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At least 1,621 records · Page 90

Two-dimensional retrieval methods for ultrafast imaging of molecular structure using laser-induced electron diffraction

Molecular structural retrieval based on electron diffraction has been proposed to determine the atomic positions of molecules with sub-angstrom spatial and femtosecond temporal resolutions. Given its success on small molecular systems, in this work, we point out that the accuracy of structure retrieval is constrained by the availability of a wide range of experimental data in the momentum space in all molecular systems. To mitigate the limitations, for laser-induced electron diffraction, here we retrieve molecular structures using two-dimensional (energy and angle) electron momentum spectra in the laboratory frame for a number of small molecular systems, which have previously been studied with 1D methods. Compared to the conventional single-energy or single-angle analysis, our 2D methods effectively expand the momentum range of the measured data. Besides utilization of the 2D data, two complementary methods are developed for consistency check on the retrieved results. Further, the 2D nature of our methods also offers a way of estimating the error from retrieval, which has never been explored before. Comparing with results from prior experiments, our findings show evidence that our 2D methods outperform the conventional 1D methods. Paving the way to the retrieval of large molecular systems, in which their tunneling ionization rates are challenging to obtain, we estimate the error of using the isotropic model in place of including the orientation-dependent ionization rate.

74 ATOMIC AND MOLECULAR PHYSICS↗

Veridical data science

Building and expanding on principles of statistics, machine learning, and scientific inquiry, we propose the predictability, computability, and stability (PCS) framework for veridical data science. Our framework, composed of both a workflow and documentation, aims to provide responsible, reliable, reproducible, and transparent results across the data science life cycle. The PCS workflow uses predictability as a reality check and considers the importance of computation in data collection/storage and algorithm design. It augments predictability and computability with an overarching stability principle. Stability expands on statistical uncertainty considerations to assess how human judgment calls impact data results through data and model/algorithm perturbations. As part of the PCS workflow, we develop PCS inference procedures, namely PCS perturbation intervals and PCS hypothesis testing, to investigate the stability of data results relative to problem formulation, data cleaning, modeling decisions, and interpretations. We illustrate PCS inference through neuroscience and genomics projects of our own and others. Moreover, we demonstrate its favorable performance over existing methods in terms of receiver operating characteristic (ROC) curves in high-dimensional, sparse linear model simulations, including a wide range of misspecified models. Finally, we propose PCS documentation based on R Markdown or Jupyter Notebook, with publicly available, reproducible codes and narratives to back up human choices made throughout an analysis. The PCS workflow and documentation are demonstrated in a genomics case study available on Zenodo.

97 MATHEMATICS AND COMPUTING↗

The solar neighborhood. XXXII. The hydrogen burning limit

We construct a Hertzsprung-Russell diagram for the stellar/substellar boundary based on a sample of 63 objects ranging in spectral type from M6V to L4. We report newly observed VRI photometry for all 63 objects and new trigonometric parallaxes for 37 objects. The remaining 26 objects have trigonometric parallaxes from the literature. We combine our optical photometry and trigonometric parallaxes with 2MASS and WISE photometry and employ a novel spectral energy distribution fitting algorithm to determine effective temperatures, bolometric luminosities, and radii. Our uncertainties range from ∼20 K to ∼150 K in temperature, ∼0.01 to ∼0.06 in log (L/L {sub ☉}) and ∼3% to ∼10% in radius. We check our methodology by comparing our calculated radii to radii directly measured via long baseline optical interferometry. We find evidence for the local minimum in the radius-temperature and radius-luminosity trends that signals the end of the stellar main sequence and the start of the brown dwarf sequence at T {sub eff} ∼ 2075 K, log (L/L {sub ☉}) ∼ –3.9, and (R/R {sub ☉}) ∼ 0.086. The existence of this local minimum is predicted by evolutionary models, but at temperatures ∼400 K cooler. The minimum radius happens near the locus of 2MASS J0523–1403, an L2.5 dwarf with V – K = 9.42. We make qualitative arguments as to why the effects of the recent revision in solar abundances accounts for the discrepancy between our findings and the evolutionary models. We also report new color-absolute magnitude relations for optical and infrared colors which are useful for estimating photometric distances. We study the optical variability of all 63 targets and find an overall variability fraction of 36{sub −7}{sup +9}% at a threshold of 15 mmag in the I band, which is in agreement with previous studies.

