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At least 1,639 records · Page 91

The bidirectional reflectance spectra of five gas-rich ordinary chondrites

In general, the spectra of the dark areas of gas-rich ordinary chondrites show reductions in both reflectance and band depth relative to the spectra of the light areas and the spectra of normal ordinary chondrites. The dark areas of these samples show spectral alteration despite having substantial fractions of light material intimately mixed with the dark, gas-rich grains. If the spectra of the dark gas-rich grains represent the spectral characteristics of a regolith soil on an ordinary chondrite body, then that surface would display a dark and strongly subdued spectrum.

Britt, Daniel T.↗

Effects of the microalgae Chlamydomonas on gastrointestinal health

The effects of consuming whole-cell biomass of the green algae Chlamydomonas reinhardtii on gastrointestinal health in mice and humans was examined. A 14-day murine model of acute colitis revealed significantly less weight loss in mice that received C. reinhardtii biomass by oral gavage. Based on this result, human volunteers with varying gastrointestinal symptoms were asked to consume 1 or 3 g of C. reinhardtii daily for 30 days. Participants reported changes in their gastrointestinal health through a questionnaire and provided stool samples to analyze the composition of their gut microbiome. Those who typically experience frequent gastrointestinal symptoms reported significantly less bowel discomfort or diarrhea, significantly less gas or bloating, more regular bowel movements, and better stool consistency when regularly consuming C. reinhardtii. Analysis of participant stool samples suggested the gut microbiome composition in all groups remained complex, and no signs of dysbiosis or adverse effect on microbial composition were observed.

60 APPLIED LIFE SCIENCES↗

A study of galaxy groups and clusters - The case for a clumpy intergalactic medium.

A nonuniform model for a dense intergalactic medium is constructed under the assumption that all groups and clusters of galaxies are gravitationally bound by ionized gas. Catalogs by de Vaucouleurs and Abell are utilized to provide an almost complete sample of the spatial distribution of groups and clusters over a wide range of richness, and a distribution function is derived for galaxy groups and clusters as a function of velocity dispersion. A simple scaling law is applied to predict velocity dispersions for the very rich Abell clusters. Thermal bremsstrahlung emission from the intracluster gas accounts for the observed emission over 2 to 10 keV from several rich clusters, and also contributes up to 20% of the diffuse X-ray background over a considerable fraction of the observed range. The amount of X-ray emitting gas is restricted to a small fraction of the virial mass, with the remainder of the binding mass present as cooler ionized clouds. Available soft X-ray and ultraviolet diffuse background observations are used to define a narrow range of permissible temperatures and densities for these clouds.

Silk, J.↗

The Phoenix Mars Lander Robotic Arm

The Phoenix Mars Lander Robotic Arm (RA) has operated for over 150 sols since the Lander touched down on the north polar region of Mars on May 25, 2008. During its mission it has dug numerous trenches in the Martian regolith, acquired samples of Martian dry and icy soil, and delivered them to the Thermal Evolved Gas Analyzer (TEGA) and the Microscopy, Electrochemistry, and Conductivity Analyzer (MECA). The RA inserted the Thermal and Electrical Conductivity Probe (TECP) into the Martian regolith and positioned it at various heights above the surface for relative humidity measurements. The RA was used to point the Robotic Arm Camera to take images of the surface, trenches, samples within the scoop, and other objects of scientific interest within its workspace. Data from the RA sensors during trenching, scraping, and trench cave-in experiments have been used to infer mechanical properties of the Martian soil. This paper describes the design and operations of the RA as a critical component of the Phoenix Mars Lander necessary to achieve the scientific goals of the mission.

Bonitz, Robert↗

Synergistic effects in trace gas-aerosol interactions

The reaction of SO2 and NO2 with soot has been studied experimentally by gravimetric determination of chemisorption with subsequent analysis of the chemisorbed species by various techniques. When samples of commercially available carbon black (used as soot surrogate) are exposed to SO2 or NO2 in dry air or N2 as carrier gas, no quantitative chemisorption (less than 5 micrograms per mg of substrate) is observed. However, exposure of the same grade of carbon to a combination of SO2 and NO2 in dry air of N2 results in significant chemisorption (180-200 micrograms/mg), a major fraction of which is analyzed as sulfate.

