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At least 1,621 records · Page 90
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NASA NTRS1980

A model for gas phase chemistry in interstellar clouds. II - Nonequilibrium effects and effects of temperature and activation energies

The chemical evolution of diffuse and dense interstellar clouds is examined via the time-dependent model outlined by Prasad and Huntress (1980). This paper presents specific results for CH, CO, CH4, O2, CH2O, CN, C2, C2H, HC3N, and NH3. Comparison with observations and predictions of other contemporary models show that cloud temperature plays a very important role through the inverse temperature dependence of radiative association reactions and through activation energies in neutral reactions and selected ion-molecule reactions. The observed fractional abundance of CN with respect to H2 and more accurate recent laboratory data on CN + O and CN + O2 reactions suggest that there is an unidentified, yet efficient, mechanism for conversion of O and O2 into polyatomic species. C2H and HC3N are synthesized early in the history of dense clouds. The value of the fractional abundance of C2H remains high, because as the cloud cools down the activation energy in the C2H + O reaction closes down this most important loss channel. A rapidly decreasing fractional abundance of O with time can also accomplish the same result. The value of the fractional abundance of HC3N remains high because it is an unreactive molecule and probably does not condense readily onto grains.

Prasad, S. S.↗
NASA NTRS1980

Carbynes in meteorites - Detection, low-temperature origin, and implications for interstellar molecules

The presence, origin and implications of carbynes in meteorites are investigated. A sample of the Allende meteorite was pyrolyzed at temperatures from 25 to 750 C and examined by solid probe time-of-flight mass spectrometry and high-resolution mass spectrometry. Fragments released upon heating at 250 to 330 C are found to be composed of macromolecules containing triply bonded carbon units and cyanoacetylenes, as well as some methyl- and phenylacetylenes. Although carbynes are well known to form from the condensation of carbon vapors above 2600 K or by shock greater than 600 kbar, which would be unlikely in Allende, it is found that carbynes rather than graphite are formed metastably by the disproportionation of CO at low temperatures when chromite is present as a catalyst. Results imply that metastable formation mechanisms may be the principal source of interstellar polycyanoacetylenes and meteoritic and terrestrial carbynes.

Hayatsu, R.↗
NASA NTRS1980

Far-ultraviolet studies. VII - The spectrum and latitude dependence of the local interstellar radiation field

A direct measurement has been made of the spectrum (1180-1680 A) and Gould-latitude dependence of the local interstellar radiation field, over about one-third of the sky. The result is corrected to give expected values for the entire sky. The average local 1180-1680 A energy density is 5.8 x 10 to the -17th ergs/cu cm A. The surface brightness falls off toward high latitudes much more steeply than published models predict.

Henry, R. C.↗
NASA NTRS1980

Supernova radio remnants and the filling factor of the hot interstellar medium

If a hot (temperature of about one-million K), tenuous gas fills about 90% of interstellar space, then the observed number and surface brightness distribution of galactic radio remnants implies a galactic supernova rate of once about every 30 years. This is consistent with estimates based on observations of historical supernovae, pulsars, and supernovae in other spiral galaxies.

Higdon, J. C.↗
NASA NTRS1981

Interstellar abundance determination using IUE data

Analysis of the silicon interstellar abundances was made for more heavily reddened lines of sight than were accessible to the Copernicus satellite. Silicon rarely had accurate column densities determined from Copernicus data because the available lines all lie on the flat portion of the curve of growth. With International Ultraviolet Explorer (IUE) it is possible to reach color excesses of E(B-V) approximately 0.5-0.7, and in addition obtain data on the weak SiII line at 1808 A, so that a wide range of oscillator strengths is available. The lower resolving power of the IUE causes difficulties in that several of the SiII lines are blended with strong lines of other species. Data on the lines of sight analyzed suggested that some of the absorption lines fall on the damped portion of the curve of growth, implying that silicon may not be as highly depleted as expected.

Joseph, C. L.↗
NASA NTRS1981

A search for interstellar molecules in the spectra of highly reddened stars

A total of ten stars were observed with cameras of the International Ultraviolet Explorer (IUE) in both high and low dispersion. One star, X Persei (HD 24534, 6.0 BE), was analyzed in detail. Ultraviolet observations of the column densities of CO match those derived from the radio to within a factor of 4, with the difference probably due to the larger beam size of the radio measurement and the assumption of a thermal population in the rotational levels of CO. Upper limits are given to the log column densities for OH, HCl, and CH2 of 14.0, 12.3 and 12.8. The carbon abundance was found to be about solar with a possible depletion of about a factor of 2. With precautions concerning both noise and correct background, the IUE can be used for studies of interstellar molecules.

Lien, D.↗
NASA NTRS1980

A radio search for interstellar phosphorus compounds

The J = 1-0 and 3-2 transitions of phosphorus nitride, PN, with resolvable hyperfine components at 46.99 GHz and blended components at 140.97 GHz, and transitions of phosphine, PH3, at 47.39 and 46.94 GHz, arising from a small induced dipole moment, have been searched for but not found in interstellar molecular clouds. The J = 3/2-1/2, F - 3/2-3/2 transition of nitric oxide, NO, and the J(K-K+) = 16(4, 12) -15(5, 11) transition of sulfur dioxide, SO2, have been detected in Orion and Sagittarius B2. An unidentified emission line, U140921.8 MHz, has been observed in IRC + 10216.