79 ASTRONOMY AND ASTROPHYSICS↗

A contribution to computer analysis of coupled-cavity traveling wave tubes

A flexible accurate large-signal computer program has been developed for the design of coupled-cavity traveling wave tubes. The program is written for a TSS-360 time sharing system. The beam is described by a disk model and the slow wave structure by a sequence of cavities or cells. The computational approach is arranged so that each cavity may have different geometrical or electrical parameters than its neighbors. This allows the program user to simulate a tube of almost arbitrary complexity. Input and output couplers, severs, complicated velocity tapers, and other features peculiar to one or a few cavities may be modeled by a correct choice of input data. The beam-wave interaction is handled by a new approach in which the RF fields are expanded in solutions to the TM wave equation retaining all significant space harmonics. The program was used to perform a design study of the TWT developed for the CTS satellite. Good agreement was obtained between the predictions of the program and the measured performance of the flight tube. The internal check on power balance was satisfied within plus or minus 0.2 per cent of input beam power.

Connolly, D. J.↗

Operating capability and current status of the reactivated NASA Lewis Research Center Hypersonic Tunnel Facility

The NASA Lewis Research Center's Hypersonic Tunnel Facility (HTF) is a free-jet, blowdown propulsion test facility that can simulate up to Mach-7 flight conditions with true air composition. Mach-5, -6, and -7 nozzles, each with a 42 inch exit diameter, are available. Previously obtained calibration data indicate that the test flow uniformity of the HTF is good. The facility, without modifications, can accommodate models approximately 10 feet long. The test gas is heated using a graphite core induction heater that generates a nonvitiated flow. The combination of clean-air, large-scale, and Mach-7 capabilities is unique to the HTF and enables an accurate propulsion performance determination. The reactivation of the HTF, in progress since 1990, includes refurbishing the graphite heater, the steam generation plant, the gaseous oxygen system, and all control systems. All systems were checked out and recertified, and environmental systems were upgraded to meet current standards. The data systems were also upgraded to current standards and a communication link with NASA-wide computers was added. In May 1994, the reactivation was complete, and an integrated systems test was conducted to verify facility operability. This paper describes the reactivation, the facility status, the operating capabilities, and specific applications of the HTF.

Thomas, Scott R.↗

Operating capability and current status of the reactivated NASA Lewis Research Center hypersonic tunnel facility

The NASA Lewis Research Center's Hypersonic Tunnel Facility (HTF) is a free-jet, blowdown propulsion test facility that can simulate up to Mach-7 flight conditions with true air composition. Mach-5, -6, and -7 nozzles, each with a 42-in. exit diameter, are available. Previously obtained calibration data indicate that the test flow uniformity of the HTF is good. The facility, without modifications, can accomodate models approximately 10 ft long. The test gas is heated using a graphite core induction heater that generates a nonvitiated flow. The combination of clean-air, large-scale, and Mach-7 capabilities is unique to the HTF and enables an accurate propulsion performance determination. The reactivation of the HTF, in progress since 1990, includes refurbishing the graphite heater, the steam generation plant, the gaseous oxygen system, and all control systems. All systems were checked out and recertified, and environmental systems were upgraded to meet current standards. The data systems were also upgraded to current standards and a communication link with NASA-wide computers was added. In May 1994, the reactivation was complete, and an integrated systems test was conducted to verify facility operability. This paper describes the reactivation activities, the facility status, the operating capabilities, and specific applications of the HTF.

