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At least 1,621 records · Page 90

A Synthesis of Light Absorption Properties of the Arctic Ocean: Application to Semi-analytical Estimates of Dissolved Organic Carbon Concentrations from Space

The light absorption coefficients of particulate and dissolved materials are the main factors determining the light propagation of the visible part of the spectrum and are, thus, important for developing ocean color algorithms. While these absorption properties have recently been documented by a few studies for the Arctic Ocean [e.g., Matsuoka et al., 2007, 2011; Ben Mustapha et al., 2012], the datasets used in the literature were sparse and individually insufficient to draw a general view of the basin-wide spatial and temporal variations in absorption. To achieve such a task, we built a large absorption database at the pan-Arctic scale by pooling the majority of published datasets and merging new datasets. Our results showed that the total non-water absorption coefficients measured in the Eastern Arctic Ocean (EAO; Siberian side) are significantly higher 74 than in the Western Arctic Ocean (WAO; North American side). This higher absorption is explained 75 by higher concentration of colored dissolved organic matter (CDOM) in watersheds on the Siberian 76 side, which contains a large amount of dissolved organic carbon (DOC) compared to waters off 77 North America. In contrast, the relationship between the phytoplankton absorption (a()) and chlorophyll a (chl a) concentration in the EAO was not significantly different from that in the WAO. Because our semi-analytical CDOM absorption algorithm is based on chl a-specific a() values [Matsuoka et al., 2013], this result indirectly suggests that CDOM absorption can be appropriately erived not only for the WAO but also for the EAO using ocean color data. Derived CDOM absorption values were reasonable compared to in situ measurements. By combining this algorithm with empirical DOC versus CDOM relationships, a semi-analytical algorithm for estimating DOC concentrations for coastal waters at the Pan-Arctic scale is presented and applied to satellite ocean color data.

Pan-Arctic↗

Assessing Uncertainties of a Geophysical Approach to Estimate Surface Fine Particulate Matter Distributions from Satellite-Observed Aerosol Optical Depth

Health impact analyses are increasingly tapping the broad spatial coverage of satellite aerosol optical depth (AOD) products to estimate human exposure to fine particulate matter (PM2.5). We use a forward geophysical approach to derive ground-level PM2.5 distributions from satellite AOD at 1 km2(exp) resolution for 2011 over the northeastern US by applying relationships between surface PM2.5 and column AOD (calculated offline from speciated mass distributions) from a regional air quality model (CMAQ; 12×12 km2(exp) horizontal resolution). Seasonal average satellite-derived PM2.5 reveals more spatial detail and best captures observed surface PM2.5 levels during summer. At the daily scale, however, satellite-derived PM2.5 is not only subject to measurement uncertainties from satellite instruments, but more importantly to uncertainties in the relationship between surface PM2.5 and column AOD. Using 11 ground-based AOD measurements within 10 km of surface PM2.5 monitors, we show that uncertainties in modeled PM2.5∕AOD can explain more than 70 % of the spatial and temporal variance in the total uncertainty in daily satellite-derived PM2.5 evaluated at PM2.5 monitors. This finding implies that a successful geophysical approach to deriving daily PM2.5 from satellite AOD requires model skill at capturing day-to-day variations in PM2.5∕AOD relationships. Overall, we estimate that uncertainties in the modeled PM2.5∕AOD lead to an error of 11 µg m−3(exp) in daily satellite-derived PM2.5, and uncertainties in satellite AOD lead to an error of 8 µg m−3(exp). Using multi-platform ground, airborne, and radiosonde measurements, we show that uncertainties of modeled PM2.5∕AOD are mainly driven by model uncertainties in aerosol column mass and speciation, while model representation of relative humidity and aerosol vertical profile shape contributes some systematic biases. The parameterization of aerosol optical properties, which determines the mass extinction efficiency, also contributes to random uncertainty, with the size distribution being the largest source of uncertainty and hygroscopicity of inorganic salt the second largest. Future efforts to reduce uncertainty in geophysical approaches to derive surface PM2.5 from satellite AOD would thus benefit from improving model representation of aerosol vertical distribution and aerosol optical properties, to narrow uncertainty in satellite-derived PM2.5.

aerosol optical depth↗

Electromagnetic Shower Reconstruction and Identification in FASER's Emulsion Detector for LHC Forward Neutrino Measurements

We present methods for electromagnetic shower reconstruction and identification in the FASERnu emulsion detector using 100 GeV and 200 GeV electron test-beam data from the CERN SPS H4 beamline. The reconstruction employs a clustering-based algorithm without energy-dependent tuning to determine shower axes. A multi-level identification chain comprising track pre-selection, a cut-based selection, and a BDT classifier achieves combined background rejection rates of 99.99% (100 GeV) and 99.94% (200 GeV). The method reaches total reconstruction and identification efficiencies of 58.9% (100 GeV) and 70.8% (200 GeV) evaluated from simulated samples. Energy reconstruction using the total number of reconstructed segments as the calorimetric estimator yields relative biases of +0.6% (100 GeV) and -0.8% (200 GeV), with resolutions of 25.4% and 22.6%, respectively. Systematic uncertainties on the energy reconstruction are dominated by variations in emulsion film detection efficiency, contributing (+10.9%/-8.2%) at 100 GeV and (+10.3%/-6.9%) at 200 GeV. The methodology provides a validated framework for electron neutrino identification with the FASERnu detector at the LHC.

