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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,621 records · Page 90
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Plasma-Assisted Surface Nitridation of Proton Intercalatable WO 3 for Efficient Electrocatalytic Ammonia Synthesis

Electrocatalytic nitrogen reduction (eNRR) offers a green pathway for the production of NH 3 from N 2 and H 2 O under ambient conditions. Transition metal oxynitrides (TMO x N y ) are among the most promising catalysts but face challenges in achieving a high yield and faradaic efficiency (FE). This work develops a hybrid WO x N y /WO 3 catalyst with a unique heterogeneous interfacial complexion (HIC) structure. This design enables in situ generation and delivery of highly active hydrogen atoms (H*) in acidic electrolytes, promoting nitrogen hydrogenation and the formation of nitrogen vacancies (Nv) on the WO x N y surface. This significantly enhances the selectivity of eNRR for NH 3 synthesis while suppressing the hydrogen evolution reaction (HER). A simple two-step fabrication process─microwave hydrothermal growth followed by plasma-assisted surface nitridation─was developed to fabricate the designed catalyst electrode, achieving an NH 3 yield of 3.2 × 10 –10 mol·cm –2 ·s –1 with 40.1% FE, outperforming most TMN/TMO x N y electrocatalysts. Multiple control experiments confirm that the eNRR follows an HIC-enhanced Mars–van Krevelen (MvK) mechanism.

Catalysts↗
DOE OSTI2021

Observations of a plectonemic configuration in a stable magnetized plasma jet

Astrophysical jets are collimated high-speed outflows emerging from spinning and accreting matter around celestial objects and may spontaneously result from self-organized processes. Magnetic self-organization is commonly observed in laboratory plasma physics experiments; however, they require close-fitting flux conservers to constrain and stabilize the toroidal or cylindrical structures. Here we report the first observations of a long, stable, free-boundary plasma jet far from chamber walls, embedding a double-helix magnetic structure resembling a force-free plectonemic Taylor state. The jets arise from an experimental setup that mimics an accretion disk and has no close-fitting solid flux conserver. The results support the hypothesis that self-organization could be a universal, intrinsic explanation for jet formation, collimation, and stability and may help explain double-helix features in celestial observations.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1999

The Onset of Magnetic Reconnection in Tail-Like Equilibria

Magnetic reconnection is a fundamental mode of dynamics in the magnetotail, and is recognized as the basic mechanisms converting stored magnetic energy into kinetic energy of plasma particles. The effects of the reconnection process are well documented by spacecraft observations of plasmoids in the distant magnetotail, or bursty bulk flows, and magnetic field dipolarizations in the near Earth region. Theoretical and numerical analyses have, in recent years, shed new light on the way reconnection operates, and, in particular, which microscopic mechanism supports the dissipative electric field in the associated diffusion region. Despite this progress, however. the question of how magnetic reconnection initiates in a tail-like magnetic field with finite flux threading the current i.sheet remains unanswered. Instead, theoretical studies supported by numerical simulations support the point-of-view that such plasma and current sheets are stable with respect to collisionless tearing mode. In this paper, we will further investigate this conclusion, with emphasis on the question whether it remains valid in plasma sheets with embedded thin current sheets. For this purpose, we perform particle-in-cell simulations of the driven formation of thin current sheets, and their subsequent evolution either to equilibrium or to instability of a tearing-type mode. In the latter case we will pay particular attention to the nature of the electric field contribution which unmagnetizes the electrons.

Hesse, Michael↗
NASA NTRS1992

Mass loading at Titan and comets

Present understanding of the cometary mass loading process (the addition of newborn ions to high speed magnetized plasma flows) is explored and the cometary lesson is applied to the environment of Titan. Mass loading is the dominant physical process controlling the interaction of the solar wind with comets, and it might play an important role in the interaction of Titan's neutral torus and exosphere with Saturn's magnetosphere. Freshly born ions follow cycloidal trajectories, resulting from the superposition of gyration and E/B drift. In the plasma frame, the resulting velocity space distribution is a ring beam distribution at comets and a ring distribution at Titan. This difference in free energy is expected to generate significantly different levels of low frequency broad band electromagnetic turbulence and, thus, result in important differences in the implanted ion distributions. It is predicted that mass loading creates a hot, equatorially trapped plasma population at Titan.

