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At least 1,639 records · Page 91

Computational And Experimental Studies Of Three-Dimensional Flame Spread Over Liquid Fuel Pools

Schiller, Ross, and Sirignano (1996) studied ignition and flame spread above liquid fuels initially below the flashpoint temperature by using a two-dimensional computational fluid dynamics code that solves the coupled equations of both the gas and the liquid phases. Pulsating flame spread was attributed to the establishment of a gas-phase recirculation cell that forms just ahead of the flame leading edge because of the opposing effect of buoyancy-driven flow in the gas phase and the thermocapillary-driven flow in the liquid phase. Schiller and Sirignano (1996) extended the same study to include flame spread with forced opposed flow in the gas phase. A transitional flow velocity was found above which an originally uniform spreading flame pulsates. The same type of gas-phase recirculation cell caused by the combination of forced opposed flow, buoyancy-driven flow, and thermocapillary-driven concurrent flow was responsible for the pulsating flame spread. Ross and Miller (1998) and Miller and Ross (1998) performed experimental work that corroborates the computational findings of Schiller, Ross, and Sirignano (1996) and Schiller and Sirignano (1996). Cai, Liu, and Sirignano (2002) developed a more comprehensive three-dimensional model and computer code for the flame spread problem. Many improvements in modeling and numerical algorithms were incorporated in the three-dimensional model. Pools of finite width and length were studied in air channels of prescribed height and width. Significant three-dimensional effects around and along the pool edge were observed. The same three-dimensional code is used to study the detailed effects of pool depth, pool width, opposed air flow velocity, and different levels of air oxygen concentration (Cai, Liu, and Sirignano, 2003). Significant three-dimensional effects showing an unsteady wavy flame front for cases of wide pool width are found for the first time in computation, after being noted previously by experimental observers (Ross and Miller, 1999). Regions of uniform and pulsating flame spread are mapped for the flow conditions of pool depth, opposed flow velocity, initial pool temperature, and air oxygen concentration under both normal and microgravity conditions. Details can be found in Cai et al. (2002, 2003). Experimental results recently performed at NASA Glenn of flame spread across a wide, shallow pool as a function of liquid temperature are also presented here.

Ross, Howard D.↗

Evaluating Possible Formation Mechanisms of Criegee Intermediates during the Heterogeneous Autoxidation of Squalene

Organic molecules in the environment oxidatively degrade by a variety of free radical, microbial, and biogeochemical pathways. A significant pathway is heterogeneous autoxidation, in which degradation occurs via a network of carbon and oxygen centered free radicals. Recently, we found evidence for a new heterogeneous autoxidation mechanism of squalene that is initiated by hydroxyl (OH) radical addition to a carbon–carbon double bond and apparently propagated through pathways involving Criegee Intermediates (CI) produced from β-hydroxy peroxy radicals (β-OH-RO 2 •). It remains unclear, however, exactly how CI are formed from β-OH-RO 2 •, which could occur by a unimolecular or bimolecular pathway. Combining kinetic models and multiphase OH oxidation measurements of squalene, we evaluate the kinetic viability of three mechanistic scenarios. Scenario 1 assumes that CI are formed by the unimolecular bond scission of β-OH-RO 2 •, whereas Scenarios 2 and 3 test bimolecular pathways of β-OH-RO 2 • to yield CI. Scenario 1 best replicates the entire experimental data set, which includes effective uptake coefficients vs [OH] as well as the formation kinetics of the major products (i.e., aldehydes and secondary ozonides). Finally, although the unimolecular pathway appears to be kinetically viable, future high-level theory is needed to fully explain the mechanistic relationship between CI and β-OH-RO 2 • in the condensed phase.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Calculation of flight vibration levels of the AH-1G helicopter and correlation with existing flight vibration measurements

