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At least 1,639 records · Page 91

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NASA NTRS2012

Application of Artificial Neural Networks to the Development of Improved Multi-Sensor Retrievals of Near-Surface Air Temperature and Humidity Over Ocean

Improved estimates of near-surface air temperature and air humidity are critical to the development of more accurate turbulent surface heat fluxes over the ocean. Recent progress in retrieving these parameters has been made through the application of artificial neural networks (ANN) and the use of multi-sensor passive microwave observations. Details are provided on the development of an improved retrieval algorithm that applies the nonlinear statistical ANN methodology to a set of observations from the Advanced Microwave Scanning Radiometer (AMSR-E) and the Advanced Microwave Sounding Unit (AMSU-A) that are currently available from the NASA AQUA satellite platform. Statistical inversion techniques require an adequate training dataset to properly capture embedded physical relationships. The development of multiple training datasets containing only in-situ observations, only synthetic observations produced using the Community Radiative Transfer Model (CRTM), or a mixture of each is discussed. An intercomparison of results using each training dataset is provided to highlight the relative advantages and disadvantages of each methodology. Particular emphasis will be placed on the development of retrievals in cloudy versus clear-sky conditions. Near-surface air temperature and humidity retrievals using the multi-sensor ANN algorithms are compared to previous linear and non-linear retrieval schemes.

Roberts, J. Brent↗

NASA NTRS2015

Evaluation of Spaceborne L-band Radiometer Measurements for Terrestrial Freeze/Thaw Retrievals in Canada

The landscape freeze/thaw (FT) state has an important impact on the surface energy balance, carbon fluxes, and hydrologic processes; the timing of spring melt is linked to active layer dynamics in permafrost areas. L-band (1.4 GHz) microwave emission could allow the monitoring of surface state dynamics due to its sensitivity to the pronounced permittivity difference between frozen and thawed soil. The aim of this paper is to evaluate the performance of both Aquarius and Soil Moisture and Ocean Salinity (SMOS) L-band passive microwave measurements using a polarization ratio-based algorithm for landscape FT monitoring. Weekly L-band satellite observations are compared with a large set of reference data at 48 sites across Canada spanning three environments: tundra, boreal forest, and prairies. The reference data include in situ measurements of soil temperature (Tsoil) and air temperature (Tair), and Moderate Resolution Imaging Spectroradiometer (MODIS) land surface temperature (LST) and snow cover area (SCA) products. Results show generally good agreement between Lband FT detection and the surface state estimated from four reference datasets. The best apparent accuracies for all seasons are obtained using Tair as the reference. Aquarius radiometer 2 (incidence angle of 39.6) data gives the best accuracies (90.8), while for SMOS the best results (87.8 of accuracy) are obtained at higher incidence angles (55- 60). The FT algorithm identifies both freeze onset and end with a delay of about one week in tundra and two weeks in forest and prairies, when compared to Tair. The analysis shows a stronger FT signal at tundra sites due to the typically clean transitions between consistently frozen and thawed conditions (and vice versa) and the absence of surface vegetation. Results in the prairies were poorer because of the influence of vegetation growth in summer (which decreases the polarization ratio) and the high frequency of ephemeral thaw events during winter. Freeze onset and end maps created from the same algorithm applied to SMOS and Aquarius measurements characterize similar FT patterns over Canada. This study shows the potential of using L-band spaceborne observations for FT monitoring, but underlines some limitations due to ice crusts in the snowpack, liquid water content in snow cover during the spring freeze to thaw transition, and vegetation growth.

soil freeze/thaw↗

DOE OSTI2025

Unusual Electrochemical Activity of Thin SiO 2 Layers Leads to Instability of Molecular Attachment in Hybrid Photoelectrodes

