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At least 1,639 records · Page 91

Annual Site Environmental Report (CY2019)

The primary purpose of this report is to summarize the performance of Ames Laboratory’s environmental programs, present highlights of significant environmental activities, and confirm compliance with environmental regulations and requirements for calendar year 2019. This report is a working requirement of Department of Energy Order 231.1B, Environment, Safety and Health Reporting. It includes descriptions of the Laboratory’s site, mission, the status of its compliance with applicable environmental regulations, its planning and activities to maintain compliance, and a comprehensive review of its environmental protection, surveillance and monitoring activities.

54 ENVIRONMENTAL SCIENCES↗

Materials response under hypersonic flow conditions probed by multi-modal diagnostics in a benchtop wind tunnel

In this LDRD “Materials response under hypersonic flow conditions probed by multi-modal diagnostics in a benchtop wind tunnel” a peer-reviewed lab-scale hypersonic wind tunnel (WT) was planned to be assembled in-house, along with time and space resolved and related flow and materials diagnostics to derive high quality measurements and the science that is able to inform the development of our modeling and simulation codes for the hypersonic regime. The baseline capability to achieve Mach 3 flow was scheduled to be completed in Q4 2020, in the first year of the LDRD. However due to the COVID-19 delays and travel restrictions starting in March, 2020 this task could not be completed to carry out the materials response studies in-house, or those planned with external partners that were engaged during this LDRD (NASA Langley, NASA Ames, Texas A&M university, and Virginia Tech). Still, using our hypersonic computational fluid simulation codes, many of the hypersonic components have been designed (for Mach 3, 5, and 7) and procured (or in procurement phase), and a new dedicated hypersonic laboratory was facilitized, 2 WT test sections have been manufactured, and a Mach 3 nozzle was 3D printed for prototyping. In parallel, unique materials diagnostics have been tested under static conditions and fully specified and awaiting validation in our partner facilities. Due to the new hypersonic initiative announced in January, 2020 we proposed a related scope increase in hypersonics research requiring energy interactions and new diagnostics well beyond what could be supported by an LDRD ER. A decision was made to end the current LDRD ER and formally propose a new LDRD SI that leverages the current effort, which will be starting in FY21. As a result of the uniqueness of this LDRD work, our early efforts have been encouraged and well received in the hypersonic research community, and is now part of multiple unsolicited internal and external project proposals expected to be funded in the coming years, which is encouraging to make LLNL a leader in experimentally probing extreme physics of local energetics critical to hypersonics.

36 MATERIALS SCIENCE↗

Effects of Cooling Rate on 6.5% Silicon Steel Ordering

Increasing Si content improves magnetic and electrical properties of electrical steel, with 6.5% Si as the optimum. Unfortunately, when Si content approaches 5.7%, the Fe-Si alloy becomes brittle. At 6.5%, the steel is so brittle that a conventional cold rolling process is no longer applicable. The heterogeneous formation of B2 and D03 ordered phases is responsible for the severe material embrittlement. Studies show that the formation of these ordered phases can be impeded by rapid cooling. However, due to the availability of quenching media, only the cooling rates of water and brine water were investigated. At Ames Laboratory, a comprehensive study of the effect of rapid cooling rate on the formation of the ordered phases was carried out. Melt spin method was used to prepare thick steel ribbon. A wide range of cooling rates was achieved by varying wheel speed and melt-injection rate. A calibrated high-resolution thermal camera was used to measure temperature changes during solidification. The microstructures of the obtained ribbons were characterized using X-ray diffraction and TEM. The electrical, magnetic and mechanical properties were characterized using 4-pt probe, VSM, and macro-indentation methods. The relations between these physical properties and ordered phases were established.

36 MATERIALS SCIENCE↗

Enabling 6.5% Silicon Electric Steel for Motor Application

Compared to the most widely used 3.2% Si steel, 6.5% Si steel exhibits superior magnetic and electric properties and promises an improvement to the efficiency and power density of electrical machines and transformers. However, due to the heterogeneous formation of B2 and D03 ordered phases, 6.5% Si steel is too brittle to be produced using the traditional cold roll process. And the thin sheet obtained via Si vapor deposition followed by diffusion process is difficult to stamp and assemble. At Iowa State University and Ames Laboratory, a novel process was developed to enable the cost-effective deployment of this brittle materials. The process is developed based on the observation that the deleterious ordered phases can be fully or partially suppressed by rapid cooling. The innovation lies in the production of small ductile flakes using rapid solidification and the consolidation of the obtained flakes directly into a fully dense part with near-net-shape.

