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At least 1,639 records · Page 91

The Effects of Temperature, Aging, and Plasticizer Content on VCE

Ethylene vinyl acetate vinyl alcohol (VCE) is a terpolymer. It is commonly used as a binder for highly filled elastomeric materials (2). Because of its use, it is important that it is studied extensively to ascertain the possible risks. It is crucial to know how VCE is affected by temperature, aging and how plasticizers may affect this polymer. Aging can be tested experimentally by using different temperatures and heating rates and times. If the VCE breaks down or reacts it could be detrimental to the application and there could be safety concerns. The starting copolymer in the synthesis of VCE is ethylene vinyl acetate (EVA).

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Thermal degradation of new and aged urethane foam and epon 826 epoxy.

Thermal desorption spectroscopy was used to monitor the decomposition as a function of temperature for the foam and epoxy as a function of temperature in the range of 60 C to 170 C. Samples were studied with one day holds at each of the studied temperatures. Both new (FoamN and EpoxyN) and aged (FoamP and EpoxyP) samples were studied. During these ~10 day experiments, the foam samples lost 11 to 13% of their weight and the EpoxyN lost 10% of its weight. The amount of weight lost was difficult to quantify for EpoxyP because of its inert filler. The onset of the appearance of organic degradation products from FoamP began at 110 C. Similar products did not appear until 120 C for FoamN, suggesting some effect of the previous decades of storage for FoamP. In the case of the epoxies, the corresponding temperatures were 120 C for EpoxyP and 110 C for EpoxyN. Suggestions for why the aged epoxy seems more stable than newer sample include the possibility of incomplete curing or differences in composition. Recommendation to limit use temperature to 90-100 C for both epoxy and foam.

36 MATERIALS SCIENCE↗

Aging of Weapon Seals – An Update on Butyl O-ring Issues

During testing under the Enhanced Surveillance Campaign in 2001, preliminary data detected a previously unknown and potentially serious concern with recently procured butyl o-rings on several programs. All butyl o-rings molded from a proprietary formulation throughout the period circa 1999 through 2001 had less than a full cure. Engineering judgment was that under curing is detrimental and could possibly lead to sub-optimum performance or, in the worst case, premature seal failure. An aging study was undertaken to ensure that suspect o-rings installed in the stockpile will retain sufficient sealing force for a minimum ten-year service life. A new prediction model developed for this study indicates suspect o-rings do not need to be replaced before the ten-year service life. Long-term testing results are reported on a yearly basis to validate the prediction model. This report documents the aging results for the period September 2002 to January 2011.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗

Aging Assessment of an Oak Ridge National Laboratory High Flux Isotope Reactor (HFIR) Service Cable

Nuclear energy is one industry where aging of safety-related materials and components is of great concern. Many U.S. nuclear power plants are approaching, or have already exceeded, 40 years of age. Analysis comparing the cost of new plant construction versus long-term operation under extended plant licensing through 60 years strongly favors the latter option. To ensure the safe, reliable, and cost-effective long-term operation of nuclear power plants, many systems, structures, and components must be evaluated. Furthermore, as new analytical techniques and testing approaches are developed, it is imperative that we also validate, and if necessary, improve upon the previously employed Institute of Electrical and Electronic Engineers (IEEE) qualification standards originally written in 1974. Fortunately, this daunting task has global support, particularly in light of the new social and political climate surrounding nuclear energy in a post-Fukushima era.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Submerged Medium Voltage Cable Systems at Nuclear Power Plants: A Review of Research Efforts Relevant to Aging Mechanisms and Condition Monitoring