Schryer, D. R.↗

Development of an effusive inlet for mass spectrometric gas analysis of hypersonic boundary layer

The use of a microchannel plate (MCP) as a mass spectrometer inlet device to allow nonintrusive sampling of flight vehicle boundary layers is investigated. Two possible configurations for mounting the inlet are studied: (1) flow coaxial with the channels; and (2) flow perpendicular to the channel axis. The test gases are pure Kr; pure Ne; and a mixture of 10 pct Kr, 10 pct Ne, and 80 pct N2. The pressure ranges studied vary from 500 to 10 microns. A mass discrimination at the quadrupole mass spectrometer is observed, indicating an enrichment in the heavier gas. Possible explanations for this enrichment are discussed. It is shown that an MCP is capable of acting as a nonintrusive sampling device. Further work that will enable quantitative determination of the species at the surface is discussed.

Brown, Kenneth G.↗

Precursor gases of aerosols in the Mount St. Helens eruption plumes at stratospheric altitudes

Nineteen stratospheric samples from the eruption plumes of Mount St. Helens were collected in five flight experiments. The plume samples were collected at various altitudes from 13.1 to 20.7 km by using the Ames cryogenic sampling system on board the NASA U-2 aircraft. The enriched, cryogenically collected samples were analyzed by chromatography. The concentrations of aerosols precursor gases (OCS, SO2, and CS2), CH3Cl, N2O, CF2Cl2, and CFCl3 were measured by gas chromatography. Large enhancement of the mixing ratio of SO2 and moderate enhancement of CS2 and OCS were found in the plume samples compared with similar measurement under pre-volcanic conditions. A fast decay rate of the SO2 mixing ratio in the plume was observed. Measurement of Cl(-), SO2(2-), and NO3(-) by ion chromatography was also carried out on water solutions prepared from the plume samples. The results obtained with this technique imply large mixing ratios of HCl, (NO + NO2 + HNO3), and SO2, in which these constituents are the respective sources of the anions. Measurement of the Rn222 concentration in the plume was made. Other stratospheric constituents in the plume samples, such as H2O, CO2, CH4, and CO, were also observed.

Inn, E. C. Y.↗

Quantitative PLIF Imaging in High-Pressure Combustion

This is the final report for a research project aimed at developing planar laser-induced fluorescence (PLIF) techniques for quantitative 2-D species imaging in fuel-lean, high-pressure combustion gases, relevant to modem aircraft gas turbine combustors. The program involved both theory and experiment. The theoretical activity led to spectroscopic models that allow calculation of the laser-induced fluorescence produced in OH, NO and 02 for arbitrary excitation wavelength, pressure, temperature, gas mixture and laser linewidth. These spectroscopic models incorporate new information on line- broadening, energy transfer and electronic quench rates. Extensive calculations have been made with these models in order to identify optimum excitation strategies, particularly for detecting low levels (ppm) of NO in the presence of large 02 mole fractions (10% is typical for the fuel-lean combustion of interest). A promising new measurement concept has emerged from these calculations, namely that excitation at specific wavelengths, together with detection of fluorescence in multiple spectral bands, promises to enable simultaneous detection of both NO (at ppm levels) and 02 or possibly NO, 02 and temperature. Calculations have been made to evaluate the expected performance of such a diagnostic for a variety of conditions and choices of excitation and detection wavelengths. The experimental effort began with assembly of a new high-pressure combustor to provide controlled high-temperature and high-pressure combustion products. The non-premixed burner enables access to postflame gases at high temperatures (to 2000 K) and high pressures (to 13 atm), and a range of fuel-air equivalence ratios. The chamber also allowed use of a sampling probe, for chemiluminescent detection of NO/NO2, and thermocouples for measurement of gas temperature. Experiments were conducted to confirm the spectroscopic models for OH, NO and 02.

Hanson, R. K.↗

Shock-implanted noble gases - An experimental study with implications for the origin of Martian gases in shergottite meteorites

The shock-implantation of gases is studied by artificially shocking whole rock and power samples of terrestrial basalt to pressures of 2-40 GPa. Ar, Kr, Xe, and Ne were implanted into the silicate. It is observed that the amount of implanted gas is linearly proportional to its partial pressure over a pressure range of 0.0001 to 0.1 atmosphere. The fractionation effect in the implanted gas and the gas diffusion properties are examined. The amounts of gas that would have been implanted with 100 percent efficiency are calculated from the measured porosities of the power samples and are compared to observed abundances. It is determined that the implantation efficiencies are approximately 0.5 percent at 2 GPa, 7 percent at 5 GPa, and greater than 50 percent at both 20 and 35 GPa. The experimental data correlate with the shock implantation of Martian gases without mass fractionation into the shock-melted phase of meteorite EETA 79001.