36 MATERIALS SCIENCE↗

Second Report of the Nuclear Data Subcommittee of the Nuclear Science Advisory Committee

The central importance of the nuclear data curated by the US Nuclear Data Program (USNDP) for clean energy generation, national security, nonproliferation, medical applications, and space exploration as well as basic science was described in a prior report issued by the DOE/NSF Nuclear Science Advisory Committee subcommittee on Nuclear Data (NSAC-ND) in September 2022. In this report, we present a set of fourteen (14) recommendations that will enhance and advance DOE-NP's stewardship of nuclear data. The first three recommendations focus on the existing core USNDP capabilities, namely: 1) Support the nuclear structure evaluation workforce to improve the currency, consistency, and accessibility of the Evaluated Nuclear Structure Data File (ENSDF); 2) Enhance nuclear reaction evaluation within the USNDP in support of the Evaluated Nuclear Data File (ENDF) through expansion of the workforce and integration of high-performance computing, automation, and machine learning and; 3) Continue atomic mass evaluation in support AME and NUBASE databases. This is followed by eight (8) recommendations representing new cross-cutting initiatives involving both measurement and evaluation to address outstanding nuclear data needs. These new initiatives require a highly trained, diverse workforce that includes personnel with expertise from both inside and outside the nuclear physics community from which evaluators have traditionally been recruited. As such, many of these initiatives are accomplished via a Topical Nuclear Data Collaborations (TNDC). A TNDC is made up of domestic and international stakeholders, subject matter and nuclear data experts, and nuclear data evaluators and features a workforce development plan to ensure that nuclear data evaluators maintain currency in the relevant applications and are seen as equity partners in the endeavor. These include: 1) Establish a coordinated effort to improve evaluation and modeling in nuclear astrophysics for stellar dynamics, multi-messenger astronomy and nucleosynthesis; 2) Initiate a TNDC to develop and maintain nuclear structure evaluation beyond discrete states, including nuclear level densities, photon strength functions and photonuclear data for improved reaction modeling, and exploring nuclear structure at finite temperature; 3) Create a TNDC to perform correlated fission data evaluation, including cross sections, fragment yields, v(A), v(E n ) for nuclear energy, national security, nonproliferation and basic science; 4) From a panel of subject matter experts to establish and annually update a roster of key decay data to nurture its accelerated dissemination including both measurement and evaluation for targeted high-value nuclides for national security, nonproliferation and medical applications; 5) Comprehensive, consistent neutron-induced structure and reaction data for nuclear energy, national security, nonproliferation and planetary nuclear spectroscopy; 6) Charged-particle stopping powers for detector design, space effects and ion beam therapy; 7) High-energy reactions for space exploration and medical nuclide production, and; 8) The creation of an infrastructure for open data and data preservation for use by the entire nuclear physics community. All told, these initiatives require approximately $6.5M increase in NP support of the USNDP in fiscal year 2023 dollars and would require at least 3-5 years to carry out due to the length of time needed to recruit and train new nuclear data researchers. This relatively modest investment would help ensure that the fruits of the nuclear data research carried out by DOE-NP and its collaborators would be brought to bear to address some of the most important needs of our nation and the world. To ensure effective execution of this plan, we present an overview of recruitment, training, and retention goals for the USNDP, the centerpiece of which is a mutually agreed upon code of conduct. Finally, we identify the facility and instrumentation needed to perform the recommended experimental activities. This includes a short review of target fabrication capabilities, reactors, neutron beam, light- and heavy-stable ion, gamma-ray, high-energy and radioactive ion beam facilities. Lastly, a more complete appendix of experimental facilities previously compiled is included with new input provided for 6 facilities.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Mechanically Robust High Magnetic Performance Sm-Co Sintered Magnets (Final Report)

