions present in the engine at the time of ignition. Combustion characteristics pertinent to the hard-start phenomenon are considered. The thermal stability of frozen mixtures of hydrazine-based fuels with nitrogen tetroxide was analyzed. Results of the tests are presented in the form of tables and graphs.

Miron, Y.↗

Operating manual for coaxial injection combustion model

An operating manual for the coaxial injection combustion model (CICM) is presented as the final report for an eleven month effort designed to provide improvement, to verify, and to document the comprehensive computer program for analyzing the performance of thrust chamber operation with gas/liquid coaxial jet injection. The effort culminated in delivery of an operation FORTRAN IV computer program and associated documentation pertaining to the combustion conditions in the space shuttle main engine. The computer program is structured for compatibility with the standardized Joint Army-Navy-NASA-Air Force (JANNAF) performance evaluation procedure. Use of the CICM in conjunction with the JANNAF procedure allows the analysis of engine systems using coaxial gas/liquid injection.

Sutton, R. D.↗

Experimental determination of turbulence in a GH2-GOX rocket combustion chamber

The intensity of turbulence and the Lagrangian correlation coefficient for a gaseous rocket combustion chamber have been determined from the experimental measurements of the tracer gas diffusion. A combination of Taylor's turbulent diffusion theory and Spalding's numerical method for solving the conservation equations of fluid mechanics was used to calculate these quantities. Taylor's theory was extended to consider the inhomogeneity of the turbulence field in the axial direction of the combustion chamber. An exponential function was used to represent the Lagrangian correlation coefficient. The results indicate that the maximum value of the intensity of turbulence is about 15% and the Lagrangian correlation coefficient drops to about 0.12 in one inch of the chamber length.

Tou, P.↗

Noise generation by ducted combustion systems

Analysis of the interaction between a zone of nonsteady combustion and its confining duct shows that resonant type oscillations occur with resulting noise intensities far greater than from corresponding unconfined flame zones. The blading action on the flow through the compressor and turbine of an engine generates discrete frequency noise which, it is found, is enhanced by the response of the combustion zone in between. Ducted combustor experiments verify the predicted resonant type noise, the amplitude and frequency of which are strongly influenced by the duct dimensions and end impedance. A convergent exit nozzle results in stronger internal resonant noise oscillations but also generates a higher jet velocity, with the attendant jet noise which exceeds noise from inside the duct at jet Mach numbers near unity.-

Chiu, H. H.↗

Measurement techniques for supersonic combustion testing

Measurement techniques used during nine years of intensive research in supersonic combustion are presented. The tests employed a number of combustor and injector configurations, which were directly connected to a Mach 3.2 supersonic nozzle, and both gaseous hydrogen and storable liquid fuels. Nominal plenum conditions for the arc-heated air were 3000 to 4500 R and 30 atm. Measurements included wall surface pressures, wall temperatures, heat flux, skin friction, instream cone-static and pitot pressures, and gas samples. Measurement and analysis techniques have been developed for determining total enthalpy of an airstream containing NO concentrations in excess of equilibrium using the two-throat technique, bulk combustion efficiency using steam calorimetry, radial gradients of fluid properties in the combustor exit plane using a stream tube method, and wall shear from measurements of heat transfer in a reacting supersonic flow using Reynolds analogy.

Orth, R. C.↗

Properties of air and combustion products of fuel with air

Thermodynamic and transport properties have been calculated for air, the combustion products of natural gas and air, and combustion products of ASTM-A-1 jet fuel and air. Properties calculated include: ratio of specific heats, molecular weight, viscosity, specific heat, thermal conductivity, Prandtl number, and enthalpy.

Poferl, D. J.↗

The hard start phenomena in hypergolic engines. Volume 3: Physical and combustion characteristics of engine residuals

An investigation was conducted to determine the cause of starting problems in the hypergolic rocket engines of the Apollo reaction control (RCS) engines. The scope of the investigation was as follows: (1) to establish that chemical reactions occurred during the preignition and post combustion periods, (2) to identify the chemical species of the products of preignition and post combustion reaction, and (3) to determine the explosive nature of the identified species. The methods used in identifying the chemical products are described species. The infrared spectra, X-ray spectra, and other signatures of the compounds are presented. The physical and explosion characteristics of various hypergolic agents are reported.

Miron, Y.↗

Theoretical nitric oxide production incidental to autoignition and combustion of several fuels homogeneously dispersed in air under some typical hypersonic flight conditions

A reaction package of 100 chemical reactions and attendant reaction rate constants defined for the autoignition and combustion of four carbonaceous fuels, CH4, CH3OH, C2H6, and C2H5OH. Definition of the package was made primarily by means of comparison between trial calculations and experimental data for the autoignition of CH4. Autoignition and combustion of each of these four fuels was calculated under three sets of conditions realistic for hypersonic flight applications, for comparison to hydrogen fuel, particularly with respect to formation of nitric oxide. Results show that, for all of the fuels including hydrogen, if NO production is a significant problem, compromise must be made between approaching equilibrium heat release and approaching equilibrium NO concentration.

Bahn, G. S.↗

Combustion instability with partial length acoustic liners

The development of analytical techniques and numerical methods for the prediction of the stability behavior of liquid propellant rocket combustors is discussed. The studies involved nonlinear wave propagation effects and nonlinear combustion zone, liner, and nozzle responses. A second primary extension of the basic theory was directed at the inclusion of the effects of injector face baffles. Attention was restricted to the linear (small amplitude) problem, finite Mach numbers, three dimensional oscillations, and distributed combustion effects.