Gombosi, Tamas I.↗
NASA NTRS1994

A detailed examination of a X-line region in the distant tail: ISEE-3 observations of jet flow and B(sub z) reversals and a pair of slow shocks

We report an observation of Petschek-type magnetic reconnection at a distant neutral line (X = -230 R(sub e)) with a full set of signatures of the magnetic merging process. These features include a reversal of plasma flows from earthward to tailward, a pair of slow shocks and the magnetic field X-type line. These two slow shocks are shown to satisfy the shock criteria used by Feldman et al. (1987). The spacecraft first crosses a slow shock to enter the earthward flowing plasmasheet with velocity of about 440 km/s. The embedded magnetic field has a positive B(sub z) component. The spacecraft next enters a region of tailward plasma flow with speed approximately 670 km/s and an embedded negative B(sub z), indicating entry into the plasmasheet tailward of the X-line. These observed velocities are comparable to calculated velocities based on Rankine-Hugoniot conservation relationships. The spacecraft subsequently returns into the south tail lobe by crossing another slow shock. Coplanarity analyses shows that the two slow shocks have orientations consistent with that predicted by the Petschek reconnection model. We note that this event occurs during northward interplanetary magnetic fields. Thus, a magnetic stress built-up in the distant tail may be responsible for this reconnection process.

Ho, C. M.↗
NASA NTRS1991

Data evaluation, analysis, and scientific study

Extensive work was performed in data analysis and modeling of solar active phenomena. The work consisted in the study of UV data from the Ultraviolet Spectrometer and Polarimeter (UVSP) instrument on board the Solar Maximum Mission satellite. These data were studied in conjunction with X-rays from the Hard X-ray Imaging Spectrometer (HXIS) instrument, and with H-alpha and magnetographic data from ground-based observatories. The processes we studied are the active phenomena which result from the interaction of the solar magnetic fields with the plasma in the outer regions of the solar atmosphere. These processes include some very dynamic processes such as the prominence eruptions and the 'microflares'. Our research aimed at characterizing the following: the observed phenomena, the possible physical models, and the relevance to the chromospheric and coronal heating.

Wu, S. T.↗
NASA NTRS2003

Self-Consistent Large-Scale Magnetosphere-Ionosphere Coupling: Computational Aspects and Experiments

Both external and internal phenomena impact the terrestrial magnetosphere. For example, solar wind and particle precipitation effect the distribution of hot plasma in the magnetosphere. Numerous models exist to describe different aspects of magnetosphere characteristics. For example, Tsyganenko has developed a series of models (e.g., [TSYG89]) that describe the magnetic field, and Stern [STER75] and Volland [VOLL73] have developed an analytical model that describes the convection electric field. Over the past several years, NASA colleague Khazanov, working with Fok and others, has developed a large-scale coupled model that tracks particle flow to determine hot ion and electron phase space densities in the magnetosphere. This model utilizes external data such as solar wind densities and velocities and geomagnetic indices (e.g., Kp) to drive computational processes that evaluate magnetic, electric field, and plasma sheet models at any time point. These models are coupled such that energetic ion and electron fluxes are produced, with those fluxes capable of interacting with the electric field model. A diagrammatic representation of the coupled model is shown.

Newman, Timothy S.↗
DOE OSTI2021

Rapid Alloy Surface Engineering through Closed-Vessel Reagent Pyrolysis

For rapid surface engineering of Cr-containing alloys by low-temperature nitrocarburization, we introduce a process based on pyrolysis of solid reagents, e.g., urea, performed in an evacuated closed vessel. Upon heating to temperatures high enough for rapid diffusion of interstitial solute, but low enough to avoid second-phase precipitation, the reagent is pyrolyzed to a gas atmosphere containing molecules that (i) activate the alloy surface by stripping away the passivating Cr 2 O 3 -rich surface film (diffusion barrier) and (ii) rapidly infuse carbon and nitrogen into the alloy. We demonstrate quantitatively that this method can generate a subsurface zone with concentrated carbon and nitrogen comparable to what can be accomplished by established (e.g., gas-phase- or plasma-based) methods, but with significantly reduced processing time. As another important difference to established gas-phase processing, the interaction of gas molecules with the alloy surface can have auto-catalytic effects by altering the gas composition in a way that accelerates solute infusion by providing a high activity of HNCO. The new method lends itself to rapid experimentation with a minimum of laboratory equipment.

