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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,639 records · Page 91
All sourcesNASA NTRSDOE OSTI
NASA NTRS2009

Assessment of SOI AND Gate, Type CHT-7408, for Operation in Extreme Temperature Environments

Electronic parts based on silicon-on-insulator (SOI) technology are finding widespread applications due to their ability to operate in harsh environments and the benefits they offer as compared to their silicon counterparts. Due to their construction, they are tailored for high temperature operation and show good tolerance to radiation events. In addition, their inherent design lessens the formation of parasitic junctions, thereby reducing leakage currents, decreasing power consumption, and enhancing speed. These devices are typically rated in temperature capability from -55 C to about +225 C, and their characteristics over this temperature range are documented in data sheets. Since electronics in some of NASA space exploration missions are required to operate under extreme temperature conditions, both cold and hot, their characteristic behavior within the full temperature spectrum must be determined to establish suitability for use in space applications. The effects of extreme temperature exposure on the performance of a new commercial-off-the-shelf (COTS) SOI AND gate device were evaluated in this work. The high temperature, quad 2-inputs AND gate device, which was recently introduced by CISSOID, is fabricated using a CMOS SOI process. Some of the specifications of the CHT-7408 chip are listed in a table. By supplying a constant DC voltage to one gate input and a 10 kHz square wave into the other associated gate input, the chip was evaluated in terms of output response, output rise (t(sub r)) and fall times (tf), and propagation delays (using a 50% level between input and output during low to high (tPLH) and high to low (tPHL) transitions). The supply current of the gate circuit was also obtained. These parameters were recorded at various test temperatures between -195 C and +250 C using a Sun Systems environmental chamber programmed at a temperature rate of change of 10 C/min. In addition, the effects of thermal cycling on this chip were determined by exposing it to a total of 12 cycles between -195 C and +250 C. Following the cycling activity, measurements were performed again at the test temperatures of -195 C, +21 C, and +250 C.

Patterson, Richard↗
NASA NTRS2011

Advances in Ceramic Matrix Composite Blade Damping Characteristics for Aerospace Turbomachinery Applications

For advanced aerospace propulsion systems, development of ceramic matrix composite integrally-bladed turbine disk technology is attractive for a number of reasons. The high strength-to-weight ratio of ceramic composites helps to reduce engine weight and the one-piece construction of a blisk will result in fewer parts count, which should translate into reduced operational costs. One shortcoming with blisk construction, however, is that blisks may be prone to high cycle fatigue due to their structural response to high vibration environments. Use of ceramic composites is expected to provide some internal damping to reduce the vibratory stresses encountered due to unsteady flow loads through the bladed turbine regions. A goal of our research was to characterize the vibration viscous damping behavior of C/SiC composites. The vibration damping properties were measured and calculated. Damping appeared to decrease with an increase in the natural frequency. While the critical damping amount of approximately 2% is required for typical aerospace turbomachinery engines, the C/SiC damping at high frequencies was less than 0.2% from our study. The advanced high-performance aerospace propulsion systems almost certainly will require even more damping than what current vehicles require. A purpose of this paper is to review some work on C/SiC vibration damping by the authors for the NASA CMC turbine blisk development program and address an importance of the further investigation of the blade vibration damping characteristics on candidate CMC materials for the NASA s advanced aerospace turbomachinery engine systems.

