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At least 1,621 records · Page 90

Stochastic simulation of occupant-driven energy use in a bottom-up residential building stock model

The residential buildings sector is one of the largest electricity consumers worldwide and contributes disproportionally to peak electricity demand in many regions. Strongly driven by occupant activities, household energy consumption is stochastic and heterogeneous in nature. However, most residential energy models applied by industry use homogeneous, deterministic activity schedules, which work well for predictions of annual energy consumption, but can result in unrealistic hourly or sub-hourly electric load profiles, with exaggerated or muted peaks. The increasing proportion of variable renewable energy generators means that representing the heterogeneity and stochasticity of occupant behavior is now crucial for reliable planning at both bulk-power and distribution-system scales. This work presents a novel and open-source occupancy simulation approach that can simulate a diverse set of individual occupant and household event schedules for all major electricity, fuel, and hot water end uses. To accomplish this, we evaluated three alternative occupant activity simulation approaches before selecting a hybrid combining time-inhomogeneous Markov chains and probability-sampling of event durations and magnitudes. Further, we integrated the stochastic occupancy simulation with an open-source bottom-up physics-simulation building stock model and published a set of 550,000 diverse household end-use activity schedules representing a national housing stock. The simulator was verified against time-use survey data, and simulation results were validated against measured end-use electricity data for accuracy and reliability. While we use data for the United States, our application demonstrates how similar approaches could be applied using the time-use survey data collected in many countries around the world.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Electrocatalytic Hydrogenation of Biomass-Derived Organics: A review

Sustainable energy generation calls for a shift away from centralized, high-temperature, energy-intensive processes to decentralized, low-temperature conversions that can be powered by electricity produced from renewable sources. Electrocatalytic conversion of biomass-derived feedstocks would allow carbon recycling of distributed, energy-poor resources in the absence of sinks and sources of high-grade heat. Selective, efficient electrocatalysts that operate at low temperatures are needed for electrocatalytic hydrogenation (ECH) to upgrade the feedstocks. For effective generation of energy-dense chemicals and fuels, two design criteria must be met: (i) a high H:C ratio via ECH to allow for high-quality fuels and blends, and (ii) a lower O:C ratio in the target molecules via electrochemical decarboxylation/deoxygenation to improve the stability of fuels and chemicals. The goal of this review is to determine whether the following questions have been sufficiently answered in open literature, and if not, what additional information is required: (1) What organic functionalities are accessible for electrocatalytic hydrogenation under a set of reaction conditions? How do substitutions and functionalities impact the activity and selectivity of ECH? (2) What material properties cause an electrocatalyst to be active for ECH? Can general trends in ECH be formulated based on the type of electrocatalyst? (3) What is the impact of reaction (electrolyte concentration, pH, operating potential) and reactor type conditions?

Catalysts, redox reactions, hydrocarbons, Aromatic↗

Strong and recyclable bio-derived poly(ester amide) hot-melt adhesive

Bio-based adhesives offer inherent advantages over conventional petrochemical-derived systems, including renewable sourcing, reduced environmental impact and potential degradability. However, most bio-based adhesives suffer from poor adhesion strength, limited substrate compatibility and a lack of chemical recyclability. Here, in this work, we present a bio-derived multiblock poly(ester amide) adhesive that leverages microphase segregation between different segments to reconcile mechanical robustness with strong interfacial bonding. Notably, this multiblock architecture is accessed through a one-pot, selective acceptorless dehydrogenative polymerization, obviating the need for multistep synthesis. The materials exhibit excellent adhesion across a range of substrates including metals, glass and wet wood surpassing commercial benchmarks, while also demonstrating thermal stability, tunable mechanical properties and closed-loop chemical recyclability even in the presence of other commodity plastics. Furthermore, the adhesive strength of these materials could be tuned for various potential applications through control over the chemical composition of the polymer. By integrating renewable feedstocks, high-performance functionality and efficient chemical circularity within a single platform, this work provides a viable pathway toward more sustainable adhesive technologies and contributes to advancing circular materials manufacturing.