Samarium-cobalt based permanent magnets (SmCo 5 and Sm 2 Co 17 ) have excellent magnetic properties, good corrosion resistance, and long-term thermal stability. Sm-Co sintered magnets have been widely used in electric machines, telecommunication, biomedical devices, and magnetic sensors. They are the most preferred magnets for high-temperature applications (200 - 550 °C). However, Sm-Co sintered magnets are brittle. They cannot be used for applications subjected to high stress, vibration, or mechanical shock. Sm-Co sintered magnets are prone to chipping, and fracture in the course of block magnet manufacturing, part machining, assembly, and operation. The brittleness leads to a magnet production loss of up to 20-30% in volume and imposes limitations on part size and shape. Developing mechanically robust high-performance Sm-Co sintered magnets is of great scientific and technical significance. This project is in response to the current market need for mechanically robust high magnetic performance Sm-Co sintered magnets and their novel manufacturing processes. The project will focus on scaling-up, validation, and technology maturation study of the mechanically tough high magnetic performance Sm-Co magnets developed by Ames Laboratory at a lab-scale with the collaboration of the industry partner Electron Energy Corporation (EEC).

36 MATERIALS SCIENCE↗

Generation of Rare Earth Metals from Rare Earth Oxide Using Microwave Plasmas

The overarching goal of the proposed project is to develop a simple, energy-saving, high-selectivity technology for efficiently converting rare-earth oxides (REOs) to rare-earth metals (RE-metals) using microwave plasma under low temperature and inexpensive H 2 and N 2 . The project was managed and led by Dr. Maohong Fan at the University of Wyoming. The collaborating institutions include Ames Lab and Colorado School of Mines. The industrial collaboration entity is Eutectix, LLC. The use of hydrogen to reduce rare earth oxides has many advantages, as it is renewable and does not produce harmful emissions during metal production. Also, it avoids the use of carbon and the emission of CO 2 . Nd 2 O 3 treated with hydrogen plasma shows new peaks alongside those of Nd 2 O 3 . Some of these peaks are close to (28.4, 29.4, 30.5, 32.3, 36.6, 42.1, 48.9, 50.08, 55.1, 59.05, 59.64, 60.68, 62.5, 63.25), which may be related to elemental Nd.

36 MATERIALS SCIENCE↗

Perception Testing in Fog for Autonomous Flight

As the path towards Urban Air Mobility (UAM) continues to take shape, there are outstanding technical challenges to achieving safe and effective air transportation operations under this new paradigm. To inform and guide technology development for UAM, NASA is investigating the current state-of-the-art in key technology areas including traffic management, detect-and-avoid, and autonomy. In support of this effort, a new perception testbed was developed at NASA Ames Research Center to collect data from an array of sensing systems representative of those that could be found on a future UAM vehicle. This testbed, featuring a Light-Detection-and-Ranging (LIDAR) instrument, a long-wave infrared sensor, and a visible spectrum camera was deployed for a multiday test campaign in the Fog Chamber at Sandia National Laboratories (SNL), in Albuquerque, New Mexico. During the test campaign, fog conditions were created for tests with targets including a human, a resolution chart, and a small unmanned aerial vehicle (sUAV). Here, this paper describes in detail, the developed perception testbed, the experimental setup in the fog chamber, the resulting data, and presents an initial result from analysis of the data with the evaluation of methods to increase contrast through filtering techniques.