Hollis, J. M.↗
NASA NTRS1980

The interstellar material in front of Chi Ophiuchus. II - Ultraviolet observations

The high-resolution UV spectrometer aboard the Copernicus satellite was used to observe the interstellar gas toward the moderately reddened star Chi Oph. The data are consistent with the hypothesis that the material in both the -6 and -12 km/s blend of gas and the -26 km/s cloud could have been affected by shock front activity, though the signatures of that activity are different in each case. These observations of the blend of gas establish that both low and high density neutral material must be present.

Frisch, P. C.↗
NASA NTRS1980

Abundance determinations for interstellar gas

The results of general abundance studies, using the Copernicus satellite are reviewed. The general pattern of depletion of some elements such as Si, Al, Mn, Fe, and Mg, near the sun is described. Techniques for obtaining abundances for various species are discussed, as are the aspects of the analysis which are uncertain. Variations in gas phase abundance from region to region are found for Fe and Si, similar to variations now known to exist for Ca and Ti based on visible spectra. A new generation of space instruments, with higher efficiency and resolution, in particular for 920-1400 A, can provide detailed interstellar line profiles.

York, D. G.↗
NASA NTRS1980

The abundance of CO in diffuse interstellar clouds - An ultraviolet survey

CO was detected in 17 directions and its upper limits were estimated in 21 directions by a UV survey carried out with the Copernicus satellite in the C-X 1088 A and E-X 1076 A lines toward 48 bright stars. The CO column densities range from 10 to the 12th to 10 to the 17th/sq cm and correlate with C I and H2. The tendency of the C I/CO ratio to be about 10 follows the ratio of particular atomic and molecular cross-sections and the physical parameters of interstellar clouds. Finally, the connection between UV observations in diffuse clouds and radio observations of (C-13)O in dark clouds is discussed.

Federman, S. R.↗
NASA NTRS1980

Comparisons of interstellar CH/+/ and H2

Copernicus observations of H2 toward stars in the Pleiades and 23 Orionis have been obtained because of their importance in understanding the formation of interstellar CH(+). No model of CH(+) equilibrium seems to agree very well with these observations; in particular, the suggestions that CH(+) is formed either from collisions between vibrationally excited H2 and C(+) or from radiative association of C(+) and H2 can apparently be excluded. These data do suggest that there is a correlation between the amounts of rotationally excited H2 and CH(+) which are present. Observations of the Pleiades also help interpretations of the reflection nebulae near these stars.

Frisch, P. C.↗
NASA NTRS1981

Submillimeter heterodyne detection of interstellar carbon monoxide at 434 micrometers

Laser heterodyne observations of submillimeter emissions from carbon monoxide in the Orion molecular cloud are reported. High frequency and spatial resolution observations were made at the NASA Infrared Telescope Facility on Mauna Kea by the use of an optically pumped laser local oscillator and quasi-optical Schottky diode mixer for heterodyne detection of the J = 6 - 5 rotational transition of CO at 434 microns. Spectral analysis of the 434-micron emission indicates that the emitting gas is optically thin and is at a temperature above 180 K. Results thus demonstrate the potential contributions of ground-based high-resolution submillimeter astronomy to the study of active regions in interstellar molecular clouds.

Fetterman, H. R.↗
NASA NTRS1981

Ultraviolet absorption by interstellar gas at large distances from the galactic plane

Eighteen high-dispersion IUE spectra of six stars in the Large Magellanic Cloud, three stars in the Small Magellanic Cloud, and two foreground stars were analyzed. Fourteen spectra cover the wavelengths 1150-2000 A, and four cover 1900-3200 A; the velocity resolution is about 25 km/s. All the Magellanic Cloud spectra exhibit very strong interstellar absorption lines due to a wide range of ionization stages at galactic velocities and at velocities associated with the IMC or SMC. The observational results are related to current theoretical ideas about the origin and physical state of gaseous galactic halos; the analysis is restricted to the Milky Way absorption features.

Savage, B. D.↗
NASA NTRS1981

Interstellar C2 molecules toward Omicron Persei

Seven weak interstellar absorption lines of the (2-0) Phillips band of C2 near the wavelength 8760 are detected in the spectrum of Omicron Persei. All of the lines have equivalent widths less than 2 mA and originate from the five lowest rotational levels of C2. The resulting total column density is N(C2) = 1.5 x 10 to the 13th/sq cm, and the excitation temperature is T = 116 plus or minus 16 K.

Hobbs, L. M.↗
NASA NTRS1980

Optical observations of interstellar molecules

Recent observational data are summarized on molecular species in diffuse interstellar clouds, and a comprehensive list of all species detected or sought is included. The discussion is focussed on the use of molecular observations to determine physical conditions in clouds, and on important species which provide constraints on cloud chemistry models. Directions for new research are suggested, including intensive work on the unidentified diffuse bands, which may have a molecular origin.

Snow, T. P., Jr.↗
NASA NTRS1980

Interstellar sulfur chemistry

The results of a chemical model of SO, CS, and OCS chemistry in dense clouds are summarized. The results are obtained from a theoretical study of sulfur chemistry in dense interstellar clouds using a large-scale time-dependent model of gas-phase chemistry. Among the results are the following: (1) owing to activation energy, the reaction of CS with O atoms is efficient as a loss mechanism of CS during the early phases of cloud evolution or in hot and oxygen-rich sources such as the KL nebula; (2) if sulfur is not abnormally depleted in dense clouds, then the observed abundances of SO, SO2, H2S, CS, OCS, H2CS, and SiS indicate that sulfur is mostly atomic in dense clouds; and (3) OCS is stable against reactions with neutral atoms and radicals in dense clouds.

Prasad, S. S.↗