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Origin and chemistry of comets

Long-period and short-period comets are all derived from a steady flux of 'new' comets coming straight from the margin of a sphere whose radius is 50,000 AU (the Oort's cloud). No empirical evidence requires that the Oort's cloud be older than a few million years, but all satisfactory theories have so far linked its formation to the origin of the solar system. 'New' comets have a size distribution consistent with the accretion of planetesimals, in contrast with older comets that are consistent with a fragmentation distribution. The H, C, N, O elemental ratios to Si suggest the comets are more primitive than the most primitive meteorites, namely the C I chondrites. Their chemistry is poorly known, but observational data suggest a protosolar ratio of C/O at least as large as 0.66, and a drastic depletion of hydrogen in the solar nebula. This could for instance imply that the T Tauri phase of the sun happened prior to the condensation of comets. An alternate explanation is possible: the interstellar grains were relatively unprocessed during their contraction in the solar nebula, and their mantles, barely modified, would have followed suit in the accretion of comets.

Delsemme, A. H.↗

Assessment of the polycyclic aromatic hydrocarbon-diffuse interstellar band proposal

The potential link between neutral and/or ionized polycyclic aromatic hydrocarbons (PAHs) and the diffuse interstellar band (DIB) carriers is examined. Based on the study of the general physical and chemical properties of PAHs, an assessment is made of their possible contribution to the DIB carriers. It is found that, under the conditions reigning in the diffuse interstellar medium, PAHs can be present in the form of neutral molecules as well as positive and/or negative ions. The charge distribution of small PAHs is dominated, however, by two charge states at one time with compact PAHs present only in the neutral and cationic forms. Each PAH has a distinct spectral signature depending on its charge state. Moreover, the spectra of ionized PAHs are always clearly dominated by a single band in the DIB spectral range. In the case of compact PAH ions, the strongest absorption band is of type A (i.e., the band is broad, falls in the high-energy range of the spectrum, and possesses a large oscillator strength), and seems to correlate with strong and broad DIBs. For noncompact PAH ions, the strongest absorption band is of type I (i.e., the band is narrow, falls in the low-energy range of the spectrum, and possesses a small oscillator strength), and seems to correlate with weak and narrow DIBs. Potential molecular size and structure constraints for interstellar PAHs are derived by comparing known DIB characteristics to the spectroscopic properties of PAHs. It is found that (i) only neutral PAHs larger than about 30 carbon atoms could, if present, contribute to the DIBs. (ii) For compact PAHs, only ions with less than about 250 carbon atoms could, if present, contribute to the DIBs. (iii) The observed distribution of the DIBs between strong/moderate and broad bands on the one hand and weak and narow bands on the other can easily be interpreted in the context of the PAH proposal by a distribution of compact and noncompact PAH ions, respectively. A plausible correlation between PAH charge states and DIB "families" is thus provided by the PAH-DIB proposal. Following this proposal, DIB families would reflect conditions within a cloud which locally determine the relative importance of cations, anions, and neutral species, rather than tracers of a specific species. Observational predictions are given to establish the viability of the PAH hypothesis. It is concluded that small PAH ions are very promising candidates as DIB carriers provided their population is dominated by a finite number (100-200) of species. A key test for the PAH proposal, consisting of laboratory and astronomical investigations in the ultraviolet range, is called for.

NASA Discipline Number 52-10↗

Aperture synthesis mapping of molecular gas in high-luminosity IRAS galaxies

The Owens Valley millimeter-wave interferometer has been used for high-resolution mapping of the 2.6 mm CO emission from the high-luminosity infrared galaxies NGC 520 (Arp 157), NGC 7469 (Arp 298), and Arp 55. Assuming the same empirical relationship between CO brightness and molecular hydrogen surface mass density as has been found for giant molecular clouds in the Milky Way, it is found that the masses of H2 gas in these concentrations are 10 to the 9th - 10 to the 10th solar masses, typically one-third of the total molecular gas content of these galaxies. The interferometric sizes correspond to radii of 0.8 kpc (NGC 520), 1.4 kpc (NGC 7469), and less than 2.8 kpc (Arp 55). For the same regions the dynamical masses estimated from the CO line width and size of the emission region are only a factor of 3-5 higher. The mean molecular gas surface densities averaged over these regions are in the range 610-825 solar masses/sq pc, a factor of 10 brighter than those obtained for corresponding regions in the nucleus of the Milky Way. The high mass fractions obtained for the interstellar medium in the central regions of these three galaxies strongly suggest that large-scale gravitational instability in the gas may play an important role in the further concentration of the gas in the nucleus and in possibly precipitating a large-scale burst of star formation.