Hybrid photoelectrodes, comprised of a light-absorbing semiconductor and a surface-integrated molecular catalyst, are attractive for applications in artificial photosynthesis, since they combine the advantages of broadband semiconductor light absorption with the selectivity of molecular catalysis. A widely used class of hybrid photoelectrodes is based on Si substrates passivated by a thin (<3 nm) layer of silicon oxide, which is commonly prepared by controlled chemical or thermal oxidation, resulting in chemical oxide (ChO) or thermal oxide (ThO) layers, respectively. However, the electrochemical stability of these oxide layers, and the chemical stability of the semiconductor-molecule assembly in hybrid photoelectrodes, are not well understood, with evidence that covalently-bound molecules detach from the oxide surface upon application of cathodic bias. We have examined the intrinsic electrochemical reactivity of silicon oxide layers and how it affects the attachment of molecular monolayers. We determined that the surface of Si|ThO is primarily terminated with hydrophobic siloxane moieties, whereas that of Si|ChO contains a higher concentration of hydrophilic silanol groups. Initial high current densities for Si|ChO under applied bias up to -2 V vs. Ag/AgCl, decrease during repeated cyclic voltammetry scans, due to the consumption of surface-bound water. This is manifested by a reversible wave around -0.5 V in CH 3 CN solution, and a similar pH-dependent wave in water, revealing the pK a of the silanol groups to be ~4. Here, our combined observations support the electrochemically-induced dehydration of the SiO 2 surface, which converts silanol groups to siloxanes and proceeds through an H-atom intermediate that is most likely stabilized by pentavalent Si. We propose that similar reactivity is responsible for the electrochemical loss of alkylsiloxane-attached molecules under cathodic bias, which has important implications for the choice of catalyst attachment strategy in hybrid photoelectrodes.

14 SOLAR ENERGY↗

NASA NTRS2000

Satellite Observed Variability in Antarctic and Arctic Surface Temperatures and Their Correlation to Open Water Areas

Recent studies using meterological station data have indicated that global surface air temperature has been increasing at a rate of 0.05 K/decade. Using the same set of data but for stations in the Antarctic and Arctic regions (>50 N) only, the increases in temperature were 0.08, and 0.22 K/decade, when record lengths of 100 and 50 years, respectively, were used. To gain insights into the increasing rate of warming, satellite infrared and passive microwave observations over the Arctic region during the last 20 years were processed and analyzed. The results show that during this period, the ice extent in the Antarctic has been increasing at the rate of 1.2% per decade while the surface temperature has been decreasing at about 0.08 K per decade. Conversely, in the Northern Hemisphere, the ice extent has been decreasing at a rate of 2.8% per decade, while the surface temperatures have been increasing at the rate of 0.38 K per decade. In the Antarctic, it is surprising that there is a short term trend of cooling during a global period of warming. Very large anomalies in open water areas in the Arctic were observed especially in the western region, that includes the Beaufort Sea, where the observed open water area was about 1x10(exp 6) sq km, about twice the average for the region, during the summer of 1998. In the eastern region, that includes the Laptev Sea, the area of open water was also abnormally large in the summer of 1995. Note that globally, the warmest and second warmest years in this century, were 1998 and 1995, respectively. The data, however, show large spatial variability with the open water area distribution showing a cyclic periodicity of about ten years, which is akin to the North Atlantic and Arctic Oscillations. This was observed in both western and eastern regions but with the phase of one lagging the other by about two years. This makes it difficult to interpret what the trends really mean. But although the record length of satellite data is still relatively short and the climate trend difficult to establish, the immediate impact of a continued warming trend may be very profound.

Comiso, Josefino C.↗

NASA NTRSDate not supplied

Numerical analysis of Microgravity Bubble Separation in Open Channels with ISS Bemchmarks

Spacecraft fluid systems often require specific considerations to operate in a manner similar to those on Earth. For instance, an open wedge shaped channel can serve as a pathway for passively separating bubbles from a liquid in a two phase flow, analogous to buoyancy effects on Earth. As the bubbles merge within the channel, they become increasingly confined in the wedge, driving them upwards and outwards toward the free surface due to capillary forces. These same forces ensure coalescence and allow the bubbles to escape through the free surface. However, in low gravity environments, a challenge arises when bubbles are not sufficiently large. Under such conditions, the bubbles tend to follow trajectories near their inscribed elevations, never fully leaving the liquid. Such unseparated bubbles can lead to downstream pump failure, cavitation, flow instabilities, dryout, and other adverse effects aboard spacecraft. Understanding and exploiting the underlying mechanisms behind this behavior is crucial for enhancing the reliability of passive capillary fluids management in space applications, including cryogenic and storable fuels transport, thermal fluids circulation, water recycling for life support, plant watering systems, and more. The joint German Aerospace Center (DLR) and NASA Capillary Channel Flow (CCF) experiment conducted on the International Space Station has provided an extensive publicly available database documenting such phenomena (https://science.nasa.gov/physical sciences informatics psi). Leveraging this resource, we aim to establish benchmarks for our numerical investigation of zero gravity bubbly two phase flow in open wedge channels. Specifically, we seek to quantitatively understand the mechanisms governing ‘inscribed’ bubble motion, considering the apparent interplay of two competing forces: Saffman lift (causing upward/outward motion) and the Magnus effect (causing downward/inward motion). Our cross cutting findings directly inform the development of robust passive phase separation methods within spacecraft plumbing systems.