In a submerged environment, power cables may experience accelerated insulation degradation due to water-related aging mechanisms. Direct contact with water or moisture intrusion in the cable insulation system has been identified in the literature as a significant aging stressor that can affect performance and lifetime of electric cables. Progressive reduction of the dielectric strength is commonly a result of water treeing which involves the development of permanent hydrophilic structures in the insulation coinciding with the absorption of water into the cable. Water treeing is a phenomenon in which dendritic microvoids are formed in electric cable insulation due to electrochemical reactions, electromechanical forces, and diffusion of contaminants over time. These reactions are caused by the combined effects of water presence and high electrical stresses in the material. Water tree growth follows a tree-like branching pattern, increasing in volume and length over time. Although these cables can be “dried out,” water tree degradation, specifically the growth of hydrophilic regions, is believed to be permanent and typically worsens over time. Based on established research, water treeing or water induced damage can occur in a variety of electric cables including XLPE, TR-XLPE and other insulating materials, such as EPR and butyl rubber. Once water trees or water induced damage form, the dielectric strength of an insulation material will decrease gradually with time as the water trees grow in length, which could eventually result in failure of the insulating material. Under wet conditions or in submerged environments, several environmental and operational parameters can influence water tree initiation and affect water tree growth. These parameters include voltage cycling, field frequency, temperature, ion concentration and chemistry, type of insulation material, and the characteristics of its defects. In this effort, a review of academic and industrial literature was performed to identify: 1) findings regarding the degradation mechanisms of submerged cabling and 2) condition monitoring methods that may prove useful in predicting the remaining lifetime of submerged medium voltage power cables. The research was conducted by a multi-disciplinary team, and sources included official NRC reports, national laboratory reports, IEEE standards, conference and journal proceedings, magazine articles, PhD dissertations, and discussions with experts. The purpose of this work was to establish the current state-of-the-art in material degradation modeling and cable condition monitoring techniques and to identify research gaps. Subsequently, future areas of focus are recommended to address these research gaps and thus strengthen the efficacy of the NRC’s developing cable condition monitoring program. Results of this literature review and details of the testing recommendations are presented in this report.

24 POWER TRANSMISSION AND DISTRIBUTION↗

High Explosive Compatibility: Aging and Compatibility of LX-21

The tasks performed in FY14 to support our overall goals include: 1) Select a mature formulation for future aging and compatibility experiments 2) Perform gross compatibility testing for a number of LX-21/material combinations using three different evaluation techniques (DSC, TGA, and CRT) 3) Evaluate moisture sorption and diffusion characteristics of LX-21 4) Get the infrastructure and procedures in place to begin long -term accelerated aging experiments with LX-21.

36 MATERIALS SCIENCE↗

A Laboratory Exposure System to Study the Effects of Aging on Super-micron Aerosol Particles

A laboratory system was constructed that allows the super-micron particles to be aged for long periods of time under conditions that can simulate a range of natural environments and conditions, including relative humidity, oxidizing chemicals, organics and simulated solar radiation. Two proof-of-concept experiments using a non-biological simulant for biological particles and a biological simulant demonstrate the utility of these types of aging experiments. Green Visolite®, which is often used as a tracer material for model validation experiments, does not degrade with exposure to simulated solar radiation, the actual biological material does. This would indicate that Visolite® should be a good tracer compound for mapping the extent of a biological release using fluorescence as an indicator, but that it should not be used to simulate the decay of a biological particle when exposed to sunlight. The decay in the fluorescence measured for B. thurengiensis is similar to what has been previously observed in outdoor environments.

54 ENVIRONMENTAL SCIENCES↗

Performance Specification for Standardized Transportation, Aging, and Disposal Canister Systems (Rev.2)

This performance specification document addresses use of a standardized transportation, aging, and disposal (STAD) canister system in the spent nuclear fuel (SNF) waste management system. This document was developed to support STAD canister system studies and potential research, development, and demonstration activities. Requirements in this specification may evolve with time based on results from analyses, experiments, design studies, system evaluations and demonstrations, as well as other factors. A STAD canister system consists of a canister, together with a storage or aging overpack/module/vault, a shielded transfer cask (STC), a site transporter, a transportation overpack, and a transportation skid. Three sizes of circular cross section STAD canister variants are specified in this document. The small STAD canister capacity is four pressurized water reactor (PWR) or nine boiling water reactor (BWR) SNF assemblies. The medium STAD canister capacity is 12 PWR or 32 BWR SNF assemblies. The large STAD canister capacity is 21 PWR or 44 BWR SNF assemblies. Using standardized canisters for SNF facilitates the interface between storage at an independent spent fuel storage installation (ISFSI) or a DOEowned interim storage facility (ISF), transportation between facilities, and disposal at a repository. Multiple STAD canisters may be stored in a single storage overpack and/or a single transportation overpack. The US Nuclear Regulatory Commission (NRC) requirements currently used for storage and transportation are adopted for the STAD canister system. Approved approaches (guidance) in NRC storage and transportation documents are also adopted as requirements for the STAD canister system to facilitate obtaining NRC Certificates of Compliance (CoCs) for STAD canister systems. Performance specifications in this document are also informed by STAD canister disposability in various geologic media and consideration of ISF (and geologic repository) handling facility design, operations, and licensing requirements.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

FY 2017 – Thermal Aging Effects on Advanced Structural Materials

This report provides an update on the evaluation of the effect of thermal aging on tensile properties of existing laboratory-sized heats of Alloy 709 austenitic stainless steel and the completion of effort on the thermal aging effect on the tensile properties of optimized G92 ferritic-martensitic steel. The report is a Level 3 deliverable in FY17 (M3AT-17AN1602081), under the Work Package AT-17AN160208, “Advanced Alloy Testing - ANL” performed by the Argonne National Laboratory (ANL), as part of the Advanced Reactor Technologies Program.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Is there a relationship between fledge age and nest temperature in Western Bluebirds (Sialia mexicana)?

