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At least 1,639 records · Page 91

Approaches for Achieving Broadband Achromatic Phase Shifts for Visible Nulling Coronagraphy

Visible nulling coronagraphy is one of the few approaches to the direct detection and characterization of Jovian and Terrestrial exoplanets that works with segmented aperture telescopes. Jovian and Terrestrial planets require at least 10(exp -9) and 10(exp -10) image plane contrasts, respectively, within the spectral bandpass and thus require a nearly achromatic pi-phase difference between the arms of the interferometer. An achromatic pi-phase shift can be achieved by several techniques, including sequential angled thick glass plates of varying dispersive materials, distributed thin-film multilayer coatings, and techniques that leverage the polarization-dependent phase shift of total-internal reflections. Herein we describe two such techniques: sequential thick glass plates and Fresnel rhomb prisms. A viable technique must achieve the achromatic phase shift while simultaneously minimizing the intensity difference, chromatic beam spread and polarization variation between each arm. In this paper we describe the above techniques and report on efforts to design, model, fabricate, align the trades associated with each technique that will lead to an implementations of the most promising one in Goddard's Visible Nulling Coronagraph (VNC).

Bolcar, Matthew R.↗

Ion Measurements During Pioneer Venus Reentry: Implications for Solar Cycle Variation of Ion Composition and Dynamics

During the final, low solar activity phase of the Pioneer Venus mission, the Orbiter Ion Mass Spectrometer measurements found all ion species, in the midnight-dusk sector, reduced in concentration relative to that observed at solar maximum. Molecular ion species comprised a greater part of the total ion concentration as O(+) and H(+) had the greatest depletions. The nightside ionospheric states were strikingly similar to the isolated solar maximum "disappearing" ionospheres. Both are very dynamic states characterized by a rapidly drifting plasma and 30-100 eV superthermal O(+) ions.

Grebowsky, J. M.↗

Total ozone-solar activity relationship

Approximately six years of global ozone monthly mean data from the Nimbus 4 BUV instrument are compared with monthly values of solar activity using 10.7-cm flux, F(10.7), as a parameter. Several techniques are explored in calculating the correlation between the two data sets, and all are found to yield relatively high correlations, ranging from R = 0.68 for 'raw' monthly means to 0.94 using a six-month running mean for each data set. It is shown, however, that the bulk of the correlation derives from the long-term decreasing trends in both data sets. When the long-term trends are removed, a cross-correlation analysis produces a maximum with no phase shift or with the ozone variations leading the solar variations by one month, thereby reducing the likelihood of a cause and effect relationship on time scales of this order. In view of the current uncertainty in the long-term stability of the BUV instrument and the resulting uncertainty in any long-term trend derived from its data, it is considered unrealistic to draw firm conclusions about a solar cycle influence on total ozone from this satellite data set.

Reber, C. A.↗

Global Monthly and Daily Precipitation Analysis for the Global Precipitation Climatology Project (GPCP): Global and Regional Variations and Trends

The 22 year, monthly, globally complete precipitation analysis of the World Climate Research Program's (WCRP/GEWEX) Global Precipitation Climatology Project (GPCP) and the four year (1997-present) daily GPCP analysis are described in terms of the data sets and analysis techniques used in their preparation. These analyses are then used to study global and regional variations and trends during the 22 years and the shorter-time scale events that constitute those variations. The GPCP monthly data set shows no significant trend in global precipitation over the twenty years, unlike the positive trend in global surface temperatures over the past century. The global trend analysis must be interpreted carefully, however, because the inhomogeneity of the data set makes detecting a small signal very difficult, especially over this relatively short period. The relation of global (and tropical) total precipitation and ENSO (El Nino and Southern Oscillation) events is quantified with no significant signal when land and ocean are combined. In terms of regional trends 1979 to 2000 the tropics have a distribution of regional rainfall trends that has an ENSO-like pattern with features of both the El Nino and La Nina. This feature is related to a possible trend in the frequency of ENSO events (either El Nino or La Nina) over the past 20 years. Monthly anomalies of precipitation are related to ENSO variations with clear signals extending into middle and high latitudes of both hemispheres. The El Nino and La Nina mean anomalies are near mirror images of each other and when combined produce an ENSO signal with significant spatial continuity over large distances. A number of the features are shown to extend into high latitudes. Positive anomalies extend in the Southern Hemisphere from the Pacific southeastward across Chile and Argentina into the south Atlantic Ocean. In the Northern Hemisphere the counterpart feature extends across the southern U.S. and Atlantic Ocean into Europe. In the Southern Hemisphere an anomaly feature is shown to spiral into the Antarctica land mass. The extremes of ENSO-related anomalies are also examined and indicate that globally, during both El Nino and La Nina, more extremes of precipitation (both wet and dry) occur than during the "neutral" regime, with the El Nino regime showing larger magnitudes. The distribution is different for the globe as a whole and when the area is restricted to just land. The recent (1998-present) Tropical Rainfall Measuring Mission (TRMM) observations are also compared with the GPCP analyses and are evaluated with regard to improving the long-term GPCP data set.

