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Materials Data on Li3H4Rh by Materials Project

Li3RhH4 crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. there are two inequivalent Li sites. In the first Li site, Li is bonded in a 5-coordinate geometry to five H atoms. There are a spread of Li–H bond distances ranging from 1.92–2.23 Å. In the second Li site, Li is bonded in a 6-coordinate geometry to six H atoms. There are two shorter (2.00 Å) and four longer (2.25 Å) Li–H bond lengths. Rh is bonded in a distorted square co-planar geometry to four H atoms. All Rh–H bond lengths are 1.68 Å. There are two inequivalent H sites. In the first H site, H is bonded in a 5-coordinate geometry to four Li and one Rh atom. In the second H site, H is bonded to four Li and one Rh atom to form a mixture of distorted corner and edge-sharing HLi4Rh square pyramids.

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Materials Data on Ca4(H4Rh)3 by Materials Project

Ca4(RhH4)3 crystallizes in the cubic Im-3m space group. The structure is three-dimensional. Ca is bonded to twelve H atoms to form CaH12 cuboctahedra that share corners with twelve equivalent CaH12 cuboctahedra, faces with six equivalent CaH12 cuboctahedra, and faces with six equivalent RhH6 octahedra. All Ca–H bond lengths are 2.58 Å. Rh is bonded to six H atoms to form RhH6 octahedra that share corners with four equivalent RhH6 octahedra and faces with eight equivalent CaH12 cuboctahedra. The corner-sharing octahedral tilt angles are 0°. There is two shorter (1.71 Å) and four longer (1.82 Å) Rh–H bond length. There are two inequivalent H sites. In the first H site, H is bonded to four equivalent Ca and one Rh atom to form HCa4Rh square pyramids that share corners with eight equivalent HCa4Rh2 octahedra, corners with thirteen equivalent HCa4Rh square pyramids, edges with four equivalent HCa4Rh2 octahedra, edges with four equivalent HCa4Rh square pyramids, and faces with four equivalent HCa4Rh2 octahedra. The corner-sharing octahedral tilt angles are 58°. In the second H site, H is bonded to four equivalent Ca and two equivalent Rh atoms to form HCa4Rh2 octahedra that share corners with fourteen equivalent HCa4Rh2 octahedra, corners with eight equivalent HCa4Rh square pyramids, edges with four equivalent HCa4Rh square pyramids, faces with four equivalent HCa4Rh2 octahedra, and faces with four equivalent HCa4Rh square pyramids. The corner-sharing octahedra tilt angles range from 0–60°.

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Materials Data on Te8Rh3 by Materials Project

Rh3Te8 crystallizes in the trigonal R-3 space group. The structure is three-dimensional. Rh+3.33+ is bonded to six Te+1.25- atoms to form corner-sharing RhTe6 octahedra. The corner-sharing octahedra tilt angles range from 62–63°. There are a spread of Rh–Te bond distances ranging from 2.68–2.71 Å. There are two inequivalent Te+1.25- sites. In the first Te+1.25- site, Te+1.25- is bonded in a 4-coordinate geometry to three equivalent Rh+3.33+ and one Te+1.25- atom. The Te–Te bond length is 2.91 Å. In the second Te+1.25- site, Te+1.25- is bonded in a 2-coordinate geometry to two equivalent Rh+3.33+ atoms.

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Materials Data on Zn3Rh by Materials Project

RhZn3 is Uranium Silicide-like structured and crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Rh is bonded to twelve Zn atoms to form RhZn12 cuboctahedra that share corners with four equivalent RhZn12 cuboctahedra, edges with eight equivalent RhZn12 cuboctahedra, edges with sixteen equivalent ZnZn8Rh4 cuboctahedra, faces with four equivalent RhZn12 cuboctahedra, and faces with eight equivalent ZnZn8Rh4 cuboctahedra. There are four shorter (2.63 Å) and eight longer (2.76 Å) Rh–Zn bond lengths. There are two inequivalent Zn sites. In the first Zn site, Zn is bonded to four equivalent Rh and eight Zn atoms to form distorted ZnZn8Rh4 cuboctahedra that share corners with twelve equivalent ZnZn8Rh4 cuboctahedra, edges with eight equivalent RhZn12 cuboctahedra, edges with eight equivalent ZnZn8Rh4 cuboctahedra, faces with four equivalent RhZn12 cuboctahedra, and faces with ten equivalent ZnZn8Rh4 cuboctahedra. There are four shorter (2.63 Å) and four longer (2.76 Å) Zn–Zn bond lengths. In the second Zn site, Zn is bonded in a distorted square co-planar geometry to four equivalent Rh and eight equivalent Zn atoms.