Thomas, S.↗

Development, Validation, and Potential Enhancements to the Second-Generation Operational Aerosol Product at the National Environmental Satellite, Data, and Information Service of the National Oceanic and Atmospheric Administration

A revised (phase 2) single-channel algorithm for aerosol optical thickness, tau(sup A)(sub SAT), retrieval over oceans from radiances in channel 1 (0.63 microns) of the Advanced Very High Resolution Radiometer (AVHRR) has been implemented at the National Oceanic and Atmospheric Administration's National Environmental Satellite Data and Information Service for the NOAA 14 satellite launched December 30, 1994. It is based on careful validation of its operational predecessor (phase 1 algorithm), implemented for NOAA 14 in 1989. Both algorithms scale the upward satellite radiances in cloud-free conditions to aerosol optical thickness using an updated radiative transfer model of the ocean and atmosphere. Application of the phase 2 algorithm to three matchup Sun-photometer and satellite data sets, one with NOAA 9 in 1988 and two with NOAA 11 in 1989 and 1991, respectively, show systematic error is less than 10%, with a random error of sigma(sub tau) approx. equal 0.04. First results of tau(sup A)(sub SAT) retrievals from NOAA 14 using the phase 2 algorithm, and from checking its internal consistency, are presented. The potential two-channel (phase 3) algorithm for the retrieval of an aerosol size parameter, such as the Junge size distribution exponent, by adding either channel 2 (0.83 microns) from the current AVHRR instrument, or a 1.6-microns channel to be available on the Tropical Rainfall Measurement Mission and the NOAA-KLM satellites by 1997 is under investigation. The possibility of using this additional information in the retrieval of a more accurate estimate of aerosol optical thickness is being explored.

Stowe, Larry L.↗

Studies of Dust Emission as Measured by DIRBE and IRAS

The main activity supported by this grant was to make the dust reddening map more useful for optical and microwave astronomy, and to increase our understanding of interstellar dust in general. We completed all the major objectives of the proposal, and we are eagerly awaiting the launch of Space Infrared Telescope Facility (SIRTF) so that we can check one of our most controversial conclusions. According to the ADS abstract service, the above paper has been cited 895 times. A number of authors have claimed the SFD98 dust maps are miscalibrated, but recent work suggests that the calibration is correct. The primary goal of this ADP grant was to determine the microwave / sum-mm spectrum of interstellar dust emission by cross-correlating the Far Infrared Absolute Spectrophotometer (FIRAS) spectra with a model based on the SFD98 dust map. Because of temperature variation, large (factor of two) variations are observed in submillimeter / 100 micron ratio, so a careful accounting of dust temperature data, based on Diffuse Infrared Background Experiment (DIRBE) 100 and 240 micron channels, was required. Even this improvement was unable to reduce the chi(sup 2) per degree of freedom below 30. Further study revealed that a two-component model, with the two components having different (but reasonable) optical properties, achieved a decrease in chi(sup 2) to less than 2, five times better than the next best fit in the literature. The resulting model uses density and temperature estimates based on DIRBE data, with only four global parameters fit using the FIRAS data. This dramatic reduction in chi(sup 2) using only four fit parameters may indicate that the model is physically correct, but in any case, it is an acceptable phenomenological model. We have released the appropriate data and software on our website (http://astro.berkeley.edu/dust) to allow users to compute the interstellar dust emission between from 100-3000 GHz (or 100 micron 3 mm) with approx. 15% precision. The paper describing these efforts appeared in ApJ 524, 867. This paper has to date been cited 24 times.