Sanders, D. B.↗

Assessment of the Polycyclic Aromatic Hydrocarbon-Diffuse Interstellar Band Proposal

The potential link between neutral and/or ionized polycyclic aromatic hydrocarbons (PAHs) and the diffuse interstellar band (DIB) carriers is examined. Based on the study of the general physical and chemical properties of PAHs, an assessment is made of their possible contribution to the DIB carriers. It is found that, under the conditions reigning in the diffuse interstellar medium, PAHs can be present in the form of neutral molecules as well as positive and/or negative ions. The charge distribution of small PAHs is dominated, however, by two charge states at one time with compact PAHs present only in the neutral and cationic forms. Each PAH has a distinct spectral signature depending on its charge state. Moreover, the spectra of ionized PAHs are always clearly dominated by a single band in the DIB spectral range. In the case of compact PAH ions, the strongest absorption band is of type A (i.e., the band is broad, falls in the high energy range of the spectrum, and possess a large oscillator strength), and seems to correlate with strong and broad DIBs. In the case of non-compact PAH ions, the strongest absorption band is of type I (i.e., the band is narrow, falls in the low energy range of the spectrum, and possess a small oscillator strength), and seems to correlate with weak and narrow DIBs. Potential molecular size and structure constraints for interstellar PAHs are derived by comparing known DIB characteristics to the spectroscopic properties of PAHs. It is found that: (i) Only neutral PAHs larger than about 30 carbon atoms could, if present, contribute to the DIBs. (ii) For compact PAHs, only ions with less than about 250 carbon atoms could, if present, contribute to the DIBs. (iii) The observed distribution of the DIBs between strong/moderate and broad bands on the one hand and weak and narrow bands on the other hand can easily be interpreted in the context of the PAH proposal by a distribution between compact and non-compact PAH ions, respectively. A plausible correlation between PAH charge states and DIB "families" is thus provided by the PAH-DIB proposal. Following this proposal, DIB families would provide tracers of conditions within a cloud which globally determine the relative importance of cations, anions, and neutral species, rather than tracers of a specific species. Observational predictions are given to establish the viability of the PAH hypothesis. It is concluded that small PAH ions are very promising candidates as DIB carriers provided their population is dominated by a finite number (100-200) of species. A key test for the PAH proposal, consisting of laboratory and astronomical investigations of the ultraviolet range, is called for.

Salama, Farid↗

The Interaction of Hot and Cold Gas in the Disk and Halo of Galaxies

Most of the thermal energy in the Galaxy and perhaps most of the baryons in the Universe are found in hot (log T approximately 5.5 - 7) gas. Hot gas is detected in the local interstellar medium, in supernova remnants (SNR), the Galactic halo, galaxy clusters and the intergalactic medium (IGM). In our own Galaxy, hot gas exists in large superbubbles up to several hundred pc in diameter that locally dominate the interstellar medium (ISM) and determine its thermal and dynamic evolution. While X-ray observations using ROSAT, Chandra and XMM have allowed us to make dramatic progress in mapping out the morphology of the hot gas and in understanding some of its spectral characteristics, there remain fundamental questions that are unanswered. Chief among these questions is the way that hot gas interacts with cooler phase gas and the effects these interactions have on hot gas energetics. The theoretical investigations we proposed in this grant aim to explore these interactions and to develop observational diagnostics that will allow us to gain much improved information on the evolution of hot gas in the disk and halo of galaxies. The first of the series of investigations that we proposed was a thorough exploration of turbulent mixing layers and cloud evaporation. We proposed to employ a multi-dimensional hydrodynamical code that includes non-equilibrium ionization (NEI), radiative cooling and thermal conduction. These models are to be applied to high velocity clouds in our galactic halo that are seen to have O VI by FUSE (Sembach et ai. 2000) and other clouds for which sufficient constraining observations exist.