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Materials Data on Ge3Rh by Materials Project

RhGe3 is alpha bismuth trifluoride structured and crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Rh is bonded to twelve Ge atoms to form RhGe12 cuboctahedra that share corners with four equivalent RhGe12 cuboctahedra, corners with eight equivalent GeGe8Rh4 cuboctahedra, edges with eight equivalent RhGe12 cuboctahedra, edges with sixteen equivalent GeGe8Rh4 cuboctahedra, faces with four equivalent RhGe12 cuboctahedra, and faces with fourteen GeGe8Rh4 cuboctahedra. There are eight shorter (2.83 Å) and four longer (3.00 Å) Rh–Ge bond lengths. There are two inequivalent Ge sites. In the first Ge site, Ge is bonded to four equivalent Rh and eight Ge atoms to form distorted GeGe8Rh4 cuboctahedra that share corners with twelve equivalent GeGe8Rh4 cuboctahedra, edges with eight equivalent RhGe12 cuboctahedra, edges with sixteen GeGe8Rh4 cuboctahedra, faces with four equivalent RhGe12 cuboctahedra, and faces with fourteen GeGe8Rh4 cuboctahedra. There are four shorter (2.83 Å) and four longer (3.00 Å) Ge–Ge bond lengths. In the second Ge site, Ge is bonded to four equivalent Rh and eight equivalent Ge atoms to form GeGe8Rh4 cuboctahedra that share corners with four equivalent GeGe8Rh4 cuboctahedra, corners with eight equivalent RhGe12 cuboctahedra, edges with twenty-four GeGe8Rh4 cuboctahedra, faces with six equivalent RhGe12 cuboctahedra, and faces with twelve GeGe8Rh4 cuboctahedra.

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Materials Data on Pt3Rh by Materials Project

Pt3Rh is Copper-derived structured and crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Rh is bonded to twelve Pt atoms to form RhPt12 cuboctahedra that share corners with four equivalent RhPt12 cuboctahedra, corners with eight equivalent PtPt8Rh4 cuboctahedra, edges with eight equivalent RhPt12 cuboctahedra, edges with sixteen equivalent PtPt8Rh4 cuboctahedra, faces with four equivalent RhPt12 cuboctahedra, and faces with fourteen PtPt8Rh4 cuboctahedra. All Rh–Pt bond lengths are 2.79 Å. There are two inequivalent Pt sites. In the first Pt site, Pt is bonded to four equivalent Rh and eight Pt atoms to form PtPt8Rh4 cuboctahedra that share corners with twelve equivalent PtPt8Rh4 cuboctahedra, edges with eight equivalent RhPt12 cuboctahedra, edges with sixteen PtPt8Rh4 cuboctahedra, faces with four equivalent RhPt12 cuboctahedra, and faces with fourteen PtPt8Rh4 cuboctahedra. All Pt–Pt bond lengths are 2.79 Å. In the second Pt site, Pt is bonded to four equivalent Rh and eight equivalent Pt atoms to form PtPt8Rh4 cuboctahedra that share corners with four equivalent PtPt8Rh4 cuboctahedra, corners with eight equivalent RhPt12 cuboctahedra, edges with twenty-four PtPt8Rh4 cuboctahedra, faces with six equivalent RhPt12 cuboctahedra, and faces with twelve PtPt8Rh4 cuboctahedra.