Mammen Abraham, Roshan [UC, Irvine]↗

Cosmological variation of G and the solar luminosity

Teller's analysis of the effects of a varying gravitational constant G on the past solar luminosity is reexamined. It is shown that if Newtonian gravitation is viewed as a nonrelativistic limit of Einstein's theory, there exists (1) a constraint between G and the total mass M of the sun and (2) a change in the radiative energy density-temperature relation, which were not included in Teller's analysis and which change his result from L is about G to the 7th power (found to be unacceptable) to L is about constant, independently of how G might vary with time.

Canuto, V.↗

In Situ ATR-FTIR Study of the Cathode–Electrolyte Interphase: Electrolyte Solution Structure, Transition Metal Redox, and Surface Layer Evolution

We present a study of the lithium nickel manganese cobalt oxide (LiNi 0.6 Mn 0.2 Co 0.2 O 2 , NMC622) cathode-electrolyte interphase (CEI) during galvanostatic charging and discharging using in situ attenuated total reflectance Fourier transform infrared (ATR-FTIR) methods to investigate the voltage dependent electrolyte solution structure changes at the interface, transition metal (TM) redox chemistry, and cathode/electrolyte interfacial layer evolution. Furthermore, our in situ cell design provides both reliable electrochemical device testing and strong FTIR vibrational absorption signals near the cathode surface. Specifically, advanced spectral analysis elucidates changes of near-surface Li+ ion (de)solvation by solvent molecules during galvanostatic cycling. Moreover, cathode metal-oxygen vibrational absorptions, sensitive to TM redox behaviors and subsequent local structural variations, were correlated to cathode de-lithiation (and lithiation) and electrolyte solution structure changes. In addition, we have detected the formation and evolution of a CEI surface layer on the NMC622 cathode that contributes to the cell's capacity fade.

25 ENERGY STORAGE↗

On the sources of interplanetary shocks at 0.72 AU

In order to understand the solar cycle variation of interplanetary shocks and their driving source at 0.72 AU, a survey of Pioneer Venus Orbiter (PVO) magnetometer and plasma data from 1979-1988 has been conducted. Known shock drivers at 1.0 AU include coronal mass ejections (CMEs) and fast/slow stream interactions. In our analysis, CMEs were identified by a decrease in plasma temperature to background or below accompanied by an increase in plasma density and dynamic pressure. It was also required that the magnetic field exhibit a coherent rotation over about a day and an increase and decline in magnitude on a timescale of hours to days. Stream interactions were identified by a characteristic increase in ion temperature and velocity coincident with a decrease in density and a coincident increase in the total magnetic field magnitude. These signatures were usually preceded within 24 hours by a change in flow angle. In all, 45 shocks were identified: 36 driven by CMEs, 6 resulting from fast/slow stream interactions, and 3 with sources that could not be defined. The shocks driven by CMEs show a solar cycle variation that roughly follows the sunspot number. These shocks all have normals consistent with radial propagation of the shock fronts from the sun. In contrast, the few stream interaction related shocks show a tendency to occur later in the solar cycle and have a broader distribution of shock normals.

Lindsay, G. M.↗

Scalar Breit interaction for molecular calculations

Variational treatment of the Dirac–Coulomb–Gaunt or Dirac–Coulomb–Breit two-electron interaction at the Dirac–Hartree–Fock level is the starting point of high-accuracy four-component calculations of atomic and molecular systems. In this work, we introduce, for the first time, the scalar Hamiltonians derived from the Dirac–Coulomb–Gaunt and Dirac–Coulomb–Breit operators based on spin separation in the Pauli quaternion basis. While the widely used spin-free Dirac–Coulomb Hamiltonian includes only the direct Coulomb and exchange terms that resemble nonrelativistic two-electron interactions, the scalar Gaunt operator adds a scalar spin–spin term. The spin separation of the gauge operator gives rise to an additional scalar orbit-orbit interaction in the scalar Breit Hamiltonian. Benchmark calculations of Au n (n = 2–8) show that the scalar Dirac–Coulomb–Breit Hamiltonian can capture 99.99% of the total energy with only 10% of the computational cost when real-valued arithmetic is used, compared to the full Dirac–Coulomb–Breit Hamiltonian. In conclusion, the scalar relativistic formulation developed in this work lays the theoretical foundation for the development of high-accuracy, low-cost correlated variational relativistic many-body theory.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Sensitivity of the simulation of passive neutron emission from UF 6 cylinders to the uncertainties in both 19 F(α,n) energy spectrum and thick target yield of 234 U in UF 6