Min, James B.↗
NASA NTRS2012

Characteristics of Control Laws Tested on the Semi-Span Super-Sonic Transport (S4T) Wind-Tunnel Model

The Semi-Span Supersonic Transport (S4T) is an aeroelastically scaled wind-tunnel model built to test active controls concepts for large flexible supersonic aircraft in the transonic flight regime. It is one of several models constructed in the 1990's as part of the High Speed Research (HSR) Program. Control laws were developed for the S4T by M4 Engineering, Inc. and by Zona Technologies, Inc. under NASA Research Announcement (NRA) contracts. The model was tested in the NASA-Langley Transonic Dynamics Tunnel (TDT) four times from 2007 to 2010. The first two tests were primarily for plant identification. The third entry was used for testing control laws for Ride Quality Enhancement, Gust Load Alleviation, and Flutter Suppression. Whereas the third entry only tested FS subcritically, the fourth test demonstrated closed-loop operation above the open-loop flutter boundary. The results of the third entry are reported elsewhere. This paper reports on flutter suppression results from the fourth wind-tunnel test. Flutter suppression is seen as a way to provide stability margins while flying at transonic flight conditions without penalizing the primary supersonic cruise design condition. An account is given for how Controller Performance Evaluation (CPE) singular value plots were interpreted with regard to progressing open- or closed-loop to higher dynamic pressures during testing.

Christhilf, David M.↗
NASA NTRS2014

Shuttle Engine Designs Revolutionize Solar Power

The Space Shuttle Main Engine was built under contract to Marshall Space Flight Center by Rocketdyne, now part of Pratt & Whitney Rocketdyne (PWR). PWR applied its NASA experience to solar power technology and licensed the technology to Santa Monica, California-based SolarReserve. The company now develops concentrating solar power projects, including a plant in Nevada that has created 4,300 jobs during construction.

Source record↗
NASA NTRS2015

Towards the Use of Space Resources

Humans are making technological progress at leveraging resources in space. Ames is a pioneer in In-Situ Resource Utilization (ISRU). ISRU is among the only cost-effective ways to construct habitats off-world.

ISRU↗
NASA NTRSDate not supplied

Overview of NASA’s Break the Ice Lunar Challenge Phase 1

As NASA works to extend human exploration of the solar system, a sustained presence on the Moon will be critical for developing and testing the technologies and systems needed for future missions to Mars and beyond. In situ resource utilization (ISRU)—the use of lunar materials for life support, fuel, energy, manufacturing, and construction—is necessary to limit the delivery of supplies from Earth. One of the most important of these resources is water. Water supports all life on Earth and will be critical to supporting human exploration beyond Earth. On the Moon, water is trapped in icy regolith at the lunar poles, including inside permanently dark and cold craters. Novel approaches are needed to excavate the icy regolith and transport it for processing in support of permanent human missions on the Moon. To accelerate the development of such approaches and to seek diverse ideas, NASA’s Centennial Challenges launched the Break the Ice Lunar Challenge in November 2020. Phase 1 of the challenge was focused on stimulating innovative approaches for excavating icy regolith and delivering water in extreme lunar environmental conditions. The challenge sought to incentivize solutions for maximizing water delivery while minimizing energy use and the mass of equipment required to be transported to the lunar surface. Submissions for phase 1 of the challenge were due in June 2021 and winners were announced in August 2021. This paper provides details about the execution of the challenge, solutions received, criteria used to select winning solutions, and status of the phase 2 of the challenge.

Naveen Vetcha↗
DOE OSTI2022

Microstructural Characterization of A709 Commercial Heats with Precipitation Treatment

This report discusses work conducted at Idaho National Laboratory in fiscal year 2022 associated with the precipitates in Alloy 709 (A709). The purpose of this work is to support the development of the A709 Code Cases to qualify A709 in Section III, Division 5 of the American Society of Mechanical Engineers Boiler and Pressure Vessel Code. This would permit the use of A709 for elevated-temperature nuclear construction. This work encompassed two broad goals. The first goal was to understand the microstructure of the second commercial heat of plate A709 purchased through the Advanced Reactors Technologies Program in both the solution-annealed and precipitation-treated conditions. Transmission electron microscopy was utilized to characterize these microstructures. Direct comparisons were then made between the solution-annealed and precipitation-treated conditions as well as between the first and second commercial heats of plate A709. The second goal was to understand the impact of variations in the time and temperature of the precipitation treatment on the properties of A709. The precipitation treatment temperature was varied from 750°C to 800°C for times ranging from 3 hours to 30 hours. The hardness of each precipitation treatment variation was measured. All of the precipitation treatment variations investigated besides a specimen from the second commercial heat of plate A709 precipitation treated at 800? for 9 hours met the room-temperature hardness requirement specified in ASTM A213 and SA-213 for UNS S31025. The hardness measured for the specimen from the second commercial heat of plate A709 that was precipitation treated at 800? for 9 hours is considered an outlier. The next step is to look at the extremes of the precipitation treatment variations investigated and conduct elevated-temperature mechanical testing. The purpose of this testing would be to assess if these time and temperature variations have any impact on the mechanical performance.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2022