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Materials Data on Hg3Rh by Materials Project

RhHg3 is Uranium Silicide-like structured and crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Rh is bonded to twelve Hg atoms to form RhHg12 cuboctahedra that share corners with four equivalent RhHg12 cuboctahedra, edges with eight equivalent RhHg12 cuboctahedra, edges with sixteen equivalent HgHg8Rh4 cuboctahedra, faces with four equivalent RhHg12 cuboctahedra, and faces with eight equivalent HgHg8Rh4 cuboctahedra. There are four shorter (2.94 Å) and eight longer (3.10 Å) Rh–Hg bond lengths. There are two inequivalent Hg sites. In the first Hg site, Hg is bonded to four equivalent Rh and eight Hg atoms to form HgHg8Rh4 cuboctahedra that share corners with twelve equivalent HgHg8Rh4 cuboctahedra, edges with eight equivalent RhHg12 cuboctahedra, edges with eight equivalent HgHg8Rh4 cuboctahedra, faces with four equivalent RhHg12 cuboctahedra, and faces with ten equivalent HgHg8Rh4 cuboctahedra. There are four shorter (2.94 Å) and four longer (3.10 Å) Hg–Hg bond lengths. In the second Hg site, Hg is bonded in a distorted square co-planar geometry to four equivalent Rh and eight equivalent Hg atoms.

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Materials Data on Ca3Fe2(RhO6)2 by Materials Project

Ca3Fe2(RhO6)2 crystallizes in the trigonal R32 space group. The structure is three-dimensional. Ca is bonded in a 8-coordinate geometry to eight O atoms. There are a spread of Ca–O bond distances ranging from 2.37–2.59 Å. There are two inequivalent Fe sites. In the first Fe site, Fe is bonded to six equivalent O atoms to form distorted FeO6 pentagonal pyramids that share faces with two equivalent RhO6 octahedra. All Fe–O bond lengths are 1.96 Å. In the second Fe site, Fe is bonded to six equivalent O atoms to form distorted FeO6 pentagonal pyramids that share faces with two equivalent RhO6 octahedra. All Fe–O bond lengths are 2.08 Å. Rh is bonded to six O atoms to form RhO6 octahedra that share faces with two FeO6 pentagonal pyramids. There is three shorter (1.96 Å) and three longer (1.99 Å) Rh–O bond length. There are two inequivalent O sites. In the first O site, O is bonded in a rectangular see-saw-like geometry to two equivalent Ca, one Fe, and one Rh atom. In the second O site, O is bonded in a distorted rectangular see-saw-like geometry to two equivalent Ca, one Fe, and one Rh atom.

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Materials Data on PtRhBr6N5Cl by Materials Project

(Pt)2RhN5Br5ClRhN5Br3Cl(Br)4 crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of eight hydrobromic acid molecules, four platinum molecules, two RhN5Br3Cl clusters, and two RhN5Br5Cl clusters. In each RhN5Br3Cl cluster, Rh4+ is bonded in a distorted octahedral geometry to five N3- and one Cl1- atom. There are a spread of Rh–N bond distances ranging from 1.88–2.08 Å. The Rh–Cl bond length is 2.45 Å. There are three inequivalent N3- sites. In the first N3- site, N3- is bonded in a distorted L-shaped geometry to one Rh4+ and one Br1+ atom. The N–Br bond length is 1.81 Å. In the second N3- site, N3- is bonded in a distorted L-shaped geometry to one Rh4+ and one Br1+ atom. The N–Br bond length is 1.89 Å. In the third N3- site, N3- is bonded in a distorted bent 120 degrees geometry to one Rh4+ and one Br1+ atom. The N–Br bond length is 1.82 Å. There are three inequivalent Br1+ sites. In the first Br1+ site, Br1+ is bonded in an L-shaped geometry to two equivalent N3- atoms. In the second Br1+ site, Br1+ is bonded in a single-bond geometry to one N3- atom. In the third Br1+ site, Br1+ is bonded in an L-shaped geometry to two equivalent N3- atoms. Cl1- is bonded in a distorted single-bond geometry to one Rh4+ atom. In each RhN5Br5Cl cluster, Rh4+ is bonded in a distorted octahedral geometry to five N3- and one Cl1- atom. There are a spread of Rh–N bond distances ranging from 1.84–2.26 Å. The Rh–Cl bond length is 2.45 Å. There are four inequivalent N3- sites. In the first N3- site, N3- is bonded in a distorted trigonal non-coplanar geometry to one Rh4+ and two equivalent Br1+ atoms. Both N–Br bond lengths are 1.97 Å. In the second N3- site, N3- is bonded in a distorted trigonal non-coplanar geometry to one Rh4+ and two equivalent Br1+ atoms. Both N–Br bond lengths are 1.95 Å. In the third N3- site, N3- is bonded in a distorted single-bond geometry to one Rh4+ and one Br1+ atom. The N–Br bond length is 2.33 Å. In the fourth N3- site, N3- is bonded in a distorted single-bond geometry to one Rh4+ and one Br1+ atom. The N–Br bond length is 1.96 Å. There are three inequivalent Br1+ sites. In the first Br1+ site, Br1+ is bonded in a single-bond geometry to one N3- atom. In the second Br1+ site, Br1+ is bonded in a single-bond geometry to one N3- atom. In the third Br1+ site, Br1+ is bonded in a 1-coordinate geometry to two N3- atoms. Cl1- is bonded in a single-bond geometry to one Rh4+ atom.