36 MATERIALS SCIENCE↗
DOE OSTI2025

High-Power Impulse Magnetron Sputter Deposition of Boron Carbide with Full-Face Erosion Magnetron and Mixed Ar-Ne Plasma

Boron carbide (B 4 C) is an attractive inertial confinement fusion ablator material. The fabrication of B4C ablators by magnetron sputtering requires process optimization. To increase process flexibility, here we explore high-power impulse magnetron sputter (HiPIMS) deposition of B 4 C in pure Ar and mixed Ar-Ne plasmas. Here, the results show that higher plasma discharge currents can be reached with a mixed Ar-Ne plasma in the entire working pressure range studied (5 𝑡𝑜 50 mTorr). At 45 mTorr with 10% of Ne in the Ar-Ne mix, high peak target current densities of ~1 A cm −2 were demonstrated. Films deposited with such a mixed Ar-Ne plasma with a full-face erosion magnetron source on substrates biased at −25 V exhibited higher density and improved mechanical properties, albeit with higher compressive residual stresses compared to the case of HiPIMS deposition in a pure Ar plasma. This work demonstrates additional process flexibility of the HiPIMS discharge mode for the deposition of B 4 C coatings.

Ablator capsule↗
NASA NTRS1985

Nonlinear astrophysical Alfven waves - Onset and outcome of the modulational instability

The nonlinear development of Alfven waves is numerically studied, with applications to Alfven waves in astrophysical plasmas. It is found that amplitude-modulated Alfven wave packets undergo a collapse instability in which the wave packets become more intense and of smaller spatial extent. The wave packet steepening is eventually halted in a process most aptly described as soliton formation. A simple analytic model based on the method of characteristics can account for many of the results of the numerical calculations. The instability probably cannot prevent particle pitch angle isotropization due to self-generated Alfven waves. Nonlinear effects of the collapse may modify the process by which energetic electrons are reaccelerated by plasma turbulence. The model calculations can semiquantitatively account for properties of shock-associated Alfven waves in the solar system.

Spangler, S. R.↗
DOE OSTI2023

Editorial: Using high energy density plasmas for nuclear experiments relevant to nuclear astrophysics

Thermonuclear reaction rates and nuclear processes have traditionally been explored by means of accelerator experiments, which are difficult to execute at conditions relevant to nucleosynthesis. High energy density (HED) plasmas generated using lasers, such as the inertial confinement fusion (ICF) platform, more closely mimic astrophysical environments in several ways, including with thermal distributions of reacting ions as opposed to mono-energetic ions impinging on a cold target; stellar-relevant plasma temperatures and densities; and neutron flux densities not found anywhere else on earth. The most extreme conditions can currently be achieved at the National Ignition Facility (NIF) laser in the US, where densities of 10 3 g/cm 3 and neutron fluxes up to 5∙10 27 neutrons/cm/s have been demonstrated over a time period of a few tens of picoseconds. The HED platform is emerging as an interesting complement to accelerator experiments.

charged-particle-induced reactions↗
NASA NTRS1989

The accretion of interplanetary dust by Ap and Am stars

Accretion of interplanetary dust and comets by A-type stars is investigated to see whether this process can explain the overabundances of heavy elements in Ap and Am stars. The dust particles spiral in by the Poynting-Robertson effect and evaporate above the star. This process is evaluated by considering the evolution of silicate and graphite particles in the radiation field of Alpha Leo (B7 V). It is found that graphite particles evaporate above 20 stellar radii and silicate dust grains above 50 stellar radii. The evaporated atoms will be quickly ionized. In the case of Am stars the ions will wander off and not reach the photosphere, but in the case of Ap stars they can be trapped by the magnetic field of the star and reach the surface. The magnetosphere of a typical Ap star is modeled, and the fate of the ions is studied. The efficiency of accretion from the magnetosphere is sensitive to the presence of any plasma in the magnetosphere. The comet impact process is found capable of producing the abundance anomalies in Ap as well as Am stars, assuming that the comet impact rate is 0.03/yr, nearly the same as in the solar system.

Kumar, C. Krishna↗
DOE OSTI2026

Bayesian optimization of laser wakefield acceleration via spectral pulse shaping

In this paper, we investigate the effect of spectral pulse shaping of the laser driver on the performance of channel-guided, laser–plasma accelerators. The study was carried out with the assistance of Bayesian optimization using particle-in-cell simulations. We used a realistic plasma profile based on a novel optical-field-ionized channel technique with ionization injection and low, on-axis plasma densities to maximize the energy gain of the electron bunch trailing the laser. Spectral shaping allows us to modify the temporal profile of the laser driver while keeping the laser energy constant, affecting the acceleration and injection processes. In addition, we consider how modifying the plasma channel parameters may affect the target outputs. Given the complexity and breadth of the parameter space in question, we used numerical optimization to identify high-performing configurations. In particular, we found laser profiles with additional spectral content that, when used with optimal plasma channel parameters, result in charge content an order of magnitude higher than the baseline Gaussian case while also increasing the mean energy of the electron bunch.