aeronautics↗

THE CHARGE STATE OF POLYCYCLIC AROMATIC HYDROCARBONS ACROSS REFLECTION NEBULAE: PAH CHARGE BALANCE AND CALIBRATION

Low-resolution Spitzer spectral map data (>1700 spectra) of ten reflection nebulae (RNe) fields are analyzed using the data and tools available through the NASA Ames PAH IR Spectroscopic Database. The PAH emission is broken down into PAH charge state using a database fitting approach. Here, the physics of the PAH emission process is taken into account and uses target appropriate parameters, e.g., a stellar radiation model for the exciting star. The breakdown results are combined with results derived using the traditional PAH band strength approach, which interprets particular PAH band strength ratios as proxies for the PAH charge state, e.g., the 6.2/11.2 μ m PAH band strength ratio. These are successfully calibrated against their database equivalent; the PAH ionized fraction ( f {sub i} ). The PAH ionized fraction is converted into the PAH ionization parameter, which relates the PAH ionized fraction to the strength of the radiation field, gas temperature and electron density. The behavior of the 12.7 μ m PAH band is evaluated as a tracer for PAH ionization and erosion. The plot of the 8.6 versus 11.2 μ m PAH band strength for the northwest photo-dominated region (PDR) in NGC 7023 is shown to be a robust diagnostic template for the PAH ionized fraction. Remarkably, most of the other RNe fall within the limits set by NGC 7023. Finally, PAH spectroscopic templates are constructed and verified as principal components. Template spectra derived from NGC 7023 and NGC 2023 compare extremely well with each other, with those derived for NGC 7023 successfully reproducing the PAH emission observed from NGC 2023.

79 ASTRONOMY AND ASTROPHYSICS↗

The PAH Emission Characteristics of the Reflection Nebula NGC 2023

We present 5–20 μ m spectral maps of the reflection nebula NGC 2023 obtained with the Infrared Spectrograph SL and SH modes on board the Spitzer Space Telescope, which reveal emission from polycyclic aromatic hydrocarbons (PAHs), C{sub 60}, and H{sub 2} superposed on a dust continuum. We show that several PAH emission bands correlate with each other and exhibit distinct spatial distributions that reveal a spatial sequence with distance from the illuminating star. We explore the distinct morphology of the 6.2, 7.7, and 8.6 μ m PAH bands and find that at least two spatially distinct components contribute to the 7–9 μ m PAH emission in NGC 2023. We report that the PAH features behave independently of the underlying plateaus. We present spectra of compact, oval PAHs ranging in size from C{sub 66} to C{sub 210}, determined computationally using density functional theory, and we investigate trends in the band positions and relative intensities as a function of PAH size, charge, and geometry. Based on the NASA Ames PAH database, we discuss the 7–9 μ m components in terms of band assignments and relative intensities. We assign the plateau emission to very small grains with possible contributions from PAH clusters and identify components in the 7–9 μ m emission that likely originate in these structures. Based on the assignments and the observed spatial sequence, we discuss the photochemical evolution of the interstellar PAH family as the PAHs are more and more exposed to the radiation field of the central star in the evaporative flows associated with the Photo-Dissociation Regions in NGC 2023.

79 ASTRONOMY AND ASTROPHYSICS↗

The imprint of surface fluxes and transport on variations in total column carbon dioxide

New observations of the vertically integrated CO{sub 2} mixing ratio, <CO{sub 2}>, from ground-based remote sensing show that variations in <CO{sub 2}> are primarily determined by large-scale flux patterns. They therefore provide fundamentally different information than observations made within the boundary layer, which reflect the combined influence of large-scale and local fluxes. Observations of both <CO{sub 2}> and CO{sub 2} concentrations in the free troposphere show that large-scale spatial gradients induce synoptic-scale temporal variations in <CO{sub 2}> in the Northern Hemisphere midlatitudes through horizontal advection. Rather than obscure the signature of surface fluxes on atmospheric CO{sub 2}, these synoptic-scale variations provide useful information that can be used to reveal the meridional flux distribution. We estimate the meridional gradient in <CO{sub 2}> from covariations in <CO{sub 2}> and potential temperature, {theta}, a dynamical tracer, on synoptic timescales to evaluate surface flux estimates commonly used in carbon cycle models. We find that simulations using Carnegie Ames Stanford Approach (CASA) biospheric fluxes underestimate both the <CO{sub 2}> seasonal cycle amplitude throughout the Northern Hemisphere midlatitudes and the meridional gradient during the growing season. Simulations using CASA net ecosystem exchange (NEE) with increased and phase-shifted boreal fluxes better fit the observations. Our simulations suggest that climatological mean CASA fluxes underestimate boreal growing season NEE (between 45-65{sup o} N) by {approx}40%. We describe the implications for this large seasonal exchange on inference of the net Northern Hemisphere terrestrial carbon sink.