Adler, Robert F.↗

BOREAS TGB-10 Oxidant Flux Data over the SSA

The BOREAS TGB-10 team collected several trace gas data sets in its efforts to determine the role of biogenic hydrocarbon emissions with respect to boreal forest carbon cycles. This oxidant data set contains measured peroxide (H2O2 and total organic peroxides (ROOH)) and ozone concentrations as well as H2O2 and ROOH deposition velocities. These data were obtained at the SSA-OJP site during the summer of 1994. Measurements were made from May to September 1994. The data are stored in tabular ASCII files. Some important results were: (1) Ozone concentrations were consistently low, 20-30 ppb, during the summer of 1994. (2) Peroxide concentrations showed a seasonal variation with highest concentrations occurring in July (IFC-2). (3) Midday H2O2 levels averaged around 1.4 ppb during IFC-2 and 0.4 - 0.5 ppb during IFC's 1 and 3. (4) Midday organic peroxide concentrations were lower, averaging 0.8 ppb during IFC-2, and 0.4 - 0.5 ppb during IFC's 1 and 3. (5) The rough pine forest canopy serves as a significant sink for H2O2. (6) Midday H2O2 deposition velocities averaged 4 - 7 cm/s. (7) Organic peroxide deposition velocities (measured as total ROOH) were approximately 40% as large as those of H2O2.

Hall, Forrest G.↗

Error analysis of Dobson spectrophotometer measurements of the total ozone content

A study of techniques for measuring atmospheric ozone is reported. This study represents the second phase of a program designed to improve techniques for the measurement of atmospheric ozone. This phase of the program studied the sensitivity of Dobson direct sun measurements and the ozone amounts inferred from those measurements to variation in the atmospheric temperature profile. The study used the plane - parallel Monte-Carlo model developed and tested under the initial phase of this program, and a series of standard model atmospheres.

Holland, A. C.↗

Drivers of Decadal Carbon Fluxes Across Temperate Ecosystems

Long-running eddy covariance flux towers provide insights into how the terrestrial carbon cycle operates over multiple timescales. Here, we evaluated variation in net ecosystem exchange (NEE) of carbon dioxide (CO 2 ) across the Chequamegon Ecosystem-Atmosphere Study AmeriFlux core site cluster in the upper Great Lakes region of the USA from 1997 to 2020. The tower network included two mature hardwood forests with differing management regimes (US-WCr and US-Syv), two fen wetlands with varying levels of canopy sheltering and vegetation (US-Los and US-ALQ), and a very tall (400 m) landscape-level tower (US-PFa). Together, they provided over 70 site-years of observations. The 19-tower Chequamegon Heterogenous Ecosystem Energy-balance Study Enabled by a High-density Extensive Array of Detectors 2019 campaign centered around US-PFa provided additional information on the spatial variation of NEE. Decadal variability was present in all long-term sites, but cross-site coherence in interannual NEE in the earlier part of the record became weaker with time as non-climatic factors such as local disturbances likely dominated flux time series. Average decadal NEE at the tall tower transitioned from carbon source to sink to near neutral over 24 years. Respiration had a greater effect than photosynthesis on driving variations in NEE at all sites. Declining snowfall offset potential increases in assimilation from warmer springs, as less-insulated soils delayed start of spring green-up. Higher CO 2 increased maximum net assimilation parameters but not total gross primary productivity. Stand-scale sites were larger net sinks than the landscape tower. Clustered, long-term carbon flux observations provide value for understanding the diverse links between carbon and climate and the challenges of upscaling these responses across space.

