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PdCd is Tetraauricupride structured and crystallizes in the tetragonal P4/mmm space group. The structure is three-dimensional. Pd is bonded in a body-centered cubic geometry to eight equivalent Cd atoms. All Pd–Cd bond lengths are 2.85 Å. Cd is bonded in a body-centered cubic geometry to eight equivalent Pd atoms.
HoCd is Tetraauricupride structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Ho is bonded in a body-centered cubic geometry to eight equivalent Cd atoms. All Ho–Cd bond lengths are 3.23 Å. Cd is bonded in a body-centered cubic geometry to eight equivalent Ho atoms.
Ba4Tb2Cd3S10 crystallizes in the orthorhombic Cmc2_1 space group. The structure is three-dimensional. there are four inequivalent Ba2+ sites. In the first Ba2+ site, Ba2+ is bonded in a 8-coordinate geometry to eight S2- atoms. There are a spread of Ba–S bond distances ranging from 3.16–3.76 Å. In the second Ba2+ site, Ba2+ is bonded to seven S2- atoms to form distorted BaS7 pentagonal bipyramids that share corners with two equivalent TbS6 octahedra, corners with two equivalent BaS7 pentagonal bipyramids, edges with three TbS6 octahedra, edges with three equivalent BaS7 pentagonal bipyramids, edges with two equivalent CdS4 tetrahedra, edges with two equivalent CdS4 trigonal pyramids, and faces with two equivalent BaS7 pentagonal bipyramids. The corner-sharing octahedral tilt angles are 16°. There are a spread of Ba–S bond distances ranging from 3.11–3.33 Å. In the third Ba2+ site, Ba2+ is bonded to seven S2- atoms to form distorted BaS7 pentagonal bipyramids that share corners with two equivalent TbS6 octahedra, corners with two equivalent BaS7 pentagonal bipyramids, corners with two equivalent CdS4 tetrahedra, corners with five CdS4 trigonal pyramids, edges with three TbS6 octahedra, edges with three equivalent BaS7 pentagonal bipyramids, an edgeedge with one CdS4 trigonal pyramid, and faces with two equivalent BaS7 pentagonal bipyramids. The corner-sharing octahedral tilt angles are 21°. There are a spread of Ba–S bond distances ranging from 3.17–3.36 Å. In the fourth Ba2+ site, Ba2+ is bonded in a 8-coordinate geometry to eight S2- atoms. There are a spread of Ba–S bond distances ranging from 3.14–3.57 Å. There are two inequivalent Tb3+ sites. In the first Tb3+ site, Tb3+ is bonded to six S2- atoms to form TbS6 octahedra that share corners with two equivalent BaS7 pentagonal bipyramids, edges with two equivalent TbS6 octahedra, edges with three BaS7 pentagonal bipyramids, and edges with four CdS4 trigonal pyramids. There are a spread of Tb–S bond distances ranging from 2.77–2.84 Å. In the second Tb3+ site, Tb3+ is bonded to six S2- atoms to form TbS6 octahedra that share corners with two equivalent BaS7 pentagonal bipyramids, corners with three equivalent CdS4 tetrahedra, edges with two equivalent TbS6 octahedra, and edges with three BaS7 pentagonal bipyramids. There are a spread of Tb–S bond distances ranging from 2.77–2.81 Å. There are three inequivalent Cd2+ sites. In the first Cd2+ site, Cd2+ is bonded to four S2- atoms to form CdS4 tetrahedra that share corners with three equivalent TbS6 octahedra, corners with two equivalent BaS7 pentagonal bipyramids, corners with two equivalent CdS4 tetrahedra, a cornercorner with one CdS4 trigonal pyramid, and edges with two equivalent BaS7 pentagonal bipyramids. The corner-sharing octahedra tilt angles range from 6–70°. There are a spread of Cd–S bond distances ranging from 2.48–2.72 Å. In the second Cd2+ site, Cd2+ is bonded to four S2- atoms to form distorted CdS4 trigonal pyramids that share corners with two equivalent BaS7 pentagonal bipyramids, corners with two equivalent CdS4 trigonal pyramids, edges with two equivalent TbS6 octahedra, and an