54 ENVIRONMENTAL SCIENCES↗

Convective and radiative heat transfer during reentry and advanced techniques for their simulation

The use of shock tubes, ballistic ranges, and combinations thereof in simulation of convective and radiative heat loads has been described. The complementary nature and the highly independent techniques used in these facilities lend great strength to the research results where they agree. The shortcomings of these facilities are such that, if possible, both should be applied to important problems. When all-out performance is required, the combination of the two can clearly provide advantages. That these advantages are becoming more widely recognized is demonstrated by the construction of new faculties at Arnold Engineering Development Center and Boeing Company, Seattle, similar to those in service at Ames Research Center since the late 1950's.

Radiative Heat Transfer↗

The Importance of Space Radiation Shielding Weight

The shielding weights required to protect astronauts against space radiation should be considered in relation to the weights of the meteoroid shielding and the life support systems. Comparisons have been carried out for a variety of crew sizes and mission durations. The radiation shield weights were based upon a 1percent probability and were obtained from Webber's data on solar proton events. A mission dose of 100 rad was used as the allowed limit. The doses allowed from solar events were reduced by 45 mrad/day due to galactic radiation and by the amount of radiation expected for two high thrust trips through the earth's trapped radiation belts. In the calculation of the shield weights, the "storm cellar" concept was employed, allotting 50 ft a per man. The meteoroid shield weights were based upon the work of Bjork and the NASA-Ames Research Center criterion. The single shield thicknesses calculated were modified to take into account the reduced penetration where two facing sheets with space between them are used as the meteoroid shield. A percent probability of penetration was assumed in the calculations. The weights of the life support system are dependent upon the assumptions made regarding the particular subsystems to use for a specific mission. Two systems were used for this comparison. The system selected for the 30-day mission provides for body waste storage rather than reprocessing. Each system assumes a cabin leakage rate of 10 Ibs/day and a power penalty weight of 320 lbs/kWe.

SPACE RADIATION↗

Comparison of Experimental and Theoretical Zero-Lift Wave-Drag Results for Various Wing-Body-Tail Combinations at Mach Numbers up to 1.9

Comparisons are made of experimental and theoretical zero-lift wave drag for several nose shapes, wing-body combinations, and models of current airplanes at Mach numbers up to 1.0. The experimental data were obtained from tests in the Ames 6- by6-foot supersonic wind tunnel and at the NACA Wallops Island facility. The theoretical drag was found by use of linear theory utilizing model area distributions. The agreement between theoretical and experimental zero-lift wave-drag coefficients was generally very good, especially for a fuselage or for fuselage-wing combinations that were vertically symmetrical. For other models that had rapid changes in body shape and/or were not vertically symmetrical, the agreement of theory with experiment ranged from fair to poor, depending on the severity of the change in shape.

DRAG COEFFICIENT↗

Prospects for manned Mars missions

Studies called "EMPIRE" (standing for Early Manned Planetary-Interplanetary Roundtrip Expeditions) were initiated early in 1962 by the Future Projects Office for the Marshall Space Flight Center. These and related studies by other NASA centers were intended to bring to light the technical problems associated with such missions. The emphasis of these studies was on single and multiple planetary fty-bys, with some consideration given to planetary orbital and landing missions. The time period considered was the early 1970's. The contractors were Aeronutronic Division (Philco-Ford Motor Company), Lockheed Missiles and Space Company and General Dynamics/Astronautics. Studies relating to the time period 1975-85 were initiated in early 1963, by contracts with General Dynamics/ Fort Worth and Douglas Aircraft Company. Follow-on EMPIRE studies were carried out by Lockheed and General Dynamics/Astronautics. In addition, studies were made of a Mars Excursion Module by Aeronutronic, a Mars Mission Module (MMM) by North American Aviation's Space and Information Division, and an Earth Return Module (ERM) by Lockheed under the direction of the Manned Spacecraft Center. Complementary to these efforts were studies initiated by the Ames Research Center early in 1963 for a Manned Mars Landing and Return Mission. These studies were conducted by North American Aviation and by the TRW Space Technology Laboratories.

MARS /PLANET/↗