Davis, Marc↗

Phase change alloy viscosities down to T{sub g} using Adam-Gibbs-equation fittings to excess entropy data: A fragile-to-strong transition

A striking anomaly in the viscosity of Te{sub 85}Ge{sub 15} alloys noted by Greer and coworkers from the work of Neumann et al. is reminiscent of the equally striking comparison of liquid tellurium and water anomalies documented long ago by Kanno et al. In view of the power laws that are used to fit the data on water, we analyze the data on Te{sub 85}Ge{sub 15} using the Speedy-Angell power-law form, and find a good account with a singularity T{sub s} only 25 K below the eutectic temperature. However, the heat capacity data in this case are not diverging, but instead exhibit a sharp maximum like that observed in fast cooling in the Molinero-Moore model of water. Applying the Adam-Gibbs viscosity equation to these calorimetric data, we find that there must be a fragile-to-strong liquid transition at the heat capacity peak temperature, and then predict the 'strong' liquid course of the viscosity down to T{sub g} at 406 K (403.6 K at 20 K min{sup −1} in this study). Since crystallization can be avoided by moderately fast cooling in this case, we can check the validity of the extrapolation by making a direct measurement of fragility at T{sub g}, using differential scanning calorimetric techniques, and then comparing with the value from the extrapolated viscosity at T{sub g}. The agreement is encouraging, and prompts discussion of relations between water and phase change alloy anomalies.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Dark Energy Survey Year 3 results: Cosmology with moments of weak lensing mass maps

We present a cosmological analysis using the second and third moments of the weak lensing mass (convergence) maps from the first three years of data (Y3) data of the Dark Energy Survey. The survey spans an effective area of 4139 square degrees and uses the images of over 100 million galaxies to reconstruct the convergence field. The second moment of the convergence as a function of smoothing scale contains information similar to standard shear 2-point statistics. The third moment, or the skewness, contains additional non-Gaussian information. The data is analyzed in the context of the Λ CDM model, varying five cosmological parameters and 19 nuisance parameters modeling astrophysical and measurement systematics. Our modeling of the observables is completely analytical, and has been tested with simulations in our previous methodology study. We obtain a 1.7% measurement of the amplitude of fluctuations parameter S 8 ≡ σ 8 ( Ω m / 0.3 ) 0.5 = 0.784 ± 0.013 . The measurements are shown to be internally consistent across redshift bins, angular scales, and between second and third moments. In particular, the measured third moment is consistent with the expectation of gravitational clustering under the Λ CDM model. The addition of the third moment improves the constraints on S 8 and Ω m by ∼ 15 % and ∼ 25 % compared to an analysis that only uses second moments. We compare our results with Planck constraints from the cosmic microwave background, finding a 2.2 – 2.8 σ tension in the full parameter space, depending on the combination of moments considered. The third moment, independently, is in 2.8 σ tension with Planck, and thus provides a cross-check on the analyses of 2-point correlations.

79 ASTRONOMY AND ASTROPHYSICS↗

A magnetic bubble domain flight recorder

A feasibility model of an all-electronic bubble memory system has been constructed. It uses a small 60k bit bubble recorder consisting of 6 chips of 10k bits each mounted in three separate packages operating as a FIFO at a 150 KHz bubble data rate. In addition to serving as a direct tape recorder replacement, the bubble recorder can be programmed for random access to each individual chip for ranom block access operation or for self-checking or by-passing any malfunctioning memory chip. Read and write operations can be performed asynchronously from very low frequency up to basic recording field frequency. A large 50M bit prototype is planned.

Chen, T. T.↗

A finite element model with nonviscous damping

A constitutive law by which structural damping is modeled as a relationship between stress, strain, and strain rate in a material is used in conjunction with the finite element method to develop general integral expressions for viscous and nonviscous damping matrices. To solve the set of nonlinear equations resulting from the presence of nonviscous damping, a solution technique is developed by modifying the Newmark method to accommodate an iterative solution and treat the nonviscous damping as a pseudo-force. The technique is then checked for accuracy and convergence in single- and multi-degree-of-freedom problems, and is found to be accurate and efficient for initial-condition problems with small nonviscous damping.