09 BIOMASS FUELS↗

Cryo-EM structure of a photosystem I variant containing an unusual plastoquinone derivative in its electron transfer chain

Photosystem I (PS I) is a light-driven oxidoreductase responsible for converting photons into chemical bond energy. Its application for renewable energy was revolutionized by the creation of the MenB deletion (ΔmenB) variant in the cyanobacterium Synechocystis sp. PCC 6803, in which phylloquinone is replaced by plastoquinone-9 with a low binding affinity. This permits its exchange with exogenous quinones covalently coupled to dihydrogen catalysts that bind with high affinity, thereby converting PS I into a stable solar fuel catalyst. Here, we reveal the 2.03-Å-resolution cryo-EM structure of a recent MenB variant of PS I. The quinones and their binding environment are analyzed in the context of previous biophysical data, thereby enabling a protocol to solve future PS I hybrids and constructs from this genetically tractable cyanobacterium.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Engineering Clostridium thermocellum for production of 2,3-butanediol from cellulose

Clostridium thermocellum is a promising host for consolidated bioprocessing due to its ability to directly ferment cellulose into fuels and chemicals. However, natural product formation in this organism is limited. Here, we report engineering C. thermocellum for the production of 2,3-butanediol (23BD), a valuable industrial chemical. We functionally expressed a thermophilic 23BD pathway in this organism resulting in a 23BD titer of 19.7 mM from cellulose, representing a metabolic yield of 24%. We used a cell-free systems biology approach to identify limiting steps in the 23BD pathway, revealing that exogenous 23BD dehydrogenase (BDH) activity was essential for production, while native acetolactate synthase (ALS) and acetolactate decarboxylase (ALDC) activities were present but limiting in the parent strain. This approach also revealed redox balance limitations. We demonstrated that this improved understanding of redox balance limitations could be used to increase 23BD titer in vivo, showing that adding acetate could be used to increase 23BD yield. This work establishes a foundation for developing C. thermocellum into a robust platform for 23BD production directly from cellulose and highlights the utility of cell-free systems for guiding metabolic engineering in non-model organisms.

09 BIOMASS FUELS↗

Quantifying Phospholipids in Organic Samples Using a Hydrophilic Interaction Liquid Chromatography–Inductively Coupled Plasma High-Resolution Mass Spectrometry (HILIC-ICP-HRMS) Method

Here, in this study, a novel method using hydrophilic interaction liquid chromatography (HILIC) coupled with inductively coupled plasma high-resolution mass spectrometry (ICP-HRMS) was introduced for the quantification of phospholipids in oil samples. The method employed a bridged ethyl hybrid (BEH) stationary phase HILIC column with a tetrahydrofuran (THF)/water mobile phase, enhancing the solubility and detection of phospholipids. During the study, a gradient/matrix effect on ICP-HRMS sensitivity was observed and successfully compensated for experimentally, ensuring reliable quantification results. This approach has proven effective for a wide range of different oil samples including vegetable oils, animal fats, and phospholipid supplements. Notably, this method allowed the direct quantification of phospholipids in oil samples, bypassing the need for prior sample preparation methods, such as solid phase extraction (SPE), thereby streamlining the analytical process. The precision, accuracy, and reduced need for extensive sample preparation offered by this method mark a significant advancement in lipids analysis. Its robustness and broad applicability have substantial implications for industries such as food and renewable energy production, where both efficient and accurate lipid identification and quantification are crucial.

09 BIOMASS FUELS↗

Tailoring renewable materials via plant biotechnology

Plants inherently display a rich diversity in cell wall chemistry, as they synthesize an array of polysaccharides along with lignin, a polyphenolic that can vary dramatically in subunit composition and interunit linkage complexity. These same cell wall chemical constituents play essential roles in our society, having been isolated by a variety of evolving industrial processes and employed in the production of an array of commodity products to which humans are reliant. However, these polymers are inherently synthesized and intricately packaged into complex structures that facilitate plant survival and adaptation to local biogeoclimatic regions and stresses, not for ease of deconstruction and commercial product development. Herein, we describe evolving techniques and strategies for altering the metabolic pathways related to plant cell wall biosynthesis, and highlight the resulting impact on chemistry, architecture, and polymer interactions. Furthermore, this review illustrates how these unique targeted cell wall modifications could significantly extend the number, diversity, and value of products generated in existing and emerging biorefineries. These modifications can further target the ability for processing of engineered wood into advanced high performance materials. In doing so, we attempt to illuminate the complex connection on how polymer chemistry and structure can be tailored to advance renewable material applications, using all the chemical constituents of plant-derived biopolymers, including pectins, hemicelluloses, cellulose, and lignins.