NASA-Langley is sponsoring a rotorcraft structural dynamics program with the objective to establish in the U.S. a superior capability to utilize finite element analysis models for calculations to support industrial design of helicopter airframe structures. In the initial phase of the program, teams from the major U.S. manufacturers of helicopter airframes will apply extant finite element analysis methods to calculate loads and vibrations of helicopter airframes, and perform correlations between analysis and measurements. The aforementioned rotorcraft structural dynamics program was given the acronym DAMVIBS (Design Analysis Method for Vibrations). Sikorsky's RDYNE Rotorcraft Dynamics Analysis used for the correlation study, the specifics of the application of RDYNE to the AH-1G, and comparisons of the predictions of the method with flight data for loads and vibrations on the AH-1G are described. RDYNE was able to predict trends of variations of loads and vibrations with airspeed, but in some instances magnitudes differed from measured results by factors of two or three to one. Sensitivities were studied of predictions to rotor inflow modeling, effects of torsional modes, number of blade bending modes, fuselage structural damping, and hub modal content.

Sopher, R.↗

A buffering heat exchanger/thermal energy storage system for desalination applications

A buffering heat exchanger/thermal energy storage (BHXTES) system was designed using a fast-response phase-change material/graphite foam (PCM/GF) medium for desalination and potentially other industrial applications. Unlike a store-now-and-use-later TES system, this study focused on developing a dynamically balanced, continuously used, system that optimized three functions. A lab-scale prototype was designed and fabricated with a PureTemp 151/GF storage medium. The experimental data showed excellent thermal performance repeatability indicating minimal effects of PCM expansion and contraction on the GF as well as negligible PCM redistribution effects. The experimental data also served as a validation of the numerical model of the BHXTES system, after which optimization of the BHXTES system was conducted through numerical simulations for both PureTemp 151/GF and solar salt/GF as the storage medium. The results show that, with a Therminol 55 heat transfer fluid, continuous operation of the system can be realized with a solar energy source through cycles of 8-h changing for desalination and energy storage with the supplied heat followed by 16-h discharging for desalination with the stored energy. As a result, the working fluid outlet temperatures are generally in the ranges of approximately 128–160 °C for a PureTemp 151/GF medium and 198–220 °C for a solar salt/GF medium.

Buffering↗

Analysis of a new multispecies tumor growth model coupling 3D phase-fields with a 1D vascular network

In this study, we present and analyze a mathematical model for tumor growth incorporating ECM erosion, interstitial flow, and the effect of vascular flow and nutrient transport. The model is of phase-field or diffused-interface type in which multiple phases of cell species and other constituents are separated by smooth evolving interfaces. The model involves a mesoscale version of Darcy’s law to capture the flow mechanism in the tissue matrix. Modeling flow and transport processes in the vasculature supplying the healthy and cancerous tissue, one-dimensional (1D) equations are considered. Since the models governing the transport and flow processes are defined together with cell species models on a three-dimensional (3D) domain, we obtain a 3D–1D coupled model.

3D–1D coupled blood flow models↗

Revisiting the three-kaon interaction and its relation with 𝐾⁡(1460)

Here, we test the hypothesis of 𝐾⁡(1460) being a hadronic 𝐽 𝑃 = 0 − molecule through nonperturbative 𝑆-wave $KK\bar{⁢K}$, 𝐾⁢𝜋⁢𝜋, 𝐾⁢𝜋⁢𝜂 coupled-channel dynamics in a three-body unitary isobar approach. The scalar two-body coupled-channel resonances 𝑓 0 ⁡(500), 𝑓 0 ⁡(980), 𝑎 0 ⁡(980), and 𝐾$^*_0$⁡(700) are generated in the subsytems in amplitudes that match phase shifts from experiment. In a first step, previous results in the limit of mass-degenerate, stable 𝑓 0 and 𝑎 0 isobars are reproduced. Once the full seven-coupled channel model is switched on, other 𝑆-matrix effects obscure and modify the resonance signal, including complex thresholds, a two-body cusp, and a triangle singularity at threshold.