Roussos, L. A.↗

Design and Principles Enabling the Space Reference FOM

A first complete draft of the Simulation Interoperability Standards Organization (SISO) Space Reference Federation Object Model (FOM) has now been produced. This paper provides some insights into its capabilities and discusses the opportunity for reuse in other domains. The focus of this first version of the standard is execution control, time management and coordinate systems, well-known reference frames, as well as some basic support for physical entities. The biggest part of the execution control is the coordinated start-up process. This process contains a number of steps, including checking of required federates, handling of early versus late joiners, sharing of federation wide configuration data and multi-phase initialization. An additional part of Execution Control is the coordinated and synchronized transition between Run mode, Freeze mode and Shutdown. For time management, several time lines are defined, including real-time, scenario time, High Level Architecture (HLA) logical time and physical time. A strategy for mixing simulations that use different time steps is introduced, as well as an approach for finding common boundaries for fully synchronized freeze. For describing spatial information, a mechanism with a set of reference frames is specified. Each reference frame has a position and orientation related to a parent reference frame. This makes it possible for federates to perform calculations in reference frames that are convenient to them. An operation on the Moon can be performed using lunar coordinates whereas an operation on Earth can be performed using Earth coordinates. At the same time, coordinates in one reference frame have an unambiguous relationship to a coordinate in another reference frame. While the Space Reference FOM is originally being developed for Space operations, the authors believe that many parts of it can be reused for any simulation that has a focus on physical processes with one or more coordinate systems, and require high fidelity and repeatability.

Moeller, Bjoern↗

Statistical Approach on Utilizing Ground-based Experiments to Model Break-up Events

Two laboratory-based impact tests have been conducted to develop and extend the capability of NASA satellite breakup models. The first experiment, the Satellite Orbital Debris Characterization Impact Test (SOCIT), was conducted by the U.S. Department of Defense and NASA in 1992. It employed a fully functional U.S. Navy Transit spacecraft, fabricated from materials commonly used in the 1960s. SOCIT fragmentation data formed the basis of the current NASA Standard Satellite Breakup Model (SSBM). A second experiment, DebriSat, was conducted in 2014 by the DebriSat consortium: the NASA Orbital Debris Program Office; the United States Space Force Space Systems Command, formerly the Air Force Space and Missile Systems Center, the Air Force Arnold Engineering Development Complex, and the University of Florida. This impact test was performed on a high-fidelity mock-up satellite assembled from modern components. Data from both experiments are expected to contribute to the next-generation models for on-orbit breakup analyses, long-term environment predictions, and debris risk assessment. This paper uses the direct statistical sampling of the SOCIT and DebriSat data ensembles to model an on-orbit breakup event, rather than the analytic expressions estimated from the samples as with as with the NASA SSBM and its predecessor. This direct method involves drawing fragments (i.e., sampling with replacement) from each fragmentation data-subset containing mass, shape category, material density, characteristic length, mass, and cross-sectional area. As part of the sampling process, the properties of sampled fragment data (e.g., area-to-mass ratios) are numerically checked to ensure they do not contain unrealistic quantities. The process to simulate a breakup cloud composed of fragments from SOCIT and DebriSat datasets is discussed. The methodology for ensuring that conservation of overall mass of the sampled fragment cloud under this sampling approach is highlighted. Finally, the results are compared with simulated clouds generated from SSBM for specific historical breakup events.