Development of Non-Nuclear Microreactor Experimental Capability

Microreactors, or small, transportable reactors with a capacity of 20 MWTH or less, are sought to provide heat and power for myriad applications in remote areas, military installations, emergency operations, humanitarian missions, and disaster relief zones. These small, transportable reactor designs, while offering many advantages, are largely untested and unproven. A non-nuclear system and component testing capability is needed to demonstrate to regulators that these designs are safe and to convince customers that the systems are robust, reliable, and efficient. Idaho National Laboratory has constructed the microreactor agile non-nuclear experimental test bed (MAGNET) to assist with the development, demonstration, and validation of microreactor components and systems. MAGNET will support microreactor technology maturation to reduce uncertainty and risk relative to the operation and deployment of this unique class of systems. Stakeholders for this test bed include microreactor developers, energy users, and regulators. Regulators will be engaged early in the design and testing to expedite regulatory approval and licensing.

42 ENGINEERING↗
NASA NTRSDate not supplied

NASA’s Top Human System Research and Technology Needs for Mars

NASA is working with industry and international partners to return humans to the moon and eventually enable a human Mars mission. Within NASA, several organizations work together to identify, prioritize, fund, execute, and operationalize the crew health and performance (CHP) research and technology development (R&D) necessary to enable these future missions. These organizations include flight programs as well as other organizations such as the Health and Medical Technical Authority (HMTA), Human Research Program, Space Technology Mission Directorate, and System Capability Leadership Teams, each of which existed for several years prior to the creation of the Moon-to-Mars (M2M) Program Office in 2023. A variety of constructs, vocabularies, and processes exist for the management of risks and strategic planning across these organizations. For example, M2M objectives, program risks, human system risks, human research gaps, capability gaps, and envisioned futures are all constructs currently used within NASA for identifying and prioritizing R&D needs. Alignment and evolution of these strategic planning constructs is ongoing and will allow for alignment and traceability between M2M objectives and R&D investments at a detailed level. While this reorganization is ongoing, and even after it is established, there is a recognized need among stakeholder organizations to identify and communicate the highest CHP R&D priorities in a unified and digestible way that synthesizes the considerations and perspectives of the CHP community across NASA. To achieve this, the HMTA facilitated a series of group discussions with representatives of NASA’s CHP community, which culminated in a product identifying the eight highest priority mission-enabling CHP capabilities for human missions to Mars, referred to as the “Top Human System Capability Needs for Mars”. The list includes Earth-Independent Human Operations; Mars Duration Food System; Mars Duration Effects on Human Physiology; Risks Mitigations for Vehicle Atmospheres; Computational Injury & Anthropometric Models; Exploration Exercise Countermeasures; Individual Variability in Responses to Spaceflight; and Sensorimotor Countermeasures. Existing strategic planning and risk management tools and processes were considered, as well as practicalities of technical, cost, and schedule feasibility associated with potential R&D risk mitigations and technology solutions. The product is not owned by any one organization and does not replace existing strategic or program planning processes; rather it aims to complement and inform them with a unified set of community generated priorities. It is anticipated that this list will be re-evaluated periodically based on R&D progress and the evolving M2M architecture.