edgeedge with one BaS7 pentagonal bipyramid. There are a spread of Cd–S bond distances ranging from 2.46–2.73 Å. In the third Cd2+ site, Cd2+ is bonded to four S2- atoms to form CdS4 trigonal pyramids that share corners with three equivalent BaS7 pentagonal bipyramids, a cornercorner with one CdS4 tetrahedra, corners with two equivalent CdS4 trigonal pyramids, edges with two equivalent TbS6 octahedra, and edges with two equivalent BaS7 pentagonal bipyramids. There are a spread of Cd–S bond distances ranging from 2.55–2.70 Å. There are ten inequivalent S2- sites. In the first S2- site, S2- is bonded to three Ba2+ and two equivalent Tb3+ atoms to form distorted SBa3Tb2 trigonal bipyramids that share corners with six SBa4Cd square pyramids, edges with two equivalent SBa4TbCd octahedra, edges with two SBa3Tb2 square pyramids, and edges with two equivalent SBa3Tb2 trigonal bipyramids. In the second S2- site, S2- is bonded to three Ba2+ and two equivalent Tb3+ atoms to form distorted SBa3Tb2 square pyramids that share corners with four equivalent SBa4Cd2 octahedra, corners with two equivalent SBa2TbCd2 square pyramids, corners with two equivalent SBa3Tb2 trigonal bipyramids, edges with five SBa4Cd2 octahedra, edges with three SBa3Tb2 square pyramids, and an edgeedge with one SBa3Tb2 trigonal bipyramid. The corner-sharing octahedra tilt angles range from 40–50°. In the third S2- site, S2- is bonded in a 5-coordinate geometry to two equivalent Ba2+, one Tb3+, and two equivalent Cd2+ atoms. In the fourth S2- site, S2- is bonded to two equivalent Ba2+, one Tb3+, and two equivalent Cd2+ atoms to form distorted SBa2TbCd2 square pyramids that share corners with two equivalent SBa4Cd2 octahedra, corners with four SBa3Tb2 square pyramids, edges with three SBa4Cd2 octahedra, and edges with three SBa3Tb2 square pyramids. The corner-sharing octahedral tilt angles are 54°. In the fifth S2- site, S2- is bonded in a distorted trigonal non-coplanar geometry to two Ba2+, one Tb3+, and two equivalent Cd2+ atoms. In the sixth S2- site, S2- is bonded to four Ba2+ and one Cd2+ atom to form distorted SBa4Cd square pyramids that share corners with two equivalent SBa4TbCd octahedra, corners with two equivalent SBa2TbCd2 square pyramids, corners with four equivalent SBa3Tb2 trigonal bipyramids, an edgeedge with one SBa4TbCd octahedra, edges with two equivalent SBa4Cd square pyramids, and an edgeedge with one SBa3Tb2 trigonal bipyramid. The corner-sharing octahedral tilt angles are 41°. In the seventh S2- site, S2- is bonded to four Ba2+ and two Cd2+ atoms to form distorted SBa4Cd2 octahedra that share corners with six SBa4TbCd octahedra, corners with six SBa3Tb2 square pyramids, edges with two equivalent SBa4Cd2 octahedra, edges with two SBa2TbCd2 square pyramids, and faces with two SBa4TbCd octahedra. The corner-sharing octahedra tilt angles range from 41–59°. In the eighth S2- site, S2- is bonded to four Ba2+, one Tb3+, and one Cd2+ atom to form SBa4TbCd octahedra that share corners with four SBa4Cd2 octahedra, corners with two equivalent SBa4Cd square pyramids, edges with three SBa4TbCd octahedra, edges with three SBa3Tb2 square pyramids, edges with two equivalent SBa3Tb2 trigonal bipyramids, and a faceface with one SBa4Cd2 octahedra. The corner-sharing octahedra tilt angles range from 21–54°. In the ninth S2- site, S2- is bonded in a 6-coordinate geometry to three Ba2+, two equivalent Tb3+, and one Cd2+ atom. In the tenth S2- site, S2- is bonded to three Ba2+, two equivalent Tb3+, and one Cd2+ atom to form distorted SBa3Tb2Cd octahedra that share corners with six SBa4Cd2 octahedra, edges with three SBa4TbCd octahedra, edges with four SBa3Tb2 square pyramids, and a faceface with one SBa4Cd2 octahedra. The corner-sharing octahedra tilt angles range from 21–59°.