09 BIOMASS FUELS↗

Fractionation of Lignocellulosic Biomass into High-Value Products - CRADA Report

Idaho National Laboratory (INL) has developed a process for adding value in the biomass feedstock supply chain. The key aspects of this process include: (1) anaerobic and chemical treatment of biomass during storage, (2) fractionation of biomass into conversion-ready feedstock and high-value coproducts, and (3) high-moisture pelleting to increase the bulk density and stabilize the feedstock. The purpose of the chemical treatment is to overcome the recalcitrant nature of the feedstock to improve the biochemical conversion process of breaking down the biomass into sugars. To maximize the utilization of the biomass, the feedstock can be fractionated into hemicellulose and lignin rich fractions. Finally, to increase the materials overall energy density, produce a shelf-stable material, and to facilitate transport, the feedstock is densified in a pelleting process. The first two steps of the processes have been verified at bench scale showing an improvement in theoretical glucose yield from 23.1% to 44.5% and an improvement in theoretical xylose yield from 8.9% to 23.1% from ground corn stover. It is hypothesized that densification will further increase the carbohydrate yield in the sample. The goal of this project was to evaluate the technical feasibility and process economics of the above process and to provide preliminary data to Golden Leaf Energy, Inc to access its potential commercialization for converting biomass to ethanol and renewable chemicals. Corn stover (CS), the largest available agricultural residue, and Chinese tallow (CT), an invasive wood species with no current commercial value, were chosen as feedstocks for this project.

09 BIOMASS FUELS↗

ACS Spotlight: Bipolar Membranes for Electrochemical Energy Conversion, Chemical Manufacturing, and Separations

Sustainable energy conversion, chemical manufacturing, and separations are central to addressing the world’s energy and environmental challenges. Electrochemical platforms stand as a cornerstone in addressing these challenges because they are low exergy and can be powered on renewable electrons. In electrochemical systems, bipolar membranes (BPMs) are emerging as a unique class of ion exchange membranes poised to revolutionize various electrochemical processes via pH control of anode and cathode chambers and in situ pH adjustment. In this Spotlight Review, we provide a comprehensive review of electrochemical platforms utilizing BPMs for energy conversion (water electrolyzers for hydrogen production, fuel cells, and flow batteries), chemical manufacturing (electrolyzers that convert carbon dioxide into value-added chemicals and nitrate into ammonia), and separations. The motivation for using BPMs, as well as their performance and durability, in electrochemical platforms are disseminated. We also discuss current challenges that impede BPM electrochemical systems from competing with state-of-the-art electrochemical systems using monopolar ion-exchange membranes (e.g., anion/hydroxide exchange membranes and cation/proton exchange membranes). Here, the review also covers molecular modeling and continuum modeling efforts to understand the basic mechanisms that govern BPM performance.

30 DIRECT ENERGY CONVERSION↗

BSM (Bioenergy Scenario Model) 2023 FKA: Biomass Scenario Model [SWR-09-09]

The U.S. Department of Energy's (DOE's) Bioenergy Technologies Office and the National Renewable Energy Laboratory (NREL) developed the BSM (Bioenergy Scenario model) to explore the development of a U.S. biofuels industry. The BSM is a system dynamics model built on the STELLA software platform. The model represents the dynamic interactions of the major sectors of the biofuels industry—feedstock production, feedstock logistics, biomass to biofuels conversion, and biofuels end use, including fuels inventory, dispensing, distribution, fuel use, and the vehicle fleet. The BSM represents contextual aspects of the developing biofuels industry, including investment in new biomass to biofuel conversion technologies, competition from petroleum fuels, vehicle demand for biofuels, and various government policies, using all of these to simulate the development of the industry. The purpose of the BSM is to generate and explore plausible scenarios for the evolution of a biofuels industry in the United States, and as a high-level system model it is not designed for precise, quantitative forecasting. Instead, it is best used to (1) analyze and evaluate alternate policies; (2) generate scenarios; (3) identify high-impact levers and bottlenecks to system evolution; and (4) seed focused discussion among policymakers, analysts, and stakeholders.