Life Support↗
DOE OSTI2021

In Situ Wood Delignification toward Sustainable Applications

As one of the most abundant and versatile natural materials on Earth, recently wood has attracted tremendous attention from scientists and engineers due to its outstanding advantages, including hierarchically porous microstructure, high mechanical strength, environmental friendliness, renewability, and biodegradability. Wood’s hierarchically porous structure and chemical components (e.g., cellulose, hemicelluloses, and lignin) enable its mechanical, ionic, optical, and thermal properties to be tuned via physical, chemical, and/or thermal modifications. Among these various approaches, the chemical delignification of bulk wood is the most fascinating, in which the majority of lignin and hemicelluloses is removed while leaving the cellulose intact, maintaining wood’s physical integrity and hierarchical structure. This delignified structure is unique, composed of hollow, aligned channels made up of cellulose microfibrils, and particularly attractive given its origin from a sustainable and renewable resource. As a result, delignified wood has attracted increasing attention for applications that go far beyond traditional wood utilization, such as lightweight yet strong structural materials, energy storage and conversion, environmental remediation, flexible electronics, and bioengineering. Here, we review recent developments in bulk wood delignification strategies toward the achievement of such advanced wood technologies for sustainable applications, with a focus on the research in our group. Similar to chemical pulping and bleaching, wood delignification involves a series of nucleophilic reactions based on alkaline Na 2 SO 3 or Na 2 S systems (i.e., chemical pulping) or electrophilic, radical, and oxidation reactions based on H 2 O 2 , ClO 2 , or NaClO systems (i.e., chemical bleaching) to deconstruct, fragment, and promote the hydrophilicity of lignin macromolecules, which finally make lignin easier to be removed. We discuss the structure and properties of partially and near-completely delignified wood, with a focus on process-structure–property relationships. The resulting delignified wood materials, with tunable structure and properties, demonstrate various advanced functions, in a wide range of advanced applications, such as building and construction, green energy, and electronics. Finally, the potential challenges and appealing perspectives of in situ wood delignification are discussed. In situ wood delignification, as a powerful modification strategy, has speeded up the development of advanced wood technologies and wood-based functional materials and products.

36 MATERIALS SCIENCE↗
NASA NTRS1995

Advanced solar panel designs

This paper describes solar cell panel designs that utilize new hgih efficiency solar cells along with lightweight rigid panel technology. The resulting designs push the W/kg and W/sq m parameters to new high levels. These new designs are well suited to meet the demand for higher performance small satellites. This paper reports on progress made on two SBIR Phase 1 contracts. One panel design involved the use of large area (5.5 cm x 6.5 cm) GaAs/Ge solar cells of 19% efficiency combined with a lightweight rigid graphite fiber epoxy isogrid substrate configuration. A coupon (38 cm x 38 cm) was fabricated and tested which demonstrated an array specific power level of 60 W/kg with a potential of reaching 80 W/kg. The second panel design involved the use of newly developed high efficiency (22%) dual junction GaInP2/GaAs/Ge solar cells combined with an advanced lightweight rigid substrate using aluminum honeycomb core with high strength graphite fiber mesh facesheets. A coupon (38 cm x 38 cm) was fabricated and tested which demonstrated an array specific power of 105 W/kg and 230 W/sq m. This paper will address the construction details of the panels and an a analysis of the component weights. A strawman array design suitable for a typical small-sat mission is described for each of the two panel design technologies being studied. Benefits in respect to weight reduction, area reduction, and system cost reduction are analyzed and compared to conventional arrays.