54 ENVIRONMENTAL SCIENCES↗

Quantification of electron correlation for approximate quantum calculations

State-of-the-art many-body wave function techniques rely on heuristics to achieve high accuracy at an attainable computational cost to solve the many-body Schrödinger equation. By far, the most common property used to assess accuracy has been the total energy; however, total energies do not give a complete picture of electron correlation. In this work, we assess the von Neumann entropy of the one-particle reduced density matrix (1-RDM) to compare selected configuration interaction (CI), coupled cluster, variational Monte Carlo, and fixed-node diffusion Monte Carlo for benchmark hydrogen chains. A new algorithm, the circle reject method, is presented, which improves the efficiency of evaluating the von Neumann entropy using quantum Monte Carlo by several orders of magnitude. The von Neumann entropy of the 1-RDM and the eigenvalues of the 1-RDM are shown to distinguish between the dynamic correlation introduced by the Jastrow and the static correlation introduced by determinants with large weights, confirming some of the lore in the field concerning the difference between the selected CI and Slater–Jastrow wave functions.

Chemistry↗

Mechanical Response of Castlegate Sandstone under Hydrostatic Cyclic Loading

The stress history of rocks in the subsurface affects their mechanical and petrophysical properties. Rocks can often experience repeated cycles of loading and unloading due to fluid pressure fluctuations, which will lead to different mechanical behavior from static conditions. This is of importance for several geophysical and industrial applications, for example, wastewater injection and reservoir storage wells, which generate repeated stress perturbations. Laboratory experiments were conducted with Castlegate sandstone to observe the effects of different cyclic pressure loading conditions on a common reservoir analogue. Each sample was hydrostatically loaded in a triaxial cell to a low effective confining pressure, and either pore pressure or confining pressure was cycled at different rates over the course of a few weeks. Fluid permeability was measured during initial loading and periodically between stress cycles. Samples that undergo cyclic loading experience significantly more inelastic (nonrecoverable) strain compared to samples tested without cyclic hydrostatic loading. Permeability decreases rapidly for all tests during the first few days of testing, but the decrease and variability of permeability after this depend upon the loading conditions of each test. Cycling conditions do affect the mechanical behavior; the elastic moduli decrease with the increasing loading rate and stress cycling. The degree of volumetric strain induced by stress cycles is the major control on permeability change in the sandstones, with less compaction leading to more variation from measurement to measurement. The data indicate that cyclic loading degrades permeability and porosity more than static conditions over a similar period, but the petrophysical properties are dictated more by the hydrostatic loading rate rather than the total length of time stress cycling is imposed.

58 GEOSCIENCES↗

A comparison of disturbance levels measured in hypersonic tunnels using a hot-wire anemometer and a pitot pressure probe.

Disturbance levels were measured in the test section of a Mach 5 blowdown jet using a constant-current, hot-wire anemometer and a pressure transducer. The disturbance levels, measured by the two instruments and normalized by local mean values, agreed within about 30%, with the pitot data higher than the hot-wire data. The rms disturbance levels measured with the hot-wire anemometer and converted to pitot pressures using a quasi-steady flow analysis, were about two-thirds the levels measured with the pitot probe. The variation of the normalized rms disturbance levels with stagnation pressure indicated that transition occurred in the boundary layer on the nozzle wall and influenced the outputs of the instruments located at the exit of the nozzle when the total pressure was about 35 N/sq cm. Below this pressure the disturbance levels decreased markedly. At higher pressures the disturbances were predominantly aerodynamic noise generated by the turbulent boundary layer on the nozzle wall.

Stainback, P. C.↗

The vertical distribution of HCl in the stratosphere

The vertical distribution of HCl in the stratosphere has been measured from infrared solar absorption spectra recorded with a balloon-borne interferometer. The flights were made in September, 1975, and May, 1976 at float altitudes of 40 km and 37 km, respectively, near Palestine, Texas. Concentration profiles derived from the data show an increase from 0.6 ppbv at 20 km to 1.7 plus or minus .5 ppbv in the region of 37 km. Above 37 km, the data permit only the total abundance to be determined; this value is found to be equivalent to 1.6 plus or minus .6 ppbv if the gas were uniformly mixed. The results from the two flights are closely similar, and no significant seasonal variation in the HCl concentrations can be discerned. The balloon data are consistent with the profile in the 14-21 km altitude region of the stratosphere reported earlier from U-2 observations.