Bush, Brian↗

Biofuel Viability for the Ocean-Going Marine Sector

Marine transport contributes significantly to global carbon dioxide emissions but is one of the most difficult sectors to decarbonize because full electrification is infeasible. Renewable, low–carbon biofuels offer a potential path to decarbonization of the marine sectors but the understanding of the effects of new biofuels on engine performance and emissions is limited. In this document we report on the results of a series of studies on the techno-economic, life cycle and technical feasibility of biofuels as replacements for heavy fuel oils currently used to fuel large ocean-going vessels.

09 BIOMASS FUELS↗

Advanced Seal Sessions I and II

As aircraft operators continue to seek higher fuel efficiency, lower emissions, and longer on-wing performance, turbine engine designers are scrutinizing all components for areas of improvement. To achieve overall goals, turbine pressure ratios and by-pass ratios continue to climb. Also, designers are seeking to minimize parasitic and cooling flows to extract the most useful work out of the flow stream, placing a renewed interest on seal technology and secondary flow path management. In the area of future manned spacecraft, advancements are being examined for both habitat seals and re-entry thermal protection system thermal barrierseals. For long duration space craft, designers are continuing to look for savings in parasitic losses to reduce the amount of cabin re-supply air that needs to be brought along. This is placing greater demands on seal designs and materials to exhibit low leakage and be resistant to space environments. For future missions to and from distant planets, the re-entry heating will be higher than for low-earth orbit or lunar return motivating advanced thermal barrier development. This presentation will provide an overview of the seal challenges and opportunities in these diverse areas.

turbine engines↗

Leveraging Real-World Driving Data for Design and Impact Evaluation of Energy Efficient Control Strategies

Modeling and simulation are crucial in the development of advanced energy efficient control strategies. Utilizing real-world driving data as the underlying basis for control design and simulation lends veracity to projected real-world energy savings. Standardized drive cycles are limited in their utility for evaluating advanced driving strategies that utilize connectivity and on-vehicle sensing, primarily because they are typically intended for evaluating emissions and fuel economy under controlled conditions. Real-world driving data, because of its scale, is a useful representation of various road types, driving styles, and driving environments. The scale of real-world data also presents challenges in effectively using it in simulations. A fast and efficient simulation methodology is necessary to handle the large number of simulations performed for design analysis and impact evaluation of control strategies. In this study, two methods are presented of leveraging real-world data in both design optimization of energy efficient control strategies and in evaluating the real-world impact of those control strategies upon large-scale deployment. Through these methodologies, strategies with highest impact on energy savings were selected to be implemented as control algorithms. The developed algorithms were incorporated into a vehicle dynamics and powertrain control architecture implemented on a Cadillac CT6 demonstration vehicle. The control algorithms were then exercised on real-world driving scenarios to determine their impact on collective energy savings. The methodology utilizes the large-scale driving data sets maintained by the National Renewable Energy Laboratory to extract real-world driving scenarios and efficient simulation software tools. The insights obtained through this research help in guiding technology selection for energy efficient driving controls.

ARPA-E↗

The role of current and emerging technologies in meeting Japan’s mid- to long-term carbon reduction goals

Using Japan as a proxy for a developed nation, we investigated the role of existing and nascent technologies in curbing carbon emissions. We simulated possible pathways to meeting 2030 and 2050 emission targets within the Japanese electricity supply sector using a single-region model in The Integrated MARKAL-EFOM System (TIMES). Critically, our simulations incorporate novel technologies like hydrogen electrolysers, carbon capture, photochemical water splitting, and emerging photovoltaic cells, assess long-term impacts up to the year 2100, and include life-cycle emissions and learning curves for parameters such as investment cost, efficiency, and emission coefficients. Results indicate that a hybrid approach, using nuclear power and hydrogen from renewable energy-based electrolysis, is cost-effective and provides long-term emission reduction along with energy security. Finally, nuclear, wind, solar, and hydrogen from renewables emerge as key emission reduction technologies, while natural gas with carbon capture plays a minor role in achieving emission reduction targets.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Critical review and analysis of hydrogen safety data collection tools