Döring, M. [George Washington Univ., Washington, D↗

Origin of the magnetic and orbital ordering in α-Sr 2 CrO 4

Motivated by recent experimental progress in transition metal oxides with the K 2 NiF 4 structure, in this study we investigate the magnetic and orbital ordering in α-Sr 2 CrO 4 . Using first principles calculations, first we derive a three-orbital Hubbard model, which reproduces the ab initio band structure near the Fermi level. The unique reverse splitting of t 2g orbitals in α-Sr 2 CrO 4 , with the 3d 2 electronic configuration for the Cr 4+ oxidation state, opens up the possibility of orbital ordering in this material. Using real-space Hartree-Fock for multi-orbital systems, we constructed the ground state phase diagram for the two dimensional compound α-Sr 2 CrO 4 . We found stable ferromagnetic, antiferromagnetic, antiferro-orbital, and staggered orbital stripe ordering in robust regions of the phase diagram. Furthermore, using the density matrix renormalization group method for two-leg ladders with the realistic hopping parameters of α-Sr 2 CrO 4 , we explore magnetic and orbital ordering for experimentally relevant interaction parameters. Again, we find a clear signature of antiferromagnetic spin ordering along with antiferro-orbital ordering at moderate to large Hubbard interaction strength. We also explore the orbital-resolved density of states with Lanczos, predicting insulating behavior for the compound α-Sr 2 CrO 4 , in agreement with experiments. Finally, an intuitive understanding of the results is provided based on a hierarchy between orbitals, with d xy driving the spin order, while electronic repulsion and the effective one dimensionality of the movement within the d xz and d yz orbitals driving the orbital order.

36 MATERIALS SCIENCE↗

Genetic Basis of Chromate Adaptation and the Role of the Pre-existing Genetic Divergence during an Experimental Evolution Study with Desulfovibrio vulgaris Populations

Hexavalent chromium [Cr(VI)] is a common environmental pollutant. However, little is known about the genetic basis of microbial evolution under Cr(VI) stress and the influence of the prior evolution histories on the subsequent evolution under Cr(VI) stress. In this study, Desulfovibrio vulgaris Hildenborough (DvH), a model sulfate-reducing bacterium, was experimentally evolved for 600 generations. By evolving the replicate populations of three genetically diverse DvH clones, including ancestor (AN, without prior experimental evolution history), non-stress-evolved EC3-10, and salt stress-evolved ES9-11, the contributions of adaptation, chance, and pre-existing genetic divergence to the evolution under Cr(VI) stress were able to be dissected. Significantly decreased lag phases under Cr(VI) stress were observed in most evolved populations, while increased Cr(VI) reduction rates were primarily observed in populations evolved from EC3-10 and ES9-11. The pre-existing genetic divergence in the starting clones showed strong influences on the changes in lag phases, growth rates, and Cr(VI) reduction rates. Additionally, the genomic mutation spectra in populations evolved from different starting clones were significantly different. A total of 14 newly mutated genes obtained mutations in at least two evolved populations, suggesting their importance in Cr(VI) adaptation. An in-frame deletion mutation of one of these genes, the chromate transporter gene DVU0426, demonstrated that it played an important role in Cr(VI) tolerance. Overall, our study identified potential key functional genes for Cr(VI) tolerance and demonstrated the important role of pre-existing genetic divergence in evolution under Cr(VI) stress conditions.