Physics - Plasma physics↗
DOE OSTI2023

A stable atmospheric-pressure plasma for extreme-temperature synthesis

Plasmas can generate ultra-high-temperature reactive environments that can be used for the synthesis and processing of a wide range of materials. However, the limited volume, instability and non-uniformity of plasmas have made it challenging to scalably manufacture bulk, high-temperature materials. Here we present a plasma set-up consisting of a pair of carbon-fibre-tip-enhanced electrodes that enable the generation of a uniform, ultra-high temperature and stable plasma (up to 8,000 K) at atmospheric pressure using a combination of vertically oriented long and short carbon fibres. The long carbon fibres initiate the plasma by micro-spark discharge at a low breakdown voltage, whereas the short carbon fibres coalesce the discharge into a volumetric and stable ultra-high-temperature plasma. As a proof of concept, we used this process to synthesize various extreme materials in seconds, including ultra-high-temperature ceramics (for example, hafnium carbonitride) and refractory metal alloys. Moreover, the carbon-fibre electrodes are highly flexible and can be shaped for various syntheses. In conclusion, this simple and practical plasma technology may help overcome the challenges in high-temperature synthesis and enable large-scale electrified plasma manufacturing powered by renewable electricity.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS2002

Alternative Processing Methods for Ultra High Temperature Ceramics

Ultra High Temperature Ceramics (UHTCs) are being developed for possible use in a number of structural applications including hypersonic vehicles, engines, plasma arc electrodes and high temperature shielding. Alternative methods of processing Ultra High Temperature Ceramics (UHTCs) will be discussed. Techniques that may improve oxidation resistance, strength, and reduce the processing temperature of the UHTCs will be presented. Hot-pressed UHTCs made using either milled/uncoated powders or non-milled coated powders will be compared.

Gusman, Michael↗
DOE OSTI2023

Comprehensive Review of DPF-based Flash Neutron Radiography Viability

MJOLNIR (MegaJOule Neutron Imaging Radiography) is a Dense Plasma Focus (DPF) being developed by LLNL as a prototype to assess the viability of a DPF as a flash neutron radiography source. To date, MJOLNIR has discharged up to 1.3 MJ of stored energy into a deuterium plasma load and achieved yields up to 1.2 × 10 12 neutrons per discharge. The MJOLNIR pulse length already meets the preliminary requirements for flash neutron radiography and we demonstrate in this report plausible paths forward to meet the yield requirement in a deuterium plasma. MJOLNIR’s neutron spot size has been characterized to be a factor of two greater than radiography requirements and presents the greatest challenge. A path forward to sufficiently shrinking spot size is outlined in this report, using a combination of gas dopants and a smaller anode implosion radius. A DPF is a plasma device with coaxial electrodes whose discharge ends with a stagnated hot and dense plasma column on-axis, at the tip of the central anode. Inside the MJOLNIR DPF plasma column, both thermal and beam target processes generate neutrons. To understand the underlying physics of neutron generation inside the DPF, we model the experiment using a combination of kinetic, fluid, and reduced-order models we have been developing for over ten years at LLNL. Our numerical tools are also pivotal to charting the path forward because they allow us to numerically test out which modifications would improve the DPF’s characteristic output.

42 ENGINEERING↗
DOE OSTI2020

Effect of magnetic field ripple on parallel electron transport during microwave plasma heating in the Proto-MPEX linear plasma device

The Prototype Material Plasma Exposure eXperiment (Proto-MPEX) is a linear plasma device located at Oak Ridge National Laboratory to develop the plasma source concept for the Materials Plasma Exposure eXperiment (MPEX). Recent experiments have demonstrated the heating of electrons in a high-density deuterium plasma (n e ~ 5 × 10 19 m -3 ) via electron Bernstein waves and source plasma production via helicon waves in this linear configuration. Moreover, experimental observations suggest that the magnetic ripple adversely affects the parallel transport of the heated electrons toward the target where material samples are to be exposed to the plasma. In order to understand the transport process during microwave application, a test-particle Monte-Carlo (MC) code has been developed that incorporates the effects of Coulomb collisions, magnetic mirror adiabatic trapping and electron cyclotron interaction via a quasilinear RF heating operator. MC calculations indicate that the absence of 2nd turning points along the trajectory of cyclotron heated electrons significantly reduces adiabatic trapping and maximizes power transport to the Target surface. Thermalization of cyclotron heating electrons is analyzed with the MC code and it is found that for conditions relevant to ProtoMPEX, a significant fraction of the absorbed heating power is coupled to the Target surface via ballistic fast electrons; however, under certain conditions, up to 60% of the absorbed RF power can be dissipated via thermalization of the fast electrons on the background plasma. Results are compared with experimental measurements. Finally, the implications of the results are discussed in the context of the upcoming MPEX device.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