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Materials Data on Pa2Rh2O5 by Materials Project

Pa2Rh2O5 crystallizes in the tetragonal P4/mmm space group. The structure is three-dimensional. there are two inequivalent Pa sites. In the first Pa site, Pa is bonded in a body-centered cubic geometry to eight equivalent O atoms. All Pa–O bond lengths are 2.60 Å. In the second Pa site, Pa is bonded to twelve O atoms to form PaO12 cuboctahedra that share corners with four equivalent PaO12 cuboctahedra, faces with four equivalent PaO12 cuboctahedra, and faces with eight equivalent RhO5 square pyramids. There are eight shorter (2.70 Å) and four longer (2.85 Å) Pa–O bond lengths. Rh is bonded to five O atoms to form distorted RhO5 square pyramids that share corners with five equivalent RhO5 square pyramids and faces with four equivalent PaO12 cuboctahedra. There are four shorter (2.04 Å) and one longer (2.13 Å) Rh–O bond lengths. There are two inequivalent O sites. In the first O site, O is bonded to four Pa and two equivalent Rh atoms to form a mixture of distorted face, edge, and corner-sharing OPa4Rh2 octahedra. The corner-sharing octahedra tilt angles range from 0–66°. In the second O site, O is bonded to four equivalent Pa and two equivalent Rh atoms to form a mixture of distorted face, edge, and corner-sharing OPa4Rh2 octahedra. The corner-sharing octahedra tilt angles range from 0–58°.

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Materials Data on Ga3Rh by Materials Project

RhGa3 crystallizes in the tetragonal P4_2/mnm space group. The structure is three-dimensional. Rh is bonded in a 8-coordinate geometry to eight Ga atoms. There are a spread of Rh–Ga bond distances ranging from 2.46–2.59 Å. There are two inequivalent Ga sites. In the first Ga site, Ga is bonded in a linear geometry to two equivalent Rh atoms. In the second Ga site, Ga is bonded in a 1-coordinate geometry to three equivalent Rh atoms.

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Materials Data on ScRhO3 by Materials Project