bubble↗

NASA NTRS2008

A Sample of What We Have Learned from A-Train Cloud Measurements

The A-train active sensors CloudSat and CALIPSO provide detailed information about cloud vertical structure. Coarse vertical information can also be obtained from a combination of passive sensors (e.g. cloud liquid water content from AMSR-E, cloud ice properties from MLS and HIRDLS, cloud-top pressure from MODIS and AIRS, and UVNISINear IR absorption and scattering from OMI, MODIS, and POLDER). In addition, the wide swaths of instruments such as MODIS, AIRS, OMI, POLDER, and AMSR-E can be exploited to create estimates of the three-dimensional cloud extent. We will show how data fusion from A-train sensors can be used, e.g., to detect and map the presence of multiple layer/phase clouds. Ultimately, combined cloud information from Atrain instruments will allow for estimates of heating and radiative flux at the surface as well as UV/VIS/Near IR trace-gas absorption at the overpass time on a near-global daily basis. CloudSat has also dramatically improved our interpretation of visible and UV passive measurements in complex cloudy situations such as deep convection and multiple cloud layers. This has led to new approaches for unique and accurate constituent retrievals from A-train instruments. For example, ozone mixing ratios inside tropical deep convective clouds have recently been estimated using the Aura Ozone Monitoring Instrument (OMI). Field campaign data from TC4 provide additional information about the spatial variability and origin of trace-gases inside convective clouds. We will highlight some of the new applications of remote sensing in cloudy conditions that have been enabled by the synergy between the A-train active and passive sensors.

Joiner, Joanna↗

NASA NTRS2003

Passive and Active Detection of Clouds: Comparisons between MODIS and GLAS Observations

The Geoscience Laser Altimeter System (GLAS), launched on board the Ice, Cloud and Land Elevation Satellite in January 2003 provides space-borne laser observations of atmospheric layers. GLAS provides opportunities to validate passive observations of the atmosphere for the first time from space with an active optical instrument. Data from the Moderate Resolution Imaging Spectrometer aboard the Aqua satellite is examined along with GLAS observations of cloud layers. In more than three-quarters of the cases, MODIS scene identification from spectral radiances agrees with GLAS. Disagreement between the two platforms is most significant over snow-covered surfaces in the northern hemisphere. Daytime clouds detected by GLAS are also more easily seen in the MODIS data as well, compared to observations made at night. These comparisons illustrate the capabilities of active remote sensing to validate and assess passive measurements, and also to complement them in studies of atmospheric layers.

Mahesh, Ashwin↗

NASA NTRS2020

NISAR flight feed passive antenna measurements

NISAR (NASA ISRO SAR, National Aeronautics and Space Administration, Indian Space Research Organization, Synthetic Aperture Radar) is an Earth science project currently in its final development phase at NASA Jet Propulsion Laboratory (JPL) and at ISRO. Due for launch in 2022 it will assess how our planet changes over time by measuring differences in the Earth’s solid surface due to factors like climate change, movement and melting of glaciers, earthquakes, land-slides, deforestation, agriculture and others. The enabling instrument for this mission is a dual band radar (L-band and S-band) that feeds a 12m deployable mesh reflector. This paper describes the measurement campaign of the L-band flight feed in its passive configuration. Further measurements will be done using the antenna with the active radar components but they are not part of this paper.