Slavin, Jonathan↗

Molecular growth upon ionization of van der Waals clusters containing HCCH and HCN is a pathway to prebiotic molecules

The growth mechanisms of organic molecules in an ionizing environment such as the interstellar medium are not completely understood. Here we examine by means of ab initio molecular dynamics (AIMD) simulations and density functional theory (DFT) computations the possibility of bond formation and molecular growth upon ionization of van der Waals clusters of pure HCN clusters, and mixed clusters of HCN and HCCH, both of which are widespread in the interstellar medium. Ionization of van der Waals clusters can potentially lead to growth in low temperature and low-density environments. Our results show, that upon ionization of the pure HCN clusters, strongly bound stable structures are formed that contain N∙∙∙H bonds, and growth beyond pairwise HCN molecules is seen only in a small percentage of cases. In contrast, mixed clusters, where HCCH is preferentially ionized over HCN, can grow up to 3 or 4 units long with new carbon–carbon and carbon–nitrogen covalent bonds. Moreover, cyclic molecules formed, such as the radical cation of pyridine, which is a prebiotic molecule. The results presented here are significant as they provide a feasible pathway for molecular growth of small organic molecules containing both carbon and nitrogen in cold and relatively denser environments such as in dense molecular clouds but closer to the photo-dissociation regions, and protoplanetary disks. In the mechanism we propose, first, a neutral van der Waals cluster is formed. Once the cluster is formed it can undergo photoionization which leads to chemical reactivity without any reaction barrier.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

The interstellar medium in the direction of the Crab Nebula - Reconciling soft X-ray and radio observations

The total soft X-ray photoabsorption cross section of the interstellar medium (ISM) in the direction of the Crab Nebula is computed on the basis of a two-phase model of the ISM. This cross section is used to reanalyze Copernicus data on the X-ray spectrum of the Crab between 0.7 and 1.5 keV. The total hydrogen column density along the line of sight to that nebula is found to be approximately 2.6 by 10 to the 21st power H atoms/sq cm. This result is evaluated in light of the two-phase model of the ISM, and the predictions based on the X-ray data are compared with results of radio and UV observations. A discrepancy between the radio and X-ray measurements of the hydrogen column density is resolved by noting that 21-cm absorption measurements sample only the neutral hydrogen in clouds while X-ray measurements are sensitive to all forms of hydrogen in both cloud and intercloud regions. It is suggested that roughly 50% of the hydrogen in the direction of the Crab Nebula is in clouds and that 85% of this hydrogen is neutral and atomic.

Ride, S. K.↗

Infrared fine-structure line diagnostics of shrouded active galactic nuclei

Far-infrared spectroscopy of celestial objects will improve dramatically in the coming decade, allowing astronomers to use fine-structure line emission to probe photoionized regions obscured in the optical band by thick clouds of dust. The ultraluminous far-IR galaxies revealed by IRAS, quasar-like in luminosity but smothered in molecular gas, probably conceal either immense starbursts or luminous active nuclei. In both scenarios, these objects ought to produce copious infrared fine-structure emission with several lines comparable to H(beta) in luminosity. This paper shows how these lines, if detected, can be used to determine the electron densities and far-IR obscurations of shrouded photoionized regions and to constrain the shape and ionization parameter of the ionizing spectra. The presence of (Ne V) emission in particular will distinguish shrouded AGN's from shrouded starbursts. Since all active galaxies photoionize at least some surrounding material, these diagnostics can also be applied to active galaxies in general and will aid in studying how an active nucleus interacts with the interstellar medium of its host galaxy.

Voit, G. M.↗

UV Spectral Variability and the Lyman-Alpha Forest in the Lensed Quasar Q0957+561