Ralph, E. L.↗
DOE OSTI2024

Achieving Unprecedented CO 2 Utilization InCO 2 Concrete™: System Design, Product Development and Process Demonstration

Anthropogenic sources of carbon dioxide are generated from a number of sources, but the key among these are ordinary Portland cement (OPC) production and combustion of fossil fuels. Cement production is the largest global CO 2 source from the mineral decomposition of carbonates. This is due to the clinkering process whereby limestone (mainly consisting of CaCO 3 ) is decomposed into CaO and CO 2 , and combined with silica rich clays at high temperatures to form clinkers (i.e. the four key minerals that comprise cement). The high temperature range of 1400 – 1550°C required for this process accounts for up to 60% of the generated CO 2 from cement production. Combination of the limestone decomposition and thermal requirements of the clinkering process causes cement production to contribute 8-9% of annual global CO 2 emissions. Combustion of fossil fuels (coal, oil and gas) was shown to contribute a much larger portion of global CO 2 emissions. As of 2018, combustion of fossil fuels accounted for 65% of global CO 2 , where 41% was derived from stationary sources for electricity and heat generation and the other 24% was related to transport. To reduce these contributions, key steps forward in CO 2 utilization technologies are required. Therefore, a CO 2 mineralization technology (CO 2 mineralization concrete) to reduce the OPC content in concrete, while utilizing flue gas emissions from fossil fuel combustion has been developed to address both areas simultaneously. This Reversa™ technology utilizes low-carbon cementation agents produced by in situ CO 2 mineralization (“mineral carbonation reactions”) to offer a promising alternative to OPC. CO 2 mineralization relies upon the reaction of dissolved CO 2 with inorganic alkaline reactants to precipitate mineral carbonates (e.g., CaCO 3 ), which bind proximate particles and achieve cementation. Herein, a concrete green body, which is composed of a mixture of binder, water, and mineral aggregates, is exposed to CO 2 borne in industrial flue gas streams. This manner of CO 2 mineralization allows the production of construction components that feature equivalent engineering attributes as their OPC-based counterparts while featuring a much smaller embodied carbon intensity (eCI). The purpose of this project is to demonstrate the feasibility of the Reversa process evolving from a TRL-3 technology at the bench-scale up to TRL-6 technology at the pilot-scale. The reliability of the Reversa technology was tested to prove the effective production of three standard industrial concrete products selected during the course of the project. The results detailed herein will demonstrate the evolution of this technology to the industrial scale. The culmination of this work resulted in 9 production runs completed at the National Carbon Capture Center (NCCC), Wilsonville, AL, using natural gas (NG) flue gas as the CO 2 source. Over the course of the production runs at NCCC, the CO 2 utilization as a function of time, 24-h CO 2 uptake, electricity usage, and 28-d net area compressive strength recorded for each run. Collection of this data will be used to determine the success of the demonstration goals: (1) achieving in excess of 0.2gCO 2 /g reactant , (2) achieving greater than 50% reduction in global warming potential compared to standard produced units, and (3) ensuring compliance of carbonated concrete with industry standard specifications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

Illinois Storage Corridor - CarbonSAFE Phase III: Policy, Regulatory, Legal and Permitting Characteristics; Subtask 5.5

The Illinois Storage Corridor (ISC) project aims to advance the commercial development and implementation of carbon capture and storage (CCS) technologies within a region in Illinois of suitable geology for carbon dioxide (CO 2 ) storage in deep saline aquifers. The project partners have annual emissions greater than 6.5 million tonnes per year; storage hubs are being explored at two sites—one near the One Earth Energy facility in east-central Illinois, and one near the Prairie State Generating Company campus in southwest Illinois. To implement the technology, legal, policy, and economic considerations must be explored. The United States Environmental Protection Agency (US EPA) administers the Underground Injection Control (UIC) program and is responsible for issuing Class VI permits to construct and operate CO 2 injection wells, i.e., a UIC Class VI well permit is required to inject CO 2 into the subsurface for geologic sequestration. The largest consideration of the Class VI well requirements is to protect underground sources of drinking water (USDWs). Additionally discussed are considerations for Class VI permits relating to public engagement. Besides permitting, property rights to storage sites, subsurface pore spaces, and areas for pipeline transportation must be secured. Pore space rights is still a novel concept being explored and not yet addressed by the Illinois legislature. It is believed that surface property rights are required for the subsurface pore space below, so long as there is not a separated mineral estate in the subsurface. Illinois legislature has addressed securing rights-of-way for CO 2 transportation, allowing for easements and the exercise of eminent domain to secure such rights. Economically, the incentives for CCS are ever-expanding. Recently, the federal government broadened the availability and increased the dollar-amounts for the § 45Q tax credits for geological storage of carbon oxides. Congress has also authorized the Advanced Industrial Facilities Development Program which allocates billions of dollars in funds to installing technology at industrial facilities to reduce greenhouse gas emissions. On the state level, Illinois has had its own incentives for CCS projects since 2009 and expanded its emission-related goals again in 2021. The law enacted in 2021 specifically creates a commission to explore implementing CCS at Prairie State Generating Company, a partner on the Illinois Storage Corridor project.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2010