Andrew Vavrin↗

Hadronic contributions to (g - 2) µ

The Muon g-2 Experiment at Fermilab, which recently started running, plans to reduce the uncertain- ties on the already very precisely measured anomalous magnetic moment of the muon by a factor of four. The goal of this effort is to probe the observed difference of more than three standard deviations between Standard-Model theory and experiment, one of the few persistent hints for physics beyond the Standard Model. The Fermilab experiment collected data from their first run last year with statistics comparable to BNL E821. They expect to release the measurement result in 2019. On the theoretical side, because the muon g - 2 arises from quantum- mechanical loop contributions in the Standard Model, it is sensitive to virtual effects of new particles, and places important constraints on Standard-Model extensions. To leverage the anticipated reduction in experimental errors, and determine unambiguously whether or not new-physics effects contribute to this quantity, the theoretical errors must be made more reliable and reduced to a commensurate precision. The Muon g-2 Theory Initiative was created to facilitate this development. The dominant sources of uncertainty in the Standard-Model prediction of the muon g -2 are from the hadronic contributions. The hadronic vacuum polarization (HVP) provides the leading correction followed by hadronic light-by-light (HLbL) scattering. There are a number of complementary theoretical efforts underway to better understand and quantify these contributions, including dispersive and data driven methods, lattice QCD, and effective field theories. Given the precision goals and the phenomenological importance, it is important to have more than one independent method for each of the two hadronic corrections, each with fully quantified uncertainties. Fostering the development of such methods is a prime goal of the initiative, as this will enable critical cross checks, and, upon combination, may yield gains in precision, to maximize the impact of E989. An important aspect of the Muon g-2 Theory Initiative’s activities are providing platforms that facilitate interactions between the different groups, as well as between the theoretical and experimental g - 2 communities. To this end, several workshops were organized in 2017 and 2018. The first meeting, held at Fermilab (June 3–6, 2017, St. Charles, IL, USA), served to kick-off the Initiative’s activities. Two meetings in early 2018 were focused respectively on the HVP and HLbL corrections. The HVP meeting was held at KEK (February 12–14, 2018, Tsukuba, Japan) and the HLbL meeting at the University of Connecticut (March 12–14, 2018, Storrs, CT, USA). The most recent workshop, which served as the second plenary meeting of the Initiative, was held at the University of Mainz (June 18–22, 2018, Mainz, Germany). An important outcome of these meetings are concrete plans for a first white paper, which is currently being written. We aim to post the white paper just prior to the release of the first E989 measurement, to present a clean theoretical prediction. The first white paper is focused on assessing and improving the reliability of the SM prediction. The purpose of the INT workshop in September 2019 is to start the next stage of the Initiative, focusing on the development of strategies to improve the theory uncertainties beyond the current level towards the E989 precision goal. We aim to accelerate theoretical developments on the hadronic contributions to the muon g - 2 so that the Standard-Model theory error can be brought to the needed precision, again in advance of the next release from E989. Hence the workshop will provide crucial theory support for a US experiment with broad impact. The Muon g-2 Theory Initiative relies on input from representatives of all the different communities that are engaged in this effort. It is therefore important that all these areas are properly represented. The funds from this grant will be used to enable more people, especially early-career scientists, to participate and make essential contributions to the workshop discussions. Since the workshop’s main goal is to kick-off the next stage of the theory initiative’s activities, support for this workshop from the DOE will help the theory community provide crucial theoretical support to the Fermilab Muon g-2 Experiment.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

An asynchronous traversal engine for graph-based rich metadata management

Rich metadata in high-performance computing (HPC) systems contains extended information about users, jobs, data files, and their relationships. Property graphs are a promising data model to represent heterogeneous rich metadata flexibly. Specifically, a property graph can use vertices to represent different entities and edges to record the relationships between vertices with unique annotations. The high-volume HPC use case, with millions of entities and relationships, naturally requires an out-of-core distributed property graph database, which must support live updates (to ingest production information in real time), low-latency point queries (for frequent metadata operations such as permission checking), and large-scale traversals (for provenance data mining). Among these needs, large-scale property graph traversals are particularly challenging for distributed graph storage systems. Most existing graph systems implement a "level synchronous" breadth-first search algorithm that relies on global synchronization in each traversal step. This performs well in many problem domains; but a rich metadata management system is characterized by imbalanced graphs, long traversal lengths, and concurrent workloads, each of which has the potential to introduce or exacerbate stragglers (i.e., abnormally slow steps or servers in a graph traversal) that lead to low overall throughput for synchronous traversal algorithms. Previous research indicated that the straggler problem can be mitigated by using asynchronous traversal algorithms, and many graph-processing frameworks have successfully demonstrated this approach. Such systems require the graph to be loaded into a separate batch-processing framework instead of being iteratively accessed, however. In this work, we investigate a general asynchronous graph traversal engine that can operate atop a rich metadata graph in its native format. We outline a traversal-aware query language and key optimizations (traversal-affiliate caching and execution merging) necessary for efficient performance. We further explore the effect of different graph partitioning strategies on the traversal performance for both synchronous and asynchronous traversal engines. Our experiments show that the asynchronous graph traversal engine is more efficient than its synchronous counterpart in the case of HPC rich metadata processing, where more servers are involved and larger traversals are needed. Furthermore, the asynchronous traversal engine is more adaptive to different graph partitioning strategies.

