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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,639 records · Page 91

Spatio-temporal coherence of free-electron laser radiation in the extreme ultraviolet determined by a Michelson interferometer

A key feature of extreme ultraviolet (XUV) radiation from free-electron lasers (FELs) is its spatial and temporal coherence. We measured the spatio-temporal coherence properties of monochromatized FEL pulses at 13.5 nm using a Michelson interferometer. A temporal coherence time of (59±8) fs has been determined, which is in good agreement with the spectral bandwidth given by the monochromator. Moreover, the spatial coherence in vertical direction amounts to about 15% of the beam diameter and about 12% in horizontal direction. The feasibility of measuring spatio-temporal coherence properties of XUV FEL radiation using interferometric techniques advances machine operation and experimental studies significantly.

43 PARTICLE ACCELERATORS↗

Head on collision of multi-solitons in an electron-positron-ion plasma having superthermal electrons

The head-on collision and overtaking collision of four solitons in a plasma comprising superthermal electrons, cold ions, and Boltzmann distributed positrons are investigated using the extended Poincare-Lighthill-Kuo (PLK) together with Hirota's method. PLK method yields two separate Korteweg-de Vries (KdV) equations where solitons obtained from any KdV equation move along a direction opposite to that of solitons obtained from the other KdV equation, While Hirota's method gives multi-soliton solution for each KdV equation all of which move along the same direction where the fastest moving soliton eventually overtakes the other ones. We have considered here two soliton solutions obtained from Hirota's method. Phase shifts acquired by each soliton due to both head-on collision and overtaking collision are calculated analytically.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Coherent kilo-electron-volt backscattering from plasma-wave boosted relativistic electron mirrors

A different parameter regime of laser wakefield acceleration driven by sub-petawatt femtosecond lasers is proposed, which enables the generation of relativistic electron mirrors further accelerated by the plasma wave. Integrated particle-in-cell simulation, including both the mirror formation and Thomson scattering, demonstrates that efficient coherent backscattering up to keV photon energy can be obtained with moderate driving laser intensities and high density gas targets.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Electronic structure of C and N co-doped TiO{sub 2}: A combined hard x-ray photoemission spectroscopy and density functional theory study

We have studied the electronic structure of C and N co-doped TiO{sub 2} using hard x-ray photoelectron spectroscopy and first-principles density functional theory calculations. Our results reveal overlap of the 2p states of O, N, and C in the system which shifts the valence band maximum towards the Fermi level. Combined with optical data we show that co-doping is an effective route for band gap reduction in TiO{sub 2}. Comparison of the measured valence band with theoretical photoemission density of states reveals the possibility of C on Ti and N on O site.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Evidence for anisotropic dielectric properties of monoclinic hafnia using valence electron energy-loss spectroscopy in high-resolution transmission electron microscopy and ab initio time-dependent density-functional theory

The effect of nanocrystal orientation on the energy loss spectra of monoclinic hafnia (m-HfO{sub 2}) is measured by high resolution transmission electron microscopy (HRTEM) and valence energy loss spectroscopy (VEELS) on high quality samples. For the same momentum-transfer directions, the dielectric properties are also calculated ab initio by time-dependent density-functional theory (TDDFT). Experiments and simulations evidence anisotropy in the dielectric properties of m-HfO{sub 2}, most notably with the direction-dependent oscillator strength of the main bulk plasmon. The anisotropic nature of m-HfO{sub 2} may contribute to the differences among VEELS spectra reported in literature. The good agreement between the complex dielectric permittivity extracted from VEELS with nanometer spatial resolution, TDDFT modeling, and past literature demonstrates that the present HRTEM-VEELS device-oriented methodology is a possible solution to the difficult nanocharacterization challenges given in the International Technology Roadmap for Semiconductors.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Relationships between the surface electronic and chemical properties of doped 4d and 5d late transition metal dioxides

Density functional theory calculations were performed to elucidate the underlying physics describing the adsorption energies on doped late transition metal dioxide rutiles. Adsorption energies of atomic oxygen on doped rutiles M{sup D}-M{sup H}O{sub 2}, where transition metal M{sup D} is doped into M{sup H}O{sub 2}, were expressed in terms of a contribution from adsorption on the pure oxide of the dopant M{sup D} and perturbations to this adsorption energy caused by changing its neighboring metal cations and lattice parameters to that of the host oxide M{sup H}O{sub 2}, which we call the ligand and strain effects, respectively. Our analysis of atom projected density of states revealed that the t{sub 2g}-band center had the strongest correlation with adsorption energies. We show that charge transfer mediated shifts to the t{sub 2g}-band center describe the ligand effect, and the radii of the atomic orbitals of metal cations can predict the magnitude and direction of this charge transfer. Strain produces systematic shifts to all features of the atom projected density of states, but correlations between the strain effect and the electronic structure were dependent on the chemical identity of the metal cation. The slope of these correlations can be related to the idealized d-band filling. This work elucidates the underlying physics describing adsorption on doped late transition metal oxides and establishes a foundation for models that use known chemical properties for the prediction of reactivity.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Magnetic field extraction of trap-based electron beams using a high-permeability grid