54 ENVIRONMENTAL SCIENCES↗

Light element ($$Z=1,2$$) production from spontaneous ternary fission of $$^{252}$$Cf

Abstract The yields of light elements ( $$Z=1,2$$ Z = 1 , 2 ) obtained from spontaneous ternary fission of $$^{252}$$ 252 Cf are treated within a nonequilibrium approach, and the contribution of unstable nuclei and excited bound states is taken into account. These light cluster yields may be used to probe dense matter, and to infer in-medium corrections such as Pauli blocking which is determined by the nucleon density. Continuum correlations are calculated from scattering phase shifts using the Beth-Uhlenbeck formula, and the effect of medium modification is estimated. The relevant distribution is reconstructed from the measured yields of isotopes. This describes the state of the nucleon system at scission and cluster formation, using only three Lagrange parameters which are the nonequilibrium counterparts of the temperature and chemical potentials, as defined in thermodynamic equilibrium. We concluded that a simple nuclear statistical equilibrium model neglecting continuum correlations and medium effects is not able to describe the measured distribution of H and He isotopes. Moreover, the freeze-out concept may serve as an important ingredient to the nonequilibrium approach using the relevant statistical operator concept.

Röpke, G.↗

Dust evolution from comets

The studies of the evolution of cometary debris are reviewed. The subject is divided into three major sections: (1) the developments in the immediate vicinity of the cometary nucleus, which is the source of the dust; (2) the formation of the dust tail; and (3) the blending of the debris with the dust component of interplanetary matter. The importance of the physical theory of comets is emphasized for the understanding of the early phase of the evolution of cometary dust. A physico-dynamical model designed to analyze the particle-emission mechanism from the distribution of light in the dust tails is described and the results are presented. Increased attention is paid to large particles because of their importance for the evolution of the zodiacal cloud. Finally, implications are discussed for the future in situ investigations of comets.

Sekanina, Z.↗

Potential for cogeneration of heat and electricity in California industry, phase 2

The nontechnical issues of industrial cogeneration for 12 California firms were analyzed under three categories of institutional settings: (1) industrial ownership without firm sales of power; (2) industrial ownership with firm sales of power; and (3) utility or third party ownership. Institutional issues were analyzed from the independent viewpoints of the primary parties of interest: the industrial firms, the electric utilities and the California Public utilities Commission. Air quality regulations and the agencies responsible for their promulgation were examined, and a life cycle costing model was used to evaluate the economic merits of representative conceptual cogeneration systems at these sites. Specific recommendations were made for mitigating measures and regulatory action relevant to industrial cogeneration in California.

Davis, H. S.↗

Finite element calculation of buoyancy-driven convection near a melt/solid phase boundary

Two iterative schemes based on the mixed finite element method are developed for analyzing steady natural convection in a melt adjacent to its solid phase. The simplest method decouples the calculation of the field variables and the shape of the melt/solid interface into two interlocked iterations that are performed successively. The second method uses Newton's iteration to solve simultaneously for both types of unknowns and has a quadratic convergence rate. Results for a model problem of melt and solid in a cylindrical ampoule show the Newton algorithm to be a factor of three more efficient.

Chang, C. J.↗

A wall interference assessment/correction interface measurement system for the NASA/ARC 12-ft PWT

Development of complex air vehicle configurations is placing increasing demands on wind tunnel testing capabilities. A major area of concern is wall induced interference. Recent developments in wall interference technology provide a means for assessing and correcting for the wall induced interference using information contained in the distribution of flow variables measured at, or near, the wall. The restoration of the NASA-ARC 12-ft pressure wind tunnel (PWT) provides an opportunity to incorporate a measurement system with which wall interference assessment/correction (WIAC) technology can be applied. In this first phase of the development of a WIAC system for the PWT, the design criteria for the placement and the geometry of wall static pressure orifices were determined with a three step approach. First, the operational environment of the PWT was analyzed as to the requirements for the WIAC system. Second, appropriate wall interference theories were evaluated against the requirements determined from the operational environment. Third, the flow about representative models in the PWT was calculated and, specifically, the pressure signatures at the location of the test section wall were obtained. The number of discrete pressure measurements and their locations were determined by curve fitting the pressure distribution through the discrete measurements and evaluating the resulting error.