Extensive research has been done on temperature during bird incubation periods, but little has been done during nestling development, and to our knowledge, no studies have been done on Western Bluebird (Sialia mexicana) nestling development. In this study, dataloggers were used to monitor nest temperatures during the nestling development phase of Western Bluebirds to determine if there was a relationship between fledge age and temperature. The study was conducted in an existing nestbox network at Los Alamos National Laboratory and the surrounding area in north-central New Mexico. Based on the age of the nestlings at fledging, the nestboxes (n=65) were split into three groups: early (16 and 17 days old, n=13), average (fledged at or between 18 and 20 days old, n=32), and late (21 days or older, n=20). The temperatures of the early and average (n=45) groups were not significantly different (p=0.32, W=3831000). There was a significant difference in the temperatures between the early and late groups (p=0.000, W=2965600). The early and average groups were then combined, tested against the late group, and were found to be significantly different (p=0.000, W=11315000). Analysis showed a difference within the first seven days post-hatch of 1.42°C between the early/average and late groupings. The results suggest that warmer nest temperatures during the nestling stage may influence the fledge date and may lead to faster fledging. There may be numerous explanations for this, such as a correlation with nestling development, and higher temperatures may allow for faster development. Brood size was non-significant and was not factored into the analysis. Future work should be directed in this area.

59 BASIC BIOLOGICAL SCIENCES↗

Analysis to Evaluate Predictors of Fiberboard Aging to Guide Surveillance Sampling for the 9975 Life Extension Program (Data Through 2017)

The analysis described in this report shows that the measurements of Upper Assembly Outer Diameter (UAOD) and Upper Assembly Inside Height (UAIH) do not have statistically significant aging trends regardless of wattage levels. In contrast, the analysis indicates that the measurement of Air Shield Gap (ASGap) shows an increasing trend with age for high-wattage containers. However, there is considerable variability in the data. Additional older high-wattage containers need to be examined before definitive conclusions can be reached. Based on these results, future 9975 surveillance will target older high-wattage containers.

36 MATERIALS SCIENCE↗

Calibration of laboratory aging practice to replicate changes to roof albedo in a Chinese city

Highly reflective roofs can save building air conditioning energy, mitigate the urban heat island, and offset CO 2 emissions. A laboratory aging methodology was developed to simulate change in the solar reflectances of field-applied roof coatings induced by one year of natural exposure in Guangzhou (China). The approach compared the changes in solar reflectance spectra observed in the naturally exposed materials with those obtained following a three-stage laboratory procedure: conditioning, soiling, and weathering. The method was systematically modified over five trials by adjusting the key variables in laboratory aging: composition of the soiling mixture, deposition mass, and conditions of soiling application. Tests were performed using a small number of specimens. Simulating exposure in Guangzhou required a loading of soiling agents greater than that used to simulate US cites. In the final trial, the reduction in solar reflectance was reproduced to within an average of 0.02 for three of the six products, and to within an average of 0.06 for the remaining three products.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Age-aware materials model for foam cushions - considering time-dependence of strain-rates and rate-independent measurements

Over the last few reports we have chronicled the progressive development of an age-aware materials model for foam cushions relevant to our systems. The latest version employs a N = 2 Ogden Hyperfoam model within a two-network Tobolsky scheme. As the material ages, the first network progressively loses in strength, while the second network progressively gains in strength. However, the two networks are in different strain states. Thus, in additive equilibrium (Tobolsky model) they manifest both permanent structural changes (measured as Compression Set) as well as changes in mechanical strength and modulus (measured as Load Retention).

36 MATERIALS SCIENCE↗

Progress Summary: 17-Month Compression Set and Load Retention of Thermally Accelerated Aged Siloxane Specimens (Additively Manufactured by the Direct-Ink-Write (DIW) 3D Printing Technique) was Measured

Accelerated aging of polymeric materials is needed to predict their long-term mechanical functionality. Two key metrics used to evaluate their performance are compression set and load retention. A baseline (time = 0) mechanical assessment was done prior to initiating the accelerated aging process to acquire initial thickness and load values for future calculation of compression set and load retention.