The wider adoption of hydrogen in multiple sectors of the economy requires that safety and risk issues be rigorously investigated. Quantitative Risk Assessment (QRA) is an important tool for enabling safe deployment of hydrogen fueling stations and is increasingly embedded in the permitting process. QRA requires reliability data, and currently hydrogen QRA is limited by the lack of hydrogen specific reliability data, thereby hindering the development of necessary safety codes and standards [1]. Four tools have been identified that collect hydrogen system safety data: H2Tools Lessons Learned, Hydrogen Incidents and Accidents Database (HIAD), National Renewable Energy Lab's (NREL) Composite Data Products (CDPs), and the Center for Hydrogen Safety (CHS) Equipment and Component Failure Rate Data Submission Form. This work critically reviews and analyzes these tools for their quality and usability in QRA. It is determined that these tools lay a good foundation, however, the data collected by these tools needs improvement for use in QRA. Areas in which these tools can be improved are highlighted, and can be used to develop a path towards adequate reliability data collection for hydrogen systems.

08 HYDROGEN↗

Producing Performance-Advantaged Bioplastics

A grand challenge for bio-based plastics is the ability to cost-effectively manufacture high-performance polymers directly from renewable resources that are also recyclable-by-design. A one-step conversion of xylose to polyesters has been reported, combining a sustainable lifecycle with impressive materials performance.

biomass feedstock↗

Fleet-wide Electrification Impacts Assessment for the Valley Transportation Authority

This report explores the long-term electrification opportunities for the Valley Transit Authority’s (VTA) transit bus fleet. The potential for transit bus electrification at VTA as well as the economic impacts of partial and complete electrification are explored. We use the Revenue Operation and Device Optimization model to determine the optimal charging, operation and lowest capital and operating cost solution to achieve different levels of electrification to meet their existing routes. This study finds that, relying on only depot charging, around 70% of the daily trips by VTA’s transit bus fleet can be replaced with battery electric buses (BEBs) today. The benefits and drawbacks of five methods for improving the electrification potential beyond that achievable with only depot charging are discussed including (1) increase charger power, (2) purchase of larger vehicle batteries, (3) en-route charging, (4) purchasing additional buses and swapping them to enable the existing routes/blocks1 to be met, and (5) route/block redesign. A strategy is developed to enable full fleet electrification by increasing charger power or allowing intraday charging as a proxy for the options mentioned above. This method allows us to develop an understanding of the impacts and trade-offs of full fleet electrification. Two charging strategies are examined. Immediate charging, when the bus is charged as soon as it arrives at a depot or en-route charging station, and smart charging, which uses a controller to determine the best times to charge to achieve the lowest charging cost, while maintaining the same trip schedules. Smart charging is effective at reducing the peak power consumption, which can be reduced by between 31% and 65% compared to immediate charging. This translates directly to lower electricity demand charges and lower costs for possible distribution system upgrades. The total lifetime net present value (NPV) costs for different scenarios are presented in Figure ES-1. Scenarios are separated into three sections. The first stacked bar on the left is the base case (business-as-usual) where all buses are diesel hybrids, the next four bars include partial and full fleet electrification utilizing only immediate charging, and the last four bars include partial and full fleet electrification utilizing smart charging. The results show that smart charging scenarios are within ±4% of the lifetime NPV cost of the diesel-hybrid only (business-as-usual) scenario. The scenarios with full fleet electrification (i.e., including intraday charging) are 4% lower cost and those with partial fleet electrification (i.e., without intraday charging) are 2%–3% higher. However, it is important to note that the intraday charging scenarios do not include any additional costs for the equipment necessary to achieve intraday charging (e.g., additional chargers, larger batteries, new route design). Additionally, it is worth noting that the Low Carbon Fuel Standard (LCFS) credit received for implementing electric buses is essential to achieving these results.

33 ADVANCED PROPULSION SYSTEMS↗