Source record↗

ROSAT X-ray observations of late-type evolved stars: On the relationship between coronal temperatures and luminosities

We present ROSAT Position Sensitive Proportional Counters (PSPC) X-ray observations of three near-solar-mass stars, in different evolutionary phases beyond the main sequence: eta Sco (F3 III-IV), iota Vir (F6 III), and HD 74772 (G5 III). All three of these nearby, presumably single stars have been detected, and we have collected enough counts to perform a detailed analysis of their soft X-ray spectra. While the X-ray spectra of eta Sco and HD 74772 can be fitted with Raymond-Smith thermal models with temperatures around 2 x 10(exp 6) K, the high signal-to-noise spectrum of iota Vir provides unambiguous evidence of a multitemperature plasma, with a two-temperature best-fit model with components at approximately 2 x 10(exp 6) K and 8 x 10(exp 6) K. Evidence of some hot plasma (T approximately 10(exp 7) K) has been also found for HD 74772. The present data, compared with spectral fitting results for other late-type stars observed with the Einstein Observatory, indicate that the low X-ray luminosity giants (L(sub x) is less than 5 x 10(exp 28) ergs/s) do not share with the higher X-ray luminosity stars of the same class the property of having substantial amount of 10(exp 7) K plasma. Moreover, our results confirm the trend of increasing X-ray luminosities with increasing coronal temperatures.

Maggio, A.↗

Rheology of Diabase: Implications for Tectonics on Venus and Mars

Two important goals of our experimental investigation of the rheological behavior of diabase rocks were: (1) to determine flow laws describing their creep behavior over wide ranges of temperature, stress and strain rate and (2) to develop an understanding of the physical mechanisms by which these rocks flow under laboratory conditions. With this basis, a primary objective then was to construct constitutive equations that can be used to extrapolate from laboratory to planetary conditions. We specifically studied the rheological properties of both natural rock samples and synthetic aggregates. The former provided constraints for geologic systems, while the latter defined the relative contributions of the constituent mineral phases and avoided the influence of glass/melt found in natural samples. In addition, partially molten samples of crustal rock composition were deformed in shear to large strains (greater than 200%) important in crustal environments. The results of this research yielded essential rheological properties essential for models of crustal deformation on terrestrial planets, specifically Venus and Mars, as well as on the geodynamical evolution of these planets. Over the past three years, we also completed our investigation of the creep behavior of water ice with applications to the glaciers, ice sheets and icy satellites. Constitutive equations were determined that describe flow over a wide ranged of stress, strain rate, grain size and temperature. In the case of ice, three creep regimes were delineate. Extrapolation demonstrates that dislocation glide and grain boundary sliding processes dominate flow in ice I under planetary conditions and that diffusion creep is not an important deformation mechanism either in the laboratory or on icy satellites. These results have already been incorporated by other investigators into models describing, for example, the thickness and stability of the ice shell on Europa and to unravel long-standing discrepancies between field observations on glaciers and laboratory results.

Kohlstedt, David L.↗

SMAP Mission Status, New Products, and Extended-Phase Goals

NASA's Soil Moisture Active Passive (SMAP) Project now has completed its prime-phase (three years) mission and has entered a new five-year extended phase. The global L-band radiometry from SMAP has enabled diverse scientific investigations in water, energy and carbon cycle research, terrestrial ecology and ocean science. These include eliciting the role of soil moisture control on the evaporation regime and vegetation gross primary productivity, observing soil-vegetation continuum water relations, analysis of flood and droughts, climate modeling and weather prediction, detecting ocean high-winds during tropical storms, and observing fresh-water outflow in coastal oceans. This paper highlights the recent enhancements to the SMAP suite of science products (from instrument level-1 to geophysical retrievals level-2 and level-3).