Far-ultraviolet spectra of the gravitational lens components Q0957+561 A and B were obtained with the Hubble Space Telescope Faint Object Spectrograph (FOS) at five equally spaced epochs, one every two weeks. We confirm the flux variability of the quasar's Lyman-alpha and O VI lambda 1037 emission lines reported in IUE (International Ultraviolet Explorer) spectra. The fluxes in these lines vary on a time scale of weeks in the local rest frame (LRF), independently of each other and of the surrounding continuum. The individual spectra of each image were co-added to investigate the properties of the Lyman-alpha forest along the two lines of sight to the quasar. Absorption lines having equivalent width W (sub lambda) greater than or equal to 0.3 Angstroms in the LRF not previously identified as interstellar lines, metal lines, or higher order Lyman lines were taken to be LY-alpha forest lines. The existence of each line in this consistently selected set was then verified by its presence in two archival FOS spectra with approx. 1.5 times higher signal to noise than our co-added spectra. Ly-alpha forest lines with W (sub lambda) greater than or equal to 0.3 Angstroms appear at 42 distinct wavelengths in the spectra of the two images. Two absorption lines in the spectrum of image A have no counterpart at that wavelength in the spectrum of image B, and two lines in image B have no counterpart in image A. Based on the separation of the lines of sight at the redshift of the absorption lines appearing in only one spectrum, the density of the absorbing clouds in the direction of Q0957+561 must change significantly over a distance of 79 (+34, -26) h (sub 50) (sup -1) kpc in the simplified model where the absorbers are treated as spherical clouds and the characteristic dimension is the radius. (We adopt H (sub 0)= 50 h (sub 50) km s (sup -1) kpc (sup -1), q (sub 0) = 1/2, and LAMBDA = 0 throughout the paper.) The two limits define the 68% confidence interval on the characteristic dimension, equivalent to the 1 sigma confidence interval for a Gaussian distribution. The 95% confidence interval extends from (32 - 250) h (sub 50) (sup -1) kpc. We show in the Appendix that the fraction of Ly-alpha forest lines that appear in only one spectrum can be expressed as a rapidly converging power series in 1/r, where r the ratio of the radius of the cloud to the separation of the two LOS at the redshift of the cloud. This power series can be rewritten to give r in terms of the fraction of Ly-alpha forest wavelengths that appear in the spectrum of only one image. A simple linear approximation to the solution which everywhere agrees with the power series solution to better than 0.8% for r greater than or equal to 2 is derived in the Appendix.

Dolan, J. F.↗

Interacting dust grains in complex plasmas: Ion wake formation and the electric potential

Dust grains have been used as minimally invasive probes to determine plasma parameters including the plasma density, temperature, and electric field in a plasma discharge. However, the dust grains in a plasma generate local potential disturbances due to the collection of charge and the subsequent electrostatic interactions between the dust and charged plasma particles. Dust grains in close proximity to one another exhibit interesting non-reciprocal interactions and self-organize into structures such as one-dimensional filamentary chains, two-dimensional “zigzags,” and three-dimensional helices, among others. The formation of these structures suggests that although the dust grains may be less invasive than traditional plasma probes, the disturbance to the local plasma environment introduced by dust grains is non-trivial. Commonly used analytic forms of the electric potential describing complex plasmas have failed to resolve the near-dust region, and as a result are insufficient to provide insight about the formation of complex dust structures. Here, we use an N-body simulation to compute the electric potential from ion densities near various dust grain configurations. We provide an alternative description to the standard analytic model for the electric potential of dust and ion wakes based on a Gaussian shaped cloud of ions. The electric potential obtained from simulations is used to identify minimum energy configurations for two and three dust grains. It is further demonstrated that the minimum potential region identified for N dust grains and their associated ion wakes does not predict the minimum-energy configuration of N + 1 dust grains.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Numerical simulations of interacting disk galaxies

Galaxy-galaxy interactions have long attracted many extragalactic astronomers in various aspects. A number of computer simulations performed in the 1970s have successfully reproduced the peculiar morphologies observed in interacting disk galaxies and clarified that tidal deformation explains most of the observed global peculiarities. However, most of these simulations have used test particles in modelling the disk component. Tidal response of a self-gravitating disk remains to be further clarified. Another topic which is intensely discussed at present is the relation between galaxy-galaxy interactions and activity. Many observations suggest that interactions trigger strong starbursts and possibly active galactic nuclei (AGN). However, the detailed mechanism of triggering is not yet clear. It is vital here to understand the dynamics of interstellar gas. In order to understand various phenomena related to galaxy-galaxy interactions (mainly for disk galaxies), the author performed a series of numerical simulations on close galaxy encounters which includes both interstellar gas and self-gravitating disk components. In these simulations, the galaxy model to be perturbed (target galaxy) consists of a halo and a disk. The halo was treated as a rigid spherical gravitational field which is assumed to remain fixed during the interaction. The disk is composed of stars and gas. The stellar disk was constructed by 20000 collisionless particles of the same mass. Those particles move in the halo gravitational field, interacting with each other and with the perturber. Therefore, the self-graviy of the disk is properly taken into account. Stellar particles were initially given circular velocities with small random motions required to stabilize the disk against local axisymmetric disturbances. The gravitational field of the stellar disk was calculated by the particle-mesh scheme (e.g. Hockney and Eastwood 1981). The gaseous component was modelled by the cloud-particle scheme (e.g. Roberts and Hausman 1984). Here, the authors represent the gas as an ensemble of small spheres (i.e. clouds) and include the creation of an OB star in a cloud-cloud collision and subsequent velocity push on nearby clouds due to a supernova explosion.