Harrell, Jefferson A.↗

NASA NTRS2022

NISAR Flight Feed Passive Antenna Measurements

Harrell, Jefferson A.↗

DOE OSTI2022

Perovskite grain wrapping by converting interfaces and grain boundaries into robust and water-insoluble low-dimensional perovskites

Stabilizing perovskite solar cells requires consideration of all defective sites in the devices. Substantial efforts have been devoted to interfaces, while stabilization of grain boundaries received less attention. Here, we report on a molecule tributyl(methyl)phosphonium iodide (TPI), which can convert perovskite into a wide bandgap one-dimensional (1D) perovskite that is mechanically robust and water insoluble. Mixing TPI with perovskite precursor results in a wrapping of perovskite grains with both grain surfaces and grain boundaries converted into several nanometer-thick 1D perovskites during the grain formation process as observed by direct mapping. The grain wrapping passivates the grain boundaries, enhances their resistance to moisture, and reduces the iodine released during light soaking. The perovskite films with wrapped grains are more stable under heat and light. The best device with wrapped grains maintained 92.2% of its highest efficiency after light soaking under 1-sun illumination for 1900 hours at 55°C open-circuit condition.

14 SOLAR ENERGY↗

DOE OSTI2020

Density Functional Theory Study of the Initial Stages of Cl-Induced Degradation of α -Cr 2 O 3 Passive Film

The ion exchange and point defect models are two prominent models describing the role of anions, such as chlorides, in the degradation of passive oxide films. Here the thermodynamic feasibility of critical steps of Cl-induced degradation of a hydroxylated α-Cr 2 O 3 (0001) surface, as proposed by these two models, are studied. Both models begin with Cl substitution of surface OH and H 2 O, which becomes less favorable with increasing Cl coverage. The initial stages of Cl-induced breakdown of the α-Cr 2 O 3 depend on Cl coverage and the presence of O vacancy near the surface as follows: (1) neither Cl insertion (supporting the ion exchange model) nor Cr vacancy formation (supporting the point defect model) is feasible at low Cl coverages except in the presence of O vacancies near the surface, where Cl insertion is thermodynamically feasible even at low coverages, (2) in the absence of O vacancies, Cr vacancy formation becomes feasible from 10/12 ML onwards whereas Cl insertion by exchange with subsurface OH only becomes feasible at full coverage. This implies that at higher coverages Cl-induced degradation first initiates through a vacancy formation mechanism, but both insertion and vacancy formation would be feasible at full coverage.

36 MATERIALS SCIENCE↗

NASA NTRS1977

Vacuum UV performance of silicon detectors

The sensitivity, time-varying response, and spatial sensitivity of four silicon detectors of vacuum UV were measured by passing a typical flux of 3 x 10 photons/s at the Lyman alpha line of 1215.7 A through an exit aperture of 0.55 mm x 0.8 mm. The detectors tested were: (1) a Fairchild FPM 200 silicon planar passivated photodiode with the window removed so that radiation could directly impinge on the center of the 1.0 mm square silicon chip, (2) a Fairchild FPM 100 silicon NPN planar passivated phototransistor, (3) the Hewlett-Packard 5082-4204 silicon planar PIN photodiode, and (4) the United Detector Technology PIN Spot/2 special sensitive silicon Schottky surface photodiode with the window removed.

Ohlhaber, R. L.↗

NASA NTRS1979

Analytic studies on satellite detection of severe, two-cell tornadoes

From funnel-cloud-length interpretation, the severe tornado is characterized by peak swirl speed relative to the axis of rotation of about 90 m/s. Thermohydrodynamic achievement of the pressure deficit from ambient necessary to sustain such swirls requires that a dry, compressionally heated, non-rotating downdraft of initially tropopause-level air lie within an annulus of rapidly swirling, originally low-level air ascending on a near-moist-adiabatic locus of thermodynamic states. The two-cell structure furnishes an observable parameter possibly accessible to a passively instrumented, geosynchronous meteorological satellite with mesoscale resolution, for early detection of a severe tornado. Accordingly, the low-level turnaround region, in which the surface inflow layer separates to become a free ascending layer and for which inviscid modeling suffices, is examined quantitatively. Preliminary results indicate that swirl overshoot, i.e., swirl speeds in the turnaround region in excess of the maximum achieved in the potential vortex, is modest.