ScRhO3 is Ilmenite-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. there are two inequivalent Sc3+ sites. In the first Sc3+ site, Sc3+ is bonded in a 6-coordinate geometry to six O2- atoms. There are a spread of Sc–O bond distances ranging from 2.08–2.27 Å. In the second Sc3+ site, Sc3+ is bonded to six O2- atoms to form distorted ScO6 pentagonal pyramids that share corners with five RhO6 octahedra, corners with two equivalent ScO6 pentagonal pyramids, edges with two RhO6 octahedra, and a faceface with one RhO6 octahedra. The corner-sharing octahedra tilt angles range from 58–84°. There are a spread of Sc–O bond distances ranging from 2.07–2.29 Å. There are four inequivalent Rh3+ sites. In the first Rh3+ site, Rh3+ is bonded to six O2- atoms to form RhO6 octahedra that share corners with six RhO6 octahedra, corners with two equivalent ScO6 pentagonal pyramids, and edges with two equivalent ScO6 pentagonal pyramids. The corner-sharing octahedra tilt angles range from 49–50°. There are two shorter (2.06 Å) and four longer (2.08 Å) Rh–O bond lengths. In the second Rh3+ site, Rh3+ is bonded to six O2- atoms to form RhO6 octahedra that share corners with six RhO6 octahedra, corners with two equivalent ScO6 pentagonal pyramids, and faces with two equivalent ScO6 pentagonal pyramids. The corner-sharing octahedra tilt angles range from 48–50°. There are four shorter (2.08 Å) and two longer (2.12 Å) Rh–O bond lengths. In the third Rh3+ site, Rh3+ is bonded to six O2- atoms to form RhO6 octahedra that share corners with six RhO6 octahedra, corners with two equivalent ScO6 pentagonal pyramids, and edges with two equivalent ScO6 pentagonal pyramids. The corner-sharing octahedra tilt angles range from 46–49°. There are a spread of Rh–O bond distances ranging from 2.06–2.08 Å. In the fourth Rh3+ site, Rh3+ is bonded to six O2- atoms to form RhO6 octahedra that share corners with six RhO6 octahedra and corners with four equivalent ScO6 pentagonal pyramids. The corner-sharing octahedra tilt angles range from 46–50°. There are a spread of Rh–O bond distances ranging from 2.06–2.11 Å. There are six inequivalent O2- sites. In the first O2- site, O2- is bonded to two Sc3+ and two Rh3+ atoms to form a mixture of distorted edge and corner-sharing OSc2Rh2 trigonal pyramids. In the second O2- site, O2- is bonded to two Sc3+ and two Rh3+ atoms to form a mixture of distorted edge and corner-sharing OSc2Rh2 trigonal pyramids. In the third O2- site, O2- is bonded to two equivalent Sc3+ and two Rh3+ atoms to form a mixture of distorted edge and corner-sharing OSc2Rh2 trigonal pyramids. In the fourth O2- site, O2- is bonded in a 4-coordinate geometry to two equivalent Sc3+ and two Rh3+ atoms. In the fifth O2- site, O2- is bonded in a distorted see-saw-like geometry to two Sc3+ and two Rh3+ atoms. In the sixth O2- site, O2- is bonded to two Sc3+ and two Rh3+ atoms to form a mixture of distorted edge and corner-sharing OSc2Rh2 trigonal pyramids.

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Materials Data on Pd3Rh by Materials Project

Pd3Rh is alpha La-derived structured and crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Rh is bonded to twelve Pd atoms to form RhPd12 cuboctahedra that share corners with four equivalent RhPd12 cuboctahedra, corners with eight equivalent PdPd8Rh4 cuboctahedra, edges with eight equivalent RhPd12 cuboctahedra, edges with sixteen equivalent PdPd8Rh4 cuboctahedra, faces with four equivalent RhPd12 cuboctahedra, and faces with fourteen PdPd8Rh4 cuboctahedra. There are eight shorter (2.77 Å) and four longer (2.79 Å) Rh–Pd bond lengths. There are two inequivalent Pd sites. In the first Pd site, Pd is bonded to four equivalent Rh and eight Pd atoms to form PdPd8Rh4 cuboctahedra that share corners with twelve equivalent PdPd8Rh4 cuboctahedra, edges with eight equivalent RhPd12 cuboctahedra, edges with sixteen PdPd8Rh4 cuboctahedra, faces with four equivalent RhPd12 cuboctahedra, and faces with fourteen PdPd8Rh4 cuboctahedra. There are four shorter (2.77 Å) and four longer (2.79 Å) Pd–Pd bond lengths. In the second Pd site, Pd is bonded to four equivalent Rh and eight equivalent Pd atoms to form PdPd8Rh4 cuboctahedra that share corners with four equivalent PdPd8Rh4 cuboctahedra, corners with eight equivalent RhPd12 cuboctahedra, edges with twenty-four PdPd8Rh4 cuboctahedra, faces with six equivalent RhPd12 cuboctahedra, and faces with twelve PdPd8Rh4 cuboctahedra.