Interest in safeguards verification measurements using passive thermal neutron counting to assay 235 U content in large 30B UF 6 canisters has grown in recent years. Here, the prohibitively high cost and impracticality of using reference 30B calibration cylinders extensively will likely make accurate simulations of increasing interest. Accuracy of the simulated response will define the confidence in the predicted response and the extent to which simulations can reasonably be relied upon. With 234 U driven 19 F(α, n) reactions being the main neutron source in low enriched UF 6 the uncertainties of the 19 F(α, n) energy spectrum and the thick target yield of 234 U in UF 6 propagate into the uncertainty in the predicted response and represent a major influence of basic nuclear data. Here sensitivity of the simulated total (Singles) and coincidence (Doubles) count rates are assessed for the Passive Neutron Enrichment Meter using six potential 19 F(α, n) neutron energy spectra over a range of enrichments and material distributions. The results indicate that variations in the Singles and Doubles due to simulated (α, n) neutron spectrum are less than 1.5% for this set of simulated neutron spectra, with dependence varying inversely with enrichment. Singles uncertainty is only slightly less than that of the thick target 19 F(α, n) yield corresponding to the primary neutron source, whereas the 19 F(α, n) yield dependence of the Doubles is reduced by the non-negligible 238 U(SF) coincident neutron emissions. Based on available thick target 19 F(α, n) yield estimates the uncertainty is on the order of 5%, establishing this as the main nuclear data limitation when simulating thermal neutron detectors response for 30B UF 6 storage cylinders. Based on these findings, it appears that the measurement and evaluation of the thick target 19 F(α, n) yield for uranium hexafluoride is due.

19F(α,n) neutron spectrum↗

Ramjet cost estimating handbook

The subject program was conducted for the purpose of generating cost information on ramjet engines and developing a methodology that could be employed to accurately predict production costs ramjet engines. The methodology addresses many different ramjet types, sizes and production quantities. The methodology determines the cost of individual modules of ramjet assemblies based on similarity of the modules to baseline components that are identified in a cost handbook. (There are typically around 20 basic components of a given ramjet to be costed.) The total cost of the engine is a summation of all the appropriate cost elements. A significant accomplishment of the program was the development of a large cost data base on many different configurations, materials of construction and variations in manufacturing processes. This data base should provide a good foundation on which to build other cost data as it becomes available.

Emmons, H. T.↗

Solar variability and terrestrial weather

The present review article indicates that the past four years have been very active in the field of sun-weather research in the U.S. Some quite specific questions which have arisen from recent research include the time variation of the VAL vs SB effect; the nature of the clear-air electric field; the relationship of the ionospheric potential to thunderstorm formation; and the constancy of the solar 'constant' both in terms of the total luminosity on the climatic time scale and for near UV radiation on the time scale of days to 11 years.

Scherrer, P. H.↗

The generation mechanism for magnetosheath lion roars

The origin of lion roars, intense electromagnetic whistler-mode waves which occur throughout the magnetosheath, is investigated based on particle and field data obtained on the ISEE satellites. Analysis of the measured magnetic fields, plasma densities and plasma wave intensities during periods of lion roar emission reveals the lion roar bursts to be correlated with decreases in magnetic field intensity, while the plasma density exhibits a strong anticorrelation with the magnetic field variability during the bursts and the total plasma pressure remains essentially constant. Results indicate that the waves can originate by the cyclotron resonant instability with anisotropic magnetosheath electrons whenever the magnetic energy per particle falls to values comparable with the electron thermal energy. Variations in the magnetic energy appear to be associated with the hydromagnetic mirror instability which in turn is excited by a pressure anisotropy in the magnetosheath ion population.

Thorne, R. M.↗

Ionospheric Absorption on 1539 Khz in Relation to Solar Ionizing Radiation

Radio wave absorption data on 1539 kHz for the summer period of 1978 to 1980 are considered in relation to variations of solar X-ray and L-alpha radiation. It is shown that under non-flare conditions L-alpha dominates in controlling absorption and that X-rays contribute about 10% to the total absorption. Optimum regression equations show that absorption is proportional to the m-th power of ionizing flux where m 1. The role of correcting L-alpha values, measured by the AE-E satellite, is discussed.