CeCd is Tetraauricupride structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Ce is bonded in a body-centered cubic geometry to eight equivalent Cd atoms. All Ce–Cd bond lengths are 3.33 Å. Cd is bonded in a body-centered cubic geometry to eight equivalent Ce atoms.
CdYb is Tetraauricupride structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Yb is bonded in a body-centered cubic geometry to eight equivalent Cd atoms. All Yb–Cd bond lengths are 3.30 Å. Cd is bonded in a body-centered cubic geometry to eight equivalent Yb atoms.
LuCd is Tetraauricupride structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Lu is bonded in a body-centered cubic geometry to eight equivalent Cd atoms. All Lu–Cd bond lengths are 3.18 Å. Cd is bonded in a body-centered cubic geometry to eight equivalent Lu atoms.
Cd7P4Cl6 crystallizes in the cubic Pa-3 space group. The structure is three-dimensional. there are two inequivalent Cd2+ sites. In the first Cd2+ site, Cd2+ is bonded to six equivalent Cl1- atoms to form edge-sharing CdCl6 octahedra. All Cd–Cl bond lengths are 2.69 Å. In the second Cd2+ site, Cd2+ is bonded to two P2- and four equivalent Cl1- atoms to form distorted CdP2Cl4 octahedra that share corners with eight equivalent CdP2Cl4 octahedra, corners with two PCd3P tetrahedra, and edges with six CdCl6 octahedra. The corner-sharing octahedra tilt angles range from 14–87°. Both Cd–P bond lengths are 2.53 Å. There are a spread of Cd–Cl bond distances ranging from 2.80–3.34 Å. There are two inequivalent P2- sites. In the first P2- site, P2- is bonded to three equivalent Cd2+ and one P2- atom to form PCd3P tetrahedra that share corners with three equivalent CdP2Cl4 octahedra, corners with six equivalent ClCd5 square pyramids, corners with three equivalent PCd3P tetrahedra, and edges with three equivalent ClCd5 square pyramids. The corner-sharing octahedral tilt angles are 71°. The P–P bond length is 2.20 Å. In the second P2- site, P2- is bonded to three equivalent Cd2+ and one P2- atom to form PCd3P tetrahedra that share corners with three equivalent CdP2Cl4 octahedra, corners with six equivalent ClCd5 square pyramids, corners with three equivalent PCd3P tetrahedra, and edges with three equivalent ClCd5 square pyramids. The corner-sharing octahedral tilt angles are 73°. Cl1- is bonded to five Cd2+ atoms to form distorted ClCd5 square pyramids that share corners with nine equivalent ClCd5 square pyramids, corners with four PCd3P tetrahedra, edges with four equivalent ClCd5 square pyramids, and edges with two PCd3P tetrahedra.
Cd5P3O12Cl crystallizes in the hexagonal P6_3/m space group. The structure is three-dimensional. there are two inequivalent Cd2+ sites. In the first Cd2+ site, Cd2+ is bonded in a 6-coordinate geometry to six O2- atoms. There are three shorter (2.36 Å) and three longer (2.41 Å) Cd–O bond lengths. In the second Cd2+ site, Cd2+ is bonded to five O2- and one Cl1- atom to form distorted CdClO5 pentagonal pyramids that share corners with six equivalent CdClO5 pentagonal pyramids, corners with three equivalent PO4 tetrahedra, and an edgeedge with one PO4 tetrahedra. There are a spread of Cd–O bond distances ranging from 2.26–2.49 Å. The Cd–Cl bond length is 2.61 Å. P5+ is bonded to four O2- atoms to form PO4 tetrahedra that share corners with three equivalent CdClO5 pentagonal pyramids and an edgeedge with one CdClO5 pentagonal pyramid. There are a spread of P–O bond distances ranging from 1.55–1.59 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a 1-coordinate geometry to two equivalent Cd2+ and one P5+ atom. In the second O2- site, O2- is bonded in a 1-coordinate geometry to two equivalent Cd2+ and one P5+ atom. In the third O2- site, O2- is bonded to three Cd2+ and one P5+ atom to form distorted edge-sharing OCd3P tetrahedra. Cl1- is bonded in a trigonal planar geometry to three equivalent Cd2+ atoms.