Mitchell, C. E.↗

Study of combustion experiments in space

The physical bases and scientific merits were examined of combustion experimentation in a space environment. For a very broad range of fundamental combustion problems, extensive and systematic experimentation at reduced gravitational levels (0 g 1) are viewed as essential to the development of needed observations and related theoretical understanding.

Berlad, A. L.↗

Combustion of bulk titanium in oxygen

The combustion of bulk titanium in one atmosphere oxygen is studied using laser ignition and several analytical techniques. These were high-speed color cinematography, time and space resolved spectra in the visible region, metallography (including SEM) of specimens quenched in argon gas, X-ray and chemical product analyses, and a new optical technique, the Hilbert transform method. The cinematographic application of this technique for visualizing phase objects in the combustion zone is described. The results indicate an initial vapor phase reaction immediately adjacent to the molten surface but as the oxygen uptake progresses the evaporation approaches the point of congruency and a much reduced evaporation rate. This and the accumulation of the various soluble oxides soon drive the reaction zone below the surface where gas formation causes boiling and ejection of particles. The buildup of rutile cuts off the oxygen supply and the reaction ceases.

Clark, A. F.↗

Analysis of liquid rocket combustion chamber turbulence levels from diffusion data

The intensity of turbulence and the Lagrangian correlation coefficient in a liquid-rocket combustion chamber have been analytically determined from an analysis of experimental diffusion data obtained in a small rocket engine which operated at 300-psia chamber pressure and produced approximately 250 pounds thrust. Results of gas-sample measurements obtained by Orsat and gas-chromatograph techniques to determine helium-concentration profiles were analyzed on the basis of Taylor's (1921) turbulent diffusion theory to obtain turbulence flow-field parameters. The results of the analysis indicate that turbulent diffusion in a combustion chamber can be adequately modeled by the one-dimensional Taylor theory, which assumes that the intensity of turbulence is a function only of axial distance in the chamber and that the Lagrangian correlation coefficient is expressed by a power law. The results indicate a higher intensity of turbulence and lower correlation than previously expected.

Smith, L. O., Jr.↗

Combustion generated noise in gas turbine combustors

Experiments were conducted to determine the noise power and spectra emitted from a gas turbine combustor can exhausting to the atmosphere. Limited hot wire measurements were made of the cold flow turbulence level and spectra within the can. The fuels used were JP-4, acetone and methyl alcohol burning with air at atmospheric pressure. The experimental results show that for a fixed fuel the noise output is dominated by the airflow rate and not the fuel/air ratio. The spectra are dominated by the spectra of the cold flow turbulence spectra which were invariant with airflow rate in the experiments. The effect of fuel type on the noise power output was primarily through the heat of combustion and not the reactivity. A theory of combustion noise based upon the flame radiating to open surroundings is able to reasonably explain the observed results. A thermoacoustic efficiency for noise radiation as high as .00003 was observed in this program for JP-4 fuel. Scaling rules are presented for installed configurations.

Strahle, W. C.↗

Analytical study of mechanisms for nitric oxide formation during combustion of methane in a jet-stirred combustor

The role of chemical kinetics in the formation of nitric oxide during the combustion of methane was examined analytically by means of a detailed chemical mechanism for the oxidation of methane, for the reaction between hydrocarbon fragments, and for the formation of nitric oxide. By comparing predicted nitric oxide levels with values reported in the literature from jet-stirred combuster experiments, it was determined that the nitric oxide levels observed in fuel-rich flames cannot be described by a mechanism in which the rate of nitric oxide formation is controlled solely by the kinetics of oxygen atom formation. A proposed mechanism for the formation of nitric oxide in methane-rich flames reproduces the observed levels. The oxidation of hydrogen cyanide appears to be an important factor in nitric oxide formation.

Jachimowski, C. J.↗

Combustion instability with partial length acoustic liners

The development is discussed of analytical techniques and numerical methods for the prediction of the stability behavior of liquid propellant rocket combustors with partial length acoustic liners, injector face baffles, and nonlinear combustion responses. Three primary objectives included: (1) extension of the Green's Function integral-iteration technique previously developed so that nonlinear three dimensional wave propagation effects could be included in stability predictions; (2) development of an analytical technique and a computer program for the prediction of the damping effects caused by injector face baffles; and (3) inclusion of a nonlinear, wave distortation dependent, combustion response model in the global stability analysis and determination of its effect on combustor stability.

Mitchell, C. E.↗

Turbulence in a gaseous hydrogen-liquid oxygen rocket combustion chamber

The intensity of turbulence and the Lagrangian correlation coefficient for a LOX-GH2 rocket combustion chamber was determined from experimental measurements of tracer gas diffusion. A combination of Taylor's turbulent diffusion theory and a numerical method for solving the conservation equations of fluid mechanics was used to calculate these quantities. Taylor's theory was extended to consider the inhomogeneity of the turbulence field in the axial direction of the combustion chamber, and an exponential function was used to represent the Lagrangian correlation coefficient. The results indicate that the value of the intensity of turbulence reaches a maximum of 14% at a location about 7" downstream from the injector. The Lagrangian correlation coefficient associated with this value is given by the above exponential expression where alpha = 10,000/sec.

Lebas, J.↗