Bogard, Donald D.↗

Test evaluation of potential heat shield contamination of an Outer Planet Probe's atmospheric sampling system

An Outer Planets Probe which retains the charred heatshield during atmospheric descent must deploy a sampling tube through the heatshield to extract atmospheric samples for analysis. Once the sampling tube is deployed, the atmospheric samples ingested must be free of contaminant gases generated by the heatshield. Outgassing products such as methane and water vapor are present in planetary atmospheres and hence, ingestion of such species would result in gas analyzer measurement uncertainties. This paper evaluates the potential for, and design impact of, the extracted atmospheric samples being contaminated by heatshield outgassing products. Flight trajectory data for Jupiter, Saturn and Uranus entries are analyzed to define the conditions resulting in the greatest potential for outgassing products being ingested into the probe's sampling system. An experimental program is defined and described which simulates the key flow field features for a planetary flight in a ground-based test facility. The primary parameters varied in the test include: sampling tube length, injectant mass flow rate and angle of attack. Measured contaminant levels predict the critical sampling tube length for contamination avoidance. Thus, the study demonstrates the compatibility of a retained heatshield concept and high quality atmospheric trace species measurements.

Kessler, W. C.↗

On the H I Content of MaNGA Major Merger Pairs

The role of H I content in galaxy interactions is still under debate. To study the H I content of galaxy pairs at different merging stages, we compile a sample of 66 major-merger galaxy pairs and 433 control galaxies from the Sloan Digital Sky Survey IV (SDSS-IV) MaNGA IFU survey. In this study, we adopt kinematic asymmetry as a new effective indicator to describe the merging stage of galaxy pairs. With archival data from the HI-MaNGA survey and new observations from the Five-hundred-meter Aperture Spherical radio Telescope (FAST), we investigate the differences in H I gas fraction (f H I ), star formation rate (SFR), and H I star formation efficiency (SFE H I ) between the pair and control samples. Our results suggest that the H I gas fraction of major-merger pairs on average is marginally decreased by ~15% relative to isolated galaxies, implying mild H I depletion during galaxy interactions. Compared to isolated galaxies, pre-passage paired galaxies have similar f H I , SFR, and SFE H I , while pairs during the pericentric passage have weakly decreased f H I (–0.10 ± 0.05 dex), significantly enhanced SFR (0.42 ± 0.11 dex), and SFE H I (0.48 ± 0.12 dex). When approaching the apocenter, paired galaxies show marginally decreased f H I (–0.05 ± 0.04 dex), comparable SFR (0.04 ± 0.06 dex), and SFE H I (0.08 ± 0.08 dex). We propose that the marginally detected H i depletion may originate from the gas consumption in fueling the enhanced H2 reservoir of galaxy pairs. In addition, new FAST observations also reveal a H I absorber (N H I ~ 4.7 × 10 21 cm –2 ), which may suggest gas infalling and the triggering of active galactic nuclei activity.

79 ASTRONOMY AND ASTROPHYSICS↗

Precision Kinematic Sunyaev--Zel'dovich Measurements Across Halo Mass and Redshift with DESI DR2 and ACT DR6: Part II. Bright Galaxy Survey and Emission-Line Galaxies