96 KNOWLEDGE MANAGEMENT AND PRESERVATION↗

Towards the development of high temperature comparison artifacts for radiation thermometry

This paper describes the methodology and first results of the development of high temperature fixed point artifacts of unknown temperature suitable for scale comparison purposes. This study is being undertaken at the Thermal Metrology Division of Inmetro, Brazil, as part of PhD studies. In this initial phase of the study two identical cobalt carbon eutectic cells were constructed and one doped with a known amount of copper. This was an attempt to achieve a controlled change in the transition temperature of the alloy during melting. Copper was chosen due to the relatively simple phase diagram it forms with carbon and cobalt. The cobalt, in powder form, was supplied by Alfa Aesar at 99.998 % purity, and was mixed with carbon powder (1,9 % by weight) of 99.9999 % purity. Complete filling of the crucible took 6 steps and was performed in a vertical furnace with graphite heating elements, in an inert gas atmosphere. The temperature measurements were performed using a KE LP3 radiation thermometer, which was previously evaluated for spectral responsivity, linearity and size-of-source effect (SSE). During these measurements, the thermometer stability was periodically checked using a silver fixed point blackbody maintained in a three zone furnace. The main purpose of the first part of this study is to dope a series of Co-C blackbody with differing amounts of copper, in order to alter their temperatures whilst still retaining good melting plateau performance. The long-term stability of the adjusted transition temperatures will also be investigated. Other dopants will be studied as the research progresses, and thermo chemical modeling will be performed in an attempt to understand the change in temperature with dopant concentration and so help select suitable dopants in the future. The overall objective is to construct comparison artifacts that have good performance, in terms of plateau shape and long-term temperature stability, but with unknown temperatures. These can then be used as comparison artifacts with no participant, except the pilot, knowing the temperature a priori.

36 MATERIALS SCIENCE↗

Comparison of structural and magnetic properties of Zn{sub x}Mg{sub 1.5-x}Mn{sub 0.5}FeO{sub 4} and MgAl{sub x}Cr{sub x}Fe{sub 2-2x}O{sub 4} spinel oxides

The spinel oxides Zn{sub x}Mg{sub 1.5-x}Mn{sub 0.5}FeO{sub 4} (x = 0.0 to 0.6) and MgAl{sub x}Cr{sub x}Fe{sub 2-2x}O{sub 4} (x = 0.0 to 0.6) abbreviated as ZMMFO and MACFO respectively, were synthesized by standard ceramic processing. The compositional purity of all the specimens was checked by EDAX technique. The X-ray diffractometry was employed to determine the lattice constants and distribution of cations in the interstitial voids. The initial decrease of cell edge parameter (a) for ZMMFO up to x = 0.2 and thereafter expected rise in the ‘a’ and the initial slower rate of reduction in the lattice constant for MACFO are explained as basic of cation occupancy. The magnetic ordering in both systems is explained by invoking statistical canting models. The compositional variation of magneton number (n{sub B}) for ZMMFO could be very well explained by Localized canting of spin (LCS) model while Random canting of spin (RCS) model was used for MACFO system.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