Cd3P2 is Hausmannite-like structured and crystallizes in the tetragonal P4_2/nmc space group. The structure is three-dimensional. there are three inequivalent Cd2+ sites. In the first Cd2+ site, Cd2+ is bonded in a 4-coordinate geometry to four P3- atoms. There are a spread of Cd–P bond distances ranging from 2.57–3.11 Å. In the second Cd2+ site, Cd2+ is bonded to four P3- atoms to form a mixture of edge and corner-sharing CdP4 tetrahedra. There are two shorter (2.54 Å) and two longer (2.86 Å) Cd–P bond lengths. In the third Cd2+ site, Cd2+ is bonded to four P3- atoms to form a mixture of distorted edge and corner-sharing CdP4 tetrahedra. There are a spread of Cd–P bond distances ranging from 2.60–3.08 Å. There are three inequivalent P3- sites. In the first P3- site, P3- is bonded in a 6-coordinate geometry to six Cd2+ atoms. In the second P3- site, P3- is bonded in a 6-coordinate geometry to six Cd2+ atoms. In the third P3- site, P3- is bonded in a 4-coordinate geometry to six Cd2+ atoms.
TmCd is Tetraauricupride structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Tm is bonded in a body-centered cubic geometry to eight equivalent Cd atoms. All Tm–Cd bond lengths are 3.21 Å. Cd is bonded in a body-centered cubic geometry to eight equivalent Tm atoms.
AgCd is Tetraauricupride structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Ag is bonded in a body-centered cubic geometry to eight equivalent Cd atoms. All Ag–Cd bond lengths are 2.94 Å. Cd is bonded in a body-centered cubic geometry to eight equivalent Ag atoms.
AuCd is Tetraauricupride structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Au is bonded in a body-centered cubic geometry to eight equivalent Cd atoms. All Au–Cd bond lengths are 2.95 Å. Cd is bonded in a body-centered cubic geometry to eight equivalent Au atoms.
Na4Cd3Se5 crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. there are four inequivalent Na1+ sites. In the first Na1+ site, Na1+ is bonded to five Se2- atoms to form distorted NaSe5 trigonal bipyramids that share corners with two equivalent NaSe6 octahedra, corners with three equivalent NaSe5 square pyramids, corners with six CdSe4 tetrahedra, corners with four equivalent NaSe5 trigonal bipyramids, edges with two equivalent CdSe4 tetrahedra, edges with four NaSe5 trigonal bipyramids, and a faceface with one NaSe6 octahedra. The corner-sharing octahedral tilt angles are 58°. There are a spread of Na–Se bond distances ranging from 2.97–3.17 Å. In the second Na1+ site, Na1+ is bonded to six Se2- atoms to form NaSe6 octahedra that share corners with three equivalent NaSe5 square pyramids, corners with five CdSe4 tetrahedra, corners with four NaSe5 trigonal bipyramids, edges with four equivalent NaSe6 octahedra, edges with five CdSe4 tetrahedra, an edgeedge with one NaSe5 trigonal bipyramid, and a faceface with one NaSe5 trigonal bipyramid. There are a spread of Na–Se bond distances ranging from 3.04–3.49 Å. In the third Na1+ site, Na1+ is bonded to five Se2- atoms to form NaSe5 square pyramids that share corners with three equivalent NaSe6 octahedra, corners with four CdSe4 tetrahedra, corners with five NaSe5 trigonal bipyramids, edges with four equivalent NaSe5 square pyramids, and edges with four CdSe4 tetrahedra. The