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Materials Data on Cu3Rh by Materials Project

Cu3Rh is beta Cu3Ti-like structured and crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Rh is bonded to twelve Cu atoms to form RhCu12 cuboctahedra that share corners with four equivalent RhCu12 cuboctahedra, corners with eight equivalent CuCu8Rh4 cuboctahedra, edges with eight equivalent RhCu12 cuboctahedra, edges with sixteen equivalent CuCu8Rh4 cuboctahedra, faces with four equivalent RhCu12 cuboctahedra, and faces with fourteen CuCu8Rh4 cuboctahedra. There are eight shorter (2.60 Å) and four longer (2.63 Å) Rh–Cu bond lengths. There are two inequivalent Cu sites. In the first Cu site, Cu is bonded to four equivalent Rh and eight Cu atoms to form distorted CuCu8Rh4 cuboctahedra that share corners with twelve equivalent CuCu8Rh4 cuboctahedra, edges with eight equivalent RhCu12 cuboctahedra, edges with sixteen CuCu8Rh4 cuboctahedra, faces with four equivalent RhCu12 cuboctahedra, and faces with fourteen CuCu8Rh4 cuboctahedra. There are four shorter (2.60 Å) and four longer (2.63 Å) Cu–Cu bond lengths. In the second Cu site, Cu is bonded to four equivalent Rh and eight equivalent Cu atoms to form CuCu8Rh4 cuboctahedra that share corners with four equivalent CuCu8Rh4 cuboctahedra, corners with eight equivalent RhCu12 cuboctahedra, edges with twenty-four CuCu8Rh4 cuboctahedra, faces with six equivalent RhCu12 cuboctahedra, and faces with twelve CuCu8Rh4 cuboctahedra.

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Materials Data on U(Zn10Rh)2 by Materials Project

U(RhZn10)2 crystallizes in the cubic Fd-3m space group. The structure is three-dimensional. U is bonded in a 4-coordinate geometry to sixteen Zn atoms. There are four shorter (3.09 Å) and twelve longer (3.11 Å) U–Zn bond lengths. Rh is bonded to twelve Zn atoms to form RhZn12 cuboctahedra that share corners with six equivalent RhZn12 cuboctahedra, edges with eighteen equivalent ZnUZn10Rh cuboctahedra, and faces with six equivalent ZnUZn10Rh cuboctahedra. There are six shorter (2.53 Å) and six longer (2.80 Å) Rh–Zn bond lengths. There are three inequivalent Zn sites. In the first Zn site, Zn is bonded in a 2-coordinate geometry to two equivalent U and twelve equivalent Zn atoms. All Zn–Zn bond lengths are 3.03 Å. In the second Zn site, Zn is bonded in a distorted linear geometry to two equivalent Rh and six equivalent Zn atoms. There are two shorter (2.69 Å) and four longer (2.83 Å) Zn–Zn bond lengths. In the third Zn site, Zn is bonded to one U, one Rh, and ten Zn atoms to form distorted ZnUZn10Rh cuboctahedra that share corners with fifteen equivalent ZnUZn10Rh cuboctahedra, edges with two equivalent ZnUZn10Rh cuboctahedra, edges with three equivalent RhZn12 cuboctahedra, a faceface with one RhZn12 cuboctahedra, and faces with fifteen equivalent ZnUZn10Rh cuboctahedra. There are a spread of Zn–Zn bond distances ranging from 2.62–2.92 Å.

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Materials Data on Ni3Rh by Materials Project

RhNi3 is beta Cu3Ti-like structured and crystallizes in the hexagonal P6_3/mmc space group. The structure is three-dimensional. Rh is bonded to twelve Ni atoms to form RhNi12 cuboctahedra that share corners with six equivalent RhNi12 cuboctahedra, corners with twelve NiNi8Rh4 cuboctahedra, edges with eighteen NiNi8Rh4 cuboctahedra, faces with eight equivalent RhNi12 cuboctahedra, and faces with twelve NiNi8Rh4 cuboctahedra. There are six shorter (2.55 Å) and six longer (2.57 Å) Rh–Ni bond lengths. There are two inequivalent Ni sites. In the first Ni site, Ni is bonded to four equivalent Rh and eight Ni atoms to form distorted NiNi8Rh4 cuboctahedra that share corners with four equivalent RhNi12 cuboctahedra, corners with fourteen equivalent NiNi8Rh4 cuboctahedra, edges with six equivalent RhNi12 cuboctahedra, edges with twelve NiNi8Rh4 cuboctahedra, faces with four equivalent RhNi12 cuboctahedra, and faces with sixteen NiNi8Rh4 cuboctahedra. There are a spread of Ni–Ni bond distances ranging from 2.51–2.62 Å. In the second Ni site, Ni is bonded to four equivalent Rh and eight equivalent Ni atoms to form distorted NiNi8Rh4 cuboctahedra that share corners with four equivalent RhNi12 cuboctahedra, corners with fourteen NiNi8Rh4 cuboctahedra, edges with six equivalent RhNi12 cuboctahedra, edges with twelve equivalent NiNi8Rh4 cuboctahedra, faces with four equivalent RhNi12 cuboctahedra, and faces with sixteen NiNi8Rh4 cuboctahedra.