HDU Pressurized Excursion Module (PEM) Prototype Systems Integration

The Habitat Demonstration Unit (HDU) project team constructed an analog prototype lunar surface laboratory called the Pressurized Excursion Module (PEM). The prototype unit subsystems were integrated in a short amount of time, utilizing a skunk-works approach that brought together over 20 habitation-related technologies from a variety of NASA centers. This paper describes the system integration strategies and lessons learned, that allowed the PEM to be brought from paper design to working field prototype using a multi-center team. The system integration process included establishment of design standards, negotiation of interfaces between subsystems, and scheduling fit checks and installation activities. A major tool used in integration was a coordinated effort to accurately model all the subsystems using CAD, so that conflicts were identified before physical components came together. Some of the major conclusions showed that up-front modularity that emerged as an artifact of construction, such as the eight 45 degree "pie slices" making up the module whose steel rib edges defined structural mounting and loading points, dictated much of the configurational interfaces between the major subsystems and workstations. Therefore, 'one of the lessons learned included the need to use modularity as a tool for organization in advance, and to work harder to prevent non-critical aspects of the platform from dictating the modularity that may eventually inform the fight system.

Gill, Tracy R.↗
NASA NTRS2005

Youth Technology Academy

One of the most important aspects of the YTA Program is that students, working with Tri-C instructors, NASA engineers, and technicians, begin to build relationships with professionals with whom they might not normally have contact. These professionals serve as role models for students and help them to apply math, science and problem-solving skills in real time to construct a competition-ready robot, allowing them to experience the satisfaction and challenges of an engineering or technical career by working diligently to solve problems that may never have been thought possible to solve. Transcending school boundaries, YTA is available to all students who are interested and qualified but who may otherwise never get an opportunity to participate because their school does not offer a robotics program. YTA fills an educational void by offering an exciting engineering and technology experience to a greater number of students than have been able to participate in the past. Our students have been working hard and see the long-term rewards for their efforts. The YTA Team 1270 was a finalist at the 2005 FIRST Robotics Florida Regional and took home second- place honors. Mark Poljak, nominated by the students of YTA Team 1270, received the Woodie Flowers Award at the FIRST 2005 Buckeye Regional competition. This award celebrates effective communication in the art and science of engineering and design. The YTA Team was also invited, as one of fifty-four teams, to participate in this year s FIRST VEX Robotics tournament representing Cuyahoga Community College and NASA GRC (Team 26), held at the FIRST Robotics National Competition in Atlanta, GA. Because of our efforts, community colleges from around the country have taken notice and have asked us to become part of the executive board of the RoboEducators, whose mission is to bring technology training to high school students in preparation for the future workforce.