We present the first high-significance spectroscopic stacked kinetic Sunyaev-Zel'dovich (kSZ) measurements of circumgalactic gas profiles for both Bright Galaxy Survey (BGS) and Emission Line Galaxy (ELG) tracers, combining DESI Data Release 2 with ACT Data Release 6. Using reconstructed line-of-sight velocities from the DESI galaxies and high-resolution ACT temperature maps, we detect the kSZ signal at high significance, reaching signal-to-noise ratios of up to $\sim$9 for BGS and $\sim$7.5 for ELGs in optimal stellar-mass selections. Together with the LRG measurements presented in Paper I, these constitute the most significant kSZ detections from any spectroscopic survey to date. We perform the analysis in both real and harmonic space, obtaining consistent results. By splitting both tracers into stellar-mass bins, we study the scaling of the kSZ amplitude with galaxy properties. Combining the kSZ measurements with ACT Data Release 6 (DR6) CMB lensing maps enables a joint calibration of the galaxy-halo connection and the gas fractions of host halos. For the BGS galaxies, we observe low gas fractions around the virial radius relative to standard expectations, likely attributable to active galactic nuclei (AGN) activity. We find some evidence for higher-mass halos retaining a larger fraction of their baryons, consistent with more efficient feedback in lower-mass systems. For the ELG sample, dominated by blue, star-forming galaxies, we provide the first detection of the gas distribution in ELG host halos. The ELGs appear to exhibit relatively high gas fractions, which points to the possibility of weaker feedback (due to e.g. low AGN and supernova feedback activity) at their mass scale. Finally, we present generalized Navarro-Frenk-White (GNFW) fits to the harmonic-space measurements, providing a compact parametrization of gas profiles for forward modeling in large-scale structure analyses.

Hadzhiyska, B. [Cambridge U.; Cambridge U., Inst. ↗

Thermophysical Property Measurement and Materials Research in the NASA/MSFC Electrostatic Levitator

Containerless processing is an important tool for materials research. The freedom from a crucible allows processing of liquid materials in a metastable undercooled state, as well as allowing processing of high temperature and highly reactive melts. Electrostatic levitation (ESL) is a containerless method which provides a number of unique advantages, including the decoupling of positioning force from sample heating, the ability to operate in ultra-high vacuum or at moderate gas pressure (approx. 3 atm), and the ability to process non-conducting materials. ESL also has the potential to reduce internal flow velocities below those possible with electromagnetic, acoustic, or aero-acoustic techniques. In electrostatic levitation, the acceleration of gravity (or residual acceleration in reduced gravity) is opposed by the action of an applied electric field on a charged sample. Microgravity allows electrostatic levitation to work even more effectively. In microgravity, ESL can position larger samples than is possible on the ground, or it can position samples which maintain their charge poorly. Microgravity also reduces the effects of buoyant convection and sedimentation. The ESL facility at NASA's Marshall Space Flight Center (MSFC) is in use for thermophysical property measurements and materials research by a number of different internal and external investigators. The methods for obtaining access to the facility, as well as a summary of current capabilities and some future directions will be discussed.

Rogers, J. R.↗

Low-Pressure, Field-Ionizing Mass Spectrometer

A small mass spectrometer utilizing a miniature field ionization source is now undergoing development. It is designed for use in a variety of applications in which there are requirements for a lightweight, low-power-consumption instrument that can analyze the masses of a wide variety of molecules and ions. The device can operate without need for a high-vacuum, carrier-gas feed radioactive ionizing source, or thermal ionizer. This mass spectrometer can operate either in the natural vacuum of outer space or on Earth at any ambient pressure below 50 torr (below about 6.7 kPa) - a partial vacuum that can easily be reached by use of a small sampling pump. This mass spectrometer also has a large dynamic range - from singly charged small gas ions to deoxyribonucleic acid (DNA) fragments larger than 104 atomic mass units - with sensitivity adequate for detecting some molecules and ions at relative abundances of less than one part per billion. This instrument (see figure) includes a field ionizer integrated with a rotating-field mass spectrometer (RFMS). The field ionizer effects ionization of a type characterized as "soft" in the art because it does not fragment molecules or initiate avalanche arcing. What makes the "soft" ionization mode possible is that the distance between the ionizing electrodes is less than mean free path for ions at the maximum anticipated operating pressure, so that the ionizer always operates on the non-breakdown side of the applicable Paschen curve (a standard plot of breakdown potential on the ordinate and pressure electrode separation on the abscissa). The field ionizer in this instrument is fabricated by micromachining a submicron-thick membrane out of an electrically nonconductive substrate, coating the membrane on both sides to form electrodes, then micromachining small holes through the electrodes and membrane. Because of the submicron electrode separation, even a potential of only 1 V applied between the electrodes gives rise to an electric field with a strength of in excess of a megavolt per meter strong enough to ionize any gas molecules passing through the holes. An accelerator grid and an electrostatic deflector focus the ions from the field ionizer into the rotating-field cell of the RFMS. The potentials applied to the electrodes of the cell to generate the rotating electric field typically range from 1 to 13 V. The ions travel in well-defined helices within this cell, after which they are collected in a Faraday cup. The mass of most of the molecules reaching the Faraday cup decreases with increasing frequency of rotation of the electric field in the cell. Therefore, the frequency of rotation of the electric field is made to vary in order to scan through a desired range of ion masses: For example, lightweight gas molecules are scanned at frequencies in the megahertz range, while DNA and other large organic molecules are scanned at kilohertz frequencies.