Boska, J.↗

Fine guidance sensor design optimization for Space Infrared Telescope Facility (SIRTF)

The present paper is concerned with the general issues of design optimization of a staring mosaic sensor for guide-star tracking, taking into account the choice of the proper interpolation algorithm. It was found that the final choice of algorithm depends on the severity of the positional accuracy requirement and the expected variation in the blur spot shape. The considered track algorithms estimate the position either of the peak or of the centroid of the image of a point source. Attention is given to aspects of problem definition, the total effect of error sources on algorithm accuracy, a parametric analysis of performance behavior, Monte Carlo results, and the design of the SIRTF Fine Guidance Sensor (FGS). The algorithm error, the signal-to-noise error, and the nonuniformity error are examined.

Grossman, S. B.↗

Effect of element size on the solution accuracies of finite-element heat transfer and thermal stress analyses of space shuttle orbiter

The effect of element size on the solution accuracies of finite-element heat transfer and thermal stress analyses of space shuttle orbiter was investigated. Several structural performance and resizing (SPAR) thermal models and NASA structural analysis (NASTRAN) structural models were set up for the orbiter wing midspan bay 3. The thermal model was found to be the one that determines the limit of finite-element fineness because of the limitation of computational core space required for the radiation view factor calculations. The thermal stresses were found to be extremely sensitive to a slight variation of structural temperature distributions. The minimum degree of element fineness required for the thermal model to yield reasonably accurate solutions was established. The radiation view factor computation time was found to be insignificant compared with the total computer time required for the SPAR transient heat transfer analysis.

Ko, William L.↗

Fracture surfaces of irradiated composites

Electron microscopy was used to analyze the fracture surfaces of T300/934 graphite/epoxy unidirectional off-axis tensile coupons which were subjected to 1.0-MeV electron radiation at a rate of 50 Mrad/h for a total dose of 10 Grad. Fracture surfaces from irradiated and nonirradiated specimens tested at 116 K, room temperature, and 394 K were analyzed to assess the influence of radiation and temperature on the mode of failure and variations in constituent material as a function of environmental exposure. Micrographs of fracture surfaces indicate that irradiated specimens are more brittle than nonirradiated specimens at low temperatures. However, at elevated temperatures the irradiated specimens exhibit significantly more plasticity than nonirradiated specimens.

Milkovich, Scott M.↗

Investigation of X24C-2 10-Stage Axial-Flow Compressor. III - Surge Characteristics

Compressor operation at low air flows for a given speed is limited by unstable flow conditions, commonly called surge. An investigation of surge in centrifugal compressors (reference 1) showed that the pulsation of pressures and velocities occurred when the slope of the compressor characteristic curve was positive and that the magnitude and frequency, as well as the incidence of surge, depended on the capacity and resistance of the total system. Although the theory presented in reference 1 is applicable to axial-floe compressors, little experimental information is available on the surge characteristics of the individual stages of axial-flow compressors, or on the variation of the surge characteristics with operating conditions. During the investigation to determine the performance of the X24C-2 compressor (references 2 and 3), instrumentation was added to study the surge characteristics and to determine the effect of speed and inlet pressure on the frequency, amplitude, and phase relation of the pressure pulsations behind each stage.

Buckner, Howard A., Jr.↗

Ionospheric Response to the Total Solar Eclipse of 22 July 2009 as Deduced from VLBI and GPS Data

A total solar eclipse occurred over China at latitudes of about 30 N on the morning of 22 July 2009, providing a unique opportunity to investigate the influence of the sun on the earth's upper ionosphere. GPS observations from Shanghai GPS Local Network and VLBI observations from stations Shanghai, Urumqi, and Kashima were used to observe the response of TEC to the total solar eclipse. From the GPS data reduction, the sudden decrease of TEC at the time of the eclipse, amounting to 2.8 TECU, and gradual increase of TEC after the eclipse were found by analyzing the diurnal variations. More distinctly, the variations of TEC were studied along individual satellite passes. The delay in reaching the minimum level of TEC with the maximum phase of eclipse was 5-10 min. Besides, we also compared the ionospheric activity derived from different VLBI stations with the GPS results and found a strong correlation between them.

Guo, L.↗

Further Examination of a Simplified Model for Positronium-Helium Scattering

While carrying out investigations on Ps-He scattering we realized that it would be possible to improve the results of a previous work on zero-energy scattering of ortho-positronium by helium atoms. The previous work used a model to account for exchange and also attempted to include the effect of short-range Coulomb interactions in the close-coupling approximation. The 3 terms that were then included did not produce a well-converged result but served to give some justification to the model. Now we improve the calculation by using a simple variational wave function, and derive a much better value of the scattering length. The new result is compared with other computed values, and when an approximate correction due to the van der Waals potential is included the total is consistent with an earlier conjecture.

DiRienzi, J.↗