Carrier, G. F.↗

NASA NTRS1995

Review of North Atlantic Source Waters

North Atlantic Deep Water (NADW) ventilates the deep World Ocean. It not only carries relatively well-oxygenated waters, but also other substances derived from recent sea-surface exchanges. There are five regional sources for NADW: (1) derivatives of the salty Mediterranean Sea outflow, (2) products of open-ocean convection in the Labrador Sea, (3) Iceland-Scotland Overflow Water from the Norwegian Sea - salty by virtue of mixing with saline water near the sills, (4) Denmark Strait Overflow Water from the Iceland and Greenland Seas - which retains a high-density, relatively low-salinity signal, and (5) remnants of deep water from the Antarctic circumpolar region - freshest of the bottom waters. Despite the differences of characteristics of the source waters, the NADW is relatively uniform. Because the formation of each of the five source waters may be viewed as a response to a complex series of events, it is difficult to examine the sensitivity of NADW to environmental fluctuations. It is known that the deep northern North Atlantic is relatively closely coupled to the sea surface in the Greenland and Iceland seas. The most recent studies indicate a minimum response time of only two years between the introduction of a passive signal north of Iceland and its appearance in the deep northwest Atlantic.

James H Swift↗

NASA NTRS1990

Precise monitoring of global temperature trends from satellites

Passive microwave radiometry from satellites provides more precise atmospheric temperature information than that obtained from the relatively sparse distribution of thermometers over the earth's surface. Accurate global atmospheric temperature estimates are needed for detection of possible greenhouse warming, evaluation of computer models of climate change, and for understanding important factors in the climate system. Analysis of the first 10 years (1979 to 1988) of satellite measurements of lower atmospheric temperature changes reveals a monthly precision of 0.01 C, large temperature variability on time scales from weeks to several years, but no obvious trend for the 10-year period. The warmest years, in descending order, were 1987, 1988, 1983, and 1980. The years 1984, 1985, and 1986 were the coolest.

Spencer, Roy W.↗

NASA NTRS1990

Investigation of several passive and active methods for turbulent flow separation control

Relative performance of several passive and active methods for controlling two-dimensional turbulent separated flow associated with a curved backward-facing ramp were investigated at low speeds. Surface static pressure measurement and oil flow visualization results indicate that submerged vortex generators, vortex generator jets, elongated arches at +-alpha, and large-eddy breakup devices at +-alpha placed near the baseline separation location reduce flow separation and increase pressure recovery. Spanwise cylinders reduce flow separation but decrease pressure recovery downstream. Arches with alpha = 0 deg, Helmholtz resonators, and Viets' fluidic flappers examined so far have no significant effect in reducing separation. Wall cooling computation indicates that separation delay on a partially cooled ramp is nearly the same as on a fully-cooled ramp while minimizing the frictional drag increase associated with the wall cooling process.

Lin, J. C.↗

NASA NTRS1992

Holographic data storage crystals for the LDEF

Lithium niobate is a significant electro-optic material, with potential applications in ultra high capacity storage and processing systems. Lithium niobate is the material of choice for many integrated optical devices and holographic mass memory systems. For crystals of lithium niobate were passively exposed to the space environment of the Long Duration Exposure Facility (LDEF). Three of these crystals contained volume holograms. Although the crystals suffered the surface damage characteristics of most of the other optical components on the Georgia Tech tray, the crystals were recovered intact. The holograms were severely degraded because of the lengthy exposure, but the bulk properties are being investigated to determine the spaceworthiness for space data storage and retrieval systems.

Callen, W. Russell↗

NASA NTRS1990

SPE (tm) regenerative hydrogen/oxygen fuel cells for extraterrestrial surface and microgravity applications

Viewgraphs on SPE regenerative hydrogen/oxygen fuel cells for extraterrestrial surface and microgravity applications are presented. Topics covered include: hydrogen-oxygen regenerative fuel cell energy storage system; electrochemical cell reactions; SPE cell voltage stability; passive water removal SPE fuel cell; fuel cell performance; SPE water electrolyzers; hydrophobic oxygen phase separator; hydrophilic/electrochemical hydrogen phase separator; and unitized regenerative fuel cell.

Mcelroy, J. F.↗