A method to form high quality electrostatically guided lepton beams is explored. Test electron beams are extracted from tailored plasmas confined in a Penning-Malmberg trap. The particles are then extracted from the confining axial magnetic field by passing them through a high magnetic permeability grid with radial tines (a so-called “magnetic spider”). An Einzel lens is used to focus and analyze the beam properties. Numerical simulations are used to model non-adiabatic effects due to the spider, and the predictions are compared with the experimental results. Improvements in beam quality are discussed relative to the use of a hole in a high permeability shield (i.e., in lieu of the spider), and areas for further improvement are described.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Gyrokinetic studies of trapped electron mode turbulence in the Helically Symmetric eXperiment stellarator

Gyrokinetic simulations of plasma microturbulence in the Helically Symmetric eXperiment are presented. Using plasma profiles relevant to experimental operation, four dominant drift wave regimes are observed in the ion wavenumber range, which are identified as different flavors of density-gradient-driven trapped electron modes. For the most part, the heat transport exhibits properties associated with turbulence driven by these types of modes. Additionally, long-wavelength, radially localized, nonlinearly excited coherent structures near the resonant central flux surface, not predicted by linear simulations, can further enhance flux levels. Integrated heat fluxes are compatible with experimental observations in the corresponding density gradient range. Despite low shearing rates, zonal flows are observed to regulate turbulence but can be overwhelmed at higher density gradients by the long-wavelength coherent structures.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Research Update: Towards designed functionalities in oxide-based electronic materials

One of the grand challenges facing materials-by-design approaches for complex oxide deployment in electronic devices is how to balance transformative first-principles based predictions with experimental feasibility. Here, we briefly review the functionality-driven approach (inverse design) for materials discovery, encapsulated in three modalities for materials discovery (m{sup 3}D) that integrate experimental feedback. We compare it to both traditional theoretical and high-throughput database-directed approaches aimed at advancing oxide-based materials into technologies.

36 MATERIALS SCIENCE↗

Analytical solutions of the planar cyclic voltammetry process for two soluble species with equal diffusivities and fast electron transfer using the method of eigenfunction expansions

Cyclic voltammetry is a powerful tool that is used for characterizing electrochemical processes. Models of cyclic voltammetry take into account the mass transport of species and the kinetics at the electrode surface. Analytical solutions of these models are not well-known due to the complexity of the boundary conditions. In this study we present closed form analytical solutions of the planar voltammetry model for two soluble species with fast electron transfer and equal diffusivities using the eigenfunction expansion method. Our solution methodology does not incorporate Laplace transforms and yields good agreement with the numerical solution. This solution method can be extended to cases that are more general and may be useful for benchmarking purposes.

36 MATERIALS SCIENCE↗

Preface: Special Topic Section on Advanced Electronic Structure Methods for Solids and Surfaces

This Special Topic section on Advanced Electronic Structure Methods for Solids and Surfaces contains a collection of research papers that showcase recent advances in the high accuracy prediction of materials and surface properties. It provides a timely snapshot of a growing field that is of broad importance to chemistry, physics, and materials science.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Active control of electron cyclotron emission radiometer channel frequencies for improved electron temperature measurements

As advanced scenarios are developed for tokamak operations, the demand for flexibility of the electron cyclotron emission (ECE) channels’ locations has increased. The tunable feature of yttrium iron garnet (YIG) filters provides this spatial flexibility. Here, we present a method of performing ECE measurements on fixed flux surfaces instead of fixed frequencies. This is achieved by adjusting YIG filters utilized in the intermediate frequency section to frequencies associated with flux surfaces in regions of interest during the discharge. Here, the key components are the application of tunable YIG filters and a control program that calculates the filter settings using flux information from real-time reconstruction equilibria (EFIT). This fast procedure facilitates T e measurements in regions of interest to investigate plasma dynamic behaviors.

47 OTHER INSTRUMENTATION↗

The future of electron microscopy

Modern transmission electron microscopes can image individual atoms and molecules. But to unlock new science, the next generation of instruments must look beyond just higher spatial resolution.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