Source record↗
DOE OSTI2022

Need for advanced research reactors for the next-generation reactor physics, analysis tools, and technology

Full text of publication follows. There is an urgent need for design and deployment of advanced research and test reactors in support of design, licensing and operation of advanced power reactors and education of next generation nuclear workforce. Existing research reactors mostly were designed and constructed decades ago with the main objectives of training operators, performing reactor physics experiments, and educating nuclear engineers and scientists. There are already gaps and significant concern about future capabilities for the existing research reactor facilities to address modern instrumentation and/or flexible environments for: performing reactor physics studies for advanced designs which have significantly different core materials forms and compositions, reactor shapes and size; validation of advanced high-fidelity software; development of machine learning algorithms for enhancement of human-machine collaboration in support of reactor monitoring, operation and safeguards; and, effective education of the next-generation workforce. The authors will focus on the need for advanced research reactors to improve and validate fast and accurate simulation tools for high-fidelity modeling and analysis of nuclear reactors in support of their design, optimization, licensing, operation, and monitoring. In the past, simulation tools were limited to relatively coarse models using approximate methodologies that benefited from two main factors: i) allowance for large margins and tolerances; ii) ability to construct prototype (e.g., zero power) reactors for adjustment of approximate methodologies. The next generation reactors have to be designed mainly by using novel high-fidelity computational tools that are accurate and fast, and therefore can be used for parametric studies and uncertainty quantification. To sufficiently demonstrate the accuracy of these tools, advanced research reactors are needed. The authors argue the need for new computational paradigms such as the MRT (Multistage, Response- function Transport) methodology which has resulted in the development of the novel high-fidelity RAPID (Real-time Analysis for Particle-transport and In-situ Detection) code system. Such code systems have to be robust in modeling any complex system, and should be fast and accurate, henceforth their uncertainties can be quantified at reasonable costs. Again, advanced research reactors are needed for the validation of the fidelity and accuracy of new computational tools. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2025

An epitaxial surface heterostructure anchoring approach for high-performance Ni-rich layered cathodes

Nickel-rich (Ni≥90%) layered oxides materials have emerged as a promising candidate for next-generation high-energy-density lithium-ion batteries (LIBs). However, their widespread application is hindered by structural fatigue and lattice oxygen loss. In this work, an epitaxial surface rock-salt nanolayer is successfully developed on the LiNi 0.9 Co 0.1 O 2 sub-surface via heteroatom anchoring utilizing high-valence element molybdenum modification. This in-situ formed conformal buffer phase with a thickness of 1.2nm effectively suppresses the continuous interphase side-reactions, and thus maintains the excellent structure integrity at high voltage. Furthermore, theoretical calculations indicate that the lattice oxygen reversibility in the anion framework of the optimized sample is obviously enhanced due to the higher content of O 2p states near the Fermi level than that of the pristine one. Meanwhile, the stronger Mo–O bond further reduces cell volume alteration, which improves the bulk structure stability of modified materials. Besides, the detailed charge compensation mechanism suggests that the average oxidation state of Ni is reduced, which induces more active Li + participating in the redox reactions, boosting the cell energy density. As a result, the uniquely designed cathode materials exhibit an extraordinary discharge capacity of 245.4 mAh g −1 at 0.1 C, remarkable rate performance of 169.3 mAh g −1 at 10 C at 4.5V, and a high capacity retention of 70.5% after 1000 cycles in full cells at a high cut-off voltage of 4.4V. Further, this strategy provides an valuable insight into constructing distinctive heterostructure on high-performance Ni-rich layered cathodes for LIBs.

25 ENERGY STORAGE↗
DOE OSTI2023

Variable-moment fluid closures with Hamiltonian structure

Abstract Based on ideas due to Scovel–Weinstein, I present a general framework for constructing fluid moment closures of the Vlasov–Poisson system that exactly preserve that system’s Hamiltonian structure. Notably, the technique applies in any space dimension and produces closures involving arbitrarily-large finite collections of moments. After selecting a desired collection of moments, the Poisson bracket for the closure is uniquely determined. Therefore data-driven fluid closures can be constructed by adjusting the closure Hamiltonian for compatibility with kinetic simulations.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