corner-sharing octahedra tilt angles range from 40–53°. There are a spread of Na–Se bond distances ranging from 3.11–3.19 Å. In the fourth Na1+ site, Na1+ is bonded to five Se2- atoms to form distorted NaSe5 trigonal bipyramids that share corners with two equivalent NaSe6 octahedra, corners with two equivalent NaSe5 square pyramids, corners with three CdSe4 tetrahedra, corners with four equivalent NaSe5 trigonal bipyramids, an edgeedge with one NaSe6 octahedra, edges with four CdSe4 tetrahedra, and edges with four NaSe5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 33°. There are a spread of Na–Se bond distances ranging from 2.88–3.12 Å. There are three inequivalent Cd2+ sites. In the first Cd2+ site, Cd2+ is bonded to four Se2- atoms to form CdSe4 tetrahedra that share corners with two equivalent NaSe6 octahedra, corners with six CdSe4 tetrahedra, corners with four equivalent NaSe5 trigonal bipyramids, edges with three equivalent NaSe6 octahedra, and edges with two equivalent NaSe5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 13°. There are a spread of Cd–Se bond distances ranging from 2.67–2.77 Å. In the second Cd2+ site, Cd2+ is bonded to four Se2- atoms to form CdSe4 tetrahedra that share corners with two equivalent NaSe6 octahedra, corners with two equivalent NaSe5 square pyramids, corners with six CdSe4 tetrahedra, corners with two equivalent NaSe5 trigonal bipyramids, an edgeedge with one NaSe5 square pyramid, and edges with four NaSe5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 48°. There are a spread of Cd–Se bond distances ranging from 2.65–2.77 Å. In the third Cd2+ site, Cd2+ is bonded to four Se2- atoms to form CdSe4 tetrahedra that share a cornercorner with one NaSe6 octahedra, corners with two equivalent NaSe5 square pyramids, corners with six CdSe4 tetrahedra, corners with three NaSe5 trigonal bipyramids, edges with two equivalent NaSe6 octahedra, and edges with three equivalent NaSe5 square pyramids. The corner-sharing octahedral tilt angles are 9°. There are a spread of Cd–Se bond distances ranging from 2.69–2.71 Å. There are five inequivalent Se2- sites. In the first Se2- site, Se2- is bonded in a 7-coordinate geometry to five Na1+ and two equivalent Cd2+ atoms. In the second Se2- site, Se2- is bonded in a 8-coordinate geometry to six Na1+ and two Cd2+ atoms. In the third Se2- site, Se2- is bonded to three equivalent Na1+ and three Cd2+ atoms to form SeNa3Cd3 octahedra that share a cornercorner with one SeNa3Cd3 octahedra, corners with two equivalent SeNa4Cd2 pentagonal pyramids, and edges with four equivalent SeNa3Cd3 octahedra. The corner-sharing octahedral tilt angles are 70°. In the fourth Se2- site, Se2- is bonded to three Na1+ and three Cd2+ atoms to form SeNa3Cd3 octahedra that share a cornercorner with one SeNa3Cd3 octahedra, corners with four equivalent SeNa4Cd2 pentagonal pyramids, and edges with two equivalent SeNa3Cd3 octahedra. The corner-sharing octahedral tilt angles are 70°. In the fifth Se2- site, Se2- is bonded to four Na1+ and two Cd2+ atoms to form distorted SeNa4Cd2 pentagonal pyramids that share corners with six SeNa3Cd3 octahedra and edges with two equivalent SeNa4Cd2 pentagonal pyramids. The corner-sharing octahedra tilt angles range from 61–74°.