Noguchi, Masafumi↗

Large-scale characteristics of interstellar dust from COBE DIRBE observations

Observations from the COBE Diffuse Infrared Background Experiment of the 140 and 240 micrometer emissions from the Galatic plane region (absolute value of b less than 10 deg) are combined with radio surveys that trace the molecular (H2), neutral atomic (H I), and extended low-density (n(sub e) approximately 10 to 100/cm(exp 3)) ionized (H II) gas phases of the interstellar medium to derive physical conditions such as the dust temperature, dust-to-gas mass ratio, and far-infrared emissivity (1) averaged over these gas phases along each line of sight and (2) within each of these three gas phases. This analysis shows large-scale longitudinal and latitudinal gradients in the dust temperature and a decrease in dust temperature with increasing Galactocentric distance. The derived dust temperatures are significantly different from those derived in similar analyses using the Infrared Astronomical Satellite (IRAS) 60 and 100 micrometer data, suggesting that small (5 A approximately less than radius approximately less than 200 A) transiently heated dust particles contribute significantly o the Galactic 60 micrometer emission. It is found that 60% to 75% of the far-infrared luminosity arises from cold (approximately 17 to 22 K) dust associated with diffuse H I clouds, 15% to 30% from cold (approximately 19 K) dust associated with molecular gas, and less than 10% from warm (approximately 29 K) dust in extended low-density H II regions, consistent with the results of the IRAS analyses of the Galactic 60 and 100 micrometer emission. Within 2 deg of longitude of the Galactic center, the derived gas-to-dust mass ratio along the line of sight, G(sub d), reverses its general trend of decreasing G(sub d) toward the inner Galaxy and increases by a factor of approximately 2 to 3 toward the Galactic center. One possible explanation for this result is that the ratio of H2 column density to (12)CO intensity is lower in the Galactic center region than in the Galactic disk.

Sodroski, T. J.↗

Shocked carbon monoxide in G333.6-0.2

Rotationally excited carbon monoxide has been detected in the Galactic H II region/molecular cloud complex G333.6-0.2 in the 163-micron J = 16 to 15 and 186-micron J = 14 to 13 transitions. These detections, together with an upper limit to the J = 21 to 20 transition at 124 microns indicate that the excited CO emission comes from gas of kinetic temperature 200 to 800 K and pressure of about 5 x 10 to the 7th/cu cm. A high-resolution spectrum of the J = 14 to 13 transition shows CO emission over more than 80 km/s, possibly with a double peaked profile centered near the systemic velocity of G333.6-0.2. The far-infrared CO emission probably comes from shocked gas in the mass outflow from newly formed, massive stars. The detection of the J = 14 to 13 transition is the first to be made of this line in any source, and is the longest wavelength line yet detected in interstellar space by nonheterodyne techniques.

Storey, J. W. V.↗

On the nature of the intercloud medium

Previous analyses of Copernicus observations of interstellar absorption in the spectra of unreddened stars are reviewed in the framework of steady-state ionization models for the intercloud (low-density) component of the interstellar medium. A simple homogeneous model is described which accounts for the H, C, N, S, and Si interstellar lines in the spectrum of lambda Sco in terms of an extensive low-density medium photoionized by Lyman continuum radiation from the II Sco OB association. Quantitative constraints are placed on the maximum permissible flux of diffuse soft X-rays, and the model is generalized to interpret the observed ion, electron, and hydrogen column densities in the low-density medium. Severe constraints are found to be imposed on ionization models by the ratios Si III/Si, Si IV/Si, and S IV/S. It is concluded that the observations may be explained if 10 to 30% of a representative line of sight passes through a photoionized medium of density 0.1 to 0.2/cu cm, if H I constitutes the bulk of the gas along the line of site, and if the gas is at a similar density or is in the form of shielded clumps or clouds.