Raper, O. F.↗

Geoid Anomalies and the Near-Surface Dipole Distribution of Mass

Although geoid or surface gravity anomalies cannot be uniquely related to an interior distribution of mass, they can be related to a surface mass distribution. However, over horizontal distances greater than about 100 km, the condition of isostatic equilibrium above the asthenosphere is a good approximation and the total mass per unit column is zero. Thus the surface distribution of mass is also zero. For this case we show that the surface gravitational potential anomaly can be uniquely related to a surface dipole distribution of mass. Variations in the thickness of the crust and lithosphere can be expected to produce undulations in the geoid.

Turcotte, D. L.↗

Rate equations analysis of phase-locked semiconductor laser arrays under steady state conditions

Rate equations analysis of phase-locked semiconductor laser arrays has been carried out. It was found that for given (laser) current densities, the photon density distribution in the array elements is that particular one which maximizes the total photon density. The results of this analysis were then combined with the waveguide properties of the laser array waveguide, yielding a basic model of phase-locked diode laser arrays. This model explains the effects of the variation of the current combination through the array elements on its mode structure that were observed recently.

Katz, J.↗

Advanced probabilistic methods for quantifying the effects of various uncertainties in structural response

The effects of actual variations, also called uncertainties, in geometry and material properties on the structural response of a space shuttle main engine turbopump blade are evaluated. A normal distribution was assumed to represent the uncertainties statistically. Uncertainties were assumed to be totally random, partially correlated, and fully correlated. The magnitude of these uncertainties were represented in terms of mean and variance. Blade responses, recorded in terms of displacements, natural frequencies, and maximum stress, was evaluated and plotted in the form of probabilistic distributions under combined uncertainties. These distributions provide an estimate of the range of magnitudes of the response and probability of occurrence of a given response. Most importantly, these distributions provide the information needed to estimate quantitatively the risk in a structural design.

Nagpal, Vinod K.↗

Current to the ionosphere following a lightning stroke

A simple analytical expression for calculating the total current waveform to the ionosphere after a lightning stroke is derived. The validity of this expression is demonstrated by comparison with a more rigorous computer solution of Maxwell's equations. The analytic model demonstrates that the temporal variation of the current induced in the ionosphere and global circuit and the corresponding return current in the earth depends on the conductivity profile at intervening altitudes in the middle atmosphere. A conclusion is that capacitative coupling may provide tighter coupling between the lower atmosphere and the ionosphere than usually considered, in both directions, which may help to explain observations which seem to indicate that magnetospheric phenomena may in some instances trigger lightning.

Hale, L. C.↗

Wintertime losses of ozone in high northern latitudes

Total column ozone data over the past 22 to 30 years from ground-based Dobson and filter ozonometer stations between 30 N and 80 N are analyzed for residual trends remaining after allowance for the known geophysical variations corresponding to: (1) the change of seasons; (2) the quasi-biennial oscillation; and (3) the 11-year solar sunspot cycle. Examination of the data from several ground stations between 45 and 55 N indicated a seasonal difference in the long-term ozone series, with statistically significant losses in several winter months. Accordingly, the data from individual stations were analyzed with multiple regression analysis, seeking trends on a monthly basis after allowance for the known geophysical cycles. Previous statistical analyses were conducted as tests of 1-D model calculations which do not show any differences with the seasons, and any trend toward change in ozone concentrations is expressed in a yearly trend without seasonal variation. Such a model is inappropriate for calculations with a data set which exhibits a pronounced tendency toward seasonal differences in the trends. Comparisons with model calculations then require 2-D models into which seasonal and latitudinal differences can easily be programmed.