NASA Soil Moisture Active Passive (SMAP)↗

Derivation of heterogeneous material distributions and their sensitivity to HM-coupled two-phase flow models exemplified with the LASGIT experiment

Abstract Advective gas transport in bentonite, a possible buffer material in repositories for radioactive materials, is difficult to simulate in numerical continuum models, partly due to the complicated microstructure of bentonite. To generate reliable models of repositories nevertheless, spatially distributed heterogeneous material properties can be used to allow localization of gas flow. In this study, a pore-size-dependent stochastic approach of the gas entry pressure is derived from Mercury Intrusion Porosimetry, which is used to replicate measurements from the LASGIT experiment. In addition, three benchmark tests are simulated to investigate the dependence of heterogeneous distributions of material properties on the mesh discretization, the temporal dependence, and the coupling between the processes influenced by the heterogeneous parameters. The numerical modeling results of the LASGIT experiment show that the onset of gas flow into the system and the subsequent increase in pressure and stress can be well reproduced using heterogeneous distributions. Compared to a model with homogeneous material properties, heterogeneous distributions may allow the generation of dilatancy-controlled microfractures—an important feature with regard to the advective gas flow in bentonites. However, it can be observed that the heterogeneous distributions in LASGIT are less significant, as technical gaps or differences in material types could have a greater impact.

Environmental Sciences & Ecology↗

TRANSENSOR: Transformer Real-time Assessment INtelligent System with Embedded Network of Sensors and Optical Readout. Final Report

Utilities across the world are wrestling with evolving market dynamics, population growth and climate change. Distributed Energy Resources (DERs) such as solar photovoltaics, distributed generators and energy storage systems are becoming important parts of the U.S. energy mix. These factors are driving an increasing need for low-cost grid asset monitoring. Aside from being costly, traditional utility monitoring systems are not sufficiently robust and do not provide real-time visibility into the condition of grid assets such as transformers. Lack of accurate real-time measurements on performance has resulted in the use of lagging indicators, such as oil sample analysis. To address this need, an innovative embedded optical sensing technology, Transformer Real-time Assessment Intelligent System (TRANSENSOR) was developed, validated and demonstrated in this project. To date, TRANSENSOR has focused on transformers but is extendable to other grid assets. In addition to the technology being embedded into new transformers during manufacturing, a retrofit configuration that can be installed on existing transformers in the field was also developed. It is anticipated that the ability to retrofit existing transformers will help accelerate adoption of the underlying TRANSENSOR technology. Phase 1 of the project focused on laboratory development and qualification of the technology. Following iterations and exploration of relevant optical sensing modalities and multiplexed configurations of interest for the transformer environment, an effective candidate configuration was agreed upon, down-selected and custom-designed for embedding into General Electric (GE) network transformers. Two new GE 500 kilovolt ampere (kVA), 27 kilovolt (kV) distribution network transformers were built with embedded fiber-optic (FO) sensors and successfully qualified per industry standards at GE’s Shreveport, Louisiana facility during Phase 1 of the project. Following the successful completion of Phase 1, the team proceeded to Phase 2, which focused on a field demonstration of the technology. Over Phase 2, the first new GE transformer built with embedded fiber-optic sensors was installed in an above-ground cage and connected to the grid at Con Edison’s Astoria facility. A second transformer equipped with TRANSENSOR was installed in an underground vault. Additionally, an older (1982 year model) GE transformer in an above-ground cage was retrofitted with fiber- optic sensors and reconnected to the grid at ConEd’s facility. Analysis of data acquired from the sensors showed interesting correlations with transformer loading. Additionally, key events such as transformer low-voltage network connection, primary-side energizing, and a pressure loss event from an oil sampling were detected by the TRANSENSOR system. Online data processing/feature extraction algorithms for the second transformer in the underground vault detected key features and event alerts that were transmitted through a wireless 4G connection. The remote deployment concept showed promising results with data collection running for a total of 8 months across the three (3) GE transformers instrumented for the Phase 2 field demonstration. This sets the stage well for further development and commercialization.

24 POWER TRANSMISSION AND DISTRIBUTION↗