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Materials Data on InRhO3 by Materials Project

RhInO3 is Ilmenite-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. there are four inequivalent Rh3+ sites. In the first Rh3+ site, Rh3+ is bonded to six O2- atoms to form corner-sharing RhO6 octahedra. The corner-sharing octahedra tilt angles range from 45–47°. There are a spread of Rh–O bond distances ranging from 2.07–2.10 Å. In the second Rh3+ site, Rh3+ is bonded to six O2- atoms to form corner-sharing RhO6 octahedra. The corner-sharing octahedra tilt angles range from 45–47°. There are a spread of Rh–O bond distances ranging from 2.09–2.14 Å. In the third Rh3+ site, Rh3+ is bonded to six O2- atoms to form corner-sharing RhO6 octahedra. The corner-sharing octahedra tilt angles range from 44–45°. There are four shorter (2.07 Å) and two longer (2.09 Å) Rh–O bond lengths. In the fourth Rh3+ site, Rh3+ is bonded to six O2- atoms to form corner-sharing RhO6 octahedra. The corner-sharing octahedra tilt angles range from 44–46°. There are four shorter (2.08 Å) and two longer (2.12 Å) Rh–O bond lengths. There are two inequivalent In3+ sites. In the first In3+ site, In3+ is bonded in a 6-coordinate geometry to six O2- atoms. There are a spread of In–O bond distances ranging from 2.16–2.32 Å. In the second In3+ site, In3+ is bonded in a 6-coordinate geometry to six O2- atoms. There are a spread of In–O bond distances ranging from 2.15–2.33 Å. There are six inequivalent O2- sites. In the first O2- site, O2- is bonded to two Rh3+ and two In3+ atoms to form a mixture of distorted edge and corner-sharing OIn2Rh2 tetrahedra. In the second O2- site, O2- is bonded to two Rh3+ and two In3+ atoms to form a mixture of distorted edge and corner-sharing OIn2Rh2 tetrahedra. In the third O2- site, O2- is bonded to two Rh3+ and two equivalent In3+ atoms to form a mixture of distorted edge and corner-sharing OIn2Rh2 tetrahedra. In the fourth O2- site, O2- is bonded to two Rh3+ and two equivalent In3+ atoms to form a mixture of distorted edge and corner-sharing OIn2Rh2 tetrahedra. In the fifth O2- site, O2- is bonded to two Rh3+ and two In3+ atoms to form a mixture of distorted edge and corner-sharing OIn2Rh2 trigonal pyramids. In the sixth O2- site, O2- is bonded to two Rh3+ and two In3+ atoms to form a mixture of distorted edge and corner-sharing OIn2Rh2 tetrahedra.

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Materials Data on RhN3Cl6O by Materials Project

Rh(NCl3)2NO is Modderite structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four nitroxyl molecules and four Rh(NCl3)2 clusters. In each Rh(NCl3)2 cluster, Rh3+ is bonded in an octahedral geometry to six Cl1- atoms. There are a spread of Rh–Cl bond distances ranging from 2.30–2.62 Å. There are two inequivalent N+1.67+ sites. In the first N+1.67+ site, N+1.67+ is bonded in a single-bond geometry to one Cl1- atom. The N–Cl bond length is 1.56 Å. In the second N+1.67+ site, N+1.67+ is bonded in a single-bond geometry to one Cl1- atom. The N–Cl bond length is 1.60 Å. There are four inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a 1-coordinate geometry to one Rh3+ atom. In the second Cl1- site, Cl1- is bonded in a water-like geometry to one Rh3+ and one N+1.67+ atom. In the third Cl1- site, Cl1- is bonded in a bent 120 degrees geometry to one Rh3+ and one N+1.67+ atom. In the fourth Cl1- site, Cl1- is bonded in a single-bond geometry to one Rh3+ atom.

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