Harris, Neil↗

Usefulness of AIRS-Derived OLR, Temperature, Water Vapor and Cloudiness Anomaly Trends for GCM Validation

Mainly due to their global nature, satellite observations can provide a very useful basis for GCM validations. In particular, satellite sounders such as AIRS provide 3-D spatial information (most useful for GCMs), so the question arises: can we use AIRS datasets for climate variability assessments? We show that the recent (September 2002 February 2010) CERES-observed negative trend in OLR of approx.-0.1 W/sq m/yr averaged over the globe is found in the AIRS OLR data as well. Most importantly, even minute details (down to 1 x 1 degree GCM-scale resolution) of spatial and temporal anomalies and trends of OLR as observed by CERES and computed based on AIRS-retrieved surface and atmospheric geophysical parameters over this time period are essentially the same. The correspondence can be seen even in the very large spatial variations of these trends with local values ranging from -2.6 W/sq m/yr to +3.0 W/sq m/yr in the tropics, for example. This essentially perfect agreement of OLR anomalies and trends derived from observations by two different instruments, in totally independent and different manners, implies that both sets of results must be highly accurate, and indirectly validates the anomalies and trends of other AIRS derived products as well. These products show that global and regional anomalies and trends of OLR, water vapor and cloud cover over the last 7+ years are strongly influenced by EI-Nino-La Nina cycles . We have created climate parameter anomaly datasets using AIRS retrievals which can be compared directly with coupled GCM climate variability assessments. Moreover, interrelationships of these anomalies and trends should also be similar between the observed and GCM-generated datasets, and, in cases of discrepancies, GCM parameterizations could be improved based on the relationships observed in the data. First, we assess spatial "trends" of variability of climatic parameter anomalies [since anomalies relative to the seasonal cycle are good proxies of climate variability] at the common 1x1 degree GCM grid-scale by creating spatial anomaly "trends" based on the first 7+ years of AIRS Version 5 Leve13 data. We suggest that modelers should compare these with their (coupled) GCM's performance covering the same period. We evaluate temporal variability and interrelations of climatic anomalies on global to regional e.g., deep Tropical Hovmoller diagrams, El-Nino-related variability scales, and show the effects of El-Nino-La Nina activity on tropical anomalies and trends of water vapor cloud cover and OLR. For GCMs to be trusted highly for long-term climate change predictions, they should be able to reproduce findings similar to these. In summary, the AIRS-based climate variability analyses provide high quality, informative and physically plausible interrelationships among OLR, temperature, humidity and cloud cover both on the spatial and temporal scales. GCM validations can use these results even directly, e. g., by creating 1x1 degree trendmaps for the same period in coupled climate simulations.

Molnar, Gyula I.↗

Recent Spatial and Temporal Anomalies and Trends of OLR as Observed by CERES and Computed Based on AIRS Retrievals

We show that a recent CERES-observed negative trend in OLR of approx.-0.1 W/sq m/yr averaged over the globe, for the time period of September 2002 through February 2010 used in this study, is found in the AIRS OLR data as well. Most importantly, even minute details (down to 1 x 1 Degree GCM-scale resolution) of spatial and temporal anomalies and trends of OLR as observed by CERES and computed based on AIRS-retrieved surface and atmospheric geophysical parameters over this time period are essentially the same. We see this correspondence even in the very large spatial variations of these trends with local values ranging from -2.6 W/sq m/yr to +3.0 W/sq m/yr in the tropics. This essentially perfect agreement of OLR anomalies and even local trends derived from observations by two different instruments, in totally independent and different manners, implies that both sets of results must be highly accurate; and indirectly validates the anomalies and trends of other AIRS derived products as well. These products show that global and regional anomalies and trends of OLR, water vapor and cloud cover over the last 7+ years are strongly influenced by El-Nino-La Nina cycles . We use the anomalies and trends of AIRS derived products to explain why the global OLR has a large negative trend over this time period; Global and tropical OLR began to decrease significantly at the onset of a strong La Nina in mid-2007. AIRS products show that cloudiness and mid-tropospheric water vapor began to increase in the tropics at roughly the same time, especially in the region 5degN - 20degS latitude extending eastward from 150degW to 30degE longitude, with a corresponding very large drop in OLR in this region. Late 2009 is characterized by a strong El-Nino, with a corresponding change in sign of observed tropical water vapor, cloud cover, and OLR anomalies. If one excludes the area 5degN - 20degS, 150degW - 30degE from the statistics, area mean OLR trends over the rest of the globe are substantially reduced over the time period under study.

Molnar, Gyula↗