Hartley, Frank↗

Novel Synthesis and Characterization of Uranium-Zirconium Carbonitride by Direct Casting

UZrCN has exhibited thermophysical properties beneficial to high temperature reactor applications such as nuclear thermal rockets. The present work investigates a novel liquid phase synthesis method involving the admission of nitrogen gas during arc melting of uranium, zirconium, and carbon. Initial microstructural examinations using SEM indicated that the samples remain heterogenous with zirconium-rich cores in a uranium-rich matrix. Heterogeneity resulted from large differences in melting temperature of the major constituents and rapid solidification. Additional EDS, combustion analysis, and inert gas fusion analysis proved that the core regions have both uranium and zirconium and establish that carbon and nitrogen are retained during the fabrication process. XRD clarifies that the light elements did not form compounds with the uranium matrix but rather incorporated into the core region forming a sub-stoichiometric UZrCN. Heat treatment performed on equimolar U-Zr-C resulted in an increase in the homogenous phase present with an XRD pattern reflecting a ternary UZrCN despite small amounts of segregation in the final button.

36 - MATERIALS SCIENCE↗

On Uranium-Zirconium Carbonitride Formation by Direct Casting - A Novel Synthesis Study

UZrCN has exhibited thermophysical properties beneficial to high temperature reactor applications such as nuclear thermal rockets. The present work investigates a novel liquid phase synthesis method involving the admission of nitrogen gas during arc melting of uranium, zirconium, and carbon. Initial microstructural examinations using SEM indicated that the samples remain heterogenous with zirconium-rich cores in a uranium-rich matrix. Heterogeneity resulted from large differences in melting temperature of the major constituents and rapid solidification. Additional EDS, combustion analysis, and inert gas fusion analysis proved that the core regions have both uranium and zirconium and establish that carbon and nitrogen are retained during the fabrication process. XRD clarifies that the light elements did not form compounds with the uranium matrix but rather incorporated into the core region forming a sub-stoichiometric UZrCN. Heat treatment performed on equimolar U-Zr-C resulted in an increase in the homogenous phase present with an XRD pattern reflecting a ternary UZrCN despite small amounts of segregation in the final button.

36 - MATERIALS SCIENCE↗

The Neutral Gas Desorption and Breakdown on a Metal-Dielectric Junction Immersed in a Plasma

New results are presented of an experimental study and theoretical analysis of arcing on metal-dielectric junctions immersed in a low-density plasma. Two samples of conventional solar arrays have been used to investigate the effects of arcing within a wide range of neutral gas pressures, ion currents, and electron number densities. All data (except video) were obtained in digital form that allowed us to study the correlation between external parameters (plasma density, additional capacitance, bias voltage, etc) and arc characteristics (arc rate, arc current pulse width and amplitude, gas species partial pressures, intensities of spectral lines, and so on). Arc sites were determined by employing a video-camera, and it is shown that the most probable sites for arc inception are trip le-junctions, even though some arcs were initiated in gaps between cells. The effect of surface conditioning (decrease of arc rate due to outgassing) was clearly demonstrated. Moreover, a considerable increase in arc rate due to absorption of molecules from atmospheric air has been confirmed. The analysis of optical spectra (240-800 nm) reveals intense narrow atomic lines (Ag, H) and wide molecular bands (OH, CH, SiH, SiN) that confirm a complicated mechanism of arc plasma generation. The rate of plasma contamination due to arcing was measured by employing a mass-spectrometer. These measurements provided quite reliable data for the development of a theoretical model of plasma contamination, In conclusion, the arc threshold was increased to above 350 V (from 190 V) by keeping a sample in vacuum (20 micronTorr) for seven days. The results obtained are important for the understanding of the arc inception mechanism, which is absolutely essential for progress toward the design of high voltage solar arrays for space applications.

Vayner, Boris↗