36 MATERIALS SCIENCE↗

Expanded Materials Degradation Analysis (EMDA) Volume 3: Aging of Reactor Pressure Vessels

In NUREG/CR-6923 ORNL/TM-2013/532, "Expert Panel Report on Proactive Materials Degradation Assessment," referred to as the PMDA report, NRC conducted a comprehensive evaluation of potential aging-related degradation modes for core internal components, as well as primary, secondary, and some tertiary piping systems, considering operation up to 40 years. This document has been a very valuable resource, supporting NRC staff evaluations of licensees' aging management programs and allowing for prioritization of research needs.This report describes an expanded materials degradation assessment (EMDA), which significantly broadens the scope of the PMDA report. The analytical timeframe is expanded to 80 years to encompass a potential second 20-year license-renewal operating-period, beyond the initial 40-year licensing term and a first 20-year license renewal. Further, a broader range of structures, systems, and components (SSCs) was evaluated, including core internals, piping systems, the reactor pressure vessel (RPV), electrical cables, and concrete and civil structures. The EMDA uses the approach of the phenomena identification and ranking table (PIRT), wherein an expert panel is convened to rank potential degradation scenarios according to their judgment of susceptibility and current state of knowledge.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Comprehensive Data Analysis and Analytic Method Development for PBX9501 Material (FY2019 Annual Report of Aging and Lifetimes Program)

In the polymer bonded explosive (PBX) 9501, a binder consisting of 2.5 wt% nitroplasticizer (NP) and 2.5 wt% Estane R 5703 (Estane) is combined with 94.9 wt% of the high-explosive HMX and 0.1 wt% stabilizer. Because of its flexibility and tensile strength, this binder lowers the sensitivity and improves the manufacturability of PBX 9501. However, like many plasticizers comprised of low molecular weight components, NP has a tendency to diffuse out of the PBX 9501 matrix and can decompose at moderate temperatures into reactive byproducts, such as NO, NO 2 , H 2 O, and HNO x . Through oxidation and hydrolysis, these molecules can further degrade NP and Estane, ultimately degrading the properties of PBX 9501. While gaseous molecules can readily diffuse out of the PBX 9501 charges, the intermediates with lower volatility are more likely trapped in the condensed phase inside the charges and, in a closed system, will co-exist with Estane for an extended period of time creating an ongoing reactive environment. Understanding the rates of formation for these volatiles and intermediates during the NP degradation is therefore a critical prerequisite for understanding the long-term stability of polymeric binders used in munition systems. To work toward this ultimate goal, in the past year, we have conducted comprehensive studies on the physical properties of NP and finished three-year long aging experiment to understand the aging behavior of NP under thermal treatment. Important results are summarized in this annual report. Although NP is widely used in the DOE complex, their physical properties are rather scattered and inconsistent in the open literature. For example, there are at least two widely different values, 14.5°C and -15°C, for the melting point of NP. Although it is known that NP is a eutectic 50:50 mixture of BDNPA and BDNPF, their eutectic phase diagram is not well documented. Furthermore, the effect of temperature on the miscibility between water and eutectic BDNPA/F mixture is rarely reported. To fill these knowledge gaps, a large set of BDNPA/F mixtures with BDNPA concentration ranging from 0 to 100 wt% was analyzed using DSC techniques. In addition to determining the eutectic melt point as -25°C, a phase diagram of the BDNPA/F system was constructed from -30°C to 45°C. With this phase diagram, the phase transition temperatures and composition can be readily found for the BDNPA/F mixtures with various mass ratios.

36 MATERIALS SCIENCE↗

HPC for the EEC: Industrial Trade Tools for the Aging Energy Infrastructure

The petrochemical and refining sectors are challenged with reliably delivering safer and cleaner energy to US consumers, while meeting an ever-growing global demand. The petrochemical and refining infrastructure in the USA is aging, and corrosion and damage mechanisms are constant threats to mechanical integrity, safety, and profitability. However, governments and industry stakeholders are reluctant to replace or upgrade the existing infrastructure due to the immense cost. To better understand and mitigate the risks of aging energy infrastructure, strong technical analysis capabilities, combined with optimized monitoring and decision making, is critical. Today, this is accomplished via complex simulations and data analysis. To this end, advanced High-Performance-Computing (HPC) software will be leveraged and integrated in easy-to-use industrial trade tools, to lower the barrier for new users, increase the ease of access for experienced users, and allow for smarter decisions to be made in the midstream and downstream energy sectors.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