Rb2Cd3Te4 crystallizes in the monoclinic C2/c space group. The structure is three-dimensional. there are three inequivalent Rb1+ sites. In the first Rb1+ site, Rb1+ is bonded in a body-centered cubic geometry to eight Te2- atoms. There are a spread of Rb–Te bond distances ranging from 3.78–4.12 Å. In the second Rb1+ site, Rb1+ is bonded in a body-centered cubic geometry to eight Te2- atoms. There are a spread of Rb–Te bond distances ranging from 3.78–4.22 Å. In the third Rb1+ site, Rb1+ is bonded in a body-centered cubic geometry to eight Te2- atoms. There are a spread of Rb–Te bond distances ranging from 3.87–4.07 Å. There are three inequivalent Cd2+ sites. In the first Cd2+ site, Cd2+ is bonded to four Te2- atoms to form a mixture of corner and edge-sharing CdTe4 tetrahedra. There are a spread of Cd–Te bond distances ranging from 2.83–3.03 Å. In the second Cd2+ site, Cd2+ is bonded to four Te2- atoms to form a mixture of corner and edge-sharing CdTe4 tetrahedra. There are a spread of Cd–Te bond distances ranging from 2.79–3.01 Å. In the third Cd2+ site, Cd2+ is bonded to four Te2- atoms to form a mixture of corner and edge-sharing CdTe4 tetrahedra. There are a spread of Cd–Te bond distances ranging from 2.82–2.99 Å. There are five inequivalent Te2- sites. In the first Te2- site, Te2- is bonded in a 7-coordinate geometry to four Rb1+ and three Cd2+ atoms. In the second Te2- site, Te2- is bonded in a 8-coordinate geometry to four Rb1+ and four Cd2+ atoms. In the third Te2- site, Te2- is bonded in a 6-coordinate geometry to four Rb1+ and two equivalent Cd2+ atoms. In the fourth Te2- site, Te2- is bonded in a 7-coordinate geometry to four Rb1+ and three Cd2+ atoms. In the fifth Te2- site, Te2- is bonded in a 7-coordinate geometry to four Rb1+ and three Cd2+ atoms.
CdHg2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Hg is bonded in a 10-coordinate geometry to five equivalent Hg and five equivalent Cd atoms. There are one shorter (3.00 Å) and four longer (3.27 Å) Hg–Hg bond lengths. There are one shorter (2.99 Å) and four longer (3.27 Å) Hg–Cd bond lengths. Cd is bonded in a distorted q6 geometry to ten equivalent Hg atoms.
Mg3Cd is Uranium Silicide-like structured and crystallizes in the hexagonal P6_3/mmc space group. The structure is three-dimensional. Mg is bonded to eight equivalent Mg and four equivalent Cd atoms to form distorted MgMg8Cd4 cuboctahedra that share corners with four equivalent CdMg12 cuboctahedra, corners with fourteen equivalent MgMg8Cd4 cuboctahedra, edges with six equivalent CdMg12 cuboctahedra, edges with twelve equivalent MgMg8Cd4 cuboctahedra, faces with four equivalent CdMg12 cuboctahedra, and faces with sixteen equivalent MgMg8Cd4 cuboctahedra. There are a spread of Mg–Mg bond distances ranging from 3.14–3.17 Å. There are two shorter (3.14 Å) and two longer (3.16 Å) Mg–Cd bond lengths. Cd is bonded to twelve equivalent Mg atoms to form CdMg12 cuboctahedra that share corners with six equivalent CdMg12 cuboctahedra, corners with twelve equivalent MgMg8Cd4 cuboctahedra, edges with eighteen equivalent MgMg8Cd4 cuboctahedra, faces with eight equivalent CdMg12 cuboctahedra, and faces with twelve equivalent MgMg8Cd4 cuboctahedra.
SrCd is Tetraauricupride structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Sr is bonded in a body-centered cubic geometry to eight equivalent Cd atoms. All Sr–Cd bond lengths are 3.53 Å. Cd is bonded in a body-centered cubic geometry to eight equivalent Sr atoms.
Ag2MgCd is Heusler structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Mg is bonded in a body-centered cubic geometry to eight equivalent Ag atoms. All Mg–Ag bond lengths are 2.91 Å. Ag is bonded in a body-centered cubic geometry to four equivalent Mg and four equivalent Cd atoms. All Ag–Cd bond lengths are 2.91 Å. Cd is bonded in a distorted body-centered cubic geometry to eight equivalent Ag atoms.