Hill, J. K.↗

Abundances of interstellar atoms from ultaviolet absorption lines

The equivalent widths of interstellar absorption lines of Mg II, P II, Cl I and II, Mn II, Fe II, Cu II, and Ni II, obtained in a Copernicus survey of Bohlin et al (1983) have been analyzed to yield column densities along the lines of sight. The measured depletions are clearly correlated with n sub H, the mean hydrogen column density along the line of sight. Depletions also seem to be weakly correlated with various ratios of hydrogen to extinction by dust grains and also variations of extinction with wavelength, although part of these effects are a secondary result of the correlation with n sub H. The apparent coupling of depletion to the mean density are interpreted in terms of an idealized model due to Spitzer (1985), where each element has one value of depletion in the low-density, warm, neutral gas and an enhanced, different value in cold clouds. The difference of apparent depletions for Mg, P, Cl, Mn, and Fe between warm and cold clouds averages 0.44 + or - 0.12 (rms) dex, and, after an allowance for observational errors is made, the scatter of individual depletions from the overall trend predicted by method is only about 0.10 dex. The identification of the observed apparent depletions with actual ones, while very likely, is not entirely secure, because of the possible presence of highly saturated compoents with very narrow profiles and the possible contamination of the results by H II regions.

Jenkins, E. B.↗

The magnetic field geometry in the vicinity of HH 7-11/HH 12 and HH 33/HH 40

The small-scale structure of the interstellar magnetic field in the vicinity of the Herbig-Haro objects HH 7-11/HH 12 and HH 33/40 is derived from CCD imaging polarimetry of stars nearby to these young stellar object driven outflows. The outflow associated with SVS 13/HH 7-11 lies approximately parallel to the local field direction. The outflow mapped by HH 33/HH 40 is also well aligned with the local magnetic field. However, the orientation of the outflow associated with HH 12 located 2 arcmin to the north of HH 7-11 is offset from the inferred magnetic field direction by 60 deg. These results taken together with those of previous studies suggest: (1) magnetic fields are directly or indirectly responsible for the observed orientation of outflows associated with newborn stars in the majority of cases; and (2) in some cases, the flow properties may depend upon other characteristics of the parent cloud core.

Heyer, Mark H.↗

The Contribution of Thermally-Pulsing Asymptotic Giant Branch and Red Supergiant Starts to the Luminosities of the Magellanic Clouds at 1-24 micrometers

We present the near-through mid-infrared flux contribution of thermally-pulsing asymptotic giant branch (TP-AGB) and massive red supergiant (RSG) stars to the luminosities of the Large and Small Magellanic Clouds (LMC and SMC, respectively). Combined, the peak contribution from these cool evolved stars occurs at approx 3 - 4 micron, where they produce 32% of the SMC light, and 25% of the LMC flux. The TP-AGB star contribution also peaks at approx 3 - 4 micron and amounts to 21% in both galaxies. The contribution from RSG stars peaks at shorter wavelengths, 2.2 micron, where they provide 11% of the SMC flux, and 7% for the LMC. Both TP-AGB and RSG stars are short lived, and thus potentially impose a large stochastic scatter on the near-IR derived mass-to-light (M/L) ratios of galaxies at rest-frame 1 - 4 micron. To minimize their impact on stellar mass estimates, one can use the M/L ratio at shorter wavelengths (e.g., at 0.8 - 1 micron). At longer wavelengths (much > 8 micron), emission from dust in the interstellar medium dominates the flux. In the LMC, which shows strong polycyclic aromatic hydrocarbon (PAH) emission at 8 micron, TP-AGB and RSG contribute less than 4% of the 8 micron flux. However, 19% of the SMC 8 micron flux is from evolved stars, nearly half of which is produced by the rarest, dustiest, carbon-rich TP-AGB stars. Thus, star formation rates of galaxies, based on an 8 micron flux (e.g., observed-frame 24 micron at z = 2), may be biased modestly high, especially for galaxies with little PAH emission.

Melbourne, J.↗

Photodissociation regions

Photodissociation regions are interstellar regions of predominantly neutral gas where the FUV radiation field plays a significant role in the chemistry and/or the heating. Photodissociation, grain attenuation of the FUV flux and grain photoelectric heating lead to copious emission of C II (158 microns), O I (63 microns), Si II (35 microns), C I (370,609 microns), H2 vibrotational and CO rotational transitions, and IR continuum. Theoretical models compared with observations diagnose such physical parameters as the density and temperature structure, the elemental abundances, and the FUV radiation field. Applications are made to Orion, M17 and galactic nuclei. Theoretical photodissociation models can explain the correlation in the C II (158 microns) and CO J = 1-0 emission and the correlation of the CO J = 1-0 luminosity with the molecular mass. Theoretical models also point to feedback mechanisms which may control the rate of star formation in galaxies and which may regulate the column density through giant molecular clouds.

